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KEY SHEET
PHYSICS
1 4 2 2 3 1 4 3 5 2
6 4 7 3 8 1 9 3 10 1
11 2 12 1 13 3 14 4 15 3
16 2 17 4 18 3 19 2 20 4
21 5 22 5 23 275 24 40 25 60
26 2 27 75 28 3 29 2 30 1
CHEMISTRY
31 2 32 1 33 2 34 1 35 3
36 2 37 1 38 4 39 1 40 2
41 2 42 3 43 2 44 1 45 3
46 2 47 4 48 4 49 2 50 3
51 8 52 2 53 4 54 4 55 3
56 2 57 3 58 3 59 1 60 7
MATHEMATICS
61 3 62 1 63 2 64 1 65 2
66 1 67 4 68 3 69 2 70 3
71 1 72 3 73 3 74 3 75 4
76 4 77 2 78 3 79 4 80 1
81 0 82 1 83 3 84 2 85 1
86 1 87 3 88 2 89 1 90 1
SOLUTIONS
PHYSICS
1. ITotal IRemaining +IRe moved Iremaining I total -IRemoved
2
m0 R
2
4 2 m0 R 13
I removed I remaining MR 2
2 4 2 24
2. 1
Mass = Volume x density m r t m r d r
2 2 2
d
I1 d 2
I mr 2 r 4 d
I 2 d1
3.
m 2L
2
mL2 mL2
I Torque, I
12 3 3 t
7.
F2 F1
a
m
5 F1
2 F1 3N Sum of moments about C.M is zero
1
F1 a x F2 x 3 0.2 x 5 x x 0.3 length of rod is
L 2 a x 1m
8. Conceptual
9.
g sin 2l K 2
a time taken to reach the bottom is, t 1 2
K2 g sin R
1 2
R
K2 3 K2 3 K2 7
for disc, 2 for solid cylinder, for solid sphere , 2
R 2 R2 2 R 5
10. 2 gL sin K2 2
V for hollow sphere, V 6 m / sec
K2 R2 3
1 2
R
11. As sphere rolls, the lowest point of the sphere should have the same acceleration as
the plankHence, a1 k a2 2 2 4 3 rad / sec
2
12. 90 1
VP 2V sin VP 2V sin
2V 2V
2 2 2
120 3 180
VP 2V sin 2V 3 V VP 2V sin 2V
2 2 2
13.
3 2 mr 2 3 2 3 2 mr 2
I I1 I 2 I3 I I 2 mr I 3 I mr mr
2 2 2 2 2
7 2
mr
2
14. l ml 2
P
4 12
15. I I C mx 2
16.
ML2
from parallel axis theorem I1
12
2
ML2 3L 11ML2
I 2 I1 Mx =
2
M =
12 2 2 24
17.
20. Ma 2mg
mg T ma I rT T a
2 M 2m
21. 2
ml2
3l
Applying parallel axes theorem I I C Md m
2
12 2
5
I ml 2 For ‘6’ Rods total M.I. is = 5ml 2
6
22. 2 7 16 MR 2
I MR 2 MR
2 2
I 3.2 MR 2
5 5 5
23. From Law of conservation of angular momentum I 22 I11 I1 I 2
2 275 f 275
24. 2 2
From (L.O.C. A.M) I11 I 22 I1 MR I 2 MR
2 2
5 3
3w1 5w2 T2 8 5 40 hrs
SEC: Jr.C-IPL Page 4
Sri Chaitanya IIT Academy, India 22-10-2022_Jr.C-IPL_Jee-Main_WTM-12_Key & Sol’s
25. 1 2
mv
K .ET 2 1
100 100 100
K .Ttotal 1 2 K2 1
2
mv 1 2
2 R 3
3
100 60
5
26.
l l ml 2 3g
mg sin 45 I mg
2 2 2 3 2 2l
27.
4F 4 4 4
N mg N mg F
5 5 5 5
4mg 4 F 3f 3
f ......(1) f mg ......(2)
5 5 5 5
from rotational equilibrium, f r F r f F ….(3)
3 75
Solving equation (1) , (3) or
4 100
28. The tendency of rotating will be about point c. For minimum force, the torque of F
about C has to be equal to the to the torque of mg about C.
3 a mg
F a mg F
2 2 3
29. Conceptual
30.
Torque
u 2 sin 2
R 1
F r mg mg 1 mu 2 sin 2
2 2 g 2
SEC: Jr.C-IPL Page 5
Sri Chaitanya IIT Academy, India 22-10-2022_Jr.C-IPL_Jee-Main_WTM-12_Key & Sol’s
CHEMISTRY
31. Low pressure and high temperature
32. Losser the rate of diffusion under similar condition so that number of moles of So2
is least diffused than CH 4 and than H 2
33. PM P
d So, more is the value of more is the density
RT T
34. Conceptual
35. From the given equation P 2 V RT
PV a
Compressibility factor Z
RT V
a
RT
a a PV v 1 a
PV RT PV RT Z
V V RT RT RTV
36. PM PNe M Ne P M
Density of a gas is given by d d Ne d Ar Ar Ar
RT RTNe RTAr
d Ne PNe M NeTAr 1 PNe 20 2 PNe 1
d Ar PAr M ArTNe 2 PAr 40 1 PAr 2
37. 1 rHe M CH4 Number of moles diffuse
r rate
M rCH M He t
4
2 K .ECH nCH 4 4 1
4
16 4
40. N2 :n = x molesT = 273 KP = 1 atmV = 10 lit PV nRT
PV 110 lit 10
n 1 1
0.446 moles = x
RT 0.0821 lit atm mol K 273 K 22.4
CH 4 : n 2 x 2 0.446 0.88 moles T 2730 C 273 546K
nRT 0.88 moles 0.0821 lit mol 1 atm k 1 546 K
V = 26.6 lit.
P 1.5 atm
41. 3RT 3PV 3P
ur .m. s .
M M d
42. Conceptual
43. 2 RT RT 1 3RT RT 1
m. p. 1 km / sec r .m. s . 3. 3. 1.224 Km / sec
M M 2 M M 2
44. Conceptual
45. Conceptual
46. Conceptual
47. Conceptual
48. Conceptual
49. CH3
1 2 3 4
CH3CH-CH2-CH3
Chlorination at C – 2 and C – 4 produces no chiral compunds
50. Conceptual
51. rH 2 VH 2 nH 2 M O2 2/2 32 32
4 w 8 gms
rO2 VO2 nO2 M H2 w / 32 2 w
52. BRT
T1 27 273 300 K T2 927 273 1200 K avg
M
927 C 1200 K
avg T 2 270 C 2 x ( 27 C x )
0
27 C
0 0
0 300 K 927 C
MATHEMATICS
61. 5
cos1 cos cos1 cos / 6 cos 1 cos / 6
6 6 6
62.
1 x 1 sin 1 x 2sin 1 a sin 1 a
2 2 2 2 4 4
1 1 1
a a
2 2 2
63. x 4 x 3
sin 1 sin 1 sin 1 cos 1 x 3
5 5 2 5 5 2
64.
2 y x z , & 2 tan 1 y tan 1 x tan 1 z
2y x z
1 y 2 1 xz
2y 2y 2
y xz x, y, z are in G.P. x y z .
1 y 2 1 xz
65. y y2
1
cos x. 1 x . 1 2
xy 1 x 2 . 4 y 2 2cos
2 4
xy 2cos 1 x 2 . 4 y 2 S.o.bs 4 x 2 4 xy cos y 2 4sin 2
66.
tan 1 cos tan 1 cos x x 2 tan 1 cos
2 2
x x
2
2 tan 1 cos x tan 1 cos 4 2
cos tan
4 2
1 tan x / 2 1 sin x
cos x sin x tan2
2
s.o.b.s. x
cos sin
1 tan x / 2 cos 2
x
2
x
1 sin x
cos sin
2 2
67. 1 4 tan tan 3
Put cos ,sin tan
5 2 17 1 tan tan 29
68. 1 2
sec 1 x sec tan 1 2 tan 2 sin
x 5
1 1 2
tan sec2 1 2
1 2 1 S.O.B.S.
x x 5
1 4 1 4 9
1 1
x2 5 x2 5 5
5 5
x2 x
9 3
69. tn tan 1 2n tan 1 2n1 Sum of n terms Sn tan 1 2n tan 1 1
lt Sn lt tan 1 2n
n n 4 4
4 2
70. a b 1 a b
tan 1 a tan 1 b tan 1 tan tan 1
1 ab 11 2
71.
lim
a 2 x 3x a 2 x 3x 3a x 2 x
x a
3a x 2 x a 2x 3x 3a x 2 x
a 2 x 3x 3a x 2 x
= Lt
xa 3a x 4 x a 2 x 3x
Lt
ax
3a x 2 x 1 2 2 a
2
x a 3 a x a 2 x 3x 3 2 3a 3 3
72. xTan2 x 2 xTanx x
lim lim Tan2 x 2Tanx
x0 4sin 4 x x0 4sin 4 x
x 2Tanx
lim 2Tanx
x0 4sin 4 x 1 Tan 2 x
x 2Tanx 2Tanx 2Tan3 x
lim
x0 4sin 4 x
1 Tan 2 x
1 x Tan3 x 1 1 1
lim 1 1 1
x0 2 sin x sin 3 x 1 Tan 2 x
2 2
73. By LH rule
1 sin x 1 sin x
1/3 1/3
lim
x0 x
2 2
1 1
3 cos x
1 sin x 3 0 cos x 1 sin x
lim 3 3
x0 1
1 1 2
1 0 1 1 0 1 1 1
2/3 2/3
3 3 3
74. h
0hq l
q
h
75. 1 a d a a 2d a d a nd a n 1 d
lim ...
n d
a a d a d a 2d a n 1 d a nd
1 1 1 1 1 1 1
= lim ...
n d a
a d a d a 2d a n 1 d a nd
1 1 1 1 1 1
= lim 0
n d a
a nd d a ad
76. By LH Rule
e x cos x 1 1
lim 2
x0 1 1
1 x 1 0
77. 1
x 2 3 x 2 if x 0 2
f x x 3x 2 x 2 x 1
1
if x 0
x 2 3 x 2
x 1, 2 x 2 3x 2 x 2 x 1 x 1, 2
At x 1, 2 f x not continuous function.
At x 0 f x 2 x 3x 2 f 0 2
78. 2
1 Kx 1 Kx
Lt 2 [ f x is continuous at x 0 ]
x0 x
Lt
1 Kx 1 Kx
1 Kx 1 Kx
2
x0
x 1 Kx 1 Kx
1 kx 1 kx 2kx
Lt 2 Lt 2
x0
x 1 kx 1 kx x0
x 1 kx 1 kx
2K
2 K 2
2
4h4
lim a lim 1 a a 1
h0 4h4 h0
4h4
RHL at x 4 lim f x lim f 4 h lim b
x4 h0 h0 4h4
lim 1 b b 1 a 1 a b b 1If a 1 a b b 1
h0
and b 1 a b a 1
80. cos x sin x 0 sin x cos x 1
lim By LH Rule lim
x
4
cos 2 x 0 x 2sin 2 x 2
4
81. 5 5 2 2
cosec 1 cosec tan 1 tan
3 3 3 3
cot cot 1 6
cot 0.35
cot cot 17
82. 3
2cos 1 x 2cot 1 x cos 1 x x = 0.85
2 6 3 6 2
83. x y z 1
84.
sin 1 sin12. 1 cos2 12 cos12 1 sin 2 12
sin 1 sin 2 12 cos2 12 sin 1 1 / 2 1.5
85. 3
sin 1 x sin 1 2 x sin 1 sin 1 2 x
3 2
3 3 3 1
sin 1 4 x 2 2 x. 1 x . 1 4 x2 2 x
2 4 2 2
86.
lim
1 Tan x 1 Tan x 1 Tan x 1 Tan x
x0
sin x 1 Tanx 1 Tanx
1+Tan x-1+Tan x
lim
x0
sin x 1 Tan x 1 Tan x
2Tan x
lim
x0
sin x 1 Tan x 1 Tan x
2sin x 2
lim 1
x0
cos x.sin x 1 Tan x 1 Tan x 11
90. 2
sec x 2 2 1
lim 0.5
x 4 4 2
4