Sec: SR.

IIT_*CO-SC(MODEL-A,B&C) GTM-19(N) Date: 17-01-24

Time: 3 HRS JEE-MAIN Max. Marks: 300
KEY SHEET
PHYSICS
1 2 2 2 3 1 4 1 5 4
6 2 7 2 8 4 9 2 10 4
11 2 12 2 13 2 14 2 15 4
16 2 17 3 18 2 19 4 20 3
21 3 22 9 23 7 24 2 25 4
26 9 27 3 28 5 29 8 30 9

CHEMISTRY
31 2 32 4 33 3 34 3 35 4
36 3 37 1 38 4 39 2 40 3
41 3 42 2 43 1 44 2 45 2
46 3 47 1 48 1 49 3 50 3
51 336 52 4 53 10 54 4 55 4
56 6 57 8 58 5 59 800 60 5

MATHEMATICS
61 4 62 4 63 4 64 1 65 3
66 2 67 2 68 2 69 4 70 2
71 3 72 4 73 1 74 3 75 3
76 3 77 3 78 3 79 4 80 4
81 5 82 10 83 2 84 2 85 2
86 2187 87 3 88 5 89 6 90 78
Narayana IIT Academy 17-01-24_SR.IIT_*CO-SC(MODEL-A,B&C)_JEE-MAIN_GTM-19(N)_KEY&SOL
SOLUTIONS
PHYSICS
1.

v 2  v12  v22
 v1    ev1    ev2 
2 2 2

 e 2  v12  v22 
 e2v 2
 v '  ev
3. Conceptual.
 
4. I  2 sin 100 t   2 cos 100 t  
 6
 2 
I  2sin 100 t   2 sin 100 t  
 3 
 2 
 2
  2   2  2  2  cos 
2 2
I0  
 3 
I 0  2 ampere
I
Rms value  0
2
2
  2 ampere
2
 3R   3R 
M 1    M 2   3R  1   2 
 8   8  8 R
5. 
M1  M 2  1  2  16
1 7
 
2 5
2.32
6. VSD  cm  0.029 cm
80
each MSD  0.03 cm
LC=MSD – VSD = 0.03 – 0.029 = 0.001 cm
Zero error =  0   80  70  0.001cm
 0.01cm
1.5
7. Vd  19 7
 1.22 104 m / s
9.25 10  1.6 10  8.25 10
28

8. Work done by the external source  change in magnetic potential energy

1 1
 
 L I 22  I12   2  64  25   39 joule
2 2
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1 1 1
9. for 1st lens    V  420cm
V  21 20

1 1 1 400
For 2nd lens,   V '  cm
V ' 400 10 41

420  400 / 41 20

Magnification (composite)     0.5
21 400 41

So size of image is nearly  2cm   0.5  1cm

1  1 
10.   tan   3; c  sin 1    sin 1  
  3
11. for constant velocity, force should be zero on the moving charge. when E  0 , but B = 0, there
would be force.

So the velocity cannot remain constant.

When E  0, B  0 ,

The net force may be zero if

      
 
qE  q V  B  0  E  B  V
12.
I A  I C  Mr12 
2
I B  I A  M  r22  r12 
I B  I C  Mr2 
 25  2.25 
I B  15.9545  20   15.9545  0.0455
 10000 
I B  16 kgm 2
13. Let x be the end correction then according to question.
v 3v
  x  2 .5 cm  0 . 025 m .
4 (l1  x ) 4 (l2  x )
14.

The body would be at rest as seen by the observer, so static friction should balance
The pseudo force. Hence friction = 20 newton.
15. when across silicon diode the potential reaches 0.7 volt, then only it shall conduct. Before that
germanium start conducting and the p.d. across the combination cannot exceed 0.3 volt.

12  0.3
I  11.7  10 4 amp; p.d  11.7  104 104
10 10 3

 11.7volt

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16. The kinetic energy and the potential energy oscillates with double the frequency of particle’s
oscillation.
Hence time period of these energy oscillation would be half.
17. 
Q   Br   B p c 2 
 B   B   4.029482  4.025964
r p

 0.003518amu
Decrease in mass appears as equivalent energy
 Q  0.003518  931MeV  3.27 MeV
hc  1 1 
18.     4.8
e   0 
hc  1 1
    1.6
e  2 0 
Dividing
1 1

 0
3
1 1

2 0
1 1 3 3 3 1 3 1
       
 0 2 0 0 0 2 
2 3 2
   0  4
0 2
19.

v2  2gL  v  2gL

2mv   2m  2m  v '
v gL
v'    2 gL
2 2

gL
0  v '2  2 gh   2 gh
2
L 5
h   1.25 m
4 4
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P
20. I av  E02  av  E02  E0  Pav
A
E 100 E
 E  2
1/ 2
Now   2  E'
E' 50 2
 C 
21. C x1  500  300 
x  
T  T0 x2  C 
 
 400  300 
x1 100 1
 
x2 200 2
20  10 10
22. at the right ride acceleration of the blocks  m / s2
2 1 3
40
Tension in the support (to the pulley)  newton
3
40 4
Now for the meter scale to be horizontal, 30     1     9  4  4   
3 13

40
30  x   1  x 
3
9x  4  4x 20  T  2a
13x  4 T  10  1a
4
x mt 10  3a
13
a  10 / 3
 10 
20  T  2  
 3
20
T  20 
3
 40 / 3
3R  284 
23. 1000 
M  103
25  284
10   10 
6 3
  M  7.1gram
M
24. Ma  Fnet  Mg  B  6 rv
At v  vT , a  0
 Mg  B  6 rvT
4 3 
 r    g
3  2
 vT   2m / s
6 r

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2 1 1  2 1 1
25. 13.6  3  2  2   13.6  Z   2  
3 5  5 
25  9  Z 
2

 Z 4
25 25
hc 6.63  1034  3  108
26.   16
 9  1010 meters  9 A0
E 2.21 10
GMm
27. For energy in radius r1   nk
2r
Where, n is integer and k is constant.
GMm
Now  nk ………….(i)
2R
GMm
  n  1 k ………….(ii).
 3R 
2 
 2 
GMm
Solving (i) and (ii), we get k 
6R
Now this implies that for Rmax ,
GMm GMm
 1  Rmax  3R
2 Rmax 6R
28. At any moment if the velocity of the rod   , then e.m.f  Bl

dq  d 
q  C  B    B C  
dt  dt 

Net force on the rod = mg  Bi

 dv   dv 
m    mg  B  BC      
 dt   dt 
 dv 
   m  B  C   mg
2 2

 dt 
dv mg 10
 
dt m  B  C 1  1 0.5 2  4 
2 2

dv
 5m / s 2
dt
29. work done = change in kinetic energy
1
  2   0  400  400 Joule
2
1
P  P0 1   2V0 / V  
2
30.
 
At V  V0 , P  P0 / 5
PV  P0 / 5  V0 P0V0
Ti   
nR nR 5nR
At V  2V0 , P  P0 / 2
PV  P0 / 2  2V0  PV
Tf    0 0
nR nR nR
4 PV
T  T f  Ti  0 0
5nR

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CHEMISTRY
31. informative
32. Group IIB sulphide: Sb 2S3
33. For positive deviation from Raoult’s, A-B inter molecular interaction are lesser than A-A or B-B
molecular interaction forces.

34. The actinides resemble the lanthanides in having more compound in +4 oxidation
state than in +3 oxidation state
3
35. Only known low spin aqua complex is Co  H 2O 6 
36. 1)  Cu  H 2O  3 F3  P) Geometrical isomerism
2)  Co  en  3  Cl3 Q) Optical isomerism
3)  Co  en 2  NO 2 2  Cl S) Ionisation isomerism
4) K 3  Cr  CN 6  R) Linkage isomerism
37. Higher the B.O means greater the no of bonds, lesser the bond length and greater the bond
energy.
38. In partition chromatography, mobile phase is liquid.
39. Due to repulsions between lone pair of electrons of oxygen and negative charge of carbon

40. HC  C  CH 2  CH 2  C  CH 
HgSo4
H 2 So4

41. Stability of carbocations order is III> I > II
42. alcoholic group gives – CAN
Either unsaturation (or) 10  (or ) 2 0 alcoholic -OH decolourises KM NO 4
OH O
 
 R  CH  CH 3 (or )  C  CH 3 gives positive iodoform test.
43. esters can’t be prepared from Grignard reagent

R mg x  Co2  Rcoo Mg x 
H 3O
 RCOOH

R mg x  HCHO  R  CH 2O Mg x 
H 3O
 R  CH 2OH
O
 
R mg x  H  C  R 
H 3O
 20  OH
44. Only benzene ring migration wont takes place
45. A mong bases in nucleic acids only thymine has SP 3 carbon
46. vapour density of A  3  vapour density of B
Molar mass of A  3  molar mass of B
47. An entropy change for anreversible process taking system and surrounding together is
always zero
48. HgI2  2KI  K 2  HgI4  Hence due to the formation of complex
49. G 0 = -2.303 RT log Keq
Keq =10 For reverse reaction = 0.1
50. The value of equivalent conductance of weak electrolyte decreases with increase in
concentration.
51. According to Zeisel’s method
Sucrose has 8 OH groups hence 8  42 times = 336
Dipolemoment
52. partial charge =
Bond dis tan ce

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18
1.2  10 esu.cm
 18
 1.2  1010 esu
1 10 cm
1.2  1010 1
The fraction of an electronic charge is 
4.8  1010 4
54. 1,7,8

55. OH
|
H  C  C  H 
HgSO4
H 2SO4
 CH3  CHO 
dil NaOH
 CH 3  CH  CH 2  CHO;
56.

w
57. 29.2%   of Hcl means
w
Mass of Hcl (w) =29.2g
Mass of solution =100g
d=1.25g/mL, mol.wt. of Hcl  36.5 g / mol 
Volume of solution  100 g / 1.25 gmL1  8mL

w 1000 29.2 1000

Molarity =     10m
M .wt Vso ln 36.5 80
200  0.4
Using M 1V1  M 2V2  10  V1  0.4  200  V1 
10
58. Given 2  30.4  107 cm
1  108.5  107 cm
let excited state of He+ be N2. it comes from n2 to n1 and then n1 to 1 to emit two successive photon
1 1 1 
 RH.z2  2  
2  1 n12 

1 1 1
7
 109678  4  2  2  n1 = 2
30.4  10  1 n1 
 
Now 1  RHz2  12  12 
1  2 n2 

1  1 1
7
 109678  4  2  2 
108.5  10  2 n2 
th
n2  5 thus excited state for He is 5 orbit.

59. w  1 20  10   10 L.atm

= -10 x 101.3 = -1013 J
E  q  w
60. At half of the first equivalent point ph is equal to pka
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MATHS
61. Conceptual
62. (1, 1), (2, 2), (3, 3), (4, 4) are to be included so that S is reflexive.
(2, 1), (3, 2), (4, 3) are to be included so that S is symmetric.
(1, 3), (2, 4) are to be included so that S is transitive.
Then (3, 1), (4, 2) are to be included so that S is symmetric.
1

A   x 6 1 x  dx
7
63.
0
6!7!
 ( ausing   function)
14!
14!
A1   23.3.7.11.13
6!7!
64. Conceptual
65.
f ( x )  x 3  3(a  7) x 2  3(a 2  9) x  1
f ' ( x)  3 x 2  6(a  7) x  3( a 2  7)

The roots of f ( x)  0 positive and distinct which is possible if
(i) b  4ac  0  6(a  7)  4(3)(3)(a  9)  0
2 2 2

29
a
7
(ii) Product of Roots > 0 a2  9  0
(iii) Sum of Roots > 0 a7  0
a7
29
a  (, 3)  (3, )
From i, ii, iii 7
66. Conceptual
67. x 2  10x  7  0
x12  10x11  7x10  0
12  1011  710  0 
 adding we get  12  12   10  11  11   7  10  10   0
12  1011  710  0 
a12  10a11  7a10  0
a12  7a10  10a11
a12  7a10
 5
2a11
4000
68.  10  x1x4001  400 and x1  x4001  50
x1x4001
( x1  x4001) 2  ( x1  x4001) 2  4 x1x4001  x1  x4001  30

1 1
69. I
40  f  z   f   z   sin zdz   f     f  0    0
4

70. If z1  x1  iy1 and z2  x2  iy2 then y12  4 x1  4  0 and y22  4 x2  4  0 so that

y1  y2 4 y  y2 
 also 1  tan  3 . Hence y1  y2  4
x1  x2 y1  y2 x1  x2 3 3

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71. We have
(sin 2 x  cos 2 x )(sin 2 x  cos 2 x)  sin 2 x cos 2 x
y
(sin 2 x  cos 2 x)2  sin 2 x cos 2 x
1
 cos 2 x  sin 2 2 x
4 4 cos 2 x  1  cos 2 2 x
 
1 4  1  cos 2 2 x
1  sin 2 2 x
4
1  4 cos 2 x  cos 2 2 x

3  cos 2 2 x
 (1  y ) cos 2 2 x  4 cos 2 x  3 y  1  0
Since cos2x is real 16  4(3 y  1)(1  y )  0 or 3 y 2  2 y  5  0
5
or (3 y  5)( y  1)  0    y  1
3

But y = 1 implies cos2x = -1 i.e. x  which is not permissible.
2
72. f '  0   1, f ' 1  1  1  ....  1  100
73. x 2  20 x  9  0
4 x5
f  x   2 x 3  36 x  15 x 2  48
f '  x   6 x 2  36  30 x  6  x 2  5 x  6 
for x   4,5 f '  x   0
max is f  5   7
74. A  adjA   A I ; A  29
  2  4x  
75. On solving  sin 1  2 
   2 tan 1 4 x
2  1  16 x  2
 2  4x 
 2 tan 1  4 x     sin 1  
 1   4 x 2 
 
 2 x 
 2 tan 1 x    sin 1  2 
; x 1
 1 x 
1 1 
x  ; x , 
 As 4x > 1  4 4 

we have 2a  a  1  3a  4a  1  a  5a  0  0  a  5 …….(A)
2 2 2
76.
Also 3a  4a  1  (3a  1)(a  1)  0  a  (,1/ 3)  (1, ).........( B)
2

Intersection of (A) and (B) yields a  (0, 1/ 3)  (1, 5)

77. Any point on or inside the region bounded by x  y  3 will have x and y coordinates lying
between – 3 and + 3 which will turn up as a throw of dice i.e. (1, 1), (1, 2), (2, 1).
3 1
Hence, probability is 
36 12
78. P  X  xi   1
20  r r
79. Tr 1  20Cr .4 3
.6 4

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Narayana IIT Academy 17-01-24_SR.IIT_*CO-SC(MODEL-A,B&C)_JEE-MAIN_GTM-19(N)_KEY&SOL
40  2 r r r

 20Cr .4 3
.2 .3
4 4

160 11r r

 20Cr .2 12
.3 4

r 160  11r
For rational terms, and must be integers and 0  r  20 .
4 12
r
So,  integer
4
 r  0, 4,8,12,16, 20
 Only two terms are rational. So 21 – 2 i.e 19 terms are irrational
80.

81. a , b, c are non-coplanar   a , b, c   0 Also  a  b, b  c, c  a are non-coplanar Given

     
d  sin x a  b  cosy b  c  2 c  a . Taking dot product with a  b  c , we get
O  sin x  a b c   cos y  a b c   2  a b c 
 sin x  cos y  2  0
 sin x  cos y  2

 x   4n  1 , y=  2n  1  , n  z
2
 5 2
for least value of x 2  y 2 , x  , y   & least value is .
2 4
82. Let E1 be the event that one of first n urns is chosen, E2 be the event that (n + 1)th urn is chosen.
A be the event that two balls drawn are black.
n 1
P  E1   ; P  E2  
n 1 n 1
A 6
C2 1  A  5 C2 2
P    10  ; P   
 E1  C2 3  E 2  10 C2 9
A
P  E 2  .P  
1 2
.
 E  E
 2 1 n 1 9
P 2      n  10
A A  A  16 n 1 1 2
P  E1  P    P  E 2  .P   .  .
E
 1 E
 2 n  1 3 n  1 9
83. f(n) is not continuous at  1
dx dy
84.  3,  2
dt dt
dx dx
x  y.  10  2   6  3   20  18  2
dt dt

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Narayana IIT Academy 17-01-24_SR.IIT_*CO-SC(MODEL-A,B&C)_JEE-MAIN_GTM-19(N)_KEY&SOL
2 2
85. 0
f 1 ( x) dx   0
f 1 ( x) dx
2
=  (2ax  b) dx  4a  2b
0
2
f(0) = 0  c = 0 f(2) = 4a + 2b = 2  
0
f 1 ( x ) dx  2
2
Min of 
0
f 1 ( x ) dx = 2

g  x    x 24 . 1  x  x 2  .  6 x5  5 x 4  4 x 3  dx
6
86.
   x 4  x5  x 6  .  6 x5  5 x 4  4 x 3  dx
6

x  x5  x 4 
6 7
t7
Put t  x 6  x 5  x 4   t 6 dt   C  C
7 7
But it passes through (0,0)  C  0
 g 1  3
7

7
87. AB  4  4  1  3
BC  1  4  4  3
AC  1  16  1  18
AB2  BC 2  AC 2  B  900
1 3
Circum-centre = S = Midpoint of AC =  ,1, 
  2 2
Ortho-centre = H= B= (2, -1, 3)
9 9 3
SH = 0 
4 4 2
88. Tn  C3
n

Tn1  n 1C3
Tn1  Tn  n 1C3  n C3
 n C2  10  n  5
 2  2  2   
89. a  b  b  c  c  a  3  2 a.b  b .c  c .a  
   3
Where a.b  b .c  c .a  
2
 2  2  2
a b  b c  c a  6
90. After replacing 30 in place of wrong observation 20
 xi  170  20  30  180
2 2 2
x  2830  20  30  3330
i

 correct variance

 
  xi 
2
2
x
  222  144  78
i
2

n  n 

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