Professional Documents
Culture Documents
CHEMISTRY
31) 2 32) 3 33) 4 34) 4 35) 2
36) 3 37) 1 38) 4 39) 1 40) 2
41) 2 42) 4 43) 1 44) 1 45) 4
46) 1 47) 2 48) 4 49) 2 50) 3
51) 6 52) 2 53) 3 54) 20 55) 3
56) 4 57) 356 58) 4 59) 2 60) 5
MATHEMATICS
61) 2 62) 3 63) 3 64) 1 65) 3
66) 1 67) 3 68) 2 69) 4 70) 1
71) 1 72) 4 73) 4 74) 2 75) 2
76) 1 77) 1 78) 4 79) 2 80) 3
81) 1 82) 167 83) 84 84) 5 85) 7
86) 2 87) 17 88) 7 89) 27 90) 7
SOLUTIONS
PHYSICS
1. 60 . Solid angle subtended by BCD is
2 1 cos
Solid angle subtended by ABDE is
ABCDE BCD 2
q q
Hence, flux through ABDE is
0 4 4 0
2. 4T
The pressure due to surface tension
R
2
The pressure due to electrostatic forces
2 0
Just before the bubble bursts.
4T 2 8T
or R 20
R 2 0
3. hc
K 0 i
4hc
and K ' 0 ii
3
4hc hc
From Eq/s i & ii , we get K ' K
3
hc
K ' K
3
hc K
But from Eq. i K 0 K ' K 0
3 3
4K 0 4K
K ' K Or K '
3 3 3
4. D
y9 position of 9th bright fringe 9
d
1 D 3 D
y 2 position of 2nd dark fringe = 2
2 d 2 d
1 g 1
Now, 1 g Or 1 g sin ic
sin ic 1 sin i c
3
1.5 sin60 1.5 1.5 0.8666 1.299 1.3
2
9. XL XC ;
R
2 2
Z
R 10, X L L 2000 5 103 10
1 1
XC 10 i.e Z 10
C 2000 50 106
V 20
Maximum current i 0 0 2A
Z 10
2
Hence i rms 1.4A And Vrms 4 1.41 5.64V
2
10. To free electron from the metal surface minimum energy required is equal to the work
function of that metal. So Assertion A, is correct
h W0 K.E max If h W0 K.E max 0
Hence reason R, is correct, But R is not the correct explanation of A.
11. Rate of decay of current between t 5 ms to 6 ms
di 5
slope of the line BC 3
5 103 A / s
dt 1 10
di
Hence induced emf L 4.6 5 103 23 103 V
dt
12. b b
I Iv b
Induced emf Bvdx 0 vdx induced emf, E 0 ln
0 a
2x 2 a
E2
power dissipated
R
2
E2 0 Iv b 1
Also, power F.V F F ln
vR 2 a vR
13. X X C X L and average power in ac circuit can be zero.
14.
5 25 10 2 35 35
Now, Vx Vy , Ceq F
5 25 10 2 6 6
17. When energy on both is same, means energy on capacitor is half of its maximum
q 2 1 Q2 Q Q 1
energy. q Q cos t cos t
2C 2 2C 2 2 2
t t LC
4 4 4
18. r1 A1
1/3
3 27
1/3
27 27
r A
1/3
A 125
r2 A 2 5 A 125 A
Number of nuclei in atom X A 52 125 52 73 .
19. For lens u 30cm,f 20cm, hence by using
1 1 1 1 1 1
v 60cm
f v u 20 v 30
The final image will coincide the object, if light ray falls normally on convex mirror
as shown. From figure, it could be seen clearly that separation between lens and
mirror is 60 – 10 = 50 cm.
5
Vx VP 3 7.5V i
2
5
Vx VQ 2 5V ii
2
On solving i & ii VP VQ 2.5volt; VQ VP .
21. Using dV E.dr
V
V E. r cos E
r cos
20 10 10 102
E 200V / m
10 102 cos120 10 10 sin 30 1 / 2
22. 2
Number of atoms in 2 kg fuel 6.02 1026 5.12 1024
235
Fission rate = number of atoms fissioned in one second
5.12 1024
1.975 1018 s 1
30 24 60 60
Each fission gives 185 MeV. Hence, energy obtained in one second,
E 185 1.975 1018 MeV s 1 142 1.975 1018 1.6 1019 106 J s 1 44.87MW
23.
2 4 1012 4
Fnet 2 F31 cos 2 0.46N
40 0.5
2
5
24. Total range is doubled, i.e., 4Ig
Now shunt required is
CHEMISTRY
31. Conceptual
32. t1/2 1 a 2 n 1 ; 120 4 102 n 1 ;n 2
t a 240 8 102
1/2 2 1
33. Assertion is false but Reason is true. The enthalpy of chemisorption is of the order
of 40 400kJmol1 while for physical adsorption it is of the order of
20 40 kJmol1 .
34. 3 2d 2 4.52 0
For bcc, d a or a 5.219 A 522 pm
2 3 1.732
zM 2 39
0.91g / cm3 910kg m 3
a N A 10 30
522 6.023 10 10
3 3 23 30
RT Zn
2
E cell E 0
cell n
nF Cu 2
Zn 2
Greater the factor
, less is the EMF
Cu
2
Hence E1 E 2
36. As colloidal particles move towards anode so these particles are negatively charged
and coagulated by cations of electrolyte.
According to Hardy Schulze rule,
Coagulation power charge of ion
Order of coagulation power is Al3 Ba 2 Na
37. Oxide in which central atom has higher charge and more electronegativity is more
acidic, i.e.
N 2O5 N 2O 4 P2O5 As 2O3
38. 2Ag 2O s 4Ag s O2 g
2Pb3O4 s 6PbO s O2 g
2PbO 2 s 2PbO s O 2 g
39. Metal halides with higher oxidation state are more covalent than the one in lower
oxidation state.
40. XeF4 is planar
41. Conceptual
42. Conceptual
Sec: Sr.Super60_NUCLEUS&STERLING_BT Page 8
SRI CHAITANYA IIT ACADEMY, INDIA 03‐01‐23_ Sr.S60_NUCLEUS&STERLING_BT _ Jee‐Main_GTM‐01_KEY &SOL’S
43. Conceptual
44. Alkyl iodides are often prepared by the reaction of alkyl chlorides/bromides with
NaI in dry acetone. This reaction is known as Finkelstein reaction.
R X NaI R I NaX
X Cl,Br
NaCl or NaBr thus formed is precipitated in dry acetone.
It facilitates the forward reaction according to lechatelier’s principle. The synthesis
of alkyl fluorides is best accomplished by heating an alkyl chloride/ bromide in the
presence of a metallic fluoride such as AgF, Hg 2 F2 ,CoF2 orSbF3 . The reaction is
termed as Swarts reaction.
H 3C Br AgF H 3C F AgBr
45. Conceptual
46. OH
3 2 1
H3C COOH
6 4
5 CH3
47. i) Gives Propanoic acid
ii) Methyl isocyanide on hydrolysis give methyl amine
48. For the preparation of Me3CNH 2 , the required alkylhalide is Me3CX which will
react with potassium phthalmide, a strong base, to form alkene rather than
substituted product. For preparing C6 H 5 NH 2 ,C6 H 5Cl will be starting halide in
which Cl is non-reactive.
49. Nylon-66 is an example of first synthetic fibres produced from the simple
molecules. It is prepared by condensation polymerization of adipic acid and
hexamethylene diamine.
50. Conceptual
51. Convulsion is caused by deficiency of vitamin B6
52. i) 5Fe 2 MnO 4 8H Mn 2 4H 2O 5Fe3
The isomers Cu NH3 2 Cl2 Pt NH3 2 Cl2 does not exist due to both parts being
neutral
57. From Raoult’s law
P P w M 121.8 120.2 15 78
P m W 121.8 m 250
15 78 21.8
Or m 356.2
250 1.6
58. 2, 3, 5, 8
59. COCH3
C6H6
CH3COOH + PCl5 CH3COCl
Anh.AlCl3
(A)
Friedle Craft
reaction
OH OMgBr
H + MgBrC2H5
C2H5 C CH3 C2H5 C CH3
Ether
hydrolysis
(C)
60. Conceptual
MATHEMATICS
61. x x x x
f x x e f x t dt x e
2 t 2 x t
f t dt x e .e f t dt x e
2 x t 2 x
e f t dt
t
0 0 0 0
x
f 1 x 2x e x .e x f x e x e t f t dt 2x f x f x x 2
0
3
x x3
f x x c f 0 0 f x x
2 2
3 3
f 3 9 9 18
62.
tan sin x 1
1 2
c
2
tan 1 sin x 1 cos x
Let, I dx
3 2sin x 1 sin 2 x
Substituting, 1 sin x t cos dx dt
tan 1 t
2
tan 1 t dt
tan 1 t dt
I c
2 t 1 2 t 1 1 t2
2
2
tan sin x 1
1 2
I c
2
63.
2x 3 ydy 1 y2 x 2 y2 y2 1 dx 0
2y dy y2 1 1
1 y 2 2 dx 1 y 2 x x 3
y2
Put u.
1 y2
2y dy du
Then
2
1 y 2 dx dx
1
du u 1 dx
3 Integrating factor e x eln x x
dx x x
1
Solution is u.x 2 dx c x 2 y 2 cx 1 1 y 2
x
64. 2n 3 1
tn .
n n 1 3n
Therefore,
2n 3 1 2 n 1 1 1 2 1 1
tn . n .
n n 1 3 n n 1 3 n n n 1 3n
n
2 n 1 n 1 2 1 1 1
n n n 1 3 n n n 1 3n
n
dx
xdy
2
dy 2
From (3) and (4), we have y 1
dx dx
66. Since x 2 y 2 4y 5 0
Centre is C1 0, 2 and Radius r1 4 5 3
Let C2 h,k be the centre of the smaller circle and its radius r2 .
Since, C1C 2 4 h 2 k 2 3 r2 4 r2 1
2
But k r2 1
Hence, using equation (1), we have
4 h 2 1 2 16 h 2 9
2
h 7
Since, h > 0
2
y 1 2
2
Hence, required circle is x 7
67. a 2 x 2 ax 1 is positive for all real values of x.
1
Area a 2 x 2 ax 1 dx
0
2
a a 1
3 2
1 2a 2 3a 6
6
1 2 3 a 18
2 a a 6
6 2 16 16
2 2 a x adx 4 b b xdx
3 a ba
8 16 a b
ab a b ab 1
3 3 2
69.
1 x2 1
2
e x 2x x 3 1
e 2 2x
2 3 x 2
2
3 x2 3 x 2
dx 1
2
e x 2x x 3
2
ex
Hence, 3 x 2
2 3 x2
c
70. The point (–2k, k + 1) is the interior point of the circle and parabola
So 2k k 1 4 0
2 2
4k 2 k 2 2k 1 4 0 5k 2 2k 3 0
k 1 k
3 3
0 k 1, 1
5 5
Now, k 1 4 2k 0
2
k 2 2k 1 8k 0 k 2 10k 1 0
k 5 2 6, 5 2 6 2
So from (1) & (2) k 1, 5 2 6
71. Total formed numbers that begin with a odd digit 5C1. 8 P4 5 8 7 6 5
Total formed numbers that end with a odd digit = 5C1. 8 P4 5 8 7 6 5
Total formed number that begin with an odd digit and also end with an odd digit
5C 2 .2!. 7 P3 5. 4 7 6 5
Thus total formed numbers that begin with an odd digit or end with an odd digits is
equal to
5.7.6.60
Total formed numbers 9 P5 9.8.76.5
Sec: Sr.Super60_NUCLEUS&STERLING_BT Page 13
SRI CHAITANYA IIT ACADEMY, INDIA 03‐01‐23_ Sr.S60_NUCLEUS&STERLING_BT _ Jee‐Main_GTM‐01_KEY &SOL’S
5
Thus, required probability
6
72. If z1 be the new complex number then z1 z 2 2 2
z1 z1 i3 /2 3 3
Also e z1 z.2 cos isin 2 1 i 0 i 2i 2 2 1 i
z z 2 2
73. See figure, the given equation is written as
3
4 , when x 1
arg z 1 i
, when x 1
4
O C
P
Co-ordinates of point P and Q are 4 5cos ,3 5sin and 4 5cos ,3 5sin
= (4 – 3, 3 + 4) and (4 + 3, 3 – 4)
(1, 7) and (7, –1)
75. Let, t 211x
2 11x 3
2
211x.22 211x .2 1
22
t3
4t 2t 2 1
4
t 3 8t 2 16t 4 0
Cubic it t has roots t1 , t 2 , t 3
i.e. t1t 2 t 3 4 211x1.211x 2 .211x3 4
Sec: Sr.Super60_NUCLEUS&STERLING_BT Page 14
SRI CHAITANYA IIT ACADEMY, INDIA 03‐01‐23_ Sr.S60_NUCLEUS&STERLING_BT _ Jee‐Main_GTM‐01_KEY &SOL’S
11 x1 x 2 x 3
2 2 2
2
11 x1 x 2 x 3 2 x1 x 2 x 3
11
76. Let, a = number of red balls.
b = number of blue balls,
p1 = probability of drawing two red balls
a
C a a 1
ab 2
C2 a b a b 1
C2 b b 1
b
p 2 probability of drawing two blue balls
ab
C2 a b a b 1
p3 probability of drawing one red and one blue ball
a
C1. b C1 2ab
ab
C2 a b a b 1
Given that p1 5p 2 & p3 6p 2
a a 1 5b b 1 and 2ab = 6b (b – 1)
a 6,b 3 Total number of balls = 9
77.
P c
A P A A B
c
P A B c
A
B c
P A B
c
1 P A B
4 3
P A P A B 7 28 13
1 P A B 25 25
28
78. Let n consecutive odd integers are
2m + 1, 2m + 3, 2m + 5, ……, 2m + 2n – 1
Given that,
452 212 2m 1 2m 3 2m 5 ....... 2m 2n 1
2mn 1 3 5..... 2n 1 2mn n 2 m 2 2mn n 2 m 2
452 212 m n m 2
2
m n 45&m 21
n 24&m 21
Hence, the numbers are
43, 45, ……, 89
79. We have
1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1
S , , , , , , , , ,
1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1
1 1 1 1 1 1 1 1 1 1 1 1
, , , , ,
1 1 1 1 1 1 1 1 1 1 1 1
n S 16
Sec: Sr.Super60_NUCLEUS&STERLING_BT Page 15
SRI CHAITANYA IIT ACADEMY, INDIA 03‐01‐23_ Sr.S60_NUCLEUS&STERLING_BT _ Jee‐Main_GTM‐01_KEY &SOL’S
Now, number of favorable cases are given by ( 0 , that is either 2or 2 )
1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1
E , , , , , , ,
1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1
n E 8 1
Hence probability that the system of equations has a unique solution
n S 16 2
80. Number of ways 9C5 - no.of ways in which she selects 5 from only of two
categories.
9C5 3. 6C5 126 18 108
Alternatively: Number of ways 1 1 3 or 2 2 1 i.e.,
3. 3C1. 3C1. 3C3 3. 3C2 . 3C2 . 3C1 27 81 108 .
81. Let x u 6 ,dx 6u 5du
dx 6u 5du u3
x 3 x u 3 u 2 u 1 du
6
1
6 u 2 u 1 du
u 1
2u 3 3u 2 6u 6ln u 1 e
2 x 3 x 6 x 6ln
3 6 6
x 1 e
a 2,b 3,c 6,d 6 a b c d 1 a b c d 1
82. x 1
x16 x 6
f t dt t .f t dt a 1
2
0 x
8 3
1
1 1 11
For x = 1, f t dt 0 a a
0
8 3 24
Diff. both sides of (1) w. r. t. x we get;
f x 0 x 2f x 2x15 2x 5
1 1
x15 x 5 11 11
2
1 x 2
dx
24
a 2 x13 x11 x 9 x 7 x 5 dx
24
a
0 0
1 1 1 1 1 11 167
2 aa
14 12 10 8 6 24 840
83. Any point on hyperbola xy = 1 (t, 1/t)
Now image of (t, 1/t) by the mirror y = 2x is
x t y 1/ t 2t 1 / t
2
2 1 5
4 3
5x 3t and 5y 4t
t t
Now eliminating t from above two equations we get,
12x 2 12y 2 7xy 25 0
bc 7 12 84
Sec: Sr.Super60_NUCLEUS&STERLING_BT Page 16
SRI CHAITANYA IIT ACADEMY, INDIA 03‐01‐23_ Sr.S60_NUCLEUS&STERLING_BT _ Jee‐Main_GTM‐01_KEY &SOL’S
84.
r 4n
1 .1
lim
n n
2
r/n 3 r 4
r 1
n
4
1
dx
2
0 x 3 x 4
Put, 3 x 4 t
3 1 2
dx dt dx dt
2 x x 3
When x = 0 then t = 4
When x = 4 then t = 10
10 10
2 1 2 1 2 1 1 1
2 dt
34t 3 t4 3 10 4 10
85. 3
4 p
Req.Area x 2 4x 3 dx Pq7
3 q
1
86. 200 C0 C1 ...... n Cn 400
n n
200 2n 400
n 8
8 r r
Tr 1 8C r 4
x 3 a 4 x5
Tr 1 8Cr a r x 2r 6
For this term to be independent of x,
2r 6 0 r 3
T4 8C3a 3 448 56a 3 a 3 8
a2
87. 1 x n r0 Cr x r
n
x 1 x r 0 Cr x r 1
n n
r 1 C 2
2n 3 n 2 . n 1 2n 2 2n 2 n 2 5n 4
n 2 n 1
r 0 r