18-04-20 - SR - IIT - N-SUPER CHAINA&N-CHAINA - Jee-Main - GTM-15 - Key & Sol's (5) 20200420211135

Sec: SR.
IIT_N-SC/N-C GTM-15 Date: 18-04-20

Time: 3 Hrs Max.Marks: 300
KEY SHEET
PHYSICS
1 C 2 A 3 D 4 B 5 A
6 C 7 B 8 C 9 C 10 A
11 C 12 C 13 B 14 A 15 B
16 B 17 C 18 A 19 A 20 C
-94.3 to
21 0.5 22 4 23 24 5 25 30
-94.4
CHEMISTRY
26 B 27 B 28 B 29 C 30 C
31 B 32 C 33 C 34 B 35 D
36 D 37 B 38 C 39 B 40 B
41 D 42 B 43 C 44 B 45 C
11.5 TO 14.28 TO
46 47 59 TO 61 48 74.5 TO 49 4.8 TO 5.2 50
12.5 75.5 14.29
MATHS
51 B 52 A 53 A 54 C 55 A
56 C 57 B 58 D 59 D 60 B
61 C 62 A 63 C 64 B 65 D
66 C 67 C 68 B 69 D 70 B
71 3 72 207 73 28 74 521 75 4
Narayana IIT Academy 15-04-20_Sr.IIT_N-SC&NC_JEE-Main_GTM-15_Key&Sol
SOLUTIONS
PHYSICS
1. X A B 1 C 3D
 100 = 2  100 +  100 +  100 +  100
X A B 3 C D
2. 1
Mean free path  =
2d2n
KB T
=  p = nKB T 
2d2p
 1.381.-23 290 
= = 1.1  10-7
 1.414  3.14   2  10   2.026  10 
2
-10 5
3KB T 3  1.38  10-23  290

Vrms = = -27
=5.1  102 m/s
m 28  1.66  10
Vrms 5.1  102

f = = = 4.6  10 9 s -1
 1.1  10-7
3. In equilibrium force due to surface tension + Force of buoyancy = Weight if the spherical liquid drop
2 3 4
2 Τ + r d2 g = r 3 d1g, T =  , d1 =  , d2 = d
3 3
2 3 4
2 + r dg = r 3 g
3 3
2
2 3 D  3
r =   =
g  2 -d  2  g  2 -d
E0
4. Z=
l0
1 T
5. n=
2l 
6. Y  2R 
2
Y  2R 
2
As, k1 = and k2 = since,
L L
k1x1 = k2x2 = W
Elastic potential energy of the system
1 1
U = k1 x12 + k1 x22
2 2
2 2
1 W 1 W
= k1   + k 2  
2  k1  2  k2 
SR.IIT_N-SC Page. No. 2
Believe you can and you’re halfway there.

1 2 1 1
= W  + 
2  k1 k 2 
1 1 L L
Now, + = +
k1 k2 4YR2 YR2
2
1  5L  5W L
 U = W2   =
2  4YR2  8 YR2
B1 n1  i1 
7. =  
B2 n2  i2 
8. C
9. v R 
10. Let the x-axis be along the length of the rod and origin at one of its ends. As rod is along x-axis, for
all points on it y and z coordinates are zero.
Centre of mass will be on the road. Now consider an element of rod of length dx at a distance x from
the origin, then dm = dx =  A+Bx  dx
11. If VA > VB both the junction diodes are forward biased and the given circuit diagram becomes a
balanced Wheatestone bridge the equivalent resistance in this case becomes 4 , if VA <VB the diodes
are reveres biased in that case 4 ,5 and 4 are in series
12. h
r=
2
 -1
13. According to Rydberg formula
1 1 1
= R 2  2 
  nf ni 
In first case, nf = 3 ni = 4
In second case nf = 2 ni = 3
14.

 = mB sin  = IAB sin  = IAB; as  = 900 
q q q
Further, as I = = =
T 2   2
2
 L  L2
A = r2 =    =
 2  4
 q   L 
2
qL2B
=     B =
 2   4   8 2

15. In the frame of B
10
t= = 1s d = 20  1 = 20m.
10
16. 
 
r
=
2
r
17. When the switch S1 is closed and S2 is open, the circuit becomes as shown in figure.
qmax = CV (it is given). Now this capacitor is discharging through R1 charge at any of time ‘t’ is
q = qmax e-t/ τ = CVe-t/R1c
-R1C
CV
At t = R1C, q = CVe -R1C =
e
At this position, S1 is opened and S2 is closed. Now the circuit becomes as shown in figure below.
Effective resistance R = R1 + R2. Now let us consider that capacitor is further charging i.e. charge on
CV  CV / e V
the capacitor increases from to a steady value CE at t =  .  Assumed that E> = >E  . For
e  C e
CV
this process q = at t - R1C and charge is q at time t.
e

q
From KVL, +I R1 +R2  -E = 0
C
q dq q
 +IR = E  R = E-
C dt C
qf
dr 2R1C+R2C dt
 = 
CV CE-q R1C RC
e
2R C+R2C
q  t  1
 - In  CE - q  CVf =  
E
 CR R1C
 
 CE - qf  2R1C+R2 C-R1C
In  = = -1
 CE- CV  C  R1 +R2 
 e 
CE - qf
 = e-1
CV
CE-
e
CE CV  1  CV
CE -q = -  qf = CE  1-  + 2
e e2  e e
18. m2 - m1
a= g
M
m2 + m1 +
2
19. eE
Here, u = 0, a = '  = ?.t = t
m
eE
 = u + at = 0, t; de-Broglie wavelength,
m
h h h
= = =
m m  eEt / m  eEt
Rate of change of de-Broglie wavelength

d h  1  -h
= - =
dt eE  t2  eEt2
20. From free body diagram
T2 - T1 = m2 l2 and T1 = m1 2l2
or T2 =  2m1 + m2  l2

2
T1 m1 2l
 =
T2  2m1 + m2  l2
2m1 2  10 20
= = = 0.5
2m1 + m2 20  20 40
21. The charge inside the cube due to each line is L . Flux due to horizontal wire through the faces
AEDH, BCGF is zero as the electric field produced will be parallel to these faces.
L
But the total flux due to this line is as it is equally distributed among the remaining four faces.
0
Similarly flux due t vertical wire through the faces DHGC, AEFB is zero.
L L L
 Flux through ABCD = + =
4 0 4 0 2 0
22. The magnetic field (due to current in wire P) at R

 0 2 I P 0 2  2.5
   
4 rPR 4 5
0
 [in the plane of paper downwards]
4
Similarly, the magnetic field (Due to current in wire Q) at R

0 2  I 0
  I [in the plane of paper downward
4 2 4
The total magnetic field at R [ due to P and Q]
 0 0 
B  I  0 1  I  [in the plane of paper downwards]
4 4 4
The force experienced by the electron F  qvB sin 
0
 evB sin 90  1.6 1019  4  105  1  I 
4
But F  3.2  1020 N (Given)
 3.2 102  1.6  1019  4  105  107 1  I 
 I  4 amp
23. From P11-  T1 = P21- T2

Here P1 = 6 atm; P2 = 1 atm
T1 = 273 + 25 =298K;  = 1.4
 6  1-1.4   298 1.4 =  1(1-1.4) T21.4
1.4  298 1.4

T21.4 =  298  6 -0.4 =
6 0.4
1 1.4
  298 1.4  1.4  298  1.4  298 
T2 =   = =
 60.4  0.4 2
 6  1.4  6  7
2
(or) log T2 = 2.4742 -  0.7782 
7
= 2.4742 – 0.2209 = 2.2533.
Antilog of 2.2533 = 17.7
 T2 = 178.7K  t2 = 178.7 - 273 = -94.3 0 C.
24. d sin  = n
25. Vin = V + VZ
CHEMISTRY
26.  MS  OH  S 2S

2 2 2
 9 1012
4S3  9  1012
9
S3   1012  S  1.31104
4
 OH    1.31 104
pOH  3.88
pH  10.12
27.  Fe  H 2O 6  Cl 2 , weak field, d 6 , 4 unpaired e
Na 3  Fe  CN 6  , strong field, d 5 , 1 unpaired e
 Fe  en 3  Q 2 , strong field, d10 , 0 unpaired e 
Ni  CO 4  , strong field, d10 , 0 unpaired e 
I  II  III  IV

28. O 2 , H 2 , CO 2
Order of TC is CO 2  O2  H 2
Higher the TC higher is adsorption

29.
30.
31.

32. Conceptual
33. B2 H 6  NH 3 

 B3 N 3 H 6
x  y
34. Trans  Anti  meso

35. Ozone layer does not permit UV radiation
36. Carbohydrates give molisch’s test starch does not give Benedict ’s test amino acids give ninhydrin test
37. Zn  2HCl  ZnCl 2  H 2
Zn  2NaOH  Na 2 ZnO 2  H 2
38. A  
 2B
 B
2
62
k  6
A 6
39. Order of basicity : imidine base  2  1  amid

40. G and b are both function of temperature
41.

Meridional Isomer
Only meridional isomer has bond angle 180C
42. Conceptual
43. Strong electrolyte solution has higher ionic conductance
44.  NO 2 is with drawing group, reduces C-Br bond length
45. As there in a large gap in 2nd and 3rd I.E. the metal is bivalent. 2 mole of bivalent metal will react with
4 mole HCl and 1 mole H 2SO 4
46.
ao
47. ln  t
at
ln 3    96
2.303  0.48 2.303
 
96 200
ln 2 .303  0.3
t1/ 2    60 hrs
 2.303 / 200
48. PV  nRT
2.66  8.2  1 0.082  T
T  266 K
75.2 / 94
T  7 K  114 
1
5
i
8
5 3
1
1 i 883
 
1 1 1 4
1 1
2 2 2
75 %

3
5.2  10
49. conc. of O 2 in ppm =  106 ppm  5ppm
1040
50.
8
% of H =  100  14.2
56
MATHS
51. A   x : x  (, 2]  [2, )
B   x : x  (1,5)
12 11
C3 .29 55  2 
52. P(E )    
312 3 3
dy 2t d2y 2
53.  , 
dx 1 t2 dx 2
1 t2
54. g  f ( x)   x
g '[ f ( x)] f '( x)  1

1
g '[ f ( x)] 
f '( x)
1  f ''( x)
g ''[ f ( x)]  3
f ''( x) 
[ f '( x )] [ f '( x)]3
20  r r
 x   1 
55. tr 1  20 Cr    
 sin    x cos  
20  r r
 1   1  20  2 r
 Cr 
20
   .x
 sin    cos  

For x , 20  2r  2  r  9
2
For x 2 , 20  2r  2  r  11
20 1 1
C9 . 9
l1 sin  cos   cot 2 
11

l2 20 1 1
C11 9
sin  cos11 
56.     c,   d , 2  a,  2  b
 2(b  d )  2( 2   )  2 (   )  ac
x t
57. f ( x)   t 2 g (t )dt. g (t )   f (u )du
1 1
F '( x)  x 2 g ( x) g '(t )  f (t )  g '( x)  f ( x)

F '(1)  g (1)  0
 F '' ( x )  x 2 g '( x)  g ( x)2 x

F '' (1)  g '(1)  g (1)(2)
 g '(1)  0
 g '(1)
 f (1)
 2  0
f has local maxima at x  1
5  5 5   5 
58. lim x    lim x       lim  5  x    5
x 0
 x  x 0  x  x   x0   x 
A5
f(x) is continuous at integral values of x.
59.
a 1 0
f ( x)  ax a 1
2
ax ax a
a 1 0
 ax a  1 ( R3  R3  xR2 )
0 0 a x
f ( x)  a (a  x) 2
f (2 x)  f ( x)  ax(2a  3 x)
60.

For
61.
2 p 6
1 2 q  (2  p)(3  q )
1 1 3
 x  ( p  2)(4q  15)
y  0
z  p  2
62. Conceptual
63.
a 2  16b 2  a 2b 2
25 a 2
  b 2  a 2  16b 2  100
4 16
 a 2b 2  100  ab  10  a  2 5, b  5
3
b 2  a 2 (1  e 2 )  e 
2
64. z  z  z  z  2  x  y 1
z lies on the rhombus

65.

1
x  1  tan 2   tan 4   .............   cos 2 
1  ( tan  )
2
1 1
y  1  cos 2   cos 4   ............  
1  cos  sin 2 
2
1 1 1
 x   1  1 x  y 
y y 1 x
66.
dv 1  v 2
vx 
dx 2v
log 1  v  log x  log c
2
x2  y 2
  c  x 2  y 2  cx
x
3
c 
2
1
67. t1t2  1, 2at1  8, t1  , t2  2
2
Other end of focal chord = (32, 32)
Eq of tangent at (32.32) is
32 y  16( x  32)
2 y  x  32
1
y  x  16
2
Slope of Tangent = 1/2
Slop of Normal = -2
68.
p  a1  a3  a5  a7  .......  a49
 a  ar 2  ar 4  .........  ar 48
q  a2  a4  a6  a8  .......  a50
 ar  ar 3  ar 5  .........  ar 49
 r (a  ar 2  ar 4  .......  ar 48
q  rp
p 1 a1
  
q r a2
69.

5 7 9 1
    1  k  32
k k k k
10  21  36  55 122 61
E ( x)   
32 32 16
70.
cos x  sin x  1  x (cos x  1  e x )  (e x  sin x  x )
 e x  sin x  x dx   e x  sin x  x
dx
 log(e x  sin x  x)  x  c
iˆ ˆj kˆ
71. a b  2 1  2  2iˆ  2 ˆj  kˆ a b  3
1 1 0
c  a  2 2   c  a  .(c  a )  8
2 2
c  2a .c  a  8
2
c  2 c  9 8  0
2
c  2 c 1  0
( c  1)2  0  c  1
(a  b )  c  a  b c sin 300
1 3
 (a  b)  c  3  (1)  
2 2
72.
S  41 C0  641 C1  1141 C2  .........  206 41C41
S  206 41C41  201 41C40  .......  41 C0
2 S  207( 41 C0  41C1  41 C2  ..........  41 C41 )
 207  2 40
S  207  2 40  k  207
73. C1  (5, 2) C2  ( 7,3) r1  7, r2  6

C1C2  13 r1  r2  13  Circles louch externally
(a,b) divides C1,C2 in ratio 7:6
49  30 19 21  ( 12) 9
a  b 
13 13 13 13
28
ba 
13
74. 100th term of 1st sequence = 991

100th term of 2nd sequence = 526
31  (n  1)10  526  n  50.5  n  50
75. Direction ratios of normal to the plane are 2, -3, 5 direction ratio of vector lying in other plane are2,-
3, 5
These planes are parallel
Eq of other plane is
2x  3 y  5z  k  0
 2(3)  3(4)  5(1)  k  0
k  11
Eq of other plane is 2 x  3 y  5 z  11  0
11  7 4
Distance = 
2 3 5
2 2 2
38

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Sec: SR.

IIT_N-SC/N-C GTM-15 Date: 18-04-20

3KB T 3  1.38  10-23  290

Vrms 5.1  102

SR.IIT_N-SC Page. No. 2

Believe you can and you’re halfway there.

13. According to Rydberg formula

SR.IIT_N-SC Page. No. 3

Believe you can and you’re halfway there.

q = qmax e-t/ τ = CVe-t/R1c

SR.IIT_N-SC Page. No. 4

Believe you can and you’re halfway there.

Rate of change of de-Broglie wavelength

T2 - T1 = m2 l2 and T1 = m1 2l2

SR.IIT_N-SC Page. No. 5

Believe you can and you’re halfway there.

22. The magnetic field (due to current in wire P) at R

Similarly, the magnetic field (Due to current in wire Q) at R

SR.IIT_N-SC Page. No. 6

Believe you can and you’re halfway there.

 6  1-1.4   298 1.4 =  1(1-1.4) T21.4

1.4  298 1.4

26.  MS  OH  S 2S

27.  Fe  H 2O 6  Cl 2 , weak field, d 6 , 4 unpaired e

Na 3  Fe  CN 6  , strong field, d 5 , 1 unpaired e

 Fe  en 3  Q 2 , strong field, d10 , 0 unpaired e 

Ni  CO 4  , strong field, d10 , 0 unpaired e 

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Higher the TC higher is adsorption

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34. Trans  Anti  meso

39. Order of basicity : imidine base  2  1  amid

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g '[ f ( x)] f '( x)  1

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F '( x)  x 2 g ( x) g '(t )  f (t )  g '( x)  f ( x)

 F '' ( x )  x 2 g '( x)  g ( x)2 x

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z lies on the rhombus

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73. C1  (5, 2) C2  ( 7,3) r1  7, r2  6

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