Sec: JR_*CO-SC(MODEL-B) Date: 31-12-2023

Time: 3 Hrs CTM-28 Max. Marks: 300

KEY SHEET
PHYSICS

1-10 D C D A B B B D A C

11-20 B D A D A A A D A C

21-23 400 2 3 4 2 2 2 21 16 4

CHEMISTRY

31-40 4 3 4 4 1 2 4 1 3 2
41-50 2 1 2 2 2 2 2 2 2 3
51-60 2 0 5 5 3 7 7 8 8 5

MATHS
61 A 62 A 63 D 64 B 65 D
66 C 67 A 68 D 69 D 70 A
71 A 72 D 73 A 74 D 75 D
76 A 77 B 78 A 79 C 80 B
81 4 82 4 83 2 84 15 85 5
86 5 87 0 88 16 89 336 90 1
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Hints & Solutions
PHYSICS

1. Flux through cone of semi-vertical angle  ,

q
  1  cos  
2 0
q
 1  cos 600 
2 0
q

4 0
 q  4 0
2. Flux leaving through cone of semi-vertical angle  must be equal to flux entering cone of
semi-
vertical angle 
q1 q2
i.e., 1  cos    1  cos 
2 0 2 0
 q1 sin 2  2  q2 sin 2  2
3. Field due to ring is given by
Qx
E 3/ 2
4 0  R 2  x 2 
 dE 
 Force on dipole is given by F  p  
 dx 
 
d Qx
F  2a  q.  
dx  4   R 2  x 2 3/ 2 
 0 
 
aqQ  R 2  2 x 2 
F
2 0   R 2  x 2 5/2 
 

4. FBD of particle is shown in figure

N  qE sin   mg cos  ……..(i)
f   N    qE sin   mg cos 
 1 3
 0.2  0.01  100   1  10    1.83 N
 2 2 

mg sin   qE cos   f  ma
mg sin   qE cos   f
a 
m

1 3
1  10 
 0.01  100 
= 2 2
1
 2.31ms 2

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h
Distance travelled by particle, s   2m
sin 
1
Using s  ut  at 2
2
2s
t   1.32 s
a
5. Let q1| and q2| are charges on spheres after closing switch
| |
v v
1 2

kq kq2|
|
1

r1 r2
q1| r1
 | 
q2 r2
Also, q1|  q2|  q1  q2
 r 
 q1|   1   q1  q2 
 r1  r2 
kq|
Common potential  1
r1
k  q1  q2 

r1  r2
6. Projected area of cone is a triangle of height h and base 2R
 Electric flux entering through the cone,
1
  E  h  2 R  ERH
2
7. Conceptual

8. Let Q be the charge on each drop, then

1 Q
V
4 0 R
Radius of bigger drop
1
3
R'  N R [Use volume conservation]

1 NQ
V '
4 0 13
N R
2
 N 3V
q2  1 1 
9. U1   4  2
4 0  a 2a 
2
q 
 4  2 
4 0 a 

Final kinetic energy of each particle will be equal and can be given by,

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Ui
K e  K p 
4

q2  1 
 1
4 0 a  2 2 


1  Q1 Q1 
10. V1  
4 0  a 2a 

1  Q2 Q 
V2    1 
4 0  a 2a 

W  q V1  V2 

q  Q1  Q2 Q1  Q2 
 
4 0  a 2a 

W
q  2 1 Q  Q 
1 2
4 0 a 2
11. Conceptual

12. The square BCED is forming a balanced Wheatstone bridge, hence C and D have same temperature
So no heat flows from C to D.
Now H  H1  H 2
ky A k A k A
TA  TB   x TB  TE   y TB  TE 
l 2l 2l
 0.92(100  TB )  0.46(TB  60)  0.92(TB  60 0 )
 TB  760 C

13. For process 1  2

 pV 1 2  p2V1 …………..(i)
For process 3  4
p2 P1

V3 V4

 p2V4  pV
1 3 ……….(ii)
Work done =Area under loop 1234.
1
W   p2  p1  V3  V2   V4  V1  
2
1
  p2V3  p2V2  p2V4  p2V1  p1V3  p1V2  p1V4  p1V1 
2
1
W   p2V3  p2V2  p1V4  p1V1 
2
1
 nR[T3  T2  T4  T1 ]
2

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1
  3  8.314  [2500  700  1100  400]
2
 W  13718 J  13.718 KJ
 W  13718 J  13.718 KJ
14. Conceptual
qin 2C
15.  
0 0

dV
16. V  Ar 2  B, E   , E  2 Ar
dr
  q
 E.ds  0
4  r3
2
2 Ar  4 r   .    6 0 A
3 0
17. Conceptual
dV
18. E
dr
 dV   E dr
r

 V    Edr
R
r
 dr
 
2 0 R r
 r
 In  
2 0  R 
 R
 In  
2 0  r 
19. Conceptual

20. Conceptual

21. Conceptual

T
22. t
4
T ml 2
T  2 , I
pE 2
p  qL
k  Q  2Q 
23. Fe      1
r2
T cos   mg      2 
T sin   Fe      3
From equation (2)and (3)
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Fe r
tan    2
mg l

1  2Q 2  mgr
 
4 0  r 2  l
1
 Q2L 3
r  
  O mg 
N  3
24. Equation of line is given by
p  p0 V  0

0  p0 V0  0
 V 
 p  p0  1   ………………………(1)
 V0 
From ideal gas equation,
pV  nRT
 V 
p0 1   V
pV V0 
T  
nR nR
 V 
p0V  1  
 V0 
 n  1 ....... 2
R
From Eq.(2)
 2V 
p0  1  
V0
dT    dV
R

dV R
  ………….(3)
dT  2V 
p0 1  
 V0 
For maximum temperature

dT
0
dV
V0
V 
2
pV
Tmax  0 0 ……………..(4)
4R
N  4
25. The rate at which the internal energy of the sphere increases is
d
C  I 2 R  K    0 
dt
Where   temperature of sphere,
0  temperature of surrounding= 00

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d
C  I 2 R  K
dt
d 1
2
 dt
I R  K C
 t
d 1
0 I 2 R  k  c 0 dt
kt
I 2R   
  1  e c

k  
I 2R
 max 
k
2
1 I R
For    max 
2 2k
I R I 2R
2

2k

k
1  ekt c 
C
 t  In 2
k
N  2
26. V  10r  10 x 2  y 2  z 2
dv 10(2 x )
Ex   
dx 2 x2  y2  z2
10 x 10  3
   3 2
x2  y 2  z2 32  4 2  52
Similarly,
E y  4 2
Ez  5 2

E  Ex iˆ  E y ˆj  Ez kˆ   2 3i  4 j  5k
 
a  b  c  2

27. Flux through surface can be calculated using concept of solid angle.
 1 
  2 1  cos    2  1  
 2
 1 
 Solid angle subtended = 2  1  
 2
q
The flux    for 4 solid angle 
0
 1 
The flux    for 2  1   Solid angle
 2
q  1  q  1 
 2 1     1 
4 0  2  2 0  2

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 N=2

28. Conceptual

29. Due to the induced charges of sphere, its potential will re\main zero because net induced charge is
Zero, Potential of sphere will be due to only eight discrete charges.
kq 16kq
V 8 
( 3 a 2) 3a
 N  16

30. E 

 F Q 1   r 
r

q 4 0 r 3
N  4

CHEMISTRY

32.


H+ 

TCP
More stable
+ carbocation
KCP H
ClΘ
Cl Cl


Easy to form More stable

product alkene

33.

H


Cl Θ

Cl

36.

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H2O Hg2+/ H+ / H2O conc.H 2SO4

Mg 2C3 CH3 C CH Me C Me

O

40. Incorrect statements are C and D only, correct choice is not available.
41.
Br Br
Ph H Br2
C C Ph CH CH CH3
H CH3 1 Alc. KOH
 2  NaNH 2

Ph CH3 H2
C C CH3
Lindlar's Ph C C
H H
Catalyst

49. (2)
H H
H H

O O O
  
O O O O O O O

Acidity order of highlighted hydrogen atoms.

Observed specific rotation (sample)
50. Optical purity 
Specific rotation of pure enantiomer
676
  100  50%
13.52
ee = 50% means 50% sample is racemic mixture and 50% pure enantiomer.
51.
Br

1. Na, liquid NH3 2. Br2 (excess) Br

Br
Br

Br

3. Alc. KOH

cis / trans
2isomers

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52.
O
1. O3 / Zn / H2O C
H
2. KMnO4
KMnO4
3. NaOH, electrolysis
4. Cr2O3,770 K, 20 atm
O
C
OH
Cr2O3
NaOH
770 K
Ekectrolysys
20 atm

56.  i   2,  ii    2  ,  iii   1 ,  iv    2 

P  X Y  Z  7
57. 7  a, c, e, h, i, j , k 

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