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ISR.

IIT-STAR-CO-SC(MODEL-B) Date 07-04-24


Time: 3:00Hr CTM-34 Max.Marks:300

PHYSICS
1-10 D D C A B C A C A B

11-20 B D A D C A A A C B

21-30 400 190 2 1 11 2 3 6 500 320

CHEMISTRY
31-40 A C C B C D A A D B

41-50 B A D A D C D C A A

51-60 8 8 2 8 8 5 2 6 2 8

MATHS
61-70 A B D C C B D C D B

71-80
C D A A A B A C B D

81-90
5 3 2 8 2 1 1 8 4 1
HINTS
PHYSICS
1. (D)
F. Δ
 F  YA.
Y = A.Δ 

1
=21011 A
100
1 F 1 2 109 A
n= 
2  2 Ad 4 A  7.7 103
n = 127.5 Hz
2. (D)

kdq
V 
Lx
kQ L dL kQ
V 0  ln2
L L x L
Q
V ln2
4 0 L

3. (C)

(T  dT )   g dz  T  0
 dT    g dz
also
T   v2
as v is independent of z , dv  0
   g dz  v 2 d 
 z
d g
   2  dz
0
 v 0
 g 
 2  z
v 
   0 e
4. (A)
2 

 5
  10 cm
 3 5 7
Positions of antinodes are, x  , , , ,......
4 4 4 4
5. (B)

1
V
d2
4qa 2qa
2

x ( R  x)2
x
R  x 
2
2R
x
 2 1 
6. (C)
For propagation of sound in liquid

B
v i.e., B = v2 

But by definition B = – V(  P/  V)
P V ( P )
So – V  v 2  , i.e.  V =
V v 2
Here  P = h2  g – h1  g
= (75 – 200) × 13.6 × 981
= – 1.667 × 106 dynes/cm2
(6 103 ) (1.667 10 6 )
So V= = 0.75 cc
0.81 (1.280 10 5 ) 2
7. (A)

2  kx 2
 a 
P 1  a0 e 
    
P0
 a0  4  a 0 
1 n2
Therefore e 2kx  , 2kx   n4 , x 
4 k
8. (C)

0.001 m g h
P
100 t
P 2.5 106 2.5 102 125
r  8
   9.9522  3.15m
4 I 4  3.14  2 10 8  3.14 12.56
9. (A)

P  P0 cos  kx  t 
1
cos k 
2
 2
k  2n  
3 
v
f

10.(B)
  4 a 2  4 b2  4 c 2 
VB     
 4 0b 4 0b 4 0 c 
  a2  b2 
VB    c
0  b 

2  1
11. (B) P0 = B.K.S0 = B   S0 P0 
   
Thus, pressure amplitude is highest for minimum wavelength, other parameters B and S0 being same for
all. From given graphs,  3 <  2 <  1. Hence, correct answer is (B)
12. (D) x = A sin (kx –  t)
d
Pex =  B = – BAk cos (kx –  t)
dx
amplitude of Pex = BAk
2 
= (5 × 105) (10–4 )   = BAk
 0.2
 2  
= (5 × 105) (10 –4)  2
 = 5  × 10 Pa
 0.2 
So correct answer is (D)
Y 4  1011
13. (A) vs = = 4
= 2 x 103 m/sec.
 10.0  10
2 l 2  100
t= = = 0.1 s
v 2000

14. (D) The pressure amplitude is

3 2
2.0  10 N/m
P0 = = 10–3 N/m2.
2
The displacement amplitude s0 is given by
P0 = B s0 k
P0 P0 
or, s0 = 
Bk 2 B
103 N / m 2  (40  10 2 m)
=
2  3.14  2 105 N / m2
= 3.185 × 10–10 m.

15. (C) As I = ( p 20 / 2v ) ; = p0    2v

So p0  (10 12 )  2  1.3  332


= 2.94 × 10–5 N/m2
Now as p0   v  A
p0 2.94 105
A= = 3
= 1.085×10 –11 m
 v 1.3  332  (2 10 )
From this it is clear that ear is extremely sensitive detector of sound waves as it can respond to
amplitude about (1/10)th the size of an atom!
16. (A)

With end correction for closed organ pipe


 
  L  e, and for open organ pipe  L  2e2
4 2
So 4  L  e1   2  L  2e2 
Now e1  0.6 r1 and e2  0.6 r2
2 L  4  e2  e1 
L  2  e2  e1   2  0.6  r2  r1 
L  1.2  r2  r1 
17. (A)

Kq 2
U   QV
d
KP Kqd
V  2  2
D D
2
Kq KQqd
U  
d D2
1
Where K is
4 0

18. (A)
V 1 Y
f0  
2L 2L 
1 9.27 1010
  4.88kHz  5kHz
2  0.6 2.7  103
19. (C)

1
 l0  11
4
2
 l0  27
4
 
 2 1 16
4
 1 1 
v    0.64 m
 256 512 
 v  512  0.64 m / s
 328 m / s
20. (B)
 2

2 3
4
  m
3
4
 v   240  320 m / s
3
3rd harmonic f3  3 f 0
240
f0   80 Hz
3

21. 400
v 11
 30  l1  m
4 l1 4
v 3
 110  l2  m
4 l2 4
 l  2 m  200 cm
So change in volume V  A l  2 ( 200 )  400 cm3
 mass of the water poured = (V )  w  (400) (1)  400 g
22. 190

For maximum possible sound intensity, pressure amplitude of wave will be equal to
atmospheric pressure, i.e.,
P0 = P = 1.01 × 105 N/m2
p 20 (1.01  105 ) 2
I=  = 1.18 × 107
2v 2  1.3  332
 107
SL = 10 log  10 log 12 = 190 dB
0 10
23. 2.00

kq 2 kQq kQq
0 U   
a a 2a
 1 
q  Q 1  
 2

Q
q  2
2 1

24. 0.48

 60
v   40 ms 1
k 1.5
T   v 2  3104  40  40  0.48 N
25. 11.00

1 T 1 Y A  ( t )
n 
2l  2l 
1 2 1011 10 6 1.21105 (20 )
 n 11 Hz
2 (1) 0.1
26. 2.00

 I 
20  10 log10  12 
 10 
I  10 10 W / m 2
B 4 104
v   200 m / s
 1
2
 Pmax   2Iv
 2  10 10 1 200
Pmax  2 10 4 N / m 2
27. 3.00


Here 5  42  0.3 10    36 cm
4
 Pressure amplitude at middle of pipe is
 2  3 P0
P  P0 sin Kx  P0 sin   21 
 36  2
28. 6.00
l
1
Total energy E   dmv 2
0
2
l l
1 1m 1
  dmAx 2 2     dx. A2 sin 2 kx.  2  mA2 2
0
2 0
2 l  4
3 T 3 Tl
  2 f  2 
2l  l m
1 9 2 Tl
 Energy  ma 2 . 2 .
4 l m
2 2
9a T
Energy 
4 l
3 a 2 2T
So, energy between two consecutive nodes, is .
4 l

29. 500.00

30. 320.00
Drumming frequency = 40 cycle/min = 40 cycle/60 sec
1 60 sec 3
Drumming time period = = = sec/cycle
f 40 cycle 2
(time duration between consecutive drumming)
During this time interval, if sound goes to mountain and comes back then echo will not be heard
distinctly.
l

3 2
= ...(1) l
2 v
1
Now, if he moves 90 m. This situation arises at t = 60 cycle/min, T = = 1 sec/cycle
f
2 (   80)
so for this case 1 = ...(2)
v
Solving equation 1 and 2
We get  = 240 m
v = 320 m/s

Chemistry
31 (A)
The formation of micelle only above certain temperature called Kraft temperature suggests positive S
of micelle formation which even overcome effect of positive H of micelle formation. Besides kinetic
effect also become important at high temperature.
32 (C)
More liquifable gases more easily adsorb
33 (C)
x ap

m 1  bp
m 1 a
 
x ap b

1
y= xC
a
34 (B)
Theory based
35 (C)
mm of CH3 COOH adsorbed = 2
number of molecule = 2 × 10–3 × 6 × 1023 = 12 × 1020
3 106
area adsorbed by each molecule =
12 1020
= 0.25 ×10–14 cm2
= 25 × 10–16 cm2 = 0.25 × 10–14 cm2
= 0.25 nm2
36 (D)
37 (A)
Dispersion medium moves towards anode
 dispersion medium has –ve charge
 dispersed phase has +ve charge
 Fe(OH)3 cannot cause coagulation
38 (A)
Theory based
(II) Colloidal particles will produce.
39 (D)
(A) AgI / Ag+ positively charged solution (excess AgNO3 )
(B) Factual information
(C) Tyndall effect is more dominating in lyophobic solution
(D) Extent of physisorption decreases with increase in temperature.
40 (B)
Fe(OH)3 is positively charged colloidal sol hence coagulation will occur at cathode.]
41 (B)
S1  3s
S2  3d for unielectronic species energy depends only on 'n'
S3  4s  S1 = S2 = S4 < S3
S4  3p
42 (A)
1mm3 = 10–9 m3
1m3  103 litre
10–4 m3  10–6 litre
1.2 109  N A
number of particle =
2.4 1013
1
= 1022  6 1023 = 30
2
43 (D)

44 (A)
(A) True
(B) Argyrol sol in siliver sol.
(C) KI is in excess, sw we get negative sol.
(D) Lyophillic colloid are added to protect lyophobic colloid.
45 (D)
46 (C)
(A) because of solution formation number of sulphur particles will be less in water.
(B) CMC  size of hydrophobic portion.
(C) it is applicable for limited range of pressure.
(D) CO2 is non polar having more molecular mass so will be adsorbed more and replace O2 (non polar
gas with less molecular mass)
47 (D)
Theory based
48 (C)
Theory based
49 (A)
50 (A)

51 (8)
1 litre gold sol will require = 1068 mg of AlCl3
Molar mass of AlCl3 = 133.5 gm/mole
1068
mm of AlCl3 required = = 8 mm / lit.
133.5
52 (8)

53 (2)
x 1
log = log K + log P
m n
x
log P = n log + log K
m
3 K(100)1/n

1.5 K(25)1/n
2
2 = 22/n  =1n=2
n
54 (8)
2.5 L is coagulated by = 20 mm
20
1 L is coagulated by = =8
2.5
55 (8)
56 (5)
100 ml is coagulated by 0.5 MM
1000 ml is coagulated by 5 MM
57 (2)
2
Millimole of NaCl for 1 litre = 10  1117 = 2
1117
58 (6)
x
= KP1/n
m
1/n
0.15  2.5  1 1
    2/n
0.30  10  2 2
2
1
n
n=2
x
 K(81)1/n
m
0.8538
= 0.8538 = K × 9  K =
9
x 0.8538
 K  (4)1/ 2 = 2
m 9
0.8538  2 1000
mm adsorbed = 6
9

59 (2)
For 400 ml Fe(OH)3 millimoles of KCl req = 6
6
For 1000 ml Fe(OH)3 millimoles of KCl req = 1000 = 15
400
1
Coagulation power =
15
30
= =2
15

60 (8)
Fe2O3 · xH2 O sol   (+) ve Sb2S3 sol  (–) ve
Ag sol  (–) ve Cu sol  (–) ve
Blood  (+) ve basic dye  (+) ve
sol of clay  (–) ve sol of starch  (–) ve
sol of sodium stearate  (–) ve sol of sodium laurylsulphate  (–) ve
Acidic dye  (–) ve sol of Aluminium
hydroxide (+) ve

MATHS
61. R lies on the circle with P and Q as end points of diameter , PQ = 5 hence radius 2.5
1 14
PQR  . b . h  7   2.8  r
2 5
Hence no such triangle is possible.
62. We know that reflection of orthocentre about any side of a triangle lies on the circum
circle.
 reflection of H(5,8) about the line x  y  0
i.e., (8,5)lies on circumcircle whose centre is (2,3). Therefore its equation , , is
( x  2)2  ( y  3) 2  (8  2) 2  (5  3) 2  40
1 9 cos3  8
63. ABC  BC 2 sin 2 = 
2 sin  5
5
Since sin   , cos   2
3 3
64.  x  5 2  16 y comparing it with x 2  4 ay ,
65. The vertex is the middle point of the perpendicular dropped from the focus to the

directrix.

66. y2 = 4x + 4y

 (y – 2)2 = 4(x + 1)

focus (0, 2)

67. y-axis is major axis  f (4 a)  f (a 2  5)


 a2  4a  5  0 ( f is )
 a  (1,5)

1 1   1
68. p  cos t , sin t  & Q  0,  
2 3   3
5 2 13
PQ 2  sin 2t  sin t 
36 9 36
1 4
 PQ 2   0  sin t  5
9 3
max of  PQ 2    max  PQ  
20 20

69. x 2  y 2  1; x 2  2 y 2  4

Let R ( x1 , y1 ) is pt of intersection of tangents drawn at P,Q to ellipse

 PQ is chord of contact of R ( x1 , y1 )

 xx1  2 yy1  4  0
This touches circle  r 2 (2  m2 )  n2

 1( x12  4 y12 )  16

3
 x 2  4 y 2  16 is ellipse e  ; LL1  2
2

70. Foci   ae,0


  a2  b2 ,0 
  cos 2   sin 2  , 0 
  1,0
b2 25  b 2
71. For ellipse a 2  16  e  1 
a2 5

 
focii    ae, 0    25  b 2 ,0 
b2 5
For hyperbola, e  1 
a2 4
 focii    ae,0     3,0 

 25  b 2  3  b 2  16
72. The given equation can be written as
2 2
 x  4 
 y  3 1
16 9
16  9 5
Therefore, the eccentricity is given by e  
16 4
2b 2
73. 8
a
 b 2  4a ------------- (1)
and 2b  ae
ae
b ------------- (2)
2
From eq (1), we have a 2  e2 1  4a
4
a ------------- (3)
e2  1
From eq (1) and (3), we have
a2e2 2
 b  4a
4
16
a ------------- (4)
e2
From eq (3) and (4), we have
4 16
 2
2
e 1 e
 e2  4e2  4
2
e 
3
74. Let the parallel tangents be y  mx  9m2  49
2 9 m 2  49
2
1  m2
5
 m
2
75. Normal at ' ' is
x y
cos   sin   1  0
4 2
It passes through (4,2)
 cos   sin   1
76. Foci of the ellipse = (  7 , 0)

x x
77. y , x0 = ,x  0
1 x 1 x

 dy  1
,x  0 = 1
, x0 thus dy
= slope of tangent is +ve for all x
dx (1  x)2 (1  x)2 dx
a
 slope of normal is –ve or  ve i.e., both a&b have same sign or ab> 0
b
x  3
78. Tangent at (1,1) to the given curve is y 
2
Solve with curve we get x  1 or x  9 / 4
Now x=9/4  y  3 / 8
79. y2  a  n  1 nx n 1  nb  n  1 x  n  2

1
80. 5 f  x   3 f    x  2... 1
 x
1
Replacing x by
x
1 1
5 f    3 f  x    2...  2 
x x
3
5  1  3   2   16 f  x   5 x  4
x
5x 3 1
 f  x   
16 16 x 4
5x 2 3 x
y  x f  x   
16 16 4
dy 10 x 1  dy  10 1 7
      
dx 16 4  dx  x 1 16 4 8

81. Centre of the circle is (-5/2,0) and slope of the line is 2


Therefore the equation of the line is 2x-y+5=0
82. C1 1,3 is centre of given circle C2  2,1
r1  1  9  6  2 r22  BC22  BC12  C1C22
 45 9
r2  3

83.  4, y  be the mid point


 equation of chord is S1  S11

 yy1  4 x  y12  16

Given slope =2  y1  2
1 1 1
84.  
AF FB a

1 1 1 1
     a = 2  LR = 8
a 3 6 2

x2 y2
85. If y  mx  c is tangent to   1then
a 2 b2
C 2  a2m2  b2
x2 y2
y  4 x  c,  1
4 1
C   65
86. 1 2 3 4  2n
cos(1 2 3 4) 1
87. Equation of chord of circle with midpoint (h, k) is xh + xk = h2 + k2 or
 h  h 2  k2
y  x  , it touches the hyperbola
 k  k
f  x  h  f  x
89. f '  x   Lt
x 0 h
f  x. f h  f  x
f '  x   Lt
x 0 h
f  h 1
= f  x  Lt
x 0 h
f  h   f  0
= f  x  Lt
h 0 h0
= f  x f ' 0
90. f  x   x  cos x  2
f  0   3  g  3  0
1
g  f  x   x  g '  f  x  
f ' x
Putting x  0
1
g '  f 0 
f ' 0
1
 g '  3  1
1  sin x

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