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Sec: SR.

IIT_*CO-SC(MODEL-A&B) PTM-14 Date: 24-12-22


Time: 3HRS JEE-MAIN Max. Marks: 300
KEY SHEET
PHYSICS
1 A 2 A 3 D 4 C 5 C
6 D 7 B 8 D 9 B 10 B
11 C 12 D 13 A 14 C 15 C
16 C 17 D 18 D 19 D 20 C
21 2 22 1 23 27 24 4 25 2
26 25 27 20 28 200 29 45 30 6

CHEMISTRY
31 C 32 C 33 B 34 D 35 D
36 C 37 D 38 D 39 C 40 D
41 A 42 A 43 A 44 C 45 D
46 B 47 D 48 A 49 B 50 B
51 4 52 5 53 4 54 6 55 7
56 5 57 4 58 4 59 4 60 4

MATHEMATICS
61 B 62 C 63 D 64 C 65 C
66 A 67 A 68 B 69 C 70 C
71 D 72 C 73 B 74 A 75 B
76 C 77 B 78 A 79 C 80 C
81 210 82 8 83 7 84 722 85 -3
86 -171 87 625 88 2 89 61 90 2
Narayana IIT Academy 24-12-22_SR.IIT_*CO-SC(MODEL-A&B)_JEE-MAIN_PTM-14_KEY&SOL
SOLUTIONS
PHYSICS
1. At any instant t, the wave equation will express the variation of y with x which is equal to the shape
of the string at an instant t.
2. In a wave equation, x and t must be related in the form (x  v t) .
1
We rewrite the given equations y
1  (x  v t)2
1
For t  0, this becomes y , as given
(1  x 2 )
1 1
For t  2, this becomes y 2
  2v  1 or v  0.5m / s .
[1  (x  2v) ] [1  (x  1)2 ]
VO2  O2  VH 2  H 2
3. Density of mixture   mix 
VO2  VH 2

V  O2   H 2   O2   H 2
  (since VO2  VH 2  V )
2V 2
 H 2  16  H 2 1
  8.5  H 2  v
2 

Vmix H2  H2 2
   
VH 2 mix 8.5  H 2 17
 
4. Speed = n =  As ab  
n(4 ab)  4 n  ab
 4

Path difference between b and e is 3


4
2 2 3  3
So the phase difference = . Path difference = . 
  4 2
5. Frequency of first over tone of closed pipe = Frequency of first over tone of open pipe
3v v 3 P 1 P  P 
     v  
4 L1 L 2 4 L1 1 L2 2   

4 L1 1 4L 1
 L2  
3 2 3 2
2 2
Er  Ar   v2  v1 
6.      1/ 9
Ei  Ai   v1  v2 
E
Therefore, t  8/ 9
Ei
ga
7. Acceleration of wave-1 w.r.t. string   g 
2
ga
Acceleration of wave-2 w.r.t. string   g 
2

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Narayana IIT Academy 24-12-22_SR.IIT_*CO-SC(MODEL-A&B)_JEE-MAIN_PTM-14_KEY&SOL
l
Time for same horizontal level : t 
2 gl
arel  0
1 l l
Height raised by the lift  g 
2 2g 4
8. y  a0 sin  kx  sin t   
kL kL  1
 n and   n  
3 2  2
3
 n  1, k 
L
9. When the microphone crosses the equilibrium position with maximum speed v0 towards the source
 v 
S, the frequency detected becomes maximum. (i.e.,) f max  f 0 1  0  , v – speed of sound.
 v
Similarly, when it crosses the equilibrium position away from the source, frequency detected
 v 
becomes minimum.(i.e.,) f min  f 0  1  0 
 v

 v v  2f v 2v v 330 1 1
f max  f min  2  f0 1  0  1  0   0 0 v0     ms
 v v v 2 f0 f0 660 2
Let ‘a’ be the amplitude of SHM so that the angular velocity
v0 v v T 2 1 0.5
 or a  0  0 a    0.16m
a  2 2 2 3.14
p0 1 n2
10. P and pa 2 , hence e 2kx  , 2kx  n4 , x 
4 4 k
p 2.5  106 2.5  102 250
11. r  8
   10  3.15m
4 I 4  3.14  2  10 8  3.14  25
12. The pressure amplitude is =Bak
13. Let S be source of sound and P the person or listner.
The waves from S reach point P directly following the path SMP and being reflected from the
ceiling at point A following the path SAP . M is mid-point of SP (i.e. SM  MP) and  SMA  90 o
Path difference between waves x  SAP  SMP
We have SAP  SA  AP  2(SA )

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Narayana IIT Academy 24-12-22_SR.IIT_*CO-SC(MODEL-A&B)_JEE-MAIN_PTM-14_KEY&SOL

= 2 (60 2  25 2 ) =130 m
 2 [(SM )2  (MA )2 ]
 Path difference = SAP – SMP  130  120  10 m
Path difference due to reflection from ceiling = 
2

 Effective path difference x = 10 
2
For constructive interference
 
 n   (2n  1)  10 (n  1, 2, 3 ....)
x  10 
2 2
2  10 20 20 20 20 20
 Wavelength    . The possible wavelength are   20 , , , , , …..
(2 n  1) 2n  1 3 5 7 9
 20 m , 6 .67 m , 4m, 2 . 85 m , 2 . 22 m , …..
 I 
14. dB  10 log 10  ;
 where I 0  10 12 Wm 2
 I0 
I  I
Since 40  10 log 10  1   1  10 4 ....(i)
 I0
 I0 
I  I2
Also 20  10 log 10  2 
   10 2 ....(ii)
 I0  I0
I2 r2
  10  2  12  r22  100 r12  r2  10 m { r1  1m }
I1 r2
15. Calculate phase difference at each point and check for intensity

16. Here 5  42  0.3 10    36 cm
4
 Pressure amplitude at middle of pipe is
 2  3P
P  P sin Kx  P sin   24  
 36  2
17. The frequencies present in the modulated wave are fC , fC  f S and fC  f S
18. Conceptual
1 1
19.  RC 
fC fm
 m2   12 
PSB  PC    1000    500W
20.  2  2
1
PUSB  PSB    250W
2
 
21. y1  10 sin  3t   ...(i)
 3
and y 2  5[sin 3t  3 cos 3t]
1 3 
 5  2   sin 3t   cos 3t 
 2 2 

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Narayana IIT Academy 24-12-22_SR.IIT_*CO-SC(MODEL-A&B)_JEE-MAIN_PTM-14_KEY&SOL
   
 10 cos sin 3t  sin cos t 
 3 3 
   
 10 sin  3t   ... (ii)
  t 
(  sin(A + B) = sinA cosB + cosA sinB)
Comparing equation (i) and (ii) we get ratio of amplitude 1 : 1.
22. mt  m 2
1  m22  m32   0..95  1
23. As with decrease in tension of the string the number of beats are decreasing hence
2  T 
nS  nT  8  nS  208 Hz     208
2  0.25  102 
T  27.04 N
24. Let the velocities of cars 1 and 2 be v1 m/s and v2 m/s respectively.
 Apparent frequencies of sound emitted by car 1 and 2 as detected at end point are
V V
f1  f 0 , f 2  f0
V  V1 V  V2
330
 300  300 ,
330  V1
330
360  300
330  V2
 V1 = 30m/s and V2 = 55m/s
The distance between both the cars just when the 2nd car reaches end point B (as shown in figure) is
100 m  V2t  V1t  t  4 s
5  103
25. The linear mass density is   2
 1.0  102 kg / m
50  10
T
The wave speed is v 

 
Thus, the tension is T   v 2  1.0  10 2  6400  64 N

T/A
The Young’s modulus is given by Y 
L / L
TL 64  0.50
The extension is, therefore, L    2mm
AY 1.0  106  16  109
4
26. cos 
5

5  4

mg  2T cos
mg T
T ,v   100m / s,
2cos 

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Narayana IIT Academy 24-12-22_SR.IIT_*CO-SC(MODEL-A&B)_JEE-MAIN_PTM-14_KEY&SOL
3
 6m
2
  4m
3 T
  25 Hz
2L 
T
27. v

For equilibrium Mg  mg sin 30  T
m Mg M (9 .8 )
 M   100  
2 9 .8  10  3 9 .8  10  3
 100  M (1000 )  M  10 kg and m  20kg
28. The situation is shown in the fig.

Both the source (engine) and the observer (Person in the middle of the train) have the same speed, but
their direction of motion is right angles to each other. The component of velocity of observer towards
source is v cos 45  and that of source along the time joining the observer and source is also v cos 45  .
There is number relative motion between them, so there is no change in frequency heard. So frequency
heard is 200 Hz.
29. Because the tuning fork is in resonance with air column in the pipe closed at one end, the frequency
is n  (2 N  1)v where N = 1, 2, 3 .... corresponds to different mode of vibration
4l
putting n = 340Hz, v = 340 m/s, the length of air column in the pipe can be
(2 N  1)340 (2 N  1) (2 N  1)  100
l  m  cm
4  340 4 4
For N = 1, 2, 3, ... we get l = 25 cm, 75 cm, 125 cm ...
As the tube is only 120 cm long, length of air column after water is poured in it may be 25 cm or 75
cm only, 125 cm is not possible, the corresponding length of water column in the tube will be (120 –
25) cm = 95 cm or (120 – 75) cm = 45 cm.
Thus minimum length of water column is 45 cm
30. Frequency of sound heard by the man from approaching train
 v  320 
na  n    240    243 Hz

 v  vs   320 4 
 v  320 
Frequency of sound heard by the man from receding train nr  n    240    237 Hz

 v  vs   320  4 
Hence, number of beats heard by man per sec
 na  nr  243  237  6

CHEMISTRY
31. Atomic number
32. Anions size > cations
1
33. EN
size
ch arg e
34. HE
size
35. Paramagnetic
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Narayana IIT Academy 24-12-22_SR.IIT_*CO-SC(MODEL-A&B)_JEE-MAIN_PTM-14_KEY&SOL
36. Conceptual
37. Conceptual
38. Conceptual
39. Conceptual
40. X  B2 H 6
41. Conceptual
42. Conceptual
43. Conceptual
44. Conceptual
45. Conceptual
46. Mn 2 has d 5 and Cr 3 has d 3 configurations
47. Conceptual
48. Conceptual
49. Stability of higher oxidation state increases in transition elements.
50. Conceptual
51. He, Be, N & Ne
52. Conceptual
53. X  1, Y  1.5
54. MgO, CaO, SiO2 , Fe2O3 , SO3 , Al2 O3
55. Conceptual
56. Conceptual
57. Conceptual
58. Al , Ga, Ge, Be
ch arg e
59. HE
size
60. Thermal stability : BeCO3  MgCO3  CaCO3  SrCO3  BaCO3
MATHS
61.

62.

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63.

64.

65.

66.

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81.

82.

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83.

84.

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