Sri Chaitanya IIT Academy provides top JEE preparation in India

Sri Chaitanya IIT Academy.
, India
A.P, TELANGANA, KARNATAKA, TAMILNADU, MAHARASHTRA, DELHI, RANCHI
A right Choice for the Real Aspirant
ICON CENTRAL OFFICE, MADHAPUR - HYD
Sec: Sr.Super60(In Coming) WTA-38 Date:01-08-21
Time: 09:00 AM to 12:00 2017_P2 Max.Marks:183
KEY SHEET
PHYSICS
1 A 2 D 3 A 4 B 5 C
6 A 7 D 8 BCD 9 ABCD 10 AD
11 ACD 12 ACD 13 ABCD 14 ACD 15 C
16 A 17 A 18 B
CHEMISTRY
19 A 20 D 21 C 22 D 23 B
24 D 25 B 26 ABC 27 C 28 BCD
29 B 30 D 31 A 32 D 33 B
34 C 35 C 36 A
MATHS
37 B 38 A 39 A 40 C 41 C
42 C 43 A 44 ABD 45 ABCD 46 ABC
47 BCD 48 BC 49 ABCD 50 ACD 51 B
52 D 53 B 54 D
Sri Chaitanya IIT Academy 27-06-21_Jr.Super60(In Coming)_Jee-Adv_2017_P2_UTA-02_Key & Sol’s
SOLUTIONS
PHYSICS
1. A
 dn   dn 
Solution: i    e  3.2 10 3    1.6 10 19 
 dt   dt 
dn
 2  1016
dt
2. D
Solution:
100 = 2 + 8 + 18 + 32 + 40
(n=1) (n=2) (n=3) (n=4) (n=5)
n2 0 25
rn  0.53  A  0.53 
z 100
1 1
 0.53  n  0.53   n 
4 4
( Bohr radius = 0.53A0 )
3. A
dV vr
Solution: E     0 0 and force on the electron
dr r
mv 2 v0 r0e nh
F  Ee. i.e  and mvr 
r r 2
2 2
mn h
 2 2 2  v0 r0e  r  n
4 m r
4. B
Solution: Let K be the initial kinetic energy of each atom. Maximum loss in KE takes
place in perfectly inelastic collision. From conservation of linear momentum
mu   mu   2mv  v  0
Where v = common velocity of after collision.
1 1 1
 Maximum possible loss in KE is K  mu 2  2  2m  0 2  2 mu 2  2 K
2 2 2
Minimum energy required to excite both the electrons is E  10.2  10.2  20.4eV .
For inelastic collision with two electrons excited
K  E  2 K  20.4  K min  10.2eV
5. C
Solution: As the accelerating potential difference is changed only the minimum
wavelength changes.
6. A
Solution: Cut-off wave length depends on accelerating voltage and characteristic
wavelength depends on nature of the target material
7. D
1 2  1 1
Solution: Using  R  z  1  2  2 
  n1 n2 
For K photon; n1  1, n2  2
Sec: Sr.Super60(In Coming) Page 2

1875 R 23
For metal A;  R  Z1  1   ; z1  26
4 4
3
For metal B; 675 R =  Z 2  12   ; z2  31
4
8. B,C,D
13.6 2 13.6 
Solution: K.E  2
eV , P.E  eV
n n2
for Hydrogen Z = 1 ; K  K f  K i
 1 1 
K .E.  13.6  2  2   10.2eV (decrease)
  2  1 
 1 1 
 P.E  2 13.6   2  2   20.4eV (increase)
  2  1 
nh
Angular momentum L 
2
h h
L   2  1   1.05 1034 J  s (increase)
2 2
9. A, B , C, D
Solution: The electron will not undergo elastic collision with the metal surface
10. A,D
ra
Solution: Tn   Tn  n3
Vn
Given Tn  8Tn  n1  2n2
1 2
11. A, C, D
Solution: Conceptual
12. A,C,D
Solution: In Bohr’s model of hydrogen atom
1 1
R  n2 , v  , T  n 3 and E  2
n n
T V
VR  n, TE  n,  n ;   n
R E
13. A,B,C,D
SOL : Since reduced mass is
m1m 2 m
 
m1  m 2 2
Now, energy is directly proportional to mass, so
E0  m
m
E   
2
E 1
 
E0 2
Since, E 0  R 0 hc

CM
θ'  m 
So, Rydberg constant is

E0
R0  m
hc
R 
R  1
  
R0 m 2
Radius of orbit is
n 2h 20
r
me2 Z
So, for n  1, Z  1 , we have
h 2 0 1
r0  2

me m
1
r 

r m
  2
r0 
Velocity of electron in first orbit is
e2
v
2h0
Which is independent of mass, hence for positronium atom and hydrogen atom
velocity of electron is same in both cases.
14. A, C, D
SOL : From n  3 to n  2
1  1 1 
 2  2 
  n1 n 2 
Since, E  hc

 1 1 
 E 2 2
 n1 n 2 
For a photon of energy E, momentum p is
E
p , where v is the speed of light
V
1 1 3

1 12 22
   4
2 1 1 5
2
 2
2 3 36

1 27
 a
2 5
hc
E 1 1  2 5
Further,    
E 2 hc 1 27
2
5 1
c  
27 a
p E 5
So, b  1  1  c 
p2 E 2 27
15. C
Solution: Energy given by H-atoms in transition from n  2 to n  1 is equal to energy
taken by He atom in transition from n  2 to n  4
n=2 3.4 eV
E  10.2 eV
n=1 13.6 eV
H atom
n=4 3.4 eV
n=3 6.04 eV
E  10.2 eV
n=2 13.6 eV
n=1 54.4 eV
He 
Z=2
16. A
Solution: Kinetic energy K  Z 2
2
K 1 1
K  H   
K He  2  4
17. A
Solution: a  n
2
x=0 x=a
a
2a h h
    ………………………(1)
n p 2Em
1
 E
a
1
E 2
a
18. B
Solution: From equation (1), we get
n2 h 2
E
8a 2 m

In ground state n  1
h2
 E1 
8ma 2
Substituting the values, we get
E1  8 meV
CHEMISTRY
19. A
Sol- Inversion is restricted when nitrogen is a part of ring.
20. D
Sol- Localised negative charge
21. C
Sol- reductive amination
22. D
Sol- It is nucleophilic acyl substitution and cyclopentyl amine is relatively strong
nucleophil
23. B
Sol- 20 -amines meets the given requirements
24. D
Sol-
NH2 N2Cl CN COOH

KCN
NaNO2
  
 H3O
HCl Cu2(CN)2  
CH3 CH3 CH3 CH3
O
COOH
 KMnO
4
O 
 
COOH
O
25. ACD
CH2NH2
Sol- 2 is most basic due to electron of N is localized .

26. ABC
Sol- A) Conjugate acid is stabilised by resonance which is extended upto  NH 2 group
27. C
Sol-

CH3 CH3 CH3 CH3 CH3 + CH3
N N N
Nu Nu
+
28. BCD
NH
||
Sol- (CH 3 )3 N < CH 3 NHCH 3 < H 2 N  C  NH2
29. B
Sol- Both dissolves in either but amine is extracted with HCl due to its basic nature.
30. D
Sol-
OH O O
+


C  NH 2  3 

 C  NH  C   NH3
31. A
CH 3
N
3 2
N
N (CH 3 ) 2 CH 3
N
1 2
Sol-
32. D
Sol- 4 CH 3  CH 2  CONH (CH3 ) , CH 3  CONH  CH 2  CH 3 ,
H  CO  NH  CH  CH3
CH 3
H  CO  NH  CH 2  CH 2  CH 3 ,
33. B
Sol- Nitrogen labeled 3 is most basic as its conjugate base has maximum resonance
stabilization
34. C
Sol- proton will attack at Nitrogen numbered -3
35. C
Sol- primary amines react with Chloroform in basic medium to form foul smelling
compound Isocyanide.
36. A

Sol- intermediates formed are : C Cl3 & : CCl2

MATHEMATICS
37. Key : B
Hint : A1 : Selecting a pair of consecutive letters from the word CHENNAI
A2 : Selecting a pair of consecutive letters from the word JAIPUR
A3 : Selecting a pair of consecutive letters from the word NAINITAL
A4 : Selecting a pair of consecutive letters from the word MUMBAI
E: Selecting a pair of consecutive letters AI
1
 A4  5 42
Required probability  P    
 E  1  1  1  1 149
6 5 7 5
38. ANS;A
S 1 12C2
P  A P   .
B  A 4 51C2 1 11
Sol: P     
 A  P A P  S   P A P  S  1 12C2 3 13C2 1  3  13  50
        .  .  
 A  A  4 51C2 4 51C2  11 
39. ANS;A
Sol: Here n  99, p  q  1 / 2
By fact  n  1 p  50
P  X  r  is maximum when r  50, r  49
40. ANS;C
1 4C2
3 4C2
PE 
1  2C2 3C2 4C2 
   
3  4C2 4C2 4C2 
1 6 3
  
1  3  6 10 5
6
41. Key:C
Hint: E1  A wins the match at the end of 11th game
E2  B wins exactly one game
2 8
1 1 1
10
C2 .   .   . (2!)
E   2   3 6 9
P 2   2 9 2 8

 E1  10  1   1  10  1   1   1  11
C1      C2   .   .   2!
 2 3  2   3  6 
42 .ANS;C
Total prob (drawing red from B)
1  3 2 2 2  3  3 C2 2 3 C1  2C1 3 2 C2 4 
      5   5  5  
4  5 3 5 3  4  C2 4 C2 4 C2 4 
8 7
Where   ,  
10 10

 2
     14
Using Baye’s th. Req. prob =  4
1 3 
        29
4 4 
43. ANS;A In first 8 drawings we must get 3 biased, 5 fair coins and in the 9th draw we
 4 3 2 11 10 9 8 7 1 
must get a biased coin. Req. prob =  C
8
3 15  14  13  12  11  10  9  8  7 
44. ANS; ABD
1 9 1
(A) P  , q   1  qn 
10 10 2
1
 qn 
2
n
 9 1
    then least n=7
 10  2
9 9 81
(B)   
10 10 100
9 9 19
(C)  1  
10 10 100
1 9 9 1 81
(D)     
10 10 10 10 100
45. ANS:ABCD
1 4 1 2 1
A) Sol.    
2 6 2 6 2
1 2 1 4 1
B)Sol.    
2 6 2 6 2
12 4
   1
26 6
C)Sol.  
12 4 14 2 2
     
2 6 6 2 6 6
12 4
   1
26 6
D) Sol.  
12 4 14 2 2
     
2 6 6 2 6 6
46) ANS;ABC
 P  B1   0.4
. B1  having 2 defective,
Sol: P  B2   0.6
B2  having 3 defective.
 
p  A   p(one defective and 10 good in 11 draws and 2nd in 12th testing).
B
 1
 
p  A   p(2defective and 9 good in 11draws and 3rd in the 12th testing)
B
 2

   
p  E   p  B1  . BA   p  B2 . p  BA   1900
99
 1  2 
47. ANS;BCD
Sol:Let E1 be the event that one of first n urns is chosen, E2 be the event that (n +
1)th urn is chosen.
A be the event that two balls drawn are black.
n 1
P  E1   ; P  E2  
n 1 n 1
6
A C 1  A  5C 2
P    10 2  ; P    10 2 
 E1  C2 3  E 2  C2 9
A 1 2
P  E 2  .P   .
 E2  E
 2 1 n 1 9
P      n  10
A A  A  16 n 1 1 2
P  E1  P    P  E 2  .P   .  .
 E1   E2  n 1 3 n 1 9
48. P  X  2   1  p  X  0   p  X  1
n n
1 1
 1     n C1.  
2 2
P  X  2   0.96
n8
E E
49. ANS;ABCD p  E  p  H p    p  T p  
H T
2 4 1 2 58
 .  . 
3 9 3 5 135
50. ANS;ACD Sol: E1 = Event that the missile is intercepted
E = Event that the missile hits the target.
1 2 3 1
  
 P(E) = P  E1  .P  E / E1   P E 1 .P E / E 1   0  . 
3 3 4 2

3
1
Required probability =    1/ 8
 2
51 & 52. ANS;B ,ANS;D

A : She get a success
T : She studies 10 hrs : P (T) = 0.1
S : She studies 7 hrs : P (S) = 0.2
F : She studies 4 hrs : P (F) = 0.7
T S
A
F
P(A/T)= 0.8; P(A/S)= 0.6; P(A/F)= 0.4

Now, P(A)= P  A  T   P  A  S   P  A  F 

= P(T) .P(A/T)+ P(S).P(A/S)+ P(F).P(A/F)
= (0.1)(0.8)+(0.2) (0.6) + (0.7)(0.4)
= 0.08+0.12 + 0.28 = 0.48
P  F  A   0.7  0.4  0.28 7
P(F/A) =   
P  A 0.48 0.48 12

P FA   P  F   P  F  A

P F/A  
 
P A 0.52

 0.7   0.28  0.42  21
0.52 0.52 26
53 & 54.
1 1 1
53) P  E1   , P  E 2   , P  E 3  
2 4 4
1
 P X 
4
7
P (exactly two engines of the ship are functioning / X ) =
8
P  X  X1  7
54) P  X / X1   
P  X1  16

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Sec: Sr.Super60(In Coming) Page 2

Sec: Sr.Super60(In Coming) Page 3

So, Rydberg constant is

Sec: Sr.Super60(In Coming) Page 4

Sec: Sr.Super60(In Coming) Page 5

NH2 N2Cl CN COOH

Sol- 2 is most basic due to electron of N is localized .

Sec: Sr.Super60(In Coming) Page 6

Sec: Sr.Super60(In Coming) Page 7

Sec: Sr.Super60(In Coming) Page 8

Sec: Sr.Super60(In Coming) Page 9

51 & 52. ANS;B ,ANS;D

P(A/T)= 0.8; P(A/S)= 0.6; P(A/F)= 0.4

Sec: Sr.Super60(In Coming) Page 10

Sec: Sr.Super60(In Coming) Page 11

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