Sri Chaitanya IIT Academy.

, India
A.P, TELANGANA, KARNATAKA, TAMILNADU, MAHARASHTRA, DELHI, RANCHI
A right Choice for the Real Aspirant
ICON CENTRAL OFFICE, MADHAPUR - HYD
Sec: Sr. ICON ALL Date: 25-12-18
Time: 09:00 AM to12:00 Noon Max.Marks:360
KEY SHEET
MATHS
1 3 2 1 3 1 4 3 5 2

6 4 7 2 8 2 9 2 10 3

11 4 12 2 13 4 14 3 15 2
16 1 17 3 18 1 19 2 20 2

21 1 22 2 23 1 24 2 25 2

26 2 27 2 28 1 29 1 30 4

PHYSICS
31 4 32 1 33 2 34 2 35 3

36 4 37 1 38 1 39 2 40 1

41 4 42 3 43 2 44 4 45 4

46 1 47 2 48 3 49 1 50 1

51 2 52 3 53 2 54 3 55 3

56 4 57 1 58 3 59 1 60 1

CHEMISTRY
61 1 62 1 63 3 64 1 65 1

66 2 67 3 68 2 69 3 70 1

71 2 72 4 73 1 74 1 75 1
76 2 77 4 78 3 79 3 80 1

81 4 82 1 83 2 84 2 85 2

86 2 87 2 88 2 89 1 90 1
Sri Chaitanya IIT Academy 25-12-18_Sr.ICON ALL_JEE-Main_GTM-2_Key & Sol’s
SOLUTIONS
MATHS
1. A and b are roots of x cos q + y sin q = a ................... (1)
2 2
a - x cos q = ysin q

x 2 + y2 cos2 q - 2ax cos q + a 2 - y 2 = 0

a 2 - y2
\ cos a cos b =
x 2 + y2
Similarly expressing (1) as quadratic in sin q , we get
a2 - x2
sin a sin b =
x 2 + y2
2. Let B 0, 0 , P h, k

1 2
area of APQ = h
2
area of PQBR = hk
1 2
area of PRC = k
2
Clearly max{area APQ, area PQBR, are PRC}
1 2 h 2
= area APQ = h for 2
2 k 9
1 h 2
= area PQBR for hk for <2 >
2 k 9
3. x 2 + 1 = y and y 2 + 1 = x
Subtracting, x 2 - y 2 = y - x
x - y x + y +1 = 0

x = y or x + y + 1 = 0
If x = y then x 2 + 1 = x x 2 - x + 1 = 0 which has no real roots
If x + y + 1 = 0 then x + y = -1
Adding, given equations, x 2 + y2 + 2 = x + y
x 2 + y 2 + 2 = -1 x 2 + y 2 + 3 = 0 which is not possible

4. Roots of x - a x - b x - c x - d = 4 are integers if they are rational.

For integral roots
x - a x - b x - c x - d = -1 -2 2 1
x - a = 1, x - b = -1, x - c = 2, x - d = -2
a +b+c+d
x= = not an integer x is irrational.
4

Sec: Sr. ICON ALL Page 2

Sri Chaitanya IIT Academy 25-12-18_Sr.ICON ALL_JEE-Main_GTM-2_Key & Sol’s
5. f(x) is an odd function
1
nx n -1 x n +1
1 1
xn
6. dx = +2 dx
0
1+ x2 1+ x2 0 0 1 + x2
2

x n +1
1
1
= +2 2
dx
2 0 1+ x
2

x n +1
Also. lim 2
= 0 as 0 < x < 1
n
1 + x2

1
=
2
7. Let ki be the roots k R
- k 2a + c + bk + 1 = 0

1
k=-
b
a
=c
b2
a = b 2c
v u-z u-z
8. w = =
uz - 1 uz - 1

Let w 1 = u - z uz - 1
2 2 2
This simplifies to u - 1 z - 1 0 z -1 0
1
424
3
- ev

9. Let P be 2 cos q, 2sin q and Q be -2 cos q, - 2sin q

2 cos q + 2sin q - 1 . -2cos q - 2sin q - 1
ab =
2
2
4 cos q + 2sin q - 1 7
=
2 2
10. PA. BP = r 2 - OP 2 ( where O is centre of circle)
15 15
1 1 2 15 1
11. x+x + + 2
2
= x+x 1+ 3
x x x
1 15 1 1
= x15 15
C0 + 15C1 x + ...... 15 C15 x15 15
C 0 + 15C1 3
+ C2 6 + ..... 15C15 45
x x x
Constant terms add up to 15 C5 15C 0 + 15 C615 C3 + 15 C7 15 C6 + 15C815 C9 + 15 C9 15C12 + 15 C10 15 C15

Sec: Sr. ICON ALL Page 3

Sri Chaitanya IIT Academy 25-12-18_Sr.ICON ALL_JEE-Main_GTM-2_Key & Sol’s
12. First, 6 distinct digits can be selected in 10 C 6 ways. Now the positive of smallest digit
in them is fixed i.e. position 4. Of the remaining 5 digits, two digits can be selected in
5 th
C 2 ways. These two digits can be placed to the right of 4 position in one way only.
The remaining three digits to the left of 4th position are in the required order
automatically
So n(S) = 10
C8 5
C2 = 210 10 = 2100

13. conceptual
14. since, sinx + siny = sin ( x+ y)
x+y x-y x+y x+y
2sin cos = 2 sin cos
2 2 2 2
x+y x-y x+y
either sin = 0 or cos = cos
2 2 2
x = 0 or y = 0 or x + y = 1
Other values are not possible as x + y = 1
1 1
Hence, the possible solutions are 0, 1 , ,m i.e six solutions
2 2
15. The curve y = log7 x + 2 and y = 6 - x intersect at one point only
16. conceptual
17. f ' x ex + 3

f ' x >3

f x +3 -f x -5
=f' c >3
8
f x + 3 - f x - 5 > 24

dx
18. TM is subtangent where T x-y , 0 and M x, 0
dy

1 dx
x-y +x =0
2 dy
dx dy dx
2x - y = 0 or 2 =
dy y x
2iny = lncx
y 2 = cx
Curve passes through (1, 1)
\ c = 1, y2 = x .
19. Let the age of friends be a, ar, ar2, r > 1 and money distributed is x, xr, xr2
respectively.

Sec: Sr. ICON ALL Page 4

Sri Chaitanya IIT Academy 25-12-18_Sr.ICON ALL_JEE-Main_GTM-2_Key & Sol’s
1+ r + r x = a 1+ r + r
2 2
+a t

Also after 3 years ar 2 + 3 = 2 a + 3

a r2 - 2 = 3

x + 105 = a + 3 t and ar + 15 = ar + 3 t (given )

1 + r x + 120 = a 1 + r + 6 t 2 a + 3 t = r 2 x - 120 = 2x + 210

r 2 - 2 x = 330

Using r 2 - 2 x = 330, a r 2 - 2 = 3 x = 110a

110a + 105 = a + 3 t 5 22a + 21 = a + 3 t

and 110ar + 15 = ( ar + 3 ) t 5( 22ar+3) = (ar + 3)t

22a + 21 a + 3
= 5ar = 7a + 6
22ar + 3 ar + 3
Where 5ar = 7a + 2 (a(r2 -2) ) {Using a (r2 -2) = 3}
3
2r 2 - 5r + 3 = 0 r = . Hence a = 12 years
2
5 23
20. and are in A.P.
2 12
-7
d=
12
37 - 7n
Tn = >0 n 5 5th term has least positive value.
12
Therefore largest term of H.P. = 6
21. Let the vertices of the rectangle be
a cos q, b sin q , - a cos q, bsin q , -a cos q, - b sin q , a cos q, - b sin q . It’s sides are
p
2a cos q, 2b sin q . Area = 2ab sin 2q is maximum when q =
4
22. Let P be a cos q, bsin q and Q be -a cos q, bsin q
p p
R is 2a cos q + , 2b sin q +
4 4

mid point of OR is same as mid point of PQ

POQR is a parallelogram
23. I1 = lim tan -1 px - tan -1 x cos x
x

p -1 x
lim tan -1 px - tan -1 x = lim tan -1 =0
x x 1 + px 2

Sec: Sr. ICON ALL Page 5

Sri Chaitanya IIT Academy 25-12-18_Sr.ICON ALL_JEE-Main_GTM-2_Key & Sol’s
I1 = 0 and I2 = 0

Determinant correspondent to a, b, g
r r r
24.
1 2 0
2 a 10 = a 2 - 24a + 240 > 0
12 2a a
r r r r r2
z+z x = y z+z x = x = y
r r r r
25.
r2
z + z x . z + z x = y =1
r r r r r r

2
z12 + z 2 x sin 2 q = 1

1 2
z- =
1 + sin q 2
7

3 p
sin q = q= = 600
2 3
26. z =O O- = -I 2

det z = - I 2 = -1

PA + PB 1
27. > PA . PB 2
2
PA + PB > 2 PT = 2 3

Maximum length occurs when PAB passes through centre i.e. PA + PB = 4

( maximum )
So, range is 2 3, 4
s s s
28. CV = V1 = V2 =
x 30 25
s s
6V1 - 5V1 = - =0
5 5
29.
30. probability of q can't be fixed
q

PHYSICS
31.

Sec: Sr. ICON ALL Page 6

Sri Chaitanya IIT Academy 25-12-18_Sr.ICON ALL_JEE-Main_GTM-2_Key & Sol’s

hc
lka Ek - EL
=
hc Ek - E m
lkb
l kb 78 - 12 22 l k a 25
= = = =
lka 78 - 3 25 l kb 22

32.

2N + kx1 = M 2g
N=0 kx1 = M 2 g

A = x 0 + x1 = x
M1g M 2 g
+ =x
k k
33. Superposing them gives
p p
2A sin kx + cos wt +
6 6
p
Nodes are given by kx + = np
6
34. conceptual

35.

Let coefficient of viscosity &thickness of film

h & x respectively
Viscous force on element ring is
Sri Chaitanya IIT Academy 25-12-18_Sr.ICON ALL_JEE-Main_GTM-2_Key & Sol’s
wr - 0
dF = h 2prdr
x
dt = dF r
h2pw 3
R
h 2p w 4
\t = r dr = R
t 0 4x
\t R4

36. 1msd = 200 0.005 = 1mm

2r = 4 1 + 25 0.005 - 5 0.005
= 4.1
r = 2.05 mm
\2
37. By dimensional analysis
2GM
38. Escape speed =
R
2GM / 2
Ve ' = = Ve
R/2
Ve= escape speed of each
3RT
Using Vrms =
M
If the rms speed of a gas molecule is more than the escape speed of the planet then the
molecule will escape.
39. P0 A.l = PA l - h
2T
P0 l = P0 + l-h
r
h=
l
Pr
1+ 0
2T

F 120 b 60
40. b= = ,r = =
v 1 2m 700 2
w = w0 2 - r 2
Kx=F
450 225 602
K= = 225 = -
2 700 700 2
225 700 - 3600
= = 0.56 rad / s
7002
41. i E i C = 10-3 A
VR1 = 2.5V
VR 2 = 5V
42. conceptual

Sec: Sr. ICON ALL Page 8

Sri Chaitanya IIT Academy 25-12-18_Sr.ICON ALL_JEE-Main_GTM-2_Key & Sol’s

43.
Angular impulse= 2TRdt
By angular impulse theorem
2TRt = L f - L i
2TRt = MR 2w
Fnet towards centre is ma N
mg = mw2 R
g
w=
R
m Rg
t=
2T
44. Scattering angle is ' 1 ' --------(I)
2d sin 2 = n -----------(II)

- 1
= 2 _______(III)
2 2
45. Charge is conserved. In order to fully convert an electron into energy, a position (the
electron’s antiparticle must be involved). That is, electron+ positron->energy,NOT
electron->positron+energy.
46. H = ni
B = mH
On heating core beyond curie temperature ferromagnetic substance changes to
paramagnetic
1
x (Curies law)
T - TC
m will decrease therefore magnetic field will decrease.
H remain same.
s 120
47. l = v f t = vf - = 0.8 10-2
vp 4
= 0.2 1.2 = 0.24m
48. df1r12 = df 2 r22
49. 2 x =

Dx =
2
50. In secondary rainbow colour are interchanged and in primary rainbow first colour is
violet and last color is red.
51.
Sri Chaitanya IIT Academy 25-12-18_Sr.ICON ALL_JEE-Main_GTM-2_Key & Sol’s

h1
20 = ..........(1)
60
h
q = 1 ..........(2)
5
eq(2) eq(1)
q 60
=
2 5
q = 240

52.
f cos a = Nsin a
mN cos a = N sin a
tan a = m
53. Df = 1.5MHz
f mod ulating = 750kHz
54. Quality factor is maximum for 1 which corresponds to a
mv 2 kZe 2 1
55. = 2 K.E , which increases
r r r
-kZe2 3
But P.E = 2 , Decreases w r 2
r
56. Since the potential difference across AD and across CD is same, so A & C are on
same potential. Therefore energy stored in the capacitor at given instant is zero.
2
Bl
57. Do not depends on F; 2
=
mL
58. B as a function of x

m0 I m0i m 0i m 0i m 0i m0 $i
yˆ + yˆ - yˆ + yˆ - yˆ yˆ
2px 2p
x
2p
x
2p
x
2p
x 2 p x
2 2 2 2
59. I =e 1000V / T
-1
d I + 1 1000
= dV
I +1 T
error in the value of current is 0.2 mA.
DT 1 D l
60. =
T 2 l
12 1
= 40 -
T 2
= 25 C
Sri Chaitanya IIT Academy 25-12-18_Sr.ICON ALL_JEE-Main_GTM-2_Key & Sol’s
-5
= 1.85 10 / C
CHEMISTRY
61. NCERT (Alkyl Halide)
64. S1 = HBO give anti markonikov product
S2 = Br2 addition is anti-addition
S3 = Peroxide effect (Anti markonikov rule)
67. NO 2 group in (II), increase its electrophilicity & increase rate of reaction, and
arenium ion ( - complex) formed
70. Phenyl ring more better for - N O 2 attack as compare to pyridine.
Pyridine is deactivating and meta directing group.
73. E 2 mechanism
75.
Sol. (1)
if ore is chalcopyrites, Self reduction is preferred. If ore content is less then Carbon
reduction is employed
76.
CHO CHO CHO CHO
H OH H OH HO H HO H
H OH HO H H OH HO H
H OH HO H H OH HO H
H OH H OH HO H HO H
HOH2C HOH2C HOH2C HOH2C

78. Sol. (3)

K 2 Cr2 O7 + H 2 SO4 K 2 SO4 + H 2 Cr2O7
H 2Cr2O7 + 4 H 2 O2 2CrO5 + 5 H 2O
Chromic acid
CrO5 is blue peroxide of Cr.
79.
1) NOT isomers
2) chain isomers
3) chain isomers
4)NOT Homologous
80.
Sol: (1)
E0cell = -0.85 + 1.44 = 0.59
0.59
log10 K C = = 10
0.059
K C = 1010
82.
NH2

Product
1)

Sec: Sr. ICON ALL Page 11

Sri Chaitanya IIT Academy 25-12-18_Sr.ICON ALL_JEE-Main_GTM-2_Key & Sol’s
2) Ph - N = N - Ph
3) Ph - NH - NH - Ph
NH2

4) NO2

85. Buna-S formed by Butadiene and styrene

CO g + NO2 g CO2 g + NO g
86 int ially 1 1 1 1
At equilibrium 0.8 0.8 1.2 1.2

Ba OH 2 + CO2 BaCO3 + H2 O
1.2 1.2 1.2 moles

1.2 1.2
\ Kc = = 2.25
0.8 0.8
87. dithionic acid is H2S2O 5
Pyro sulphuric acid is H2S2O7
88. NCERT
89. Sol . (3)
k1k 3
k=
k2
differentiating with respect to T
dk d k1k 3
=
dT dT k 2
E a = E a3 + E a1 - E a2 = 20 + 40 - 30 = +30 kJ / mole

90. conceptual

Sec: Sr. ICON ALL Page 12