Sri Chaitanya IIT Academy 01-05-2020_Sr.

ICON All_GTM_Key & Sol's

Sri Chaitanya IIT Academy., India.

AP, TELANGANA, KARNATAKA, TAMILNADU, MAHARASHTRA, DELHI, RANCHI
A right Choice for the Real Aspirant
ICON Central Office , Madhapur – Hyderabad
Sec: Sr.Icon All GTM Date: 01-05-2020

Time: 09.00am to 12.00 Max.Marks:300

Key Sheet
MATHEMATICS:
1 3 2 3 3 2 4 4 5 2
6 3 7 4 8 1 9 1 10 4
11 1 12 2 13 1 14 1 15 1
16 2 17 2 18 3 19 1 20 1
21 0000.25 22 0006.00 23 0001.70 24 0004.50 25 0009.50

PHYSICS:
26 3 27 4 28 4 29 1 30 2
31 2 32 4 33 1 34 4 35 1
36 1 37 3 38 2 39 4 40 3
41 3 42 2 43 3 44 3 45 1
46 0005.62 47 0000.83 48 1500.00 49 0001.33 50 0003.00

CHEMISTRY
51 4 52 2 53 4 54 1 55 1
56 3 57 2 58 2 59 1 60 2
61 1 62 1 63 2 64 3 65 1
66 4 67 3 68 3 69 3 70 2
71 0016.00 72 0003.00 73 0007.75 74 -0445.83 75 0003.00

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Sri Chaitanya IIT Academy 01-05-2020_Sr.ICON All_GTM_Key & Sol's
SOLUTIONS:
MATHEMATICS
1
1. x  1  x  x 2  .....1  x 
1 5 1
x  x 2  x  1  0, x   x  2sin18
1 x 2
2. Interior angle = 150  each 
Each exterior angle = 30
360
 Number of sides=  12
30
n  n  3  12  9
 Number of diagonals =   54
2 2
a b c
3. = = =2R Always true
sinA sinB sinc
abc abc
 4R   2R  Is always true
 2
2 2 2
h1  , h2  , h3  
a b c
 abc 2 / 3 
abc
=2 R always true
1/ 3
 2  2  2   2
 a  b  c  
   

a b c
= = =2 R If A  B  C  60 , a=b=c
sinA sinB sinC
2 1/2 2 2
3

 a2  b2  c2 
3
3a 
3
 
.2 R sin A

 2 R only when equilateral triangle

x2  a
4. Let y 
x 1
x 2  xy   a  y   0
as x  R, b 2  4ac  0 y 2  4  a  y   0 y  R
y 2  4 y  4a  0
0

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Sri Chaitanya IIT Academy 01-05-2020_Sr.ICON All_GTM_Key & Sol's
a  1
5. 1 x  2
 1  x3  8
2  2 x3  16  3  2 x3  5  11
x  2, 1,0,1,2....10
 No of points of discontinuous = 13
1 x 2017
6.  x  x 2018 +1 dx=  dx x 2018  t;2018 x 2017 dx=dt
x 2018
x 2018

+1
1 1 1 1 1  1  t 
dt= - dt= log  +c
2018  t  t+1 2018   t t+1 
  
2018  t+1 
1  x 2018 
 log  2018 
c
2018  1  x 
p  q  r  3 2018  6054

7.  n  i 4  n4  4n3i  6n2i 2  4ni 3  i 4

  
 n 4  6n 2  1  i 4n3  4n 
For this is to be integer 4n3  4n  4n n 2  1 must be zero  
 n  0, n  1
Number of values of n=3
8. Each toss can lost or win in two ways
 n  S   214
No 13 lost and one win n  A   14
14 7
 P  A  
214 213
9.  2
y 2  8 x p  at1 ,2at1   2,4  
2
2  2t1 , 4  4t1
t1  1
2
 
Q  at2 2 ,2at2  t2  t1 
t1
 3

 Q  18, 12   C  mid po int PQ  (10, 4)

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Sri Chaitanya IIT Academy 01-05-2020_Sr.ICON All_GTM_Key & Sol's
Image of C in y=x is (-4, 10)
10. Foci S1   3,3 S2   4,4 
P   0,0  S1S 2  2ae
5 2  2ae
5 2  7 2e
PS1  PS 2  2 a e=5/7
3 2  4 2  2a
2a  7 2
11. 3x 2  8 xy  2 y 2  3  0
6 x  8  xy '  y   4 yy '  0
dy 6 x  8 y

dx 8 x  4 y
3
M=slope of tangent at (1, 0) = 
4
4
Slope of normal=
3
Vector along normal is 3iˆ  4 ˆj
 3iˆ  4 ˆj 
Unit vector =   
 5 
Vector of length 10   6iˆ  8 ˆj 
12. Let y  mx  c be the line
dy
m
dx
 mx  c  m  m 2 x
 m  m2 , c  m
m  m  1  0  m  0,1
 Number of lines= 2
 
1 
1  1  2  1   2i  1   2i  1 
13. tan  2   tan  2   tan
 2i   4i   1  4i 2  1 
   

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Sri Chaitanya IIT Academy 01-05-2020_Sr.ICON All_GTM_Key & Sol's
 
 1 
 tan 1  2     tan 1  2i  1  tan 1  2i  1 
i 1  2i  i 1
 
 2 n   1 
 
 t  Lt tan 1  2n  1  tan 1 1  tan 1  1
  tan  1
n
 1   2n  1  1 
 n
 
 1 
t  lt tan 1    t  tan 1 1  tan t  1
n 1
1 
 n
14. The coefficient of x18 in the polynomial is given by
20
 x x2 x18 
1  x  1   2
 ..... 18

 1  x 1  x  1  x  
 x19 
1  19 
  1  x    x19 
1  x 20 21
 1  x  1  19

 1   1  x  
 
 1  x 
21 2
 1  x   1  x  x19
21  20  19
2
Coefficient of x18 in 1  x    1330  k
6
 Sum of digits of k  1  3  3  0  7

15. Circle x 2  y 2  4 x  8 y  5  0
Centre (2, 4), r  4  16  5  5
Circle intersects the line 3 x  4 y  m  0 at the points
 Distance from centre to line < radius of circle
6  16  m
  5  10  m  25
5
 35  m  15
  
16. C.V   v1  ,V2 
x 30 25
 
6V1  5V2    0
5 5
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Sri Chaitanya IIT Academy 01-05-2020_Sr.ICON All_GTM_Key & Sol's
17. P is true, Q is false, R is true
By option
P    Q  R   T  T  T   T
18. n A  B  2  4  8
Number of subsets having 3 (or more elements) is
8C3  8C4  8C5  8C6  8C7  8C8
 28   8C0  8C1  8C2   219
2
19. BC  I, A( BC )  A, A  BC   A......;Tr  A   2  1  3
 A  A
 Tr  A   Tr    Tr    ......
2 4
 
 1 1   1 
 Tr  A  1   2  ...  Tr  A    2.Tr  A   2  3  6
 2 2  1
1  
 2
 a1  a2 . b1  b2 
20. Shortest distance between L1 and L2  9
b1  b2
a1  3iˆ  6 ˆj b1  4iˆ  3 ˆj  2kˆ
a2  2iˆ  ˆj  6kˆ b2  4iˆ  ˆj  kˆ They are non-coplanar
21. L is the slope of line x  y  k  L  1
M is the slope of line y   x  M  1
L2  M 2 2 1
    0.25
8 8 4
1 sin  1
22. A   sin  1 sin 
1  sin  1

  
 1 1  sin 2   sin    sin   sin    1 sin 2   1

A  2 1  sin 2  
We have 0  sin 2   1

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Sri Chaitanya IIT Academy 01-05-2020_Sr.ICON All_GTM_Key & Sol's
 1  1  sin 2   2

 2,4   a, b
a  b  6 23. y  x3  2 x 2  4; A  2,4  equation of tangent
dy
 3 x 2  4 x y  y1  m  x  x1 
dx
 dy 
m   3(4)  4(2)  4 y  4  4  x  2 
 dx (2,4)
y  4  4x  8
4x  y  4  0
T 1,0 
k 2 17
 AT=K  17   1.7
10 10
24. y  2x  x2 ; y   x
Solving above we get, x 2  3x  0  x  0,3
3 3
Area =  2
  2

0  2 x  x    x dx  0 3x  x dx
9
  4.5
2
25. A   2,0,0  , B   0,3,0  , C  (0,0, 5)
AB  2iˆ  3 ˆj, AC  2iˆ  5kˆ
Area of
1 1 1 1 19
ΔABC= AB×AC  15iˆ  10 ˆj  6kˆ  225  100  36  361   9.5
2 2 2 2 2

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Sri Chaitanya IIT Academy 01-05-2020_Sr.ICON All_GTM_Key & Sol's
PHYSICS
26. from parabolic equation
y  Ax  Bx 2
A=Tanθ=1  θ  45
g
B  0.8 
2u cos 2θ
2

g
0.8 
u2
u 2 10

g 8
u2 5
Total distance=   1.25 m
g 4
27. For a particle in circular path acceleration is constant in magnitude but varies in
direction. Hence it is
Non-uniform accelerated motion.

a
a

28.

dx

  dfx  I
 μρ2π×dx  x=  ρ2πxdx  x 2
R R
μ  x dx=  x 3dxα
2

0 0

4µ
1 
3R
For second disc

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Sri Chaitanya IIT Academy 01-05-2020_Sr.ICON All_GTM_Key & Sol's
R R
µ  x 2dx=  x 3dx
R/2 R/2

 56µ 
 2   
 45R 
 0   1t 1   0   2 t 2  0
t 2 1 15
 
t1  2 14
t1  14sec  t 2  15sec
29. The beat frequency of two wave is f1  f 2 and is independent of amplitude of
waves
Hence beat frequency remains same
-K2π  ldT
30. Heat current H=
dx
r2 2 T
dx
H  =-Kl2π  dT
r
x T
1 1

r 
Hlog  2  =-Kl2π  T2 -T1 
 r1 
r 
H=2πlK  T2 -T1  log  2 
 r1 
r 
 H  log  2 
 r1 
π
31. At t=0, y  2cos  1m
3

2A=4m
t=1 t=0

0m 1m

π 2π
w= =  T  12sec
6 T
At t=1, y=0
At t= 7, y=0
Hence from 1 to 7 sec particle travel a distance=2 A=4 m
(or)
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Sri Chaitanya IIT Academy 01-05-2020_Sr.ICON All_GTM_Key & Sol's
In time 7-1=6 sec particle travels a distance half the length of the oscillation
T
32. Max efficiency = 1  2
T2
300 1
1   50%
600 2
33. Temperature at B T1  400 K
At C= T2 =300K
du=nC V dT
 3R 
 1   100 
 2 
= 1245J
 1
34. Normal shift  t 1- 
 µ
 2
 12 1  
 5
=7.2 cm away
35. Electron microscope wave length of matter waves of electrons is smaller than
light waves. Hence resolving power of electron microscope is greater than optical
microscope
36. M1 =iπr 2 N1
M 2 =ia 2 N 2
N1  1
N2  2
2πr=8a
r 2
=
a π
2
M1  4  1 8
=π    =
M2  π  2 π
37. Constructive interference path difference x  n (n  0,1,2,.....)
Path 1 X1   0d
d
Path 2 X 2 =   μ 0 +αx  dx
0

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Sri Chaitanya IIT Academy 01-05-2020_Sr.ICON All_GTM_Key & Sol's
d2
X 2  µ 0d 
2
X 2 -X1 =n
d2
 n
2
2n
d

2
For dmin n=1  d min 


38. Induced emf e  Blv

e  B 2x  V
Y

V
i x x

X
t
e
Induced current, i 
R
B2x v
i ’
 2x
i  t
39. At resonance V= iR
R  10 
6 R
cosθ  
10 Z
100
Z
6

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Sri Chaitanya IIT Academy 01-05-2020_Sr.ICON All_GTM_Key & Sol's
V 100
i   6A
Z  100 
 
 6 
V2 2002
40. p R  400 
R 100

If there are n bulbs in series

V 600
I 
R 400n  100

V across each bulb < 240

 600 
400   240
 400n  100 
9
n
4

Minimum n is 3
41. Cnet  3 F
1
Energy= C net V2
2
1
=  3 F 10V 2 = 150  J
2

42. Work function Q = 2 e V

12400
Energy E 

12400
2

 max  6200A 
energy
43. power 
time
18
40   200Mev 10 
P  
100  sec 
 P  13MW

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Sri Chaitanya IIT Academy 01-05-2020_Sr.ICON All_GTM_Key & Sol's
44. Inertia of an object is depends on the total mass of the particles. Hence it only
depends on mass of an object
45. Force at bottom F1  P1A1
F1   lρg  πr 2
Average force at walls F2 =P2A 2
 lρg 
F2   2πrl
 2 
F2 l

F1 r
46. M is the total mass of hemisphere
In hemisphere center of mass at 3R/8
M x -M x
X cm  1 1 2 2
M1 -M 2
M1  Mass of hemisphere = M
M
M 2 = Mass of small hemisphere =
8
3R
x1 
8
3 R 
x2   
8 2 
3R M 3 R
M×  
X cm  8 8 82
7M
8
45R 45  14 45
    5.62
16  7 16  7 8
47. f  ma
v  u+at
  I
mr 2
f r  
2
2f

mr
For pure rolling

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v  rw
u+at=r  w 0   t 
f  2f 
t  r w 0 - t 
m  mr 
 2µg 
µgt  r  w 0 - t
 r 
4t  10  8t 
10
t  0.83sec
12
dV 60000
48. E 
dr r2
F  Eq  ma
60000
 (0.1)  (1)a
22
 a  1500 m / s 2
49. for focal length to be infinity
Refractive index of lens= refractive index of medium
4
µ   1.33
3
50. F  2t
f max  µ 0mg  8N
8  2t
At t  4sec, body starts
Fnet  F-f k
a  2t  6
v 5
5
 dv= 4 2tdt- 6dt
0 4
v  3m / s

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CHEMISTRY
51. N2  3H 2  2 NH 3
Intially 0.5 2 0
At equilibrium 0.5 x 23 x 2x
At equilibrium, it is mentioned that there is 1 mole of NH 3 i.e., 2x=1; x=0.5
14
nN 2   0.5
28
Moles of N 2 unused  0.5  x  0.5  0.5  0
4
nH 2  2
2
Moles of H 2 unused = 2  3 x  2   0.5  3   0.5
17
nNH 3  1
17
Weight of unused H 2  0.5  2  1g
52. P H  12
POH  14  12  2
OH    102 N
 
 OH   2 3
 Ba  OH  2       Ba   5  10 M
 2 
Ba  OH  2  Ba 2  2OH 
S 2S
3
2
K sp  S   2S   4S 3  4 5  103    500  10 9  5  107
53. For the reaction 2 A  B  products
x y
r  k  A  B 
x x
Eqn.1 0.3 k  0.1 0.1 1 1
  x x
=  x ; 2 x  2; x  1
Eqn.3 0.6 k  0.2   0.1 2 2
x y
Eqn.2 2.4 k  0.2 0.2
  x y
; 4  2 y ; 22  2 y ; y  2
Eqn.3 0.6 k  0.2 0.1

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Sri Chaitanya IIT Academy 01-05-2020_Sr.ICON All_GTM_Key & Sol's
1
54. Number of hybrid orbitals on the central atom Xe  No. of monovalent species 
2
(group to which central atom belongs – no. of monovalent species (bivalent
1
considered as two monovalent groups) ) = Xe  5   8  6   5  1
2
3 2
Five bond pairs and 1 lone pair. sp d Hybridization.Square pyramidal molecule.
O
F F
Xe

F F
3
55. Volume a  b  c  215.424 A0  
24 3
= 215.424  10 cm
= 2.154  1022 cm3
z.M 4  21.76
d 
N 0a 3 6.023  1023  2.154  1022
27.04
  0.67 g / cc
129.4
Excess of NaOH
56. Al  NaOH  Al  OH 3    NaAlO2
White gelatinous
ppt


Al  OH 3   Al2O3  3H 2O
X used in
chromatography

57. H 2 2  4e    1s 2  1s 2
1
Bond order   2  2  0
2
With B-O zero, the chemical species does not exist. In all other options, the B.O is
positive and such a species can exist.
58. partial pressure=X×total pressure
6
2  total pressure
2  4  6  10
44
Total pressure=  7.33
6
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Sri Chaitanya IIT Academy 01-05-2020_Sr.ICON All_GTM_Key & Sol's
59. Highest freezing point implies least depression in freezing point. Depression is F.P
is decided by the product of (i x M). As concentration of all solutions is the same,
lower Vant Hoff’s factor, results in lower depression in freezing point. As glucose is
non-electrolyte, it’s i = 1, it does not dissociate. So, glucose solution exhibits
highest freezing point.
60.
O
O O
O
OH
H
H2 H

O
O
H3O

HO

61. PAN is produced by photo chemical smog. Primary pollutant and oxidant like
O3 , NO2 oxidize hydrocarbons in presence of light energy to form PAN.
62.
O O

C-NH2 C-NH2
Br2/hv

CH2-CH3 CH2CH3

-
OH Br

O
-
CH2 NH
C

NH

CH2-CH3

CH3
Br

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32 weight of BaSO4
63. S   100
233 organic compound weight
32 2.33
   100  10%
233 3.2
O

C CH3
64. Molecule with group exhibit iodoform test due to enolization.
O
OH
C CH3 CHI3 COO
I2 
Molecule with carbonyl group answer 2, 4 – DNP test
Aromatic primary amines exhibit azo-dye test
65.

O CH2 + HI

OH + I-CH2

66. LiHCO3 does not exist in solid state, due to less lattice enthalpy and high
hydration enthalpy.
O
67. CH3  C(CH3) = CH  CH3  3
Zn / H O
 CH3CHO +CH3COCH3
2

68. CO  NH 3  Cl3  exhibits fac and mer isomerism and both these isomers contain
 3 
plane of symmetry, so they are not optically active.

69. H 3 PO4 is tribasic and non-reducing agent

H 3 PO3 is dibasic and reducing agent
70. They differ in configuration at C-1 position, so they are anomers
71. n=4, l=0, m=1
n=4, l=1, m=3
n=4, l=2, m=5
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Sri Chaitanya IIT Academy 01-05-2020_Sr.ICON All_GTM_Key & Sol's
n=4, l=3, m=7
(OR)
Number of sub shells with principal quantum number (n) are n 2  42  16 .
Total possible values of magnetic quantum numbers are 1+3+5+7 = 16
72. Between third and fourth ionization energies, there is a large difference in
ionization energy. So, removal of 4th electron is nothing but the removal of electron
from inert gas, which is associated with high ionization energy. So, there are three
valence electrons as first three IE values are moderate.

73. NO3  N H 4
5  3
Change in oxidation state is 8
Equivalent mass of NO3 =62/8=7.75
74. E 0cell  E 0cathode  E 0 anode
 0.8   0.74   1.54V
G 0   nFE 0cell
 3  96500  1.54
 445.83KJ
75. Change in concentration of CH 3COOH  0.05M
W 1000
M 
G.M .Wt V  ml 
W 1000
0.05    0.05  30  1.5 g of acetic acid is adsorbed per 0.5g of activated
60 500
charcoal.
 x   1.5 
  3
 m   0.5 

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