Sec: JR.

*CO SC(MODE-A) Date: 23-07-2023

Time: 3HRS WAT-12 Max. Marks: 198
KEY SHEET
MATHS
1 B 2 C 3 B 4 C 5 D

6 C 7 AB 8 AC 9 BD 10 AC

11 ABC 12 ABD 13 8 14 2 15 0.5

16 3 17 9 18 0

PHYSICS
19 C 20 B 21 A 22 C 23 C

24 D 25 A,B,C,D 26 A,D 27 A,B 28 A,B,C,D

29 B,C 30 A,C 31 10.16 32 0.5 33 8

34 0.4 35 0.75 36 8

CHEMISTRY
CHEMISTRY
19 C 20 D 21 D 22 D 23 A

24 A 25 AC 26 ABC 27 ACD 28 CD

4.40 to
29 ABC 30 ABCD 31 1 32 33 2
4.50

34 1.02 35 1 36 4
Narayana IIT Academy
SOLUTIONS
MATHS
1. sin x  4sin 2x  sin 3x  3  cos x  4cos 2x  cos3x   0
2sin 2x cos 4sin 2x  3  2cos 2x cos x  4cos 2x   0
 2cos x  2  sin 2x  3 cos 2x   0
2. Take x,y,z from C1 ,C 2 ,C3 respectively and multiply R 1 ,R 2 , R 3 with x,y,z
a b a a b b
3. x b c b y b c c
ax  by bx  ay 0 ax  by bx  ay 0
 Apply C1  C1  C 3 and C 2  C 3
  b 2  ac  ax 2  ay 2  2bxy   0
 b 2  ac  G.P.
4. There are six terms in the expansion and all of them cannot be one at the same time. Thus
value of determinant cannot be 6 or 5. Maximum possible value is 4.
5. c1  c1  c2 ,c 2  c 2  c1 ,c3  c3  2c1
2 1 2 1 1 2 1 0 0
1    1    1  1   2
4  3  1 1 3    1 1 2    1
2 2
    1     2   0    1,   2,   4
 The cubic equation is x 3  7x 2  14x  8  0
   r  a r  100  1 r
100
 1 
r

S             

r 1     b   r1  2   2

50
1  1 
 1    
4   4   2  1 
 2   1  100 
 1 3 2 
1  
 4

6. xsin   ysin 2  zsin   sin 4 is satisfied by a,b,c

1 1
7.  2sec x  1 3   sec x  1 3  1
1 1
2sec x  1  sec x  1  3  2sec x  1 3  sec x  1 3  1
1 1 1 2
3 2sec x  1 3  sec x  1 3  3 1  sec x   sec x  1 or  2sec x  1 3    sec x  1 3

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2
2sec x  1    sec x  1  sec2 x  0
 3 
8.  3  sin 2x  sin  r  
  sin  3x  
 4  4 
       
 sin  x   6  sin 2x  4sin 2  x    0  sin  x    0
 4   4   4
9. Squaring and adding
2  1  cos6 B  sin 6 B  2cos4 B  2sin 4 B
3 2
0 sin 2B  2cos 2B
4
2 2
10. a1   2m  1 ,a 2   2n  1 ,
a1  a 2  4  m  m  1  n  n  1   8k
So, difference of any two odd square is always a multiple of 8.
Now, apply c1  c1  c3 and c 2  c 2  c3
then c1 and c 2 both become multiple of 8, so  always a multiple of 64.
11.   3,  1
12. Multiplying C 1 by x, C 2 by y, and C3 by z.
then apply, C1  C1  C 2  C3
13. 8sin 2 x cos x  3 sin x  cos x  4sin 2x sin x  3sin x  cos x
cos x 3 sin x
2 cos x  cos3x   3 sin x  cos x    cos3x
2 2
14. Apply A.M.G.M
x
15. Put sin x and cosx in terms of tan  
2
16. Apply row column transformations.
1 1
a11 a12 a13
2 4
1
17.  2  2a 21 a 22 a 23  1 Multiply the first row with 2.
2
4a 31 2a 32 a 33

2 2 2
18.  ax  b    bx  c    cx  d   0
ax  b  bx  c  cx  d  0
b c d
x  
a b c
 a, b, c, d are in G.P.
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Let a, b  ar, c  ar 2
33 14 ln a 33 14 ln a 33 14 ln a
65 27 ln b  65 27 ln ar  65 27 ln a  ln r
97 40 ln c 97 40 ln ar 2 97 40 ln a  2ln r
Applying R 3  R 3  R 2 after that R 2  R 2  R1
33 14 lna
 32 13 ln r , R 2  R3
32 13 ln r

PHYSICS

19.

2kl0 cos   mg
3 kl0 3
2kl0  mg ; m
2 g
20. First, let us find the total height of ascent. At the beginning and the end of the path of velocity
of the body is equal to zero, and therefore the increment of the kinetic energy of the body is
also equal to zero. On the other hand, in according with work-energy theorem T  0 is equal
to the algebraic sum of the works A performed by all the forces, i.e. by the force F and
gravity, over this path. However, since T  0 then A = 0. Taking into account that the
upward direction is assumed to coincide with the positive direction of the y-axis, we can
write
h    h
 
A   F  mg .r   Fy  mg dy 
0 0
h
 mg  1  2ay  dy  mgh 1  ah   0
0

Whence h  1/ a .
The work performed by the force F over the first half of the ascent is
h /2 h /2
AF   Fy dy  2mg  1  ay  dy  3mg / 4a
0 0

The corresponding increment of the potential energy is

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U  mgh / 2  mg / 2a
21. (ref HC Verma)
Gain in Gravitational PE =loss in elastic potential energy
Assume h is the height raised above the relaxed length position of spring
1 2
mgh  kx
2
1
(0.25)(10)( h)  (100)(0.1) 2
2
22 Area under the graph gives change in momentum
At t= 4.5sec, momentum is 4.5 N-s
p 2 (4.5) 2
So use the formula KE    5.06 J
2m 2 2
1 2 1 2 v
23. For maximum compression being x0 , W.E. theorem gives mv0  kx0 and v  0 , we get
2 2 2
1  2 v02  1 3
2  
4 2

m  v0    k x02  x 2  kx 
2

kx0

24. Potential energy (Spring + Gravitational) with position is as shown

The above graph is traversed twice (back and forth) so, v0 is achieved four times.
25. Reference HCV page no 122
26. ac
1
 mc  x  kx2
2

2mc
x
k
2mc  mc
a
m

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In ground frame
amax  c  c  2c
27.  0  3  1 max displacement

  0  3  1 max entension
 2 0 cos 300   0
=2
mg 0 1 2
 k  2
2 2
mg 0 4
k
4

2

3 1 
After releasing the mass

ABC is isosceles
So, AB = BC
And displacement of the ring = BC
BC   3 1
2
After rationalization BC 
3 1
dU
28. (i) is positive at origin.
dx
 Force is negative at origin and particle will move in negative x – direction.
dU
(ii) is negative to the right of x  2
dx

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Force is positive and the particle speeds upto the right. It will have maximum KE at x  5
where the PE is minimum

(iii) Unstable equilibrium is characterized by maxima of PE. x  10, x  2 and x  10 are

positions of unstable equilibrium.
(iv) particle will first move to right and then will return back to cross x  10 if its total
energy exceeds 15 J
1
 K  U  x 5  15   2  v2  15  15
2
 v  30 ms 1

29 Work done by spring on block,

1 1 1
ws 
2 2 2

kah2  kb2  k a 2  b 2 
By working energy theorem,
Ki  w  Kf
1 1
0  ka 2  mg  a  b   kb 2  0
2 2
1

mg  a  b   k a 2  b 2
2

k a  b

2mg
dU 2a
30. For equilibrium  0, r 
dr b
2a d 2 U
At r  . is +ve hence stable
b dr 2
dF dU
For Fmax   0 where F  
dr dr
31. W f   k f  U f    ki  U i 

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1 2
 0  K  2cm 
2
1 2 1 2 
  m 10   K  2cm   mg 8cm 
2 2 
1
   0.2  100  0.2  10  0.08
2
 10  0.16  10.16J

32. Initially

kx   s mg.....1 at the edge of slipping

1 1
k mg  x  y   kx 2  ky 2
2 2
2k mg  k  x  y 
2 k mg  kx  ky
2 k mg   s mg  k  s  x 
2 s mg  2 k mg  ks
ks
s  k 
2mg
m N
g  10 2
; k  0.47; k  100
s m
2
100  6  10
 s  0.47   0.50
2  1 10
4mg
33. Min – extension required for ‘4m’ to lift  y  say  using W.E. theorem on block of
k
mass ‘m’ Wall   K .E

4mg 1 16m 2 g 2 1
mg   k 2
  mv02
k 2 k 2
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8m 4m 2 g 2 8m 2 g 2 1
v0  g    mv02
k k k 2
8mg 2 2 4m 2 g 2 1 2 8m
 v0  mv0 v0  g
k k 2 k
34. Block comes to rest after losing its kinetic energy in work done against friction and a part of
it goes into the potential energy of spring.

Using work energy theorem, from the instant of impulse to the time it comes to rest, we use
1 2  2
mu  Kx   mg  x 
2 2
1 1
  0.18 u 2   2  36  104  0.1  0.18  10  0.06
2 2
 u  0.4 m / s
35. 
Force on the particle is given as F   yiˆ  2 xjˆ 
Here work done along AB is given as WAB   1iˆ  .1iˆ   1J
Work done along BC is given as WBC  1J
Work done along CD is given as WCD  0.25 J
Work done along DE is given as WDE  0.5 J
Work done along EF and FA is given as WEF  WFA  0 J
 Net work done in cycle  0.75J

36. Acceleration of blocks is given as a 

 m2  m1  g  0.36  10  10 m / s 2
m1  m21 1.08 3
1 2 1 10 2 5
Displacement of blocks during first second is given as s  gt    1  m
2 2 3 3
Tension in string of given Atwood’s machine is given as
2m1m2 g 2  0.36  0.72  10
T  N
m1  m2 3  0.36
 T  2  2.4 N  4.8 N
Work done by string on block of mass 0.36 kg is given as

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CHEMISTRY
37. A) On dilution, conc. of HA  104
c 2
So K a 
1

3
104  2 
1 10 
1   
2
 10
1
 2  10  10  0

10  100  4  10 1


2

10  140 1.83

   0.915
2 2
B) On mixing of weak acid HA and salt of strong base NaA in equal we will get a
buffer with
pH = pK a
So pK a  3.3  K a  103.3  104  100.6
So K a  5  104
c 2 4 102. 2
Ka   5  10 
1 1
 20 2    1  0

1   1  4  20  1

40
8
  0.20
40

  0.2
2

C) K a 
 c 
c.  

103 10 3
1103 
c  103
c  2  10 3    0.5

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38. A) these lines represents weak acid and weak base in equal proportion so it form a
simple buffer (salt of weak acid and weak base)
B) In this mixture, we have strong base and weak acid in excess, means that finally we
have a mixture of weak acid and salt of weak acid and strong base which can acts as
buffer
C) It is a mixture of strong acid and weak acid and weak base which can acts as buffer
D) In this mixture we have strong acid and weak acid strong acid is in excess so if
cannot acts as buffer

39. rf  K f
2
rb  K b  Pb 2   I  

So rate of forward reaction is independent of any term and remains constant, but at
point ‘t’, decrease in back ward rate indicate that, sudden drop in conc of  Pb 2  or,  I  

(or) both which is possible only in option D

A) If temperature changes, both rf and rb must be influenced
B,C) With the addition of products, rb first increase, and then decreases
40. Buffer capacity is to be influenced following factors
1. Temperature
2. Nature of acid / base
3. Relative concentration of solution

Buffer capacity   2.303 

  S  A 

  S    A 

Where  S   concentration of salt

 A  Concentration of acid
So, (D)
41. At saturated condition
 M aq2   2OH aq 
M  OH 2 s  

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So  M
 OH   10
 4
2
 
2 2
 5  105

2
So K sp  5 105 104   5 1013

So we have to maintain  OH   in solution so that

K sp 5  1013
 OH  

  5  1011
M 2
102

 50  106

K b  base 
OH   in buffer =
 salt 
1.8 105  102
6
50  10 
 salt 
1.8 106  102
50  106 
 salt 
42 A) K sp of xy   x   y    2  103  103  2 106
2 2
B) K sp of xy2   x 2  y     2 103 103 

 2  109
2 2
C) K sp of x2 y   x    y 2    2 103  10 3 

 4  109
2 2
D) K sp of xy2   x 2  y    2 103 103   2 109

43. Reaction for 1st dissociation of H 3 PO4 is

 H 2 PO4  aq   H 
H 3 PO4  aq  


G 0 of r  n  G 0fP   G 0fR

G 0   1302  103  298 (84) 

  1290  103   298(176  

= 13926
G 0   RT ln K   ln K  2.44
44. Potential electrolytic is a compound which won’t have ions but gives ions in aq.
solution
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B) on x times dilution of strong acid  H    c / x

And new pH =  log c  log x

On x time dilution of weak acid  acid   c / a
c
And new pH =  log  . 2 
x  
  log c  log x  log  2

Where initial pH =  log c  log 1

 2   2 so pH of weak acid is less them in strong acid

C) If strong acid exists as one of reactant, it reacts with base in buffer and causes loss of
buffer action
D) An acidic buffer may have pH > 7, based on K a value
45. A) At point of neutralization pH may be great (or) less (or) equal to 7
B) Buffer with pK a nearer to pH acts as better buffer
C) By using heat of neutralization and heat of ionization, we can calculate  from
which we can calculate K a
D) With increases in concentration, degree of ionization decrease and heat released also
decreases
46.  A  aq   B   aq  H  ve
AB  s  

So Lattice Energy of AB  Hydration energy of AB

 C   aq   D   aq  , H  ve
CD  s  

So L.E of CD  HE of CD
So, as temperature, increases K sp of AB decreases and K sp of CD increases

47. A) Any amphiprotic solvent can undergoes autoprotolysis

B) h  kh

C) At infinite dilution any solution behaves as water and pH = 7


  B  OH    H 
D) H 3 BO3  H 2O  4

48. A) By considering degree of hydrolysis of anion and cation as same only. We can give
pH expression

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B) Expression remains same
C) pH = 7 means, K a  Kb

49. Total dissolved  Zn  OH 2

 
Zn  OH 2  aq   Zn  OH   Zn 2   Zn  OH 3 

  Zn  OH  4 

50.  HB  A
AB s   H  

103 s  s
2  100
K sp s2
K  
K a 1 108 103

2  105  s 2

s  20 106

 4.47  103

51.  H  is 100 times  OH  means,  H   10

   6

 OH   10
 8

 Cr 3  3OH 
C  OH 3 
3
6  1032  s  OH  

s  6  108 so x  6 / y  8
52 Sudden change in pH indicant equivalent point
So 10  c  25.5  0.2  2
 c  1.02m
53. At equilibrium, pressure in left and right side chambers is same.
In left chamber, PHe  2 atm
42
 PNH3  PH 2 S   1 atm
2
 K p  1 1  1 atm 2

54. 4 (i, v, vi, vii)

 HB  aq   A  aq 
HA  aq   B   aq   K eq  104
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K eq is very small, so reaction shift in backward direction

(1) HB is more stronger acid than HA

(2) A is more stronger base than B 
(3) B  and HB are conjugate acid – base pair

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