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Chem Terengganu - trial sem 1 chemistry

chemistry (Kolej Matrikulasi Johor)

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STPM 2023
PEPERIKSAAN PERCUBAAN
SEMESTER 1

CHEMISTRY
962/1

Nama
Kelas

DIBIAYAI OLEH KERAJAAN NEGERI TERENGGANU

Tidak dibenarkan menyunting atau mencetak mana-mana bahagian dalam
kertas soalan ini tanpa kebenaran Pengarah Pendidikan Negeri Terengganu

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962/1 STPM 2023

MODUL PERKEMBANGAN PEMBELAJARAN 1

CHEMISTRY

PAPER 1

1 Hour 30 Minutes
Instructions to candidates:

DO NOT OPEN THIS QUESTION PAPER UNTIL YOU ARE ALLOWED TO DO SO.

Answer all questions in Section A.

Answer all questions in Section B.

Answer two questions only in Section C.

All working should be shown. For numerical answers, units should be quoted wherever appropriate.

Answers may be written in either English or Malay.

Fill in your personal details.

Arahan kepada calon:

JANGAN BUKA KERTAS SOALAN INI SEHINGGA ANDA DIBENARKAN

BERBUAT DEMIKIAN.

Jawab semua soalan dalam Bahagian A.

Jawab semua soalan dalam Bahagian B.

Jawab dua soalan sahaja dalam Bahagian C.

Semua kerja hendaklah ditunjukkan. Bagi jawapan berangka, unit hendaklah dinyatakan di mana-
mana yang sesuai.

Jawapan boleh ditulis dalam bahasa Inggeris atau bahasa Melayu.

Isi maklumat diri anda.

This question paper consists of 12 printed pages

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962/1 STPM 2023

MODUL PERKEMBANGAN PEMBELAJARAN 1

CHEMISTRY

PAPER 1

Instructions to candidates:

Tear off pages 7 and 8 of your answer sheets of Section B and tie them together with your answer
sheets of Section C.

Arahan kepada calon:

Koyakkan halaman 8 dan 9 helaian jawapan anda bagi Bahagian B dan ikatkannya bersama-sama
dengan helaian jawapan anda bagi Bahagian C.

(Untuk kegunaan pemeriksan)

Section A
(Bahagian A)
Question Marks Marks
Number Obtained
1 15 15
Section B
(Bahagian B)
16 8
17 7
Section C
(Bahagian C)
18 15
19 15
20 15
Total 60
(Jumlah)

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Section A [15 marks]

Answer all questions.

Indicate the correct answer on the Multiple-choice Answer Sheet provided.

1 Which of the following species does not produce a peak in the mass spectrum of
propane-2-ol?
H

CH3 C CH3

OH

A CH3CHCH3+
B CH3CH2OH+
C CH3CH(OH)+
D CH3CH(OH)CH3+

2 Which of the diagrams correctly represents the line spectrum of hydrogen in the visible
region?

Frequency

Frequency

Frequency

Frequency

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3 The electronic structure of the Fe 3+ ion may be represented as

A
3d 4s

B
3d 4s

C
3d 4s

D
3d 4s

4 In the presence of excess ammonia, copper (II) ion forms the deep blue [Cu(NH3)4]2+ complex
ion. What type of bond is formed between the nitrogen atom in NH3 and the Cu2+ ion?

A Coordinate bond
B Ionic bond
C Hydrogen bond
D Covalent bond

5 The shape of a molecule depends on the following factors, except

A The number of lone-pair electrons

B The number of bond-pair electrons
C The number of attractions between the electron orbitals
D The number of atoms bonded to the central atom

6 Which of the following statements is not true about hydrogen bond?

A It causes the helix shape of protein

B It causes the dimerisation of carboxylic molecules
C It makes hydrogen chloride gas very soluble in water
D It makes the boiling point of water exceptionally high

7 Ammonia is an example of a non-ideal gas because

A the molecular size is small

B the attractive forces are strong
C the volume occupied can be neglected
D ammonia is easily compressible at low temperature and high pressure.

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8 Which of the following statements explains why liquids have densities that are quite similar
to their solids for most substances?

A The particles in liquids and solids have nearly the same size.
B The distance between particles in liquids and solids are nearly the same.
C The attractive forces between particles in liquids and solids are nearly the same.
D The mass of particles in liquids and solids are nearly the same.

9 Which of the following is correct with regard to a catalyst?

A It decreases the temperature of the reaction.

B It alters the mechanism of the reaction.
C It increases the yield of the products.
D All catalytic actions can be explained by the Collision Theory.

10 Which statements about the activation energy of an endothermic reaction is true?

A The activation energy of the reaction varies with temperature.

B The rate of the reaction is higher if the activation energy of the reaction is larger.
C The presence of a catalyst has no effect on the activation energy of the reaction.
D The activation energy for the forward reaction is larger than that of the backward reaction.

11 Which of the following is correct with regard to the equilibrium constant, Kc and Kp of a
reversible reaction?

A Both have the same value under the same pressure.

B Both have the same value for gaseous system only.
C Both are constant under all conditions.
D Both will change when temperature changes.

12 The partial pressure of nitrogen, hydrogen and ammonia for the reaction
N2(g) + 3H2(g) 2NH3(g) are and c respectively. If the pressure is increased to twice its
original value, at constant temperature, the expression for the equilibrium constant, Kp is given by

A Kp = c2
3
4

B Kp = c2
3
2

C Kp = c2
3

D Kp = 2c2
3

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13 What is the pH of the solution obtained when 300 cm3 of 0.2 mol dm-3 sulphuric acid is added
to 200 cm3 of 0.4 mol dm-3 aqueous potassium hydroxide?

A 1.10
B 6.88
C 9.52
D 12.60

14 Which of the following graphs correctly shows the variation of pH when 20.0 cm3 of 0.2 mol
dm aqueous sodium carbonate is titrated with a 0.2 mol dm-3 of nitric acid using phenolphthalein and
-3

methyl orange.

A B
pH pH

0 20 40 0 20 40
Volume of HNO3/cm3 Volume of HNO3/cm3

C D
pH pH

0 20 40 0 20 40
Volume of HNO3/cm3 Volume of HNO3/cm3

15 The Ag+ concentration in a saturated solution of argentum ethanedioate, Ag2C2O4, is

2.3 x 10 mol dm-3 at 298 K. What is the solubility product, Ksp of argentum ethanedioate at the same
-4

temperature?

A 2.3 x 10-4 mol dm-3

B 5.3 x 10-8 mol2 dm-6
C 6.1 x 10-12 mol3 dm-9
D 1.2 x 10-11 mol3 dm-9

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Section B [15 marks]

Answer all questions.

Write the answers in the spaces provided.

16 The phase diagram for water is shown above.

(a) Write the position of curved OB. [1]

(b) Discuss the slope of the curve OB in melting point and density of ice. [3]

(c) What happens when water at point X is slowly heated under constant pressure. Draw on
the graph above and explain. [4]

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17 The figure below shows a partly completed boiling point against composition diagram at
constant pressure for two miscible liquids A and B

(a) Given the boiling point of pure A is 86°C and that pure B is 100°C, complete the diagram
with label boiling point of pure A. [2]

(b) A liquid mixture consisting of 50% of A by mass is subjected to fractional distillation.

(i) What is the boiling point of the mixture? [1]

(ii) What is the composition of the vapour of A and B in equilibrium with the liquid
mixture at its boiling point? [2]

(c) On the boiling point against composition diagram you would expect to obtain at constant
temperature for mixtures of A and B on the graph above. Label your diagram where appropriate.
[2]

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Section C [30 marks]

Answer two questions only.

You may answer all the questions but, only the first two answers will be marked. Write the
answers on the answer sheets provided. Begin each answer on a new page of the answer sheet.

18 (a) Boron trifluoride, BF3 is a Lewis acid and ammonia, NH3 is a Lewis base.

(i) Explain the formation of BF3 and NH3 molecule using the concept of overlapping
and hybridization. [8]

(ii) Using the Lewis structure, deduce the formation of bonding between the BF3 and
NH3 molecule. [2]

(b) Hydrogen bonding can affect the boiling point of a substance. Both ammonia and water
molecules can form hydrogen bonding. Which molecule has higher boiling point? Explain your
answer. [5]

19 (a) The half-life of thorium is 2600 years. Calculate the time taken for a sample of thorium to
decay to 25% of the initial concentration. [3]

(b) The table below shows the results of an experiment for the reaction

X(aq) + Y(aq)

that was carried out at 42 oC.

Time / Second Concentration of X(aq) / mol dm-3

0 1.38
500 1.24
1200 1.07
2000 0.82
2800 0.61

(i) Plot a graph to determine the order of this reaction with respect to the concentration of
X. [5]

(ii) What is meant by the term order of reaction? [2]

(c) Temperature / K Rate constant, k / s-1

300 1.86 x 10-5
400 7.74 x 10-5
The rate constants for the decomposition of N2O5 at two different temperatures are shown above.
Determine the order of reaction and calculate the activation energy, Ea for the reaction. [5]

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10

20 (a) Define Kw and explain why when the temperature increases, the Kw value also increases.
[3]

(b) A solution was prepared by mixing 100 cm3 of 0.03 mol dm-3 methanamine solution with
100 cm of 0.01 mol dm-3 of hydrochloric acid. Calculate the pH of the aqueous solution formed at 25
3
o
C. The base dissociation constant, Kb for methanamine is 4.30 x 10-4 mol dm-3 at 25 oC. [8]

(c) H2O(g) + C(s) H2(g) + CO(g) -1

(i) increasing pressure. [2]

(ii) increasing temperature. [2]

END OF QUESTIONS

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11

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12

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STPM 2023
PERATURAN PEMARKAHAN
PEPERIKSAAN PERCUBAAN
SEMESTER 1

CHEMISTRY
962/1

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SECTION A [15 marks]

Question No. Answer Question No. Answer

1 B 9 B
2 D 10 D
3 D 11 D
4 A 12 C
5 C 13 A
6 C 14 C
7 B 15 C
8 B

SECTION B [15 MARKS]

QUESTION SUGGESTED ANSWERS SUGGESTED

NO. MARKS
16 (a) The curve slopes to the left. 1

16 (b) This shows that the melting point decreases as the pressure 1
increases.
It also shows that as ice melts, its volume decreases, 1
indicating that the density of ice is lower than that of liquid water 1

16 (c) When solid water (ice) at X is heated under constant pressure, its
temperature increases as indicated by the dotted line on the graph
below.

Draw
1

1
Y OR ANY SYMBOL

At Y, ice starts to sublime, changing from the solid state into the
1
gaseous state without passing through the liquid state.
1
During sublimation, the temperature remains constant.

When all the ice has sublimed, continued heating will cause the
temperature of the water vapour to rise.

TOTAL 8

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QUESTION SUGGESTED ANSWERS SUGGESTED

NO. MARKS
17 (a)

Draw 1

Label 1
86oC

17 (b) (i) Boiling Point of mixture = 112° C 1

17 (b) (ii) 30% of A by mass 1

and 70% of B by mass 1
17 (c)

Vapour 1

Liquid 1

TOTAL 7

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SECTION C [30 MARKS]

QUESTION SUGGESTED ANSWERS SUGGESTED

NO. MARKS
18 (a) (i) The valence shell of configuration of Boron is 2s2 2p1
1

2s 2p

To form three covalent bonds with fluorine atoms, three unpaired 1

electrons are required. One electron from 2s orbital will be excited to
2p orbitals.
sp2 hybridizations between the 2s and 2p orbitals produces 3
equivalent hybrid orbitals arranged in trigonal planar geometry.
1

2s 2p
Boron needs 3 hybridized orbitals to make bonds with 3 atoms of F 1
where the 2p orbitals get overlapped with these hybridized sp2
orbitals and bonds are formed.

F 1

1
B F

1
The valence shell of configuration of nitrogen is 2s2 2p3

2s 2p

sp3 hybridizations between the 2s and 2p orbitals produces 4

equivalent hybrid orbitals arranged in tetrahedral geometry.

Overlapping between three of the hybrid orbitals with the 1s orbital

of hydrogen atoms gives the NH3 molecule with trigonal pyramidal
geometry

H
H

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QUESTION SUGGESTED ANSWERS SUGGESTED

NO. MARKS
18 (a) (ii) NH3 has a lone pair electron which can donor to BF3 that has 1
insufficient electron to form a dative bond. 1

18 (b) Water has higher boiling point than ammonia. 1

Oxygen atom has two lone pair electrons. So each H2O molecules 1
can form two intermolecular hydrogen bonding. 1

Nitrogen atom in ammonia has only one lone pair electron. Thus 1
each NH3 molecule can form only one intermolecular hydrogen 1
bonding.
TOTAL 15

19 (a) t½ = 0.693 1
k
k = 0.693 1
2600
= 2.67 x 10-4 years-1 1
19 (b) (i) Concentration of X against time :

[X] / mol dm-3

Labeled Axes
1
1.4
Points + Shape
1

1.2

1.0

0.8

0.6 Time / s
0 1000 2000 3000
1
The graph is a straight line with a negative gradient. 1
This shows that the rate of reaction against the concentration of X is
a constant. 1
Thus, the reaction is zero order with respect to X.
19 (b) (ii) The order of reaction is the sum of the powers of the concentration 1
of the reactants in the rate equation, if rate = k[A]m[B]n
Thus, the order of reaction = m + n 1

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QUESTION SUGGESTED ANSWERS SUGGESTED

NO. MARKS
19 (c) The order of reaction can be inferred from the unit of the rate
constant.
The unit s-1 is for first order reaction. 1

ln k1 = ln A Ea
RT1 1

ln k2 = ln A Ea
RT2

ln k1 = Ea 1 - 1
ln k2 R T2 T1 1

ln 1.86 x 10-5 = Ea 1 - 1
7.74 x 10-5 8.31 400 300 1

Ea = 14.8 kJ mol-1 1

TOTAL 15

20 (a) Kw is the ionic product for water. 1

Since the water dissociation process is endothermic, thus the heating 1
process will cause the equilibrium position shift to the right.
H2O(l) H+(aq) + OH-

Thus, Kw will increase with the heating process. 1

20 (b) The mixture is a buffer solution. CH3NH2 + HCl CH3NH3Cl

[CH3NH2] = 100 × 0.03 1

200
= 0.015 mol dm-3
[HCl] = 100 × 0.01 1
200
= 0.005 mol dm-3
Conc. of salt, [CH3NH3Cl] = Conc. of HCl, [HCl] = 0.005 mol dm-3 1
[CH3NH2] in excess = 0.01 mol dm-3 1

pOH = pKb + log [ ] 1

[ ]
pOH = log (4.30 × 10-4) + log (0.005) 1
(0.01)
= 3.37 + ( 0.3)
= 3.1 1
Therefore, pH = 14 3.1 = 10.9 1

20 (c) (i) Number of moles of gas on the left = 1

Number of moles of gas on the right = 2

Increasing the pressure will cause the equilibrium position to shift to 1

the left

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QUESTION SUGGESTED ANSWERS SUGGESTED

NO. MARKS
because the forward reaction involves an increase in the number of 1
moles of gas.

20 (c) (ii) The reaction to the right is endothermic. 1

Thus, heating will cause the equilibrium position shift to the right. 1

TOTAL 15

END OF MARKING SCHEME

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