Njeets - Fulltest-4 (29-12-2022)

FIITJEE - NJEETS
(JEE MAIN TEST SERIES - 2023)

CLASS – XII & XII PASS
Q.P. Code
FULL TEST - 4
0000.0
CONDUCTION DATE: 29-12-2022
Time Allotted: 3 Hours Maximum Marks: 300
▪ Do not open this Test Booklet until you are asked to do so.
▪ Please read the instructions carefully. You a re allotted 5 minutes specifically for this purpose.
Important Instructions
Caution: Question Paper CODE as given above MUST be correctly marked in the answer OMR sheet before
attempting the paper. Wrong CODE or no CODE will give wrong results.
A. General Instructions
1. Attempt ALL the questions. Answers have to be marked on the OMR sheets.
2. This question paper contains Three Sections.
3. Section-I is Physics, Section-II is Chemistry and Section-III is Mathematics.
4. Each Section is further divided into Two Parts: Part-A & C in the OMR. Part-B of OMR to be left unused
5. Rough spaces are provided for rough work inside the question paper. No additional sheets will be provided for rough
work.
6. No candidate is allowed to carry any textual material, printed or written, bits of papers, clip boards, log tables, slide
rule, calculator, cellular phones, pagers and electronic devices ext. except the Admit Card inside the examination hall
/ room.
B. Filling of OMR Sheet:

1. Ensure matching of OMR sheet with the Question paper before you start marking your answers on OMR sheet.
2. On the OMR sheet, darken the appropriate bubble with Blue/Black Ball Point Pen for each character of your
Enrolment No. and write in ink your Name, Test Centre and other details at the designated places.
3. OMR sheet contains alphabets, numerals & special characters for marking answers.
4. Do not fold or make any stray marks on the Answer Sheet.
C. Marking Scheme for All Two Parts:

(i) Part-A (01-20) – Contains Twenty (20) multiple choice objective questions which have four (4) options each and only
one correct option. Each question carries +4 marks will be awarded for every correct answer and -1 mark will be
deducted for every incorrect answer.
(ii) Part-C (01-05) contains Five (05) Numerical based questions with single digit integer as answer, ranging from 0 to 9
(both inclusive). Each question carries +4 marks will be awarded for every correct answer and NO MARKS will be
deducted for every incorrect answer.
Name of the Candidate :_______________________________________________
Batch :_______________________ Date of Examination :____________________
Enrolment Number :___________________________________________________
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www.facebook.com/FIITJEENOIDAOFFICIAL @fiitjee_Noida F Website:www.fiitjeenoida.com
NJEETS-2023 - FT -4 -PCM -2
Useful Data Chemistry:

Gas Constant = 8.314 J K−1 mol−1
R
= 0.0821 Lit atm K−1 mol−1
= 1.987  2 Cal K−1 mol−1
Avogadro's Number Na = 6.023  1023
Planck’s Constant h = 6.626  10–34 Js
= 6.25 x 10-27 erg.s
1 Faraday = 96500 Coulomb
1 calorie = 4.2 Joule
1 amu = 1.66 x 10-27 kg
1 eV = 1.6 x 10-19 J
Atomic No : H=1, D=1, Li=3, Na=11, K=19, Rb=37, Cs=55, F=9, Ca=20, He=2, O=8,
Au=79.
Atomic Masses: He=4, Mg=24, C=12, O=16, N=14, P=31, Br=80, Cu=63.5, Fe=56,
Mn=55, Si = 28 Pb=207, u=197, Ag=108, F=19, H=2, Cl=35.5
Useful Data Physics:
2
Acceleration due to gravity g = 10 m / s

Section – I (Physics)
PART – A
Single Correct Choice Type
1. Find the centre of mass of a uniform circular arc from point O.

R
  2R   
(A) 2R sin   (B) sin  
2   2 O 
R 
  R  
(C) sin   (D) sin  
  2 2  2
2. An insulating rod of length l carries a charge q distributed uniformly on it. The rod is pivoted at its mid point
and is rotated at a frequency f about a fixed axis perpendicular to rod and passing through the pivot. The
1
magnetic moment of the rod system is  qfl 2 . Find the value of a.
2a
(A) 6 (B) 4 (C) 5 (D) 8
3. The magnetic flux (in weber) linked with a coil of resistance 10 is varying with respect to time t as
 = 4t 2 + 2t + 1. Then the current in the coil at time t = 1 second is
(A) 0.5 A (B) 2 A (C) 1.5 A (D) 1 A
4. A mono atomic ideal gas is filled in a non conducting container. The gas can be compressed by a movable
non conducting piston. The gas is compressed slowly to 12.5% of its initial volume. The ratio of initial
adiabatic bulk modulus of the gas to the final value of adiabatic bulk modulus of the gas is :
1 1 1 1
(A) (B) (C) (D)
4 8 32 16
5. If the ratio of lengths, radii and Young’s modulii of steel and

brass wires in the figure are a, b and c respectively. Then the Steel
corresponding ratio of increase in their lengths would be:
M
2a 2 c 3a
(A) (B) Bras
b 2b 2 c
2ac 3c
(C) (D) 2M
b2 2ab2
space for rough work

T
6. In a thermodynamic process, helium gas obeys the law = constant. The heat given to the gas when
P2 5
temperature of 2 moles of gas is raised from T to 2T
(A) 8RT (B) 4RT (C) 16RT (D) Zero
7. The self inductance of a choke coil is 10 mH. When it is connected with a 10 V. D.C. Source, then the loss of
power is 20 watt. When it is connected with 10 V A.C. source loss of power is 10 watt. The frequency of A.C.
source will be
(A) 50 Hz (B) 60 Hz (C) 80 Hz (D) 100 Hz
8. 200  resistance and 1H inductance are connected in series with an A.C. circuit. The frequency of the
200
source is Hz. The phase difference in between V and I will be
2
(A) 30 (B) 60 (C) 45 (D) 90
9. In a circuit L, C and R are connected in series with an alternating voltage source of frequency f. The current
leads the voltage by 45. The value of C is
1 1 1 1
(A) (B) (C) (D)
2f (2fL + R ) 2f (2fL − R ) f (2fL − R ) f (2fL + R )
10. A mirror is inclined at an angle of  with the horizontal. If a ray of light is incident at an angle  as shown,
then the angle made by reflected ray with the horizontal is

(A)  (B) 2 (C) (D) zero
2

11. A ray of light travels from optical denser medium to rarer medium. The critical angle for the two media is C.
The maximum possible deviation of the refracted light ray can be

(A)  −C (B) 2C (C)  − 2C (D) −C
2
12. A uniformly tapering vessel is filled with a liquid of -3 2
density 900 kgm-3. The force that acts on the base of Area = 10 m
the vessel due to the liquid is (g = 10 m/s2) 0.4m
2  10 m
-3 2
(A) 3.6 N (B) 7.2 N (C) 9.0 N (D) 12.6 N
13. An ice block floats in a liquid whose density is less than water. A part of block is outside the liquid. When
whole of ice has melted, the liquid level will
(A) rise (B) go down
(C) remain same (D) first rise then go down
14. The condition for a uniform spherical mass m of radius r to be a black hole is : (G = gravitational constant
and g = acceleration due to gravity at the surface of sphere)
(A) (2 Gm/r)1/2  c (B) (2 gm/r)1/2 = c (C) (2 Gm/r)1/2  c (D) (Gm/r)1/2  c
15. The largest and the shortest distances of the earth from the sun are r 1 and r2. Its distance from the sun when
it is at the perpendicular to the major axis of the orbit drawn from the sun, is :
r1 + r2 r1r2 2r1r2 r1 + r2
(A) (B) (C) (D)
4 r1 + r2 r1 + r2 3
16. The gram specific heat of many solids at low temperatures varies with absolute temperature T according to
the relation S = AT3, where A is a constant. The heat energy required to raise the temperature of a mass m
of such a solid from T = 0 K to T = 20 K is :
(A) 4 × 104 mA (B) 2 × 103 mA (C) 8 × 106 mA (D) 2 × 106 mA


17. A black body is at a temperature of 2800 K. The energy of radiation emitted by this object with wavelength
between 499 nm and 500 nm is U1, between 999 nm and 1000 nm is U2 and between 1499 nm and 1500 nm
is U3. The Wien’s constant b = 2.80 × 106 nm K. Then :
(A) U1 = 0 (B) U3 = 0 (C) U3 > U2 (D) U2 > U1
18. A stationary source of sound emits waves with frequency f Hz and the speed of sound in air is V m/sec. Two
observers move away from this source in opposite directions each with a speed 0.2 V relative to the source.
The ratio of frequencies heard by the two observers will be
(A) 3 : 2 (B) 2 : 3 (C) 1 : 1 (D) 4 : 10
19. A source of sound is travelling towards a stationary observer. The frequency of sound heard by the observer
is of three times the original frequency. The velocity of sound is v m/sec. The speed of source will be
2 3
(A) v (B) v (C) v (D) 3v
3 2
20. Two hydrogen atoms are in excited state with electrons residing in n = 2. First one is moving towards left and
emits a photon of energy E1 towards right. Second one is moving towards left with same speed and emits a
photon of energy E2 towards left. Taking recoil of nucleus into account during emission process
(A) E1 > E2 (B) E1 > E2 (C) E1 = E2 (D) information insufficient
PART – C
Numerical Based Questions
1. Consider thick hollow sphere of inner radius R and outer radius 2R with inner surface maintained at 600k
and outer surface at 300k. Assume that the material of sphere has uniform thermal conductivity. If the
temperature at a radius 1.5R can be written as (100n)k, then find n?
2. The gravitational potential of two homogeneous spherical shells of same surface density at their respective
centres are 3 V and 4 V. If the two shells coalesce into single one keeping surface density same, the
potential at a point inside the shell is kv. Find k.
3. A raft of wood of mass 120 kg floats in water. The weight that can be put on the raft to make it just sink is
(10 x) kg. Find value of x. Given density of raft = 600 kg / m 3.
4. A horizontal telegraph wire 0.5 km long running east and west is a part of a circuit whose resistance is 2.5 .
The wire falls on the ground from a height of 5m. If g = 10 m/s2 and B = 2  10−5 weber/m2, then the current
induced in the circuit is k amp. Then the value of 100k is
5. A charged particle +q of mass m is placed at a distance d from q,m

   −2q,2m
another charged particle -2q of mass 2m in a uniform magnetic 2Vm 2Vm
field B as shown in figure. If the particle are projected towards
each other with equal speed of 2Vm where Vm is the maximum   
value for which the two particles do not collide, then the time after
d
which collision occurs between the particles is found to be
m   
nqB
where value of n is

Section – II (Chemistry)
PART - A
1. At a certain temperature, Kp for dissociation of solid of CaCO3 is 4 × 10–2 atm and for the reaction,
C( s ) + CO2 2CO is 2.0 atm respectively. Calculate the pressure of CO at this temperature when solid C,
CaO, CaCO3 are mixed and allowed to attain equilibrium.
(A) 0.28 (B) 0.68 (C) 0.98 (D) 1.08
2. Calculate pH of 0.2 M HCOONH4 solution. ( K HCOOH = 1.8 10−4 , K NH3 = 1.8 10−5 )
[The value of log(3.16) =0.499]
(A) 6.5 (B) 4.6 (C) 5.6 (D) 5.9
3. N2O4 dissociates as N2O4 2 NO2 . At 55°C and an equilibrium pressure of one atmosphere the
decomposition of N2O4 is 50.3%. At what P and same temperature, the equilibrium mixture will have the
mole fraction ratio of N 2O4 : NO2 as 1 : 8 ?
(A) 1.9 (B) 0.29 (C) 0.19 (D) 0.91
4. Which of the following has lowest PKa value? (Considering planar structures are more resonance stabilized)
CH
(A) (B) CH2
(C) H (D) H

5. Which one of the following would be most stable?
(A) (B) (C) (D)
6. How many constitutional isomers are there in the molecular formula C5H11Br?
(A) 5 (B) 6 (C) 8 (D) 10
7. The ion that cannot be precipitated by both HCl and H2S is

2+ + + 2+
(A) Pb (B) Cu (C) Ag (D) Sn
8. The value of  = 0 for a molecule AB3. Which of the following species represents AB3?
(A) PH3, ICl3 (B) SO3, ICl3
(C) PCl3, SO3 (D) SO3, BCl3
The oxidation of certain metal is found to obey the equation A = t +  , where A is the thickness of the
2
9.
oxide film at time t,  and  are constants. What is the order of this reaction?
(A) 1st order (B) - 1 order (C) 2 order (D) zero order
10. The species having pyramidal shape is

(A) SO3 (B) BrF3 (C) PCl5 (D) SOF2
11. Which one in reaction with NaOH solution gives inflammable gas?
(A) S (B) Zn (C) NH4Cl (D) I2
12. Which of the following sublime on heating?
(A) Al2O3 (B) Al(OH)3 (C) (AlH3)n (D) (AlCl3)n


13. The silicate anion in the mineral kinoite is a chain of three SiO 4 tetrahedral that share corners with adjacent
tetrahedral. The change of the silicate anion is:
(A) –4 (B) –8 (C) –6 (D) –2
14. For which elements would XH3 be a stable species:

(A) C (B) Si (C) P (D) S
15. When Mg burn in air, it produces:

(A) MgO, MgO2 (B) MgO, Mg3N2, MgO2
(C) Mg3N2 only (D) Mg3N2 and MgO
16. If the equilibrium constant of the two reactions; 2NH3 N2+3H2

1 3
and N2 + H2 NH3 are K1& K2 respectively at 25C, then the relation between K1 and K2 is
2 2
1 1 1
(A) K1 = K2 (B) K2 = (C) K1 = (D) K1 =
K 12 K 22 K2
17. The stereochemical relationship between the following pair of molecules is

Br H H Br
Cl
Cl H H
(A) identical (B) enantiomers (C) diastereomers (D) constitutional isomers
18. A solution gives the following colours with different indicators:

(I) Methyl orange  Yellow
(II) Methyl red  Yellow
(III) Bromothymol blue  Orange
Range of indicators is:
Methyl orange 3.1− 4.5
Red Yellow
Methyl red 4.2− 6

Pink Yellow
Bromothymol blue 6.3 − 7.5

Orange Blue
What is the pH of solution given?
(A) pH range is between 4.5 to 6 (B) pH range is between 6 to 6.3

(C) pH range is between 4.2 to 4.5 (D) pH range is between 4.2 to 7.5

NJEETS-2023 - FT -4 -PCM -10
19. Benzene reacts with Cl2 in the presence of FeCl3 and in absence of sunlight to form
(A) benzyl chloride (B) benzal chloride (C) chlorobenzene (D) benzenehexachloride
20. Which of the following reagent will bring about the following transformation?
HO H
(A) Cl2/H2O (B) PBr3/H+ (C) Hg(OAc)2/H+ (D) Hydroboration oxidation
PART – C
1. Total number of boron atoms in anionic part of borax which participate in back bonding.
2. What is the pOH of 0.1 M kB (salt of weak acid and strong base) at 25°C? (Given : PK b of B– = 7)
3. The hydration energy of alkaline eather metal ions is higher than that of alkali metal ions. So
MgCl2 , XH 2 O and CaCl2 , XH 2 O can exist. What is the value of X ?
4. The number of hydroxyl group in pyrophosphoric acid is
5. An acid type indicator HIn differs in colour from its conjugate base (In-). The human eye is sensitive to colour
differences only when the ratio [In-]/[HIn] is greater than 10 or smaller than 0.1. What should be the minimum
change in the pH of solution to observe a complete colour change?
( Ka = 110−5 )
pace for rough work

NJEETS-2023 - FT -4 -PCM -11
Section – III (Mathematics)

PART – A
1. Let p, q be integers and let  ,  be the roots of equation x 2 − x − 1 = 0 where    . For n = 0, 1, 2, …, let
an = p n + q n . (Note If a and b are rational numbers and a + b 5 = 0 then a = b = 0.) Then a12 is equal
to
(A) a11 – a10 (B) a11 + a10 (C) 2a11 + a10 (D) a11 + 2a10
2. From external point P, pair of tangent lines are drawn to the parabola y 2 = 4x. If 1 and 2 are inclination of

these tangents with x axis such that 1 +  2 = then locus of P is
4
(A) x − y +1 = 0 (B) x + y −1 = 0 (C) x − y −1 = 0 (D) x + y +1 = 0
Let S be the set of all non –zero real numbers  such that the quadratic equation  x − x +  = 0 has two
2
3.
distinct real roots x1 and x 2 satisfying the inequality x1 − x2  1. Then find the interval which is a subset of
S.
 1   1 1   1   1 
(A)  ,10  (B)  − , −  (C)  − ,0  (D)  0, 
 2   2 5  5   5
4. If [ x ] denotes greatest integer  x and ( ) n

g = 3 + 5 , then [g] must be
(A) (3 + 5 ) + (3 − 5 )
n n
+1 (B) (3 + 5 ) + (3 − 5 )
n n
−1
(C) (3 + 5 ) + (3 − 5 ) (D) (3 + 5 ) − (3 − 5 )
n n n n
5. A seven digit number without repetition and divisible by 9 is to be formed by using 7 digits out
of 1,2,3,4,5,6,7,8,9 . The number of ways in which this can be done is
(A) 9 (B) 2 7 (C) 4 7 (D) none of these


NJEETS-2023 - FT -4 -PCM -12
6. The number of words that can be made by writing down the letters of the word CALCULATE, such that each
word either start with U or end with T, is
15 ( 7 !) 3 ( 7 !) 3(5 !)
(A) (B) (C) 2 (7 !) (D)
( 2)3 ( 2)3 4
7. The area bounded by the curve |x| + |y| ≥2 and x² + y² ≤ 4 is
(A) 2 (B) π (B) 4(π – 2) (D) 4 (π + 2)
8. The area contained between the curve y²(a – x) = x² (a + x) and the line x = a (a > 0) is
       
(A) 2a 2 1 +  (B) a 2 1 +  (C) 2a 2 1 +  (D) a 2 1 + 
 4  4  3  3
2 3
 dy  x 2 y 2  dy  x 3 y 3  dy 
9. The solution of DE x = 1 +  xy  +   +   + ...... is
 dx  2  dx  3  dx 
(C) y =  ( ln x ) +c
2
(A) y = lnx + c (B) y = (lnx)² + c (D) None of these
10. Solution of (1 – xy – x⁵y⁵)dx = x²(x⁴y⁴ + 1)dy is
( xy ) ( xy )
5 5
(A) ln x = xy + +c (B) ln y = xy + +c
5 5
( xy )
4
(C) ln y = xy + +c (D) None of these

4
11. A letter is taken at random from the letters of the word (STATISTICS) and another letter is taken at random
from the letter of the word ‘ASSISTANT’. The probability that they are the same letter is
1 13 19 5
(A) (B) (C) (D)
45 90 90 18

NJEETS-2023 - FT -4 -PCM -13
1
12. Let E1 , E2 , E3 ,.....En are n independent events such that P ( E1 ) = for 1  i  n. The find probability that
2i + 1
none of E1 , E2 , E3 ,...En occurs is
( n) ( n)
2 2
1 n
(A) (B) 2 n
(C) 2 2n
(D) 2 n
n +1 2n + 1 2n + 1 2n + 1
x2 y2 PM 2
13. If normal at any point P to the ellipse + = 1 ( a  b ) meet the axes at M and N so that = . Then
2 2 PN 3
a b
the value of eccentricity is
1 2 1
(A) (B) (C) (D) None of these
2 3 3
ax by x2 y 2
14. If straight line + = c is a normal to the ellipse + = 1 ( a  b ) , then a 2 − b 2 is equal to
3 4 2 2
a b
(A) 4c (B) 5c (C) 6c (D) None of these
15. If the eccentricity of the hyperbola x 2 − y 2 sec2  = 5 is 3 times the eccentricity of the ellipse
2 2 2
x sec  + y = 25, then a value of ‘α’ is
(A) /6 (B) /4 (C) /3 (D) /2
16. The locus of the foot of the perpendicular from the centre of the hyperbola xy = c 2 on a variable tangent is
( x2 − y2 ) = 4c2 xy ( x2 + y2 ) = 2c2 xy
2 2
(A) (B)
(C) ( x 2 + y 2 ) = 4c 2 xy (D) ( x 2 + y 2 ) = 4c 2 xy
2

NJEETS-2023 - FT -4 -PCM -14
17. Intercept made by the circle zz + z + z + r = 0 on the real axis on complex plane is
(A) +−r (B) (  +  )2 − 2r (C) (  +  )2 + r (D) (  +  )2 − 4r
18. If |z − 25i|  15, then, |max arg(z) − min arg(z)| equals

(A) 2 cos−1 ( 3 5 ) (B) 2 cos−1 ( 4 5 ) (C) + cos−1 ( 3 5 ) (D) sin −1 ( 3 5 ) − cos−1 ( 3 5 )
2
19. In triangle ABC if sin 3 A + sin 3 B + sin 3 C = 3 sin A  sin B  sin C then triangle is
(A) obtuse angled (B) right angled (C) equilateral (D) None of these
20. The number of solutions of the equation tan 2 x − sec10 x + 1 = 0 in (0, 10) is
(A) 3 (B) 6 (C) 10 (D) 0
PART – C
1. In a triangle ABC, a : b : c = 4 : 5 : 6. The ratio of the radius of the circumcircle to that of the incircle is k then
value of (7k-8) is…
2. The number of solutions of the pair of equations 2 sin 2  − cos 2 = 0 and 2 cos2  − 3 sin  = 0 in the interval
[0, 2] is
3. Number of common tangent with finite slope to the curves xy = c 2 and y 2 = 4 ax is…
x2 y 2
4. If S and S are the foci of the ellipse + = 1 and P is any point on it, then difference of maximum and
25 16
minimum value of SP  SP is…
5. If a > 0, and the equation |z − a2 |+|z − 2 a|= 3 represents an ellipse, then number of integral values of a is….

NJEETS-2023 - FT -4 -PCM -15
FIITJEE - NJEETS
(JEE MAIN TEST SERIES - 2023)
CLASS - XII
FULL TEST - 4
CONDUCTION DATE: 29-12-2022
Q.P.CODE: 00000.0
ANSWERS
PART – A
1. B 2. A 3. D 4. C
5. B 6. D 7. C 8. C
9. A 10. D 11. D 12. B
13. B 14. C 15. C 16. A
17. D 18. C 19. A 20. B
PART – C
1. 4 2. 5 3. 8 4. 2
5. 6
PART – A
1. A 2. A 3. C 4. D
5. C 6. C 7. D 8. D
9. B 10. D 11. B 12. D
13. B 14. C 15. D 16. C
17. B 18. B 19. C 20. D
PART – C
1. 2 2. 4 3. 6 4. 4
5. 2

PART – A
1. B 2. C 3. B 4. B
5. C 6. A 7. C 8. A
9. C 10. A 11. C 12. C
13. C 14. B 15. B 16. D
17. D 18. B 19. C 20. A
PART – C
1. 8 2. 2 3. 1 4. 9
5. 2

NJEETS-2023 - FT -4 -PCM -16
HINTS & SOLUTIONS

PART – A
1. B
Sol. Consider an element on the arc.
then use the formula,
1
M
xCM = xdm
2. A
q 
 dx  
dm = 
l 
Sol.  x2
2
q 2 ql 2 q fl 2
l /2
M=  x dx; M = =
−l / 2
2l 24 12
3. D
Sol. Given  = 4t 2 + 2t + 1wB
d d
 = ( 4t 2 + 2t + 1) = 8t + 2 = 
dt dt
 8t + 2 8t + 2
Induced current, I = = = A
R 10 10
At t = 1s,
8 1 + 2
I= A = 1A
10
4. C
dP  − P 
Sol.  = −V = −V  =P
dV  V 
i  Pi V j
5/3 5/3
1 1
= = 5/3 =   =
Bj  Pj Vi 8 32
5. B
LB ( 2mg ) L  ( br ) cY
2
Sol. =
LS  r 2Y 3mgaL
LS 3a
= 2
LB 2b c
6. D
Sol. TP2/5 = constant  PV5/3 = constant
5
=
3
Adiabatic process
Q=0
7. C
V 2 (10 )
2
Sol. R= = = 5
P 20
V2  V 2  R 
In AC circuit, P = VI cos  = cos  =   
Z  Z  Z 
NJEETS-2023 - FT -4 -PCM -17
10 =
(10)2 5  L = 5
(5)2 + (L)2
5  5 5
 = f = = = = 80 Hz
L 2 2L 2.3.14 10 10 −3
8. C
x  L  −1  200  1 
Sol.  = tan −1   = tan −1   = tan   = 45
R  R   200 
9. A
xc − xL 1
Sol. tan 45 = R= − 2fL
R 2fC
I
45°
V
1 1
 R + 2fL = C =
2fC 2f (2fL + R )
10. D
Sol. By drawing reflected ray and using geometry.
11. D
 
Sol. Maximum possible deviation =  = −C
2 
12. B
Sol. (  gh ) A = F
900 10  0.4  2 10−3 = 7.2
13. B
Sol. As being floating as ice same volume of water is displaced as the amount of water obtained by melting that
ice.
14. C
Sol. The criterion for a star to be black hole is :

Gm 1

c 2r 2
2Gm
or c .
r
15. C
Sol.
x 2 + ( r2 − r1 )
2
x
r1
r1 r2 – r1
sun focus 2
x+ ( r2 − r1 )
+ x 2 = 2a = r1 + r2
2
solve and get x.

16. A

NJEETS-2023 - FT -4 -PCM -18
20 20
Sol. Q =  ms dT = m AT 3 dT
0 0
Q = 4 × 104 mA
17. D
Sol. According to Wien’s Law, mT = b

b 2.80  106
So,  m = = = 1000nm
T 2800
Hence, U2 is maximum, i.e., U2 > U1
18. C
Sol. Conceptual
19. A
c
Sol. f = f  3c − 3v = c
c−v
2
v= c
3
20. B
Sol.
In the first case K.E. of H-atom increases due to recoil whereas in the second case K.E. decreases due to
recoil
 E2  E1
PART – C
1. 4
 1 1
Sol. T = T0 – C  − 
R r 
Temperature at r = 1.5 R, is T = 400 K
2. 5
− K 4 R 2
Sol. Potential V = = cR
R
 is surface mass density
c is constant
R = R12 + R22 by conserving mass
3 = cR1
4 = cR2
V = cR = c R12 + R22 = 5
3. 8
Sol. Mass of displaced

Water = volume of raft× density of water
120
=  100 = 200 kg
600
Wt. Kept on reft = 200 –120 = 80 kg

NJEETS-2023 - FT -4 -PCM -19
4. 2
e 1 d
Sol. I= =
R R dt
Here, d = B  A = 2  10−5  0.5  103  5 = 5  10−2
dt = time taken by the wire to fall at ground
2A 10
= = = 1 second
g 10
1  5  10 −2  −2
 I=   = 2  10
2.5  1 
5. 6
d t
Sol.
2 0 
= 2Vm cos dt
PART – A
1. A
Sol. For dissociation of CaCO3
CaCO3( s ) CaO( s ) + CO2( g )
Given that, K p = 4 10−2 = P 'CO2
For the formation of CO, C( s ) + CO2( g ) 2CO( g )
( PCO )2
Kp = = 2.0
P 'CO2
Now both are at equilibrium and thus P 'CO2 = 4 10−2 which should remain constant,
Thus 2.0 =
( P 'CO )2
 P 'CO = 0.28
4 10−2
2. A
HCOO − + NH 4+ + H 2O HCOOH + NH 4OH
Sol. Weak base Weak base
At equilibrium C(1–h) C(1-h) C −h C −h
Kw 10−14
Kh = = = 3.09 10−6
K a  Kb 1.8 10−4 1.8 10−5
h
Degree of hydrolysis, = K h = 3.09 10−6 = 1.76 10−3
1− h
h = 1.7569 10−3
For the dissociation of HCOOH
HCOOH HCOO − + H +
C −h C (1− h )
 H +  = Ka
 HCOOH  = Ka  C.h = K  h = 1.8 10−4 1.76 10−3 = 3.168 10−7
   HCOO−  C (1 − h )
a
1− h
 
or − log  H +  = − log 3.168  10−7
or pH = 6.4992
3. C

NJEETS-2023 - FT -4 -PCM -20
N 2O4 2 NO2
Sol.
At t = 0 1 0
At equilibrium (1 -  ) 2
( nNO )  P n ( 2 )2  P 
2 1
KP =  2
=  
( nN O4 )  n  (1 −  )  (1 +  ) 
2
4  ( 0.503) 1
2
4 2 P
KP = = = 1.355 ( = 0.503)
1 − 2 1 − ( 0.503)
2
N 2O4 2 NO2
1 0
(1− x ) 2x
N 2 O4 1 − x 1
Or = =  x = 0.8
NO2 2x 8
Writing KP again at pressure P
4 x2  P
 KP =
1 − x2
4  ( 0.8)  P
2
1.355 =  P = 0.19 atm
1 − ( 0.8)
2
4. D
Sol. Due to planarity
5. C
Sol. Since the two  bonds are in resonance as well as most hyperconjugated.
6. C
Sol. It is based on parent hydrocarbon C5H12
Mono brominaton of above give 8 isomer.

7. D
Sol. Sn 2 + can be precipitated by H2S but not by HCl.
8. D
Sol. Symmetric structures of SO3 and BCl3.
9. B
Sol. A2 =  t + 
On differentiating the equation
−2AdA =   dt
dA  
=  A
−1
− =
dt 2 A 2
Thus, reaction has order = -1
10. D
Sol.
S
O F
F
11. B
Sol. NaOH + Zn ⎯→ Na2ZnO2 + H2
12. D
Sol. Factual

NJEETS-2023 - FT -4 -PCM -21
13. B
Sol. Si3O188–
14. C
+3 +5
Sol. NO2− ⎯⎯→ NO3−
15. D
1 
Mg + O2 ⎯⎯ → MgO
Sol. 2

3Mg + N 2 ⎯⎯ → Mg3 N 2
16. C
1
Sol. For opposite reactions, K1 =
K2
For multiple of reaction, K1 = ( K 2 )
n
17. B
Sol.
Br Cl
Draw fisher projection
Cl Br
18. B
Sol. Factual
19. C
20. D
Sol. HBD reaction gives antimarkonikoff’s product with rearrangement.
PART – C
1. 2
OH
B
O O
Sol. O
HO B B OH
O O
B
OH
2. 4
K w.c
Sol. OH−  =
ka
3. 6
Sol. MgCl2  6 H 2 O and CaCl2  6 H 2O can exist.
4. 4
Sol. H 4 P2O7
O O
HO P O P OH
OH OH
4 –OH group are present
5. 2
( ln − )
Sol. ( pH )1 = pK a + log = pK a + log10 = pK a + 1
 Hln 

NJEETS-2023 - FT -4 -PCM -22
( ln ) = pK
−
1
( pH )2 = pK a + log + log = pK a − 1
 Hln  a
10
( pH )1 − ( pH )2 = ( pKa +1) − ( pKa −1) = 2
PART – A
1. B
Sol. As an +1 = an + an −1 .
2. C
1
Sol. y = mx +
m
m h − mk + 1 = 0
2
k 1
m1 + m2 = , m1m2 =
h h
 tan 1 + tan  2
1 +  2 =  1 =
4 1 − tan 1 tan  2
k
1 = h  y = x −1
1
1−
h
3. B
 1 1 1
Sol. (i) D  0     − ,  ; x1 + x2 = ; x1 x2 = 1; x1 − x2  1
 2 2 
1
− 4 1
2
4. B
Sol. (
g = 3+ 5 )
n
= [g] + f
Consider another fraction f = 3− 5 ( )
n
 [g] + ( )(
n
f + f  = 3 + 5 3 − 5 = integer ) n
and 0  f  1 and 0  f   1  f + f  = 1
( ) (
n
so [ g ] = 3 + 5 + 3 − 5 − 1 )
n
5. C
Sol. Sum of 7 digit=a multiple of 9
Sum of numbers 1,2,3,4,5,6,7,8,9=45
So two left should also have sum of 9 ie left pair of numbers are (1,8)( 2,7)( 3,6 )( 4,5 )
So total number formed = 4  7
6. A
Sol. Solve by inclusion exclusion principle
7. C
1
Sol. Area of circle = π(4) and area of square =  4 4 − 4 2 = 8
2
so required area = (4π – 8).
8. A

NJEETS-2023 - FT -4 -PCM -23
a a
a+x
a
x (a + x)
Sol. Required Area = 2 ydx = 2 x 
0

0
a−x
dx = 2
0 a2 − x2
dx
Put x = a sin
9. C
dy ln x
Sol. x = e( xydy / dx ) → xy = ln x → dx = ydy
dx x
( ln x )
( )
2
y2
c+ = → y 2 = ( ln x ) + K → y =  ( ln x ) +K
2 2
2 2
10. A
Sol. (1 − xy ) dx − x2dy = x6 y 4dy + x5 y5dx
 x dx =  ( x y 4 + 1) dxy
1 4
11. C
2 2 9 6 19
Sol. Probability of choosing A, I, S, T is + + + =
90 90 90 90 90
12. C
P ( Ei ) = 1 − P ( E1 ) = 1 −
1 2i
Sol. =
2i + 1 2i + 1
22 n ( n )
2
2  4  6  8....2n
( ) ( )
so P E1 P E2 .....P ( En ) =
3  5  7  ....( 2n + 1)
=
2n + 1
13. C
a4
Sol. (
PM2 = b2 1 − e2 cos2  , PN 2 = ) b2
(1 − e2 cos2 )
2
 PM  4 b4 b2 2
  = = 4 2 =
 PN  9 a a 3
14. B
Sol. a sec x − b cosecy = a2 − b2 ... (i)
a b
x+ y =c ... (ii)
3 4
(i) and (ii) are identical
3c −4c
cos  = , sin  =
2 2
a −b a − b2
2
15. B
2
Sol. eH = 1 + cos2 , eE2 = sin2 
16. D
Sol. hx + ky = h2 + k 2 ... (i)
x
+ yt = 2c ... (ii)
t
(i) and (ii) are identical
k h2 + k2
ht = =
t 2c
17. D
Sol. ( z1 + z2 )2 − 4z1 z2 = (  +  )2 − 4r

NJEETS-2023 - FT -4 -PCM -24
A(z1, 0) B(z2, 0) Real axis
18. B
  OA 4
Sol. cos  −   = =
 2  OC 5
y
25 i 15
B 25 A

x
O 19. C
3 3 3
Sol. sin A + sin B + sin C − 3 sin A  sin B  sin C = 0
(
( sin A + sin B + sin C ) ( sin A − sin B)2 + ( sin B − sin C )2 + ( sin A − sin C )2 )=0
sin A + sin B + sin C  0
sin A = sin B = sin C
20. A
Sol. (
sec2 x 1 − sec8 x = 0 )
2
sec x = 1
PART – C
1. 8
a b c R abc  S 16
Sol. = = = then = =
4 5 6 r 4 2 7
2. 2
 5
Sol. = ,
6 6
3. 1
Sol. Draw diagram of hyperbola and parabola
4. 9
Sol. ( SP )( SP ) = 25 − 9 cos2 
5. 2
Sol. |a2 − 2 a| 3


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FIITJEE - NJEETS

(JEE MAIN TEST SERIES - 2023)

Time Allotted: 3 Hours Maximum Marks: 300

B. Filling of OMR Sheet:

C. Marking Scheme for All Two Parts:

Name of the Candidate :_______________________________________________

Batch :_______________________ Date of Examination :____________________

Enrolment Number :___________________________________________________

FIITJEE Tower, C-56A/26, Institutional Area,Sec-62, Noida-201307. Ph: 0120-4754800/ 9599596524

Useful Data Chemistry:

FIITJEE Tower, C-56A/26, Institutional Area,Sec-62, Noida-201307. Ph: 0120-4754800/ 9599596524

1. Find the centre of mass of a uniform circular arc from point O.

(A) 0.5 A (B) 2 A (C) 1.5 A (D) 1 A

5. If the ratio of lengths, radii and Young’s modulii of steel and

space for rough work

FIITJEE Tower, C-56A/26, Institutional Area,Sec-62, Noida-201307. Ph: 0120-4754800/ 9599596524

FIITJEE Tower, C-56A/26, Institutional Area,Sec-62, Noida-201307. Ph: 0120-4754800/ 9599596524

(A) 3.6 N (B) 7.2 N (C) 9.0 N (D) 12.6 N

(A) (2 Gm/r)1/2  c (B) (2 gm/r)1/2 = c (C) (2 Gm/r)1/2  c (D) (Gm/r)1/2  c

(A) 4 × 104 mA (B) 2 × 103 mA (C) 8 × 106 mA (D) 2 × 106 mA

FIITJEE Tower, C-56A/26, Institutional Area,Sec-62, Noida-201307. Ph: 0120-4754800/ 9599596524

(A) U1 = 0 (B) U3 = 0 (C) U3 > U2 (D) U2 > U1

(A) E1 > E2 (B) E1 > E2 (C) E1 = E2 (D) information insufficient

5. A charged particle +q of mass m is placed at a distance d from q,m

space for rough work

FIITJEE Tower, C-56A/26, Institutional Area,Sec-62, Noida-201307. Ph: 0120-4754800/ 9599596524

(A) 0.28 (B) 0.68 (C) 0.98 (D) 1.08

(A) 6.5 (B) 4.6 (C) 5.6 (D) 5.9

(A) 1.9 (B) 0.29 (C) 0.19 (D) 0.91

(A) (B) CH2

space for rough work

FIITJEE Tower, C-56A/26, Institutional Area,Sec-62, Noida-201307. Ph: 0120-4754800/ 9599596524

5. Which one of the following would be most stable?

(A) (B) (C) (D)

(A) 5 (B) 6 (C) 8 (D) 10

7. The ion that cannot be precipitated by both HCl and H2S is

10. The species having pyramidal shape is

(A) S (B) Zn (C) NH4Cl (D) I2

12. Which of the following sublime on heating?

(A) Al2O3 (B) Al(OH)3 (C) (AlH3)n (D) (AlCl3)n

FIITJEE Tower, C-56A/26, Institutional Area,Sec-62, Noida-201307. Ph: 0120-4754800/ 9599596524

14. For which elements would XH3 be a stable species:

15. When Mg burn in air, it produces:

16. If the equilibrium constant of the two reactions; 2NH3 N2+3H2

17. The stereochemical relationship between the following pair of molecules is

18. A solution gives the following colours with different indicators:

Methyl red 4.2− 6

Bromothymol blue 6.3 − 7.5

(A) pH range is between 4.5 to 6 (B) pH range is between 6 to 6.3

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(A) Cl2/H2O (B) PBr3/H+ (C) Hg(OAc)2/H+ (D) Hydroboration oxidation

4. The number of hydroxyl group in pyrophosphoric acid is

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Section – III (Mathematics)

4. If [ x ] denotes greatest integer  x and ( ) n

(A) 9 (B) 2 7 (C) 4 7 (D) none of these

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7. The area bounded by the curve |x| + |y| ≥2 and x² + y² ≤ 4 is

(A) 2 (B) π (B) 4(π – 2) (D) 4 (π + 2)

10. Solution of (1 – xy – x⁵y⁵)dx = x²(x⁴y⁴ + 1)dy is

(C) ln y = xy + +c (D) None of these

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(A) 4c (B) 5c (C) 6c (D) None of these

Batch :___ Date of Examination :