Sec: JR.

IIT_*COSC(MODEL-A) CAT-18 Date: 10-12-23

Time: 3 Hrs 2021_P2 Max. Marks: 180
KEY SHEET
MATHEMATICS
1 AC 2 ACD 3 ABD 4 ACD 5 BC
6 ABCD 7 4 8 0 9 3 10 2
11 3 12 3 13 D 14 B 15 A
16 A 17 3 18 2 19 5

PHYSICS
20 AB 21 ABC 22 BD 23 C 24 ABCD

25 ABC 26 3 27 4.25 28 19.6 29 9.8

30 6 31 75 32 D 33 C 34 C

35 C 36 7 37 2 38 9

CHEMISTRY
39 BD 40 ABCD 41 D 42 ABCD 43 ABCD
0.89 19.6
44 AB 45 10 46 6 47 to 48 to
0.99 21.8
49 1.33 50 1.20 51 A 52 A 53 A

54 B 55 5 56 2 57 7
Narayana IIT Academy 10-12-23_JR.IIT_*CO SC(MODEL-A)_JEE-ADV_CAT-18_KEY&SOL
SOLUTIONS
MATHS
1.

2. Re place x by y and y by x, we get .....(i )

f  y  x   2 y f ( x)  4 x f  y 
2x f  y   4 y f  x   2 y f  x   4x f  y 
f  x f  y
  k  let 
4 2
x x
4y  2y

f  x   k  4x  2x 
f '  x   k  4 x ln 4  2 x ln 2 
f '  o   k ln 2  ln 2  k  1
f  x   4x  2x
f  4   44  24  256  16  240
2
 1 1
f  x    2x   
 2 4
1
Minimum value of f  x  is
4
f  x  2

4x  2x  2   2x   2x  2  0
2

  2 x  2  2 x  1  0
 x 1
 x  9,  4  x  3
 x  9,  10  x  8  2 x  12,  3  x  2
 
3. f  g  x    1,  8  x  4 and g  f  x    8, 2 x2
 12  2 x, 2 x3
  x  3,  4  x  2 
9  x, 3 x  4
4. Let p( x)  ax 4  bx3  cx 2  dx  e
 p(0)  p| (0)  0, p (0)  2
p| (1)  p| (2)  0
p| ( x)  0 has roots 0,1 and 2
 p| ( x)  a( x)( x  1)( x  2)
 a ( x 3  3 x 2  2 x)
 p|| ( x)  a(3x 2  6 x  2)
Put x  0

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2  a(2)  a  1
 p| ( x )  x 3  3 x 2  2 x
x 4 3x 3 2 x 2
p( x )    k
4 3 2
Put x  0
0k
x4
 p( x)   x3  x 2
4
5. Using expansion, we get
x2 x3 x2
a (1  x    ...)  b(1   ...)  c  dx
lim 2! 3! 2! 3
x 0 x3
x( x   ...) 2

3!
 a b  2 a 3
(a  b  c)  (a  d ) x    x  x  ...
lim  2  6
3
2
x 0 x
x (1   ...)
3 2

3!
 in the denominator lowest power of x is 3
For the limit to be finite, the numerator lowest power of x should be 3
 a  b  c  0........(1)
a  d  0.......(2)
a b
 0.......(3)
2
a
 
Now,  6   3  a  18
1
From (1), (2), (3), we get,
a  18, b  18, c  36, d  18
An  An  2  A2  I  A50  A48  A2  I
6.
further ,
A48  A46  A2  I
A46  A44  A2  I
. . . .
. . . .
A4  A2  A2  I
_______________
adding
A50  25 A2  24 I
Here,
1 0 0  1 0 0  1 0 0 
A  1 0 1 1 0 1  1 1 0 
2

 0 1 0  0 1 0  1 0 1 
 25 0 0 1 0 0  1 0 0 
A   25 25 0   24  0 1 0    25 1 0 
50  
 25 0 25  0 0 1   25 0 1 

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Also, tr  A
50
  1  1  1  3. Further,
1 0 0   x  1   x  1 
 25 1 0   y    25   y   U   0 
       1  
 25 0 1   z   25  z   0 
similarly,
0  0 1 0 0 
U 2  1  and U 3  0   U   0 1 0  .i.e., U  1
   
0  1   0 0 1

7. Let slope of line BC be m

8.

9. For x<0

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10.

11 and 12

t 2  4t  10
P (t ) 
t 2  4t  5
5 5
 1 2  1
t  4t  5 (t  2) 2  1
Range of P (t ) is [1,6]
13. Q( x)  54  P (t )x  R
 x 2  2mx  6m  41  54  6 x
 x 2  2mx  6m  7  0 x
0
 4m 2  4(1)(6m  7)  0
 m 2  6m  7  0
 (m  7)( m  1)  0
 m  [1,7]
14. x 2  2mx  6m  41  0
Product of roots = - ve
6m  41  0
41
m
6
Natural numbers possible for 'm' are 1, 2,3, 4,5,6
15.

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16.

x3  1 x2 y x2 z
17. xy 2 y 3  1 y 2 z  11
xz 2 yz 2 z 3  1
1
x2  x2 x2
x
1
 xyz y2 y2  y2  11
y
1
z2 z2 z2 
z
x3  1 x3 x3
 y3 y3  1 y 3  11
z3 z3 z3  1
1 1 1
 (1  x  y  z ) y
3 3 3 3
y 1
3
y 3  11 R1  R1  R2  R3
z3 z3 z3 1

1 0 0
C2  C2  C1
 (1  x  y  z ) y
3 3 3 3
1 0  11
C3  C3  C1
z3 0 1
 1  x3  y 3  z 3  11
x3  y 3  z 3  10
( x, y, z )  (1,1, 2) (or) (2,1,1) (or) (1, 2,1)
  x  
18. sgn  sin 1     1
  6 
 x   x 
 sin 1    0     1
 6   6 
x 6 12
1 2  x
6  
Integral value of x are 2 and 3
19. Let AC,BD intersect at P

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PHYSICS
1 2
m  m 2
 2
19. T1  2  2 T2  2 3
3
 2m  g.  
mgl 3g
 4
4m3 8
2 3  2 8 T2
 9 
2
3mgl 9g T1 2 13
2 3
Conserving angular momentum about hinge, before and after the collision.
1 2 4  3g
m   m 2 1  1     0 
3 3 4 2
9g  1
 0  New 3 1 4  0  New 
1   0  New    0  New  0
8   0  4 4 3   0  12
21. The blocks will come to rest in COM frame at maximum extension.
 They both will have speed v/3 i.e. same as that of COM.
v
During this motion they both will sometime have velocity  in COM frame and at that time their
3
individual absolute velocity will be zero.

22.

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st st nd
23. 0→1 1 →2 2 → 3rd
nd
3rd → 4th
V.S. 0.95 0.90 0.85 0.80
Difference is = 0.5 mm = 0.05 cm
Net reading is = 3.1 + 0.05 = 3.15 cm
24.

  1 
25.   
1  x 1 
T
26.

th
3
27. Between time t = 2s to t  t 0 , the particle completes   of an oscillation
4
3 9
 t 0  2  .T,  t 0  2   4.25s
4 4

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28. After the upper spring is cut, the block 1 and 2 will move with same acceleration.
 a  2g
29. Conceptual
30&31.

   3 
 p 0   w g  H      p0  gH 
  2     3
32. p av   p 0   w g  H  
2  4 

   3 
On slant face, Fnet  p av  Area   p0   w g  H    L
  4  

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33.  M styrrofoam  m  g  Fsurface tension  Buoyant free
1  3    1  3 1   3
   L  sf  g   2L.cos 300  2.  T           Lw g
 2 2   2   2 2 2 2 2 2 

2 3 3 3 2 T
Lsf  m  L w   2L   
4 16 g
2 3 3 2 3 T L 2 3  3  T
m L w  Lsf   2L      w  sf    2L   
16 4 g 4 4  g
34.

h 19.2 1
35. tan    
x 38.4 2
36.

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37.

a a a  sin     
 B  
sin      sin  aB sin 
ma B cos   ma 
ma B cos   Ma 
m a sin      1  2  2
    2
M a B cos  sin .cos  2  1  1
38. Consider the object as two portion ‘A’ uniform rod and ‘A’ frustum with thermal resistance R 1
and R 2 respectively then
 2
R1  1 
k1 A1 4kr 2
 Equivalent thermal resistance R eq  R1  R 2
5
 R eq  ................ 1
4kr 2
Now if we consider the same lamina with equivalent thermal conductivity K eq , then

  3
R eq  R1  R 2    ........  2 
k eq r k eq  2r  2k eq r
2 2 2

By equation the terms of R eq from eqn. (1) & (2), we get

5 3

4kr 2
2k eq r 2
6k
k eq 
5
 N6

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CHEMISTRY
39. Bent’s Rule Application
40. NCERT data based
41. Variation of entropy with equilibrium constant (previous adv question)
42. Based on Group 14th elements, bonding in molecules.
2A
43. r
3 A
So, integrated rate equation of the above reaction is
1
t   A    A   3n
 A  
2  A  
1 3
So, t1 2   A   n2
4 2
3 A  3
t3 4   3n2   8  3  0.7  5.1minutes
8 8
44. Total moles vaporized = 1
Moles of benzene vaporized = x
Moles of toluene vaporized = 1  x
x
Mole fraction of benzene in vapoure phase =
1
1 x
Mole fraction of toluene in vapoure phase =
1
Moles of benzene left in liquid phase = 1  x
Moles of toluene left in liquid phase = x

1 x
Moles fraction of benzene in liquid phase =
1
Apply daltons and raoults law for benzene
T.P.YB  PB0 X B
PB0 X B
YB 
TP
32(1  x)
x ..................1
TP
Apply daltons and roults law for toluene
T.P.YT  PT0 X T
PT0 X T
YT 
TP
128x
1  x   ............... 2 
TP
From (1) and (2)
x 32(1  x) / TP

1 x 128x / TP

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2 2
x 32(1  x)  x  32  x  1
  
1  x 128(x) 1  x  128 1  x  4
x 1

1 x 2
2x 1  x
2x  x  1
3x  1
1
Mole fraction of benzene in vapour phase =
3
2
Mole fracation of toluene in vapour phase =
3
1 2
YB  YT 
3 3
2 1
XB  XT 
3 3
45 & 46.
X =10, y =6

CH 2Cl
H 3C Cl *
* Cl
* *
(4) products, Cl (4) products

47 & 48

Irreverible
H 2O   1 atm,  10 C  
process
 H 2O(S,1 atm,  10C)
 T1   T1 
Reversible Reversible
(1) (3)
H 2O   ,1 atm, 0 C  
Phase
 H 2O(S,1 atm,0C)
 T2  change
 T2 
For reversible process : (T = 263 K)
q irr
Ssurr 
T
q irr  H   5.55kJ / mole
5550
 Ssurr   21.1J / K  mole
263
dq rev
Now calculate, Ssys , ds sys 
T
For reversible process,
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T2  H fusion  T1
Ssys  nCP water  ln    nC Pice  ln
T1  Tf .P.  T2
273 600 263
 1  75  ln   1  30  ln
263 273 273
273 6000
 ln 75  30 
263 273
6000
 0.04  45 
273
  20.18J / K-mole
 Ssys  20.18J / K-mole
ST  S sys  S surr
  20.18  21.1 J / K-mole
 0.92 J / K-mole


 3  BH 2  NH 3 2   BH 4 

49. 3B2 H 6  6 NH 3 
 2 B  OH 3  6 H 2 
B2 H 6  6 H 2O 
 R
2 NaBH 4  I 2 
 B2 H 6   2 NaI  H 2 
(X ) Y  Z 
B2 H 6  2 NaH 
 2 NaBH 4

 3  BH 2  NH 3 2   BH 4 

3B2 H 6  6 NH 3 


2 B3 N 3 H 6  12 H 2
a= 2, b= 6, c=6
ab 
  1.33
c 6
50. 1.20
51. Lithium and beryllium shows greater tendency to form complexes due to high polarizing power of
both the metal ions
2
52. Beryllium hydroxide dissolves in excess of alkali to give a beryllate ion.  Be  OH 4  just as

aluminum hydroxide gives aluminate ion,  Al  OH 4 
100  0.3
53. Molarity of solution 'A'   0.2 M  pH  0.7
150
54. Solution C cannot act as a buffer
 Ag    10 5 M ; No of moles of Ag  ions in 0.15 lit solution = 1.5  10 6

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55.
Ph
Ph
Ph
Ph
Ph
56.

*
D
*

D
57. 12x = 84, x =7
 1
No. of gram equivalents of BrO3 unused  5.1   2  103
25
1 1
 No. of moles of BrO3 unused =5.1   2  103   6.8  105
25 6
20
No. of moles of BrO3 used =  103  6.8  105  2.6533  104
60
5
No. of moles of SeO32  2.6533  104 
2
5
Weight of SeO32  2.6533  104    79  48  0.084 g  84mg
2

JR.*CO SC Pg.No: 15