Sec: OSR.

IIT_*CO-SC GTA-1(P1) Date: 17-03-23

Time: 3HRS 2016_P1 Max. Marks: 198
KEY SHEET
MATHEMATICS
1 B 2 C 3 A 4 D 5 D
6 CD 7 AB 8 AD 9 AD 10 AB
11 AD 12 BCD 13 ABCD 14 6 15 3
16 3 17 3 18 6

PHYSICS
19 D 20 B 21 B 22 C 23 A

24 ABCD 25 A 26 ABC 27 BD 28 AD

29 AB 30 BCD 31 AC 32 9 33 3

34 1 35 3 36 4

CHEMISTRY
37 D 38 B 39 B 40 C 41 D

42 C 43 ABCD 44 ABD 45 AD 46 BD

47 AD 48 ACD 49 A 50 3 51 7

52 0 53 9 54 6
Narayana IIT Academy 17-03-24_OSR.IIT_*CO-SC_JEE-ADV_GTA-1(P1)_KEY&SOL
SOLUTIONS
MATHS
1. AB = 8, AC = 7, BC = 9
MF = MP =  and PN = NE = 
3 3 
  
8 7 9
5 9
 = 1,  = , 1 =
4 4
35 8
Similarly 2 = , 3 =
12 3
A
M P N
F E

B C
D
2. g(x) = (g(0))x – 1
 g(x) is one-one function.
g(f2(x) + 2 + x2f2(x)) = g(x2f(x) + 3f(x))
 f2(x) + 2 + x2f2(x) = x2f(x) + 3f(x)
(f2(x)) (1 + x2) – (x2 + 3) f(x) + 2 = 0
2
 for x  R, f(x) = 1 or f(x) = .
1  x2
f is continuous on R and f(2023) = f(2024)  f(0)
 2
, x 1
then f(x) = 1  x2
1 x 1

 1 8 13
f    f(2)   1 
2 5 5

3.   1
     1 
 
a11  f x 212  f   , a21  f x 4 1 2  f  x  , a12  f x 2 2  2  f  2  and a22  f x 4 2 2  f 1 .
x x 
  1   1    1 
 f   f  2   f 1 f  
 A    x   x   and B    x 
 f x
 f 1 
  
 f x 2 f  x  

  1 
 x 
 
 x
1
 f    f 1 f  2   f x

 
2

 A  BT   
  1 
 f  x   f  x  f 1  f  x  
   
From given matrix,
 1
f    f 1   x 2 f   x   f 1  ………. (i)
x
 1 
   1   1 
f  2   f x 2   1  4  f  2  ……….. (ii)
x   x  x 
 1  1 1 
f  x   f    f    1  2  ………. (iii)
x  x  x 
1  1  f 1 
f 1  f  x   
f  ………. (iv)
x 2  x 
From (ii), x  1 2f 1  0  f 1  0

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Narayana IIT Academy 17-03-24_OSR.IIT_*CO-SC_JEE-ADV_GTA-1(P1)_KEY&SOL
(i),  x2 f  x   f   ……… (*)
1
 Eqn.
x
1x
Now,  f  t  dt  I
x
1
t 1x
t  1 
Replace x
 1  1
1x
 1 1
 2I    f  t   t 2
f  t   dt  0 from (*)

I  f  t    t
1x
2 

dt   f  t  t
x
2
dt x

i.e., I  0  f 1

cos x sin x cos 2x

4.  f  x  g  x  h  x    tan x sin 3x cos 4x
cos 3x sin 5x cos 6x
 
 
0
 f, g, h  x  dx    f,
0
g, h    x  dx

 
  f,
0
g, h dx    f,
0
g, h dx  C1  C1 

  f,
0
g, h dx  0

  
5. 
a1   a, b  , a2  a  2, b  5 , a3  a  2, b  5   
  
Area of  , whose vertices are a1, a2 and a3 , is
1 a b
1
  1 a2 b 5
2
1 a2 b 5
1 a b 1 a b
1
 2  1 a  2 b  5 1 a  2 b  5
4
1 a2 b 5 1 a2 b 5
     
a1  a2  3, a1  a3  3, a2  a3  4
and
   5  2  2 1  2 5
     
1  a1.a1 1  a1.a2 1  a1.a3
     
 1

2
2 5  1  a2 .a1 1  a2 .a2 1  a2 .a3
4      
1  a3 .a1 1  a3 .a2 1  a3 .a3
 Required answer = 4 x 5 x 4 = 80

6.  
g x 2  f  x  f   x 

 A
8. 1  tan     tan 
4 4
 B
 2  tan     tan 
4 4
  C
3  tan     tan 
4 4

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Narayana IIT Academy 17-03-24_OSR.IIT_*CO-SC_JEE-ADV_GTA-1(P1)_KEY&SOL

  
2

k k
9. Either cos & cos both lie in (–1, 1) or both together can be 1 or –1.
4 6

10. (A) Apply LMVT on ln (f(x))

(B) Apply LMVT on (x – 2) (x – 4) f(x).

11. y3  3x 2 y  x3  0


dy  6xy  3x


2


3 2xy  x 2

y   
dx 2
3y  3x 2
 2
3 y x 2

x  
 dy  y
   dx  dx i.e.,  x dx  y  c
 f  x   c or xf '  x   c

1  1 
2x 2   x x  2x  2  dx
12.  
x dx  
 x 
 
xdx  1 2

 ln  x 2    tan1 x 3 2 
1  x3   1
x  x2   
1  x3 2 
2
 x 3
 x 
1
2 2x 2   x
9 2 1 
  
1
x
1 x 3
dx  ln    cos1 
 4
  3 3 6

13. Origin, 5i, z2 and z3 lies on a circle whose end points of diameter are 5i and z3 .

 3x  x   
cos  p  x   1
2
14.   cos cos     1  0
 2p  2p 3  
 1
 x  p  2n, x  2p  k  
 3
6n
p  pleast  6
6k  5
4 4
15. f  2   0 The other root lies between 2 and 3 as  a  2
a 3
4
So    2,3  2 tan   0
a
 cot   1  1  1  cot  
cot 1 2 tan    tan 1      tan    tan      2L
 2   2 tan    2 
6L
So is equal to 3


16. PAB = PAC = PAI.

Similarly, PBC = PBA = PBI
And PCA = PCB = PCI

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Narayana IIT Academy 17-03-24_OSR.IIT_*CO-SC_JEE-ADV_GTA-1(P1)_KEY&SOL

17. Since f(x) = –1 – 3x2 < 0  x  R.

Hence f is decreasing.

nm nm
18.  k r
C r . n  r Cm   k r
Cr . n  r C n  m  r
r 0 r 0

   Coefficient of x 
nm
 k 1  m 1
  Coefficient of x r in 1  x  nmr
in 1  x 
r 0
 m  k  2 
= coefficient of x n  m in 1  x 
 n  k 1 Cn  m
n
 n  k 1
Cn  m  n 1Cn  m  n  2Cn  m      2 n 1Cn  m
k 0
2 n 2
 Cn  m 1  n 1Cn  m 1
i.e. f 100,50   202C51  101C51
PHYSICS
19.     60 ...........1 0

R R

sin1200 3
sin 
2 1

3 3 sin
1
sin  
2

    600...........1
R R

sin1200 3
sin 
2 1

3 3 sin
1
sin  
2
  30 0

From equation 1   

 collision is elastic
4U 0  1  1
20. U  12 V
2

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Narayana IIT Academy 17-03-24_OSR.IIT_*CO-SC_JEE-ADV_GTA-1(P1)_KEY&SOL
I C  mx 2 I  m( L  x ) 2
21. T = 2 = 2 C
mg x mg ( L  x)
IC I
 mx = C  m( L  x)
x Lx

 L  2x 
I C    m( L  2 x)
 x ( L  x) 
IC = mx (L – x)

mxL  mx 2  mx 2 L 4 2 L
T = 2 = 2 g=
mgx g T2

x  L–x
22. Potential gradiant
V 9r 9V
 . 
10r L 10 L
V
  p.Gr1  BL1
2
10 L
BL1 
18
V 9r 9V
If 5r is in series to V pGr2  . 
15r L 15 L
V
  pGr2  BL2
2
V 15 L
.  LB2
2 9V
15 L
LB2 
18
23. Centrifugal force =  dmx2   adx.x2
L
 a 2
F  (a2 ) 
L h
xdx 
2
(2Lh  h2 ) .............................(1)

centripetal force is provided by mg. .............................(2)

2
a
(1) and (2)  (2Lh  h2 )   ahg
2
2g
  .
(2L  h)
p0a

acceleration

mg

p0a
GMm
24. Einitial  
2R
GMm
E final 
R

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Narayana IIT Academy 17-03-24_OSR.IIT_*CO-SC_JEE-ADV_GTA-1(P1)_KEY&SOL
 E final  2Einitial
The motion of planet after stopping can be considered to be along a strongly
extended flat ellipse and the extreme points of the ellipse are located on the
planet's orbit and at the centre of the sun. Thus the semi major axis of this
orbit would be half the semi-major axis of planet's orbit.
T '2  a / 2
3
T
   T' 
T2 a3 2 2
T' T
 Time of fall = 
2 4 2
kq k 2Q k  4Q  q  k 2Q
25.   
r 2r 3r 3r
4Q q 2Q 2q Q Q
q Q     q
3 3 3 3 3 2
kQ k 3Q kq '
  0
2 R 3R 2 R
q '    Q  2Q   3Q
q  Q

 d 
  N cos 45 , N sin 45   dm  g
0 0
26. 2T 
 2 

T
 dm  g  mg ; l  T  2 R 
d 2a aY
1
And U   s train  Y  2 Ra 
2

2
27. For rotation equilibrium, taking torque about the point from where normal force passes.
a a
 laB0  laB0  mgx  0
2 2
2
la B0
x
mg
a mg
For the block not to topple x   l 
2 2aB0
28. For t  t0 , linear retardation, a  f / m   g
a

f
 fR 2 g
  
I 1 2 R
 mR 
2 
Let  and  be the linear and angular velocities at t  t0
2  gt0
So,   0  at0  0   gt0 and    t0 
R
For t  t0 , workdone by friction upto time t = K.E of disc at time t-K.E of disc at time t = 0
1 1 1
W  mv 2  I  2  mv02
2 2 2
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2
1 11   2  gt  1 2
m  v0   gt    mR 2   
2
  mv0
2 22   2  2
m gt
On solving , W   3 gt  2v0 
2
For t  t0 , frictional force is zero for pure rolling
For t  2t0 , W will remain same.
29. (a) In an adiabatic expansion, internal energy decreases and hence temperature decreases.
 From equation of state of ideal gas.
PV  nRT , the product of P and V decreases.
3kT
(b) Vrms 
m
c) The temperature in Kelvin scale is not doubled
1 1 R
30. mv 2  kA 2  A 
2 2 4
m 3 m 3T
T  2 & given t   
k 4 k 8
x  A sin t  V  A cos t
R k 2 3T R k  1 
 V0  cos   
4 m T 8 4 m  2 
R k ˆ
V0   (i)
4 2m
R 2  3T R
x  A sin t   sin  
4 T 8 4 2
R R 
 U 
object distance  2 4 2 
1 1 1 v  f 
     2 2
f v u u  f  u
2
 v
VI    v 0
 u
Velocity of image
R k 2k
VI  8  R
4 2m m

1 3RC
31.  (z  1) 2
 4

32. mu  mv1 cos   2 wv2 cos 

mv1 sin   2 wv2 sin 
21 2 1
 mu   2mv2
2

32  2
11 2 1
 mu   2mv1
2

3 2  2
Solving equation v1  v2  u / 3

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Narayana IIT Academy 17-03-24_OSR.IIT_*CO-SC_JEE-ADV_GTA-1(P1)_KEY&SOL

o    1200 and   900 and  90
10
33. Q = u+w
Q = u + Q/4
u = 3Q/4
Cvt = (3/4) CT
4 4  5R 
 C  Cv   
3 3 2 
  emission -emission Deuteron
34.
1  4 3  2  2 3 3
dN
Activity =  N
dt
These activities are same at t=0
 N1 : N2 : N3  1: 2 : 4 where N1 , N2 , N3 are the number of initial nuclei of ,  and deuteron
respectively.
1 N1
16 1 1
P1600   
1 N1  2 N 2  3 N3 1  4  8 13
 
16 4 2
1 1 1
35.  
R R1 R2
 R1  R1  R2
2
 2

R R 1R22
R  R  R 
100  100 R  21  22 
R  R1 R2 
5 10  0.2 0.1 
 100    
15 5  5 10 10 
10
 4  0.2  0.1
3
9

3
=3%
36. Let the velocities of car 1 and car 2 be V1m / s and V2 m / s .
 Apparent frequencies of sound emitted by car 1 and car 2 as detected at end point are
V V
f1  f 0 , f2  f0
V  V1 V  V2
330 330
 330  300 , 360  300
330  V1 330  V2
 V1  30m / s and V2  55m / s .
The distance between both the cars just when the 2nd car reach and point B (as shown in figure is)
100m  V2t  V1t
 t  4sec

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CHEMISTRY
37. BeH 2 is polymetric while MgH 2 is monomeric

Saline hydrides are the ones formed by most active metals like IA IIA with H2
Metallic hydrides are the ones formed by H2and transition / inner transition elements (from d block
only group 3,4,5,6 form hydrides not from 7,8,9...this is called hydride gap). These are also known
as interstitial hydrides. Metallic hydrides mostly are non-stoichiometric.
38. AgCl(s)  Ag  (aq)  Cl  (aq) K sp  1010
1
Ag  (aq)  Br  (aq)  AgBr(s), K
Ksp
1010
AgCl(s)  Br  (aq)  AgBr(s)  Cl (aq) 200  K   5  1013
 K sp  AgBr sp AgBr

2AgBr(s)  2Ag  (aq)  2Br  (aq)

2Ag  (aq)  S2 (aq)  Ag 2S(s)
2AgBr(s)  S2 (aq)  Ag 2S(s)  2Br  (aq)
K 
2
25  1026  25 
K 
sp AgBr
1.6  1024    50
  10  15.625  10
50
 1.56 1049
K  sp Ag S
2
 K sp 
Ag 2S
sp Ag S
2
 1.6 
41. H 2 PO 
2  HPO 2
4  H
0.4M 6.4 103 9  106

42. Al2O3 ,SnO,SnO2 , PbO, PbO2 ; ZnO, BeO, Cr2O3, MnO2, CrO2 and Mn3O4 are amphoteric N2O, NO,
CO are neutral oxides
LiHCO3 exists only in aqueous solution similar to IIA bicarbonates.
43. During free expansion, volume increases but W=0
 
3
44. Cu  CN 4   tetrahedral sp 3

45. Y is coke

CaC2  N 2   CaCN 2  C
CaCN  H 2 O 
2  NH 3  CaCO3
cal.cyanamide

CaCO3 is sparingly soluble

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Narayana IIT Academy 17-03-24_OSR.IIT_*CO-SC_JEE-ADV_GTA-1(P1)_KEY&SOL
NH2

N N

melamine is C3H 6 N6 , H2N N NH2

46. [XeF] [PF6 ]

XeF2  PF5 
XeF4  O2 F2  XeF6  O2
XeF2  H 2O  Xe  HF  O2
2 1 1
XeF4  2 H 2O  Xe  XeO3  HF  O2
3 3 2
XeF6  H 2O  XeOF4  XeO2 F2  XeO3

47.
CH2 CH2 CH2 CH2

Br Br Br Br

H3C H3C H3C H3C

Br Br

H3C H3C

48. Time period  n3

50. b  3.42  105 m3 mol 1

51. P=3 Q=2,3 R=1 S=3,4

52. Methionine, cysteine are S containing AAs
Na2  Fe  CN 5 NO    S 2  Na4  Fe  CN 5 NOS 
reddish brown violet
Sodium nitroprusside sod. thionitro prusside
Fe 2 : d 2 sp3 ;   0
53. 9th statement is wrong
54.

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