28-12-19 SR - Icon All Gtm-5 Code-B Key & Sol's

Sri Chaitanya IIT Academy 28-12-19_Sr.
Icon All_GTM-5 CODE-B_Key & Sol's
Sri Chaitanya IIT Academy., India.

AP, TELANGANA, KARNATAKA, TAMILNADU, MAHARASHTRA, DELHI, RANCHI
A right Choice for the Real Aspirant
ICON Central Office , Madhapur – Hyderabad
Sec: Sr.Icon All GTM-05 Date: 28-12-19
Time: 09.00am to 12.00 CODE-B Max.Marks:300
Key & Solutions

MATHEMATICS
1 3 2 3 3 4 4 3 5 3
6 3 7 4 8 2 9 4 10 1
11 2 12 2 13 4 14 1 15 4
16 3 17 1 18 4 19 3 20 4
21 0010.00 22 0002.25 23 0202.00 24 0048.00 25 0001.00
PHYSICS
26 2 27 1 28 3 29 4 30 2
31 3 32 1 33 4 34 1 35 3
36 2 37 2 38 4 39 1 40 2
41 3 42 2 43 2 44 2 45 1
46 0006.00 47 0003.00 48 0023.60 49 0240.00 50 0001.00
CHEMISTRY
51 2 52 1 53 2 54 2 55 2
56 2 57 1 58 2 59 1 60 3
61 4 62 2 63 4 64 4 65 2
66 1 67 3 68 1 69 3 70 1
71 0057.50 72 0056.75 73 0004.00 74 0000.05 75 0008.00
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Sri Chaitanya IIT Academy 28-12-19_Sr.Icon All_GTM-5 CODE-B_Key & Sol's
SOLUTIONS
Mathematics
1 2017 2
1. Given that A1  1 2017 4
 
1 2018 8 
0 0 2
A1  1 2017 4 R1  R1  R2
1 2018 8
 2(1)  2
1 1
We have, A  
A1 2
 1
Now, 2 A  2 A1  8     8  2   4  16  12
 2
4
log x 2
2. Let  log x 2  log dx
2 36  12 x  x  2
4
2log x
 dx
2
2 2log x  log  6  x 
4
log x
I  dx  1
log x  log  6  x  
2
4
log x  6  x 
I dx   2 
2
log  6  x   log x
 b b 
  f  x  dx   f  a  b  x  dx 
 
 a a 
On adding Equations 1& 2, we get
4
log x  log  6  x 
2I   dx
log  6  x   log x
2
 2I  2  I  1
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3.
A a 
P p
B b  C c 
   
Given that PA  2PB  3PC  0
 OA  OP  2(OB  OP )  3(OC  OP)  O
a  2b  3c
 OP 
6
1
Area of APC  ( a  b  b  c  c  a )
6
1
Area ofABC  (a  b  b  c  c  a )
2
 Ratio of area of ABC to that of APC is 3
10
1 
4. Given expansion   x sin x  , Here n  10 is even
x 
7
Middle term  Tn  T19  T51  7  given 
1 1 8
2 2
5
10 1 5 63
 C5    x sin x  
x 8
10  9  8  7  6 1 5 5 63
 x sin x 
5  4  3  2  1 x5 8
63
 63  4sin 5 x 
8
1
 sin 5 x 
32
1
 sin x 
2
nπ
 x  nπ   1 , n  z
6
5. Given that : x1  x2  ....  x8  30.....1
x1, x2 ,...x8  2
Let u1  x1  2, u2  x2  2....u8  x8  2
From(1), u1  u2  ...  u8  30  16  14
Number of solutions n  r 1 Cr 1 = 14  8 1 C8 1  21C 7 .
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6.
r

h 4 l
Given rate of change in surface area

ds
 2cm 2 /s
dt
Surface area, S  π rl
l
 πl 
2  r
 sin 45  l 
π 2  
 l
2
dS π dl dl
Now, 2   2l.  π 2  4   l  4 
dt 2 dt dt
1 dl
  .
2 2π dt
dl 2
  cm/sec
dt 4π
7. Given that y 1  xy  dx  x dy
dy y  xy 2 y
   y2
dx x x
y
put  v  y  vx
x
dv
Hence, v  x  v  v 2 x 2
dx
1
  dv   x dx
v2
1 x2
  C
v 2
x x2
  C
y 2
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x x2 1 x2  1
   
y 2 2 2
1 1
 1   C  C 
2 2
2x
Hence, y  
x2  1
 1 1 4
 f      .
 2 1
1 5
4
8. Given point P  2,3 and given line is  2 x  3 y  4   k  x  2 y  3   0
 2 x  3 y  4  0.........1
And x  2 y  3  0............ 2 
Point of intersection is (1) and (2) is A 1, 2 
P  2,3
A
M
1,2  P1  b, k 
Let P  h, k  be the point on locus.

As, AP  AP '
2 2
  AP    AP ' 
2 2 2 2
  2  1   3  2    h  1   k  2 
 h 2  k 2  2h  4k  3  0
Locus of  h, k  is x 2  y 2  2 x  4 y  3  0
Radius, r  g 2  f 2  c  1  4  3  2 .
9.
5R
2G
5
P (one red ball) 
7
2 6 12
case (i) ;   .
7 7 49
2
P (one green ball) 
7
5 4 20
case (ii) ;  
7 7 49
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12 20 32
P (2nd ball is red)    .
49 49 49
2x
10. Given that f  x  
x 1
2
 f  x  2 
x 1
Differentiate with respect to ‘x’
2
f ' x    0
2
 x  1
f is strictly decreasing, so f is one.-one
2x
We have, y   yx  y  2 x
x 1
 yx  2x  y
y
x
y2
range  codomain.
 f is injective but not surjective.
 19  n 
-1 
11. cot  cot 1+  2p  

 n=1  p=1  
  
 19 
=cot   cot -1 1+n  n+1  
 
 n=1 
 19  1 
=cot   tan -1   
  1+n  n+1  
 n=1
 19  n+1-n  
=cot   tan -1   
  1+n  n+1  
 n=1
 19 
=cot    tan -1  n+1 -tan -1n  
  
 n=1 
=cot  tan -1 2-tan -11+tan -13-tan -12+....+tan -1  20  -tan -1 19 
 

=cot tan -1  20  -tan -1 1 
  20-1  
=cot  tan -1  
  1+20  
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  21  
=cot  cot -1   
  19  
21

19
12. Given that
P : 5 is a prime number.
Q : 7 is a factor of 192.
R : LCM of 5 and 7 is 35
 P is true , Q is false and R is true
Option (1):
 P  Q   R
 T  T    F 
T  F
F
Option (2):
P   Q  R
 T  T  T 
T T
T
Option (3):
 P   Q  R 
 F F  T 
FF
F
Option (4):
 P   Q  R
 F  T  T 
 F T
F
Option (2) is true
13.
Solving x 2  4 y; x  2 y  4 2  0 is
y2 , y 8
And x  2 2 , x  4 2
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 
 P 2 2,2 and Q 4 2,8  
2
Length of chord,PQ   6 2   36  6 2  1  6 3 .
x 1 y  2 z  3
14. Given line is   and palne is x  2 y  kz  3
2 1 2
Let ‘ θ ’ be the angle between plane and line, then
al  bm  cn
sinθ=
a 2  b2  c2 l 2  m2  n2
 2 2
 cos  
 3 
 1 
  sin   
 3 
1 2 1  2 1  k  2 
 
3 4 1 4 1 4  k2
 5  k 2  2k
 5  k 2  4k 2
5
 k2 
3
5
k
3
15. Given that z1  9
Centre of circle C1  0,0 
Radius, r1  9
And z2  3  4i  4
Centre of circle, C2  3,4 
Radius, r2  4
C1C2  9  16  5
r1  r2  9  4  5
z1  z2 min  0
 x   x , 1  x  1

16. Given that f  x    x  x , 1  x  2
 x   x  , 2  x  3,

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  x  1, 1  x  0
 x, 0  x 1

 f  x    2 x, 1 x  2
 x  2, 2  x  3

 6, x3
At x  0 :
Now, lim f  x   lim x  0
x  0 x 0
and lim f  x   lim  x  1  1
x 0  x 0
 lim f  x   lim f  x 
x  0 x  0
 f  x  is discontinuous at x  0
At x  1 :
Now, lim f  x   lim 2 x  2
x 1 x 1
and lim f  x   lim x  1
x 1 x 1
 lim f  x   lim f  x 
x 1 x 1
At x  3 :
Here, f  3  6
Now, lim f  x   lim x  2  3  2  5
x 3 x 3
 lim f  x   f  3 
x 3
 f  x  is discontinuous at 3 points.
17. Given that difference of the lengths of major axis and minor axis is 10
 2b  2a  10
 b  a  5....1
 
And given foci is 0,5 3   0,be 

Now, a 2  b 2 1  e 2 
b 2e2  b2  a 2  75  b 2  a 2
b  a  15.... 2 
Solving (1)&(2) we get
Sec: Sr.Icon All 9

b  10, a  5
2
 Length of latus rectum,(L.L)  2a     5
2 25
b 10
18.
1,2 
 0,1
 1,0
1

 Required Area    x  1  2 x dx 
0
1 1
 x2  1  2 
x
     x 0   
 2   log 2 
 0  e 0
1 1
  0 1  0   2  1
2 log 2e
3 1 
  2 
sq.units
 2 log e 
19. Since a, b, c are in G.P with common ratio r then
a, b  ar , c  ar 2
Since 3a,7b and 15c are in A.P then
2  7b   3a  15c
 14ar  3a  15ar 2
 15r 2  14r  3  0 a  0
 15r 2  9r  5r  3  0
3r  5 r  3   1  5 r  3   0
1 3
 r  ,r 
3 5
1
0r 
2
Common difference of A.P  7b  3a
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7  2a
 7 ar  3a  a  7 r  3   a   3  
3  3
 2a 
4th term of A.P  a   n  1 d = 3a  3 a
 3 
x4  1 x3  k 3
20. Given lim  lim
x 1 x  1 xk x2  k 2
 x  1 x  1  x2  1  x  k   x 2  kx  k 2 
 lim  lim
x 1  x  1 x k  x  k  x  k 
3k 2
4
2k
3k 8
4 k 
2 3
21. Since given system of linear equations x  ky  3z  0,3x  ky  2 z  0. and
2 x  4 y  3z  0 has a non-zero solution then
1 k 3
3 k 2  0  (3k  8)  k ( 9  4)  3(12  2k )  0
2 4 3
 3k  8  5k  36  6k  0
 4k  44  k  11
Let z  
x  11y  3  0......1
2 x  4 y  3  0......... 2 
1   2 
 3x  15 y
 x  5 y
From(1), 5 y  11y  3
 6 y  3

y 
2
5
x 
2
5 2
xz 2

Hence,   10
2 2
y 
4
Sec: Sr.Icon All 11
22. Given that
f  x   cos 2 x  sin x , x  0, π 
Differentiating with respect to ‘x’
f '  x   2cos x sin x  cos x  0
 cos x 1  2sin x   0
1
 cos x  0 or sinx =
2
π π
x  ,x 
2 6
Now, f  0   1
π 3 1
f      1.25
6 4 2
π
f   1
 2
f  π  1
 Sum of absolute maximum and minimum  1  1.25  2.25
 2020 2 x 2020 sin 1 2020 x dx
23.  1   2020 2 x  
x
 2020  sin 1  2020 
x

2x
 2020  dx
1   2020 
x
Put sin 1  2020   t
1 x
  2020   loge  2020  dx  dt
2x
1   2020 
t
   2020   loge2020 dt
t

 2020 
 loge 2020  c .
loge2020
2 1 x

 log e2020   2020 sin  2020   C
2
  log e2020  10k 
sin 1
 2020  x  C  given 
 10 k  2020
 k  202
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2  4  10  12  14  a  b
24. mean, x   xi  8
7
 a  b  14  1
Variance=  xi2   x 2  a 2  b2  4  16  100  144  196  82  16

n 7
 a 2  b 2  100   2 
From (1)&(2),
a 2  b2  100
2
  a  b   2ab  100
 196  100  2ab
 ab  48
 Product of remaining two numbers, ab  48
25. 
Given that 5  2 x  1  2 x 2 x  2 
Put 2 x  t
5  t  1  t  t  2
 t  1  t 2  2t  5
 number of real roots =1
PHYSICS
26. Given wavelength of photon  
hc
The energy of the photon is Ee    ........(1)

Where h  planks constant
  work function
work function
hc hc hc
  
 2 2
27. from text question
Initial velocity u  0
From equation motion
1
s  ut  at 2 ( s  h)
2
1
For AG, h  gt12
2
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2h
 t12 
g
For AB ,
h 1
  gt22
n 2
2h
 t22 
ng
1/2 1/2
 2h   2h 
  t1  t2      
 g   ng 
1/2
 2h 
 
 g 
 n1/2  1  t2  n1/2  1
If t2  t AB ,  t1  t2   t BG  t AB  n1/2  1
t 1 1
or AB  
t BG

1/2
n 1   7 1 
So n  7
h h
So, AB  
n 7
28. As the body is floating in each case, the force of buoyancy is equal to weight of the body.
29. Whether switch is open or closed the current through the battery in steady state. So there
is so flow of charge thus no heat is produced.
30. Number of turns per meter  2  104
Number of turns N  100
Resistance R  10π 2 Ω
The total charge flown through the coil,
   NBA 
Q     NBA 
R R
N o nA  i1  i2 
  B  o ni 
R
2
100  4π  107  2  104  π  0.01   4  0 

10π 2
 32  106 C  32µC
31. Given
Mass of ring P  m
m
Mass of block Q 
2
Sec: Sr.Icon All 14
ma T cos60
60
T sin 60 a cos60
a cos60
m
2
m
Free Body diagram of
2
T
a cos60
m
g
2
mg ma
T  cos60....1
2 2
Free Body diagram of m
N
T cos60
60
T
mg
T cos60  ma
ma
T
cos 60
T  2ma..... 2 
Sec: Sr.Icon All 15

From (1) & (2), we get
mg ma
 2ma   cos60
2 2
mg ma
  2ma 
2 4
g 9a
 
2 4
2g
a 
9
32.
V
A
R  50Ω
From diagram
R  50
Requ  v .... 1
Rv  50
2 98
Requ  R  R R.... 2 
100 100
98 R  50
  50  v
100 Rv  50
98 Rv  98  50  100 Rv
2 Rv  98  50
Rv  49  50
Rv  2450Ω
 x
33. Given Electromagnetic wave is E y  66cos 2π  1011  t   ....1
 C
E
We know C  o ....  2 
Bo
In an Electromagnetic wave electric field and magnetic field vectors and direction of
propagation of Electromagnetic wave are mutually perpendicular
From (2)
E 66
Bo  o   2.2  107 T
C 3  108
2πC  x
Now Bz  Bo cos t  
  C
Sec: Sr.Icon All 16
 x
Bz  2.2  107 cos 2π  1011  t  
 C
34. Given
Side of cubical vessel= a
Density of water  w  
Density of liquid l  2 
Mass of cube m   v   a3  v  a 3 
Weight of cube F  mg   a3 g
a  a
The buoyant force F '  2  a 2   x  g  2  a 2 g  2  a 2 xg
2  2
a3
Restoring force is F  F '  F  2  g  2  a 2 xg   a 3 g  2  a 2 xg
2
F 2  a 2 xg
Restoring acceleration a   f
m m
Compare with a   2 x
2 a 2 g
2 
m
2  a2 g
 2 
 a2
2g
 
a
2π a
T   2π
 2g
V
35. tan 1 
H cosθ
V H sin 
V V
tan  2  
H cos 90  θ
  H sin θ
Sec: Sr.Icon All 17

tan 1 sinθ
   tan θ
tan  2 cosθ
 tan 1 
Or θ  tan 1  
 tan  2 
36. Two lenses used are eyepiece and objective
For eyepiece, f e  1cm D  ve  25cm
1 1 1
 
ve ue f e
1 1
  1
25 ue
25
 ue   cm
26
For objective uo  60cm, f o  10cm
1 1 1
 
vo uo f o
1 1 1
  
vo 60 10
1 1 1
  
vo 10 60
1 5 60
   vo   12cm
vo 60 5
Length of telescope
25
L  vo  uo  12   12.96cm
26
37. In the given circuit diode D1 is reverse biased while D2 is forward biased, so the circuit
can be redrawn as
4Ω
D2
D1
12V 3 2
Apply KVL to get current flowing through the circuit

12  4i  2i  0
12
Or i   2A
6
T
38. Efficiency of carnot engine 1  1  2
T1
Sec: Sr.Icon All 18
1 T
 1 2
6 T1
T 5
 2  .....1
T1 6
T  62
2  1  2
T1
1 T  62
1 2
3 T1
T  62 2
 2  ...... 2 
T1 3
On solving Equation (1) and (2) , we get
5 T2  62  2

6T2 3
 4T2  5T2  5  620
 T2  310
6  310
And T1   372 K
5
39. Given
The ratio of cube of circumference of the orbit of a satellite to the volume of the earth is
 6  1010 g R
We know
2π r 3 K r
Time period T   , if K  2πr
R g R g
K K
=
R 2πg
2K 3
R
3 2 K 3R
 
 4 3 3 Vg
 πR  g
3 
K 3 6  1010 g
Given, 
V R
2  6  1010
So, T   2  105 sec
3
Sec: Sr.Icon All 19

40. Number of beats produced  6
k 100  f  6  f  6 10 2f
    19
f  k 81  6  f  6 9 12
 f  19  6  114Hz
41.
d /2
d /4
d /4 SO O
d
3d / 4
d /4 D
Given
 d d d   3d d  
x          
4 4 2  4 4 2
Due to reflection phase difference of π is included in upper wave hence central maxima
1  D  1  50000 
position is      250 from O
2  d  2  100 
42.
3V
1µF R1
4
R2
1
Given
Capacitance C  1µF
Internal resistance r  0.5Ω
In steady state current in the branch containing the capacitor is zero and hence
electromotive force E is shared between r and R2 in the ratio of their resistance.
Voltage across
ER2
R2 is  2 volts=voltage across capacitor
R2  r
 Q  CVC  1µF  2V  2µC
Sec: Sr.Icon All 20

43. Given
Mass of disc  m
Radius of disc= R
Angular velocity= 
2πxdx 2  mgx
Now dN   mg .  dx
πR 2 R2
dx
x
2  mgx 2dx
 d  xdN 
R2
R
2  mg 2 2
  d  x dx   mgR
R2 0 3
1 2  mR 2 
 I  mR   I  
2  2 
 
4 g
  . If t be the time for complete stop
3 R
 3 R
t    t  
 4 g
44. Given
q
Specific charge  
m
Magnetic field strength  B
Speed V   2 d  B
Electromagnetic force will provide the necessary centripetal force
Sec: Sr.Icon All 21

       
       
       
       
       
       
       
2r        
       
       
       
       
      
mv 2
qBv 
r
r
mv

v

 2 d  B   2d
qb B  B 
45. Given
Focal length of concave lens= f
y
θ
b
x
f
From diagram
b dy b
tan θ   
f dx f
b
 dy  dx
f
bx
 y c
f
At x  0, y  b
bx
 y  b
f
46. Let mass of the boulder that can be swept by the river be given by.
m  kV x g y d z
 m   V x  g  y d z
x y z
 M 1L0T 0    L1T 1   L1T 2   M 1L3 
       
Sec: Sr.Icon All 22
  M z Lx  y 3 zT  x  2 y 
 
z  1; x  y  3z  0;  x  2 y  0
Solving x  6; y  3, z  1
 m  kV 6 g 3d
m V
  100  6  100
m V
 6  1  6%
The percentage change in mass is 6% when speed changes by 1%
47. Given
 π
y1  a sin  kx  t   k   .....1
 2
 π
y2  a sin  kx  t   ... 2 
 3
From principle of superposition
  π 
y  y1  y2  a sin  kx  t   sin  kx  t  
  3 
 π  π
 2a sin  kx   .cos  t  
 6  6
 π
Nodes are positions where A  2a sin  kx    0
 6
π π
 x   π,2π,3π........ for x  0
2 6
x  1  1  1
  1   ;  2   ;  3   ;..........
2  6  6  6
5 11 17 23
 , , , .......
3 3 3 3
5 11 17
Obviously , x  , , and lie between x  1 and x  6m
3 3 3
So there are 3 nodes between x  1 and x  6m
48. Total binding energy of helium atom  2 He4   4  7  28MeV
Total binding energy of deuteron 1 H 2 1 p  1n   2  1.1  2.2MeV
Hence, binding energy of 2 deuterons  2  2.2  4.4MeV
So, the energy released in forming helium nucleus from two deuterons is
28  4.4 MeV  23.6 MeV
Sec: Sr.Icon All 23

49. With S open
Net electro motive force = 0
 Charge on all capacitors = 0
With S closed
Energy stored in capacitors
U  240µJ
Work done by cells  480µJ
Heat produced  240µJ
12V
 2µF
4µF   q1  16µC
q1 q1 
6µF
  3µF q1  24µC
 q2 q2 
12V
50.
B
A V
VO
V' 2V
Given, 1 o ,
V V
or V '  V  2Vo ,
or V '  Vo  V  Vo
Velocity of separation = Velocity of approach so, e  1.0
Sec: Sr.Icon All 24

CHEMISTRY
51. Given,
Volume of aqueous solution , V 10 mL
Weight of diprotic acid, W  4 mg = 4  10 3g
P H = 2,
Gram molecular weight , GMW = ?
P H =  log  H  
 
 2=  log  H  
 
 H +   10 2  Normality
 
W 1000
N 
E V  in mL 
2 4  103 1000
 10  
E 10
 E  40 g
GMW
E  n  factor  2 
n  factor
(Or)
 GMW  n  factor  E
 2  40
 80 g
52. Let the molecular masses of A and B be M A and M B recpectively.
Pressure exerted by the gas B  1.5  1.0   0.5 atm
Volume and temperature are same in the both the gases
For gas A:
P  1 atm
W 1g
M  MA
We know that,
W
PV  RT
M
1
 1 V   RT
MA
Sec: Sr.Icon All 25

RT
 MA  ………..(i)
V
For gas B;
P  0.5 atm
W  2g
M  MB
2
 0.5  V   RT
MB
2 RT
 MB  .................(ii)
V
Diving equation(i) by equation (ii),
M RT V
 B  
MA V 2 RT
M 1
 A  Thus,
MB 2
M A : M B  1: 2
53. NH 4HS(S)  NH3(g)  H 2S(g)
Total pressure is P atm . One half of this is equal to partial pressure of ammonia. It is
also equal to to partial pressure of hydrogen.
1 P
 PNH3  PH 2S   P 
2 2
P P
at old equilibrium K p     atm2
  2 
2
P2
at new equilibrium
4 atm

2   P atm  P H S
2 
P
 PH2S  atm = 0.25P
4
54. Given ,
 
 t1   3
 
 2 1
 
 t1   2
 
 2 2
 a  x 100  25  75%
 a  x 100  75  25%
Sec: Sr.Icon All 26
t1
?
t2
Applying 1st Order kinetics
2.303  a 
K log  
t ax
Or
1  a 
K  In  
t ax
0.693 2.303  100 

  log    1
3 t1  25 
0.693 2.303  100 
  log     2
2 t2  25 
From equations 1 & 2
2 t2 log 4  log 3
 .
3 t1 log 4
t1 3 0.6  0.48
 
t2 2 0.6
3 0.12
   3 :10 .
2 0.6
55. Given,
Volume, V1  1L
Volume, V2  4 L
Pressure, P1  10 atm
Pressure, P2  5 atm
External pressure, Pext  1atm
Heat capacity, C  50 J/ o C
Final temperature, T  T2
Enthalpy change, H  ?
For the state1,
Pv  nRT
 1  10  n  0.0821  300
 n  0.4
For the state 2,
 4  5  0.4  0.0821  T2
 T2  600K
U  q  w
 U  (C  T )    Pext  V
Sec: Sr.Icon All 27
 U  50  300 J 1atm  3L
 U 15000  300
(  1L.atm  100 J )
U 14700 J
H  U    Pv 
 H 14700 J   (5  4)  10 atm L
 H 15700
H 15.7 KJ
56.  e Ba 3  PO 4 2  160  140  100
 m Ba 3  PO 4 2  1200  1.cm. mol 1
1000 K
m 
 solubility 
1000  1.2  105 1000  1.2  105
 Solubility, S =  3
 105 molL1
m 1.2  10
Ba3 ( PO4 ) 2  3 Ba 2  2 PO43
3S 2S
 S  105 mole.lit 1
3 5
 K sp   3S  (2 S ) 2  (27  4) S 5  108  10 5 
 108  1025
Or 1.08  1023 .
3
57.  - form : 2r  a
2
1 1
 - form : 2r  a
2
Since distance between the nearest neighbors is the same,
3 1 1
 a a
2 2
2 1
a a
3
3
d   form

 
4  M / a1  N A
d  form 2  M / a3  NA
Sec: Sr.Icon All 28

1 3
4M /  a   NA 4 2
 3
 .
 2 1 3 3
2M /  a   NA
 3 
58. Lithium does not give ethynide on reaction with ethyne.
59. Boric acid is not a bronsted acid. Products hydrolysis of SiC 4 gives silicates
60. 1) If only diluted nitric acid is used, nitric oxide instead of nitrogen dioxide is given out,
and the reaction becomes:
3Cu  s   dilute.8HNO3  aq   3Cu NO3 ) 2  aq   4H2O  l   2NO  g 
(
MnO2
2) 2 KClO3   2 KCl  3O2
3) 4Zn  10
HNO  dilute   4Zn  NO3 2  5H 2O + N 2O
3
4) Chlorine can be prepared by reacting HC with MnO 2 .The reaction is represented by
this equation. MnO2  s   4HC  aq   C 2  g   MnC 2  aq   2H 2O .
Chlorine is an yellow green gas.
61. 1) Xenon tetrafluoride react with water
6XeF4  12H 2O  2XeO 3  4Xe  3O 2
2) Calcium hydroxide react with chlorine
2Ca  OH 2  2C 2  Ca  CO 2  CaC 2  2H 2O
3) White phosphorus react with sodium hydroxide and water
P4  3NaOH  3H 2O  PH 3  3Na
White phosphorus react with sodium hydroxide and water to produce phosphine and
sodium hypophosphite . Sodium hydroxide - cold, concentrated solution. This reaction
takes place slowly.
NO  O3  NO 2  O 2 it is a redox reaction
62.
C MgBr
C 2 / h alc.KOH CH3MgBr
 CH 4
3-chloro cycle pentence Cyclopentadiene methane
Cyclopentene
Cyclopenta diene carbanion
63 Both aliphatic & aromatic aldehydes answer silver mirror test.
Sec: Sr.Icon All 29

64. In proline, the R-group is bonded to the central carbon as well as the nitrogen atom of the
amino group, forming a house-like structure, as seen below. This makes proline unique in
structure among all other amino acids.
O
OH
NH
Proline structure contain secondary amine group
65. Ofloxacin is a bactericidal antibiotic
66.
3-methylhex-4-en-1-yne
67.
O CH 3
HBr *
OH BrCH2 COOH
68.
+
OH O
C C
OH HNO2 -N2 H

 OH   + H
NH 2 

-H
N2 +
trans
OH
H H
H O
OH HNO2 OH 
H
NH 2  
shift

NH 2
N 2
69 More electropositive metals like calcium are usually prepared by electrolysis. Carbon
forms a carbide with calcium instead.
70. Linkage, Geometrical, optical isomers given by option -1
71. Given,
Boiling point of pure Benzene, T  353.23K
Weight of solute, W1  1.80g
Weight of solvent, W2  90g
Boiling point of solution, Ts  354.4 K
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1
Ebullioscopic constant, K b  2.53 K Kg M
Molar of solute, M =?
Tb  K b .m
Tb  Ts  To
 354.11  353.23k  0.88
 1.8 1000 
 0.88   2.53   
M 90 
 M  57.50 g mol-1
72.
 KMnO4  N1V1  N 2V2  H 2O2 
 0.5  100  N  50
 N for H 2O 2  1eq. L-1
 0.5 mol. L-1
 No of moles O 2 by decomposition  2.5  103
g 
Volume of O 2 at STP  2.5  10 3  22700 mL
g 
 56.75 mL
73 Teflon, orlon , Buna-N, Natural Rubber.
74. Recommended limits for certain substances in Drinking Water.
Manganese Mn 
2+

 0.05ppm
75.
CH3 -CH=CH-CHO CH3  CH 2  CH  C  CHO
Cis +trans CH 3
E+Z
CH3 - CH = C - CHO
CH 3 CH3  CH 2  CH  CH  CHO
E+Z Cis  trans
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Icon All_GTM-5 CODE-B_Key & Sol's

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Time: 09.00am to 12.00 CODE-B Max.Marks:300

Key & Solutions

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Given rate of change in surface area

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Let P  h, k  be the point on locus.

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Variance=  xi2   x 2  a 2  b2  4  16  100  144  196  82  16

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Apply KVL to get current flowing through the circuit

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0.693 2.303  100 

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E+Z Cis  trans

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