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IIT-IZ-CO-SPARK_PH-I_ JEE-MAIN_GTM-4_Key&Sol’s
CHEMISTRY
C–NH2 Br2 in C–NH2 ..
1. CCl4
NH2
O .. :
O O
Br
+ Br
Br
–H+ NH2
NH
O O
Br Br
0 .1 c 9 Ka
Ka = ; c= = 90 Ka.
9 0 .1
3. Among option (a) and (c), rate would be less in (a) (HNO 3 and HCl are both
strong acids). Among (a), (b) and (d), the conc. of TA is same but the conc.
of H+ will be 0.20 M in (a) and less than 0.20 M in (b) and (d) each. As
acetic acid is a weaker acid than HCO2H, the least rate of hydrolysis will be
with 0.1 M in TA and 0.20 M in CH3CO2H.
4. Conceptual
5. Conceptual
Alcoholic
6. R–OR + H–I R–OH + R–I AgNO3
AgI + R+ NO3
solution
Ether with one mole of methoxy group reacts with one mole of HI to form
one mole of CH3I, which can react with alcoholic AgNO3 to give 1 mole of
AgI precipitate. Similarly, 1 mole of ether with ‘n’ moles of methoxy group
reacts with ‘n’ moles of HI to give ‘n’ moles of AgI precipitate.
0.2063
Moles of organic compound =
168
0.2063 0.8658
Moles of AgI produced = n =
168 235
n = 3.
7. Conceptual
8. Let total number of moles of Ni are x, out of which 96% are in +2 state and
4% are in +3 state.
Maintaining the electroneutrality,
96 4
x 100 (2) x 100 (3) =2
200 50
x= = = 0.98
204 51
CIS: Me2C(CN)–N=N–C(CN)Me2
N2 + Me 2C(CN)
Me 2C(CN) + Bu3Sn–H
Bu 3S n + Me2CH(CN)
Br . .
CPS: Bu3Sn
+ Bu3Sn–Br
. .
ring Bu3Sn–H + Bu3Sn
closure
Ease of formation of a five membered ring is greater than that of a six membered
ring.
– d[A] = k1
= k.
dt k2
– d[A] = k1[A]
= k1[A]
dt 1
PV 1 1 6
T= = 1
= = 73.08 K ~ 73 K.
nR 0.0821 0.0821
6
3RT 3 8.314 73
RMS = = = 9.1 105 ms 1 .
M 2 103
12. Conceptual
13. I2 + 2Na2S2O3 2NaI + Na2S4O6
Millimoles of Na2S2O3 consumed = 6.
Millimoles of I2 consumed = 3.
3I2 + 6NaOH 5NaI + NaIO3 + 3H2O
30 6
Millimole of I2 reacted with NaOH = = 12
2
14. Conceptual
O
CH2–OH O O O–C–CH3
3CH3–C–O–C–CH3
15. HO–CH2–CH–CH–CHO H3C–O–H2C CH CH–CHO
O
OH
(A) CH2–O–C–CH3
One mol of this compound can react with only 1 mol of HIO4. It is oxidised
by Br2/H2O to give carboxylic acid which forms a lactone ring of five
member on heating.
c
c(1 )
M theoretical 30 6
= =
M observed 150 c
= 0.96.
K2Cr2O7
17. (CH3)3C–CH2–CH2–OH (CH3)3C–CH2–COOH
SOCl2
(CH3)3C–CH2–COCl
(A) (B)
2(CH3)2NH
CH3 O
LiAlH4
(CH3)3C–CH2–CH2–N–CH3 (CH3)3C–CH2–C–N(CH3)2
(P) (C)
18. Conceptual
19. Conceptual
20. Conceptual
21. NH 2 is angular while N3 is linear. So bond angle increases in this convention .
In the remaining cases bond angle decreases
22. During partial hydrolysis XeF6 convents to XeOF4 sp3d 2 or XeO2 F2 sp3d
MATHS
31. Lt f x f 0
x 0
2 2 2
32.
a b b c c a 0 3 2 a.b b.c c.a 0
abc 0
2a 5b 5c 3 a 3
5a 9b 9c 4 a 4
33. Augmented matrix
1 2 1 1 1 2 1 1 1 2 1 1
1 3 4 k 0 1 3 k 1 0 1 3 k 1
1 5 10 k 2 0 3 9 k 2 1 0 0 0 2
k 3k 2
39. Conceptual
1
sin 2 cos 2 x sin 2 2 x
x cos 4 x sin 2 x cos 2 x
40. y 4
sin 4 x cos 4 x sin 2 x.cos 2 x 1 2
1 sin 2 x
4
1 y cos 2 2 x 4cox 2 x 3 y 1 0
∆>0
3 y2 2 y 5 0
5
y 1
3
41.
V aX b X a aX b X b
V b a 1 a.b b a
42. Clearly 2 side are x 2 y 1 0 and x y 0
1
Let z
t
dz g x
1
1
Z I .F g x
dx g x g x
g x
Solutionis Z .g x x c xc
t
46. f x x 2 x 3 x ...... nx
1 1 1
Period of f x L.C.M 1, , ,.... 1
2 3 n
47. f A sin 2sin 1 A sin 2 A
2
2
2
A f x .sin 2 A dx A sin 2 A dA sin t dt
2 2
0 0 0
4
48. Total No. of tickets =15+15=30
49. Conceptual
50. A 1 3t ,3 t , 2 t
B 3 3 ,3 2 ,5 4 are two points on given line
DR’s of AB are one proportional to 7, 4, -1
51. Conceptual
52. Conceptual
53. f 0 0, f 1 0 lies in 1, 0
1
tan 1 cot 1
54. favourable cases are (1,1) (1,2) (2,1)
Probability = 3
36
Sr. IIT-IZ-CO-SPARK_JEE_MAIN _Sol Page 7
Narayana IIT Academy 07-02-16_Sr. IIT-IZ-CO-SPARK_PH-I_ JEE-MAIN_GTM-4_Key&Sol’s
3
55. Equation of normal at is 2 x sec y cos ec 1It passes through , 2
2 4
S.D = (distance from p(θ) to centre ) – radius
3 1
2
56. Using L.M.V theorem
57. Conceptual
58. Conceptual
1 1
1
59. Dr 1 x
0
50 101
dx x 1 x 50 101
0 x 101 1 x
0
50 100
50 x dx
49
5050 1 x50 x50 1 1 dx Nr 5050 Dr
0
Nr
5051
Dr
60. Conceptual
PHYSICS
61. In positive half cycle, diode becomes forward biased and conducting, capacitor
will be charged until voltage across it becomes peak value. In negative half
cycle, diode becomes reverse biased and no charge can flow through it. Hence
capacitor cannot discharge.
62. Comment for discussion. In the ideal case that we normally consider each
collision transfers twice the magnitude of its normal momentum. On the face
EFGH, it transfers only half of that.
63. Conceptual
64.
0 I
d B da dr L
2 r
x L
IL dr o IL L
o ln 1
2 x
r 2 x
Let l is the distance between two wires. Net flux through the loop is zero when
A and B carry currents in opposite directions and A B
Narayana IIT Academy 07-02-16_Sr. IIT-IZ-CO-SPARK_PH-I_ JEE-MAIN_GTM-4_Key&Sol’s
o 2 L L o (1) L L
ln 1 ln 1
2 L 2 L l
L L 2L
2ln 2 ln 1 1 4l
L l Ll 3
nRT dV 3 dT v 3 T
PdV nCv dT dV nCv dT ln 2 ln 2 V T 3/2
65. V V 2 T v1 2 T1
V 2 CT 3 . where C is constant
2r 1
66. r l
2
l 2r
l
2
r
2 4 R
67. For cm of B, V rw 2 R
T T
1 1
KEB MV 2 I c 2
2 2
1 2 1 MR 2 V 2
MV 2
2 2 2 R
2
3 4 R
M
4 T
12 2 R 2
T2
68. At ‘O’, PE is same in both the orbits but KE may be different due to difference
in total energies.
69. In positions(1) and (2), PE of interaction between wire and loop is same
U 0 work done is zero. According to same reason, W2 0 .
70. Conceptual
1 1 1
71. 1 5
f R1 R2
1 1
5 1.5 1 ....1
R1 R2
In liquid,
Sr. IIT-IZ-CO-SPARK_JEE_MAIN _Sol Page 9
Narayana IIT Academy 07-02-16_Sr. IIT-IZ-CO-SPARK_PH-I_ JEE-MAIN_GTM-4_Key&Sol’s
1 1.5 1 1
1
1
f 4 R R2
1
3
4/3 1.5 4 / 3 1 1
P1 4 / 3 ....... 2
f 4 / 3 R1 R2
1 5 0.5
1
2 p 4 1
3 8
5
p1 D
3
1MSD
72. Least count
N
1MSD
0.1mm
20
F2
73. W , here F is same for both the springs since they are in series.
2K
W1 K 2 3
W2 K1 2
74. Net external force on the system =0 acm 0 . For the system, KEi 0 and at
maximum extension, KE f 0
F F
m
3m
x1
x2
1 2
Wext PE Fx1 Fx2 k x1 x2
2
2F
x1 x2 xmax in spring
K
78.
In the first case K.E. of H-atom increases due to recoil whereas in the accond
case K.E decreass due recoil but E1 KE1 E2 KE2
1 2 2I
79. I 0 E C or E0
2 0 0C
2X 4
E0
8.8 X 10 12 X 3 X 108
55 NC 1
Narayana IIT Academy 07-02-16_Sr. IIT-IZ-CO-SPARK_PH-I_ JEE-MAIN_GTM-4_Key&Sol’s
80.
r 3
tan 37 0
8 4
r 6m
F P0 hpg r 2 105 10(800)10 36 1.8(36) (105 ) 2 107 N
a .b
Projection of a onb a
81. b 7/5
Projection of b on a b .a b
a
82. V 2n l2 l1 : for second resonance, water level in the tube has to be decreased.
For that, reservoir has to be descended down to equalize the water levels in both
tube and reservoir.
83.
3
84. I I0
4
3
I 0 cos 2 / 2 I0
4
3
cos / 2
2
/ 2 300
600
3 6
x
31
5
6 6
31
2 1 t
6
31
t substituting t 9.3 m
3 2 1
85. After tow hours
No No
x: y : 1:1
2 2
No 3 No
Four hours : 1: 3
4 4
No 7 No
Six hours : 1: 7
8 8
Here it is 1: 4
So t 4 hrs 6hrs
86. In general R (rate of collection ) =vA cos θ.
Where θ is the angle between the velocity of the rain and the normal to the cross
section A of the vessel.
R vA cos 00 vA
When the wind blows, R’=v’A cos θ, where v’ is the new velocity of rain. Now
v ' u2 v2
v
And cos
u2 v2
R ' v ' A cos
vA R
87. r 1 x
For diamagnetic substance r 1 is negative.
88. Power factor cos ∅ =R/Z
If R is constant, then cos ∅ ∝ 1
Z
Z cos 1 1/ 4 1
1 Z 2 2 Z1
Z 2 cos 2 1/ 2 2
2 Z 1 Z1
Percentage change X 100 100 0 0
Z1
89. Follow color coding Table
1 2
KE TE PE TE KA
90. Required ratio R 1 2 2
1 n2 1
PE PE PE 1 A
K
2 n