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CHEMISTRY
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1. Given E 1
cos 600 r 0
59
cos r 0
r 1
59 sin 30 r
r 1 cos r
sin31.sin 32............sin89 cos1 cos 2 cos3....cos59
1
cos1.cos 2............cos59 cos1 cos 2 cos3....cos59
2. E 2, A 2, R 1
T 1, H 1, Q 1,U 1, K 1
EEATQK
7!
2!
π
2
sin 2 x sin 2 x
3. Let I dx...........(1)
1 2017 1 2017 x
0
π
2 π π
2 sin x
2 2 dx
π π
π 1 2017 + x
2 2
2
π
x
2017 sin 2 x
2
I dx...........(2)
x
π 1 2017
2
(1)+(2)
π
1 2017 x sin 2 x
2
2I dx
x
π 1
2017
2
z w max 9, z w min 1
5. Given that E x 2017 y 2017 z 2017 2017 xyz
Use A.M G.M.
x 2017 y 2017 z 2017 1
1 .... 1 1
2017
2014 times
z 2017
.y 2017 2017
.z
.1.1............1 2017
E 2014
n n
6. Given that xi2 400 and xi 100 ,
i 1 i 1
2
2 xi2 xi
Use variance, 0 0
n n
400 10000
0 n 25
n n2
12. Let z be the event of 2 comes when the fair dice is thrown.
1 5
Pz
6
P z 6
P (2 comes in even trial)
P zz or zz zz or ...........
3
5 1 5 1
. .............
6 6 6 6
5 1
a
6 6
5 In G.Pseries, S
2 11 1 r
5
1
6
cos ec 2 x
13. Let I dx
9
cos ecx cot x 2
Put cos ecx cot x z
1
cos ecx cot x
z
1
2cos ec 2 x dx 1 dz
z2
1
1 9 13
1 2 1
I z dz z 2 dz z 2 dz
2 9 2
z 2
7
11
1z 2 z 2
= 2 2 C
2 7 11
7
1 z 2
2
= z C
7 11
7 1 (cos ecx cot x) 2
cos ecx cot x 2 C
7 11
7 2
1 cosecx cot x
cos ecx cot x 2 C (given)
11
7
14. Given that x cot y ln cos x dy ln sin y y tan x dx 0
x cot y dy lnsin y dx ln cos x dy y tan x dx 0
d x ln sin y d y ln cos x 0
x lnsin y y ln cos x c
Sec: Sr.Icon All 6
Sri Chaitanya IIT Academy 28-12-19_Sr.Icon All_GTM-5_CODE-A_Key & Sol's
x y
sin y . cos x c
12 12
12 1211 11
15. Given that 12K. CK . CK-1 12K. CK-111CK-1
K 1 K 1
K
12 2 n n n 1
12 2
11
CK-1 Cr
r
Cr 1
K 1
22! (2n)!
122. C02 +C12 +C22 +......+C2n
11!11! n!(n-r)!
21.19.17.........3 12
12. 2 .6
11!
12 21 19 17 ..... 3 12
2 P (Given)
11!
P 6
1
3 2
Required area, A 2 x 3 x 3 x 1 dx
0
1
A x3 3x 2 3x 1 dx
0
1
x4 3 3x
2 1
A x x sq.units
4 2
0 4
If p 3
1 1
f " x
p p 1 x
p 4
x p 4 sin 2 x p 3 cos
x
x
for x 0
0, x0
f '' x to be continuous p 4,
18.
p q p q p q p q q q p q p q q
T T T T F F F
T F F T T F F
F T F T F F F
F F F T T F F
Given compound statement is always false. So it is a contradiction.
19. The normal at the extremities of focal chord meet at right angle. So orthocentre is the
point of intersection of normals
2
2
If P at1 ,2at1 , q at2 ,2at2 then t1t2 1,
Point of intersection of normals
h a t12 t22 t1t2 2
k at1t2 t1 t2
k a t1 t2
2
h a t1 t2 t1t2 2
k 2
h a 3
a
a h 3a k 2
Locus of h, k is y 2 a x 3a
20. Given equation is ax by c 0 c ax by.....(1)
Since a, b, c are in A.P then
a c 2b a 2b c 0
a 2b ax by 0
a(1 x) b( y 2) 0
It represents family of concurrent lines.
x 1, y 2
Let 1, 2 ,
Equation of the circle is
x 12 y 2 2
x2 y 2 2 x 4 y 5 0.....(2)
It is orthogonal to x 2 y 2 4 x 4 y 1 0....(3)
2 gg ' 2 ff ' c c '
4 8 5 1
8
1 2 8 7
2 x4 14 x 2 8 x 49
21. Given that f x
x4 7 x2 4 x 23
3
f x 2
x 4 7 x 2 4 x 23
h x 3
Range of h( x) is [3, )
Range of f x is (2,3]
1
22. Given system of equation is x3 3x 2 2019 x 2017 sin 2 θ and
2
1
y3 3 y 2 2019 y 2017 cos2 θ adding two equations
2
1
x 13 2016 x 1 sin 2 θ
2
1
y 13 2016 y 1 cos2 θ
2
x 13 y 13 2016 x y 2 0
( x y 2)[ x 1) 2 ( y 1) 2 ( x 1)( y 1) 2016] 0
x y 2 0 x y 2
x y 2 2
23. Let ABCD have coordinates
O, i j , j k , i k respectively
d1
cosecθ 3
d
Where θ is angle between AB and normal of BCD
24. x6 2 x3 8 x 1 x 2 ..... x 6
2 6 2 2 3 8 2 1 2 1 .... 2 6
2
On multiplying 40 g 1 g 2 ............g 6
25. Given that a 7, b 3, c 5
mg
Given
Length of cylinder= l
Depth= d
M
From diagram F Mg l x g mxg
l
1
F .dx
0
l
mg x2
l 2
0
mg l 2
l 2
mgl
2
0.5mgl
27. Increasing b increases the torque due to each hand. So, increase b and l unchanged.
28. Horizontal component of velocity is decreased (or) due but vertical component remains
same.
29. Given
Length of rod= l
T cosθ
c
N
mg
θ
N T cosθ 0
if N 0
T 0
So, answer is tensile force in the rod
30.
V A
+ -
r
Let r internal resistance of the battery
We shall take the resistance for the ammeter to be equal to zero and that of voltmeter to
be R
Initially V Ir
I
rR
R
So, V .....1
rR
After the voltmeter is shunted
By principle of superposition
Magnetic field exist at the centre of the second cube is Bo j Bo k Bo i
Bo i j k
32. Given
Mass of hydrogen m 1.0g
Root mean square speed of air molecules Vrms 500 m s
The average molecular mass of air molecules M 2.9g mol = 29 10 3 kg mol
We know that
3RT
Root mean square speed Vrms
M
3RT
500
29 10 3
25 104 29 103
RT
3
25 29 10
RT
3
5
Total internal energy du nRT
2
m 1
Where n
M 2
5 1 25 29 10
du
2 2 3
25 29 25
du
6
du 3020.8
du 3021J
33.
T
From relation
T T 1
sin sin sin
T 1
(or)
sin sin
sin sin
sin sin
90-θ
90-θ
θ θ
18 2 v f 5
v f 4
J North mv f mvi
North
v f ,n 3
vf 5
1 2
W K .E. m 5 5 0
2
2
43. Given
Weight of a body at the equator of planet is half of that at the poles
g
i.e.., g
2
g
g R 2
2
g
R 2 g
2
g
R 2
2
g 2 R 2
We know vo R
The escape velocity ve 2 gR
ve 2 R 2 R 2
ve 4 R 2 2
ve 2 R 2vo
44. Newton’s laws
2T cosθ mg
2T 'cosθ f B mg
F Po a 2 ..... 2 A a 2
From (1) & (2) , Po a 2 mg
mg
Po
a2
We know
Volume of cube V a3
1
a V 3
mg
Po
2
V 3
2
PV 3
o m
g
Divide by M on both sides
2
Pv 3 m
o n
Mg M
2
PV 3
n o
Mg
We know PV nRT
2
P V 3 RT
PV o
Mg
1
PV 3 RT
P o
Mg
1
x 0.33
3
47. Given radius of circular path R 20m
Radius of car wheel 25cm=0.25m
m
mg cosθ
mg sinθ mg M
From Diagram
Constrain relations & Newton’s laws
F F cosθ N sinθ ma.....1
F mg sin θ mg cosθ mar ...... 2
From (1) F 3a F cosθ N sin θ
F F cosθ N sinθ
(or) a ..... 3
m
F mg sin θ mg cosθ
From (2) ar ..... 4
m
B c c A A
A
c c c
C Br C
Br Br C
Br C Br
54. Elements in their highest oxidation state can act only as oxidizing agents but in middle
oxidation states can act as both oxidizing and reducing agents.
55. SF6 has regular octahedral structure and XeF4 square planar structure. So in both all
bond lengths are equal. BrF5 has square pyramid, PC 5 has trigonal bi pyramid
structures in which all bond lengths are not equal. Due to distorted octahedral structure in
XeF6 all bond lengths are not equal.
56. With the increase in number of more electronegative bonded atoms positive charge on
central atom increases due to which EN increases.
57. Pollution is a foreign substance the makes something dirty, or impure, especially waste
from human activities while pollution is the act of polluting (or) the Stat of being polluted
especially the contamination of the environment by harmful substance
58.
12, 400
E=
12, 400
eV= 1.83
12, 400
eV= 1.83
3000
4.13eV= 1.83
2.3eV
A 4 4A
59. At initial 1 0
At equlibrium 1 4
Let a be the atomic mass of A
Thus mol mass of A 4 4A
r M2
From Graham’s Law 1 =
r2 M1
40 / a 4 4a
60 / 4a 1 a
16 8
6 1
NH 2 NH
NH
(I) (III)
(II) O
Aniline N-Phenye acetamide
N- Phenye-N-ethanamine
Basicity III > I > II.
66.
O CHO
Glyoxal
O
Ozonolysis + 2HCHO
O
Glyoxal
O
Ozonolysis
3
O
Glyoxal
67. All are primary halides. Rate of SN 2 is proportional to stability of transition state i.e.
stability of charge on C.
68. Substitution not possible at bridgehead carbon.
69. 1)Mannose is a monosaccharide.
HO
CH 2
H O H
H
OH OH
OH OH
H H
2)A disaccharide is the sugar formed when two monosaccharide (simple sugar)are joined
by glycosidic linkage.Like monosaccharides, disaccharides are soluble in water.Three
common examples are sucrose lactose & maltose.
70
NO 2
O2N
CH I,K CO
3 2 3 H SO ,HNO
HO
2 Me O 2 4 3 Me
O
SN EAS
71. Cu, Hg, Pb, Ag produce NO gas with dil. HNO3 , Fe and Zn gives N2O , Sn produce
NH4 NO3 . Au has no reaction with dil. HNO3 .
72. Given, Initial Volume, V V1
V
Final Volume, V2 = 1
3
Initial Pressure 750 – 100 650 mm
PV = 650×V =P ×V1
1 1 P2V 2 1 2
3
Sec: Sr.Icon All 26
Sri Chaitanya IIT Academy 28-12-19_Sr.Icon All_GTM-5_CODE-A_Key & Sol's
Initial Pressure, P1 750 100 650mmHg
Final Pressure, P2 ?
Final Pressure, = 1950
Final P total 1950 100 2050 mm 2050 torr.
73. 3 1011 3 101 :2 108 104 :2 1010 2 10 5
9 1010 : 2 10 4 : 2 1010 2 103
9 106 : 2 : 40
9 106 9000000
% 100 100 100.00%
9000042 9000042
74.
i, iii, iv, v, vi.
Rate of SN 2 is proportional to stability of transition state i.e. stability of charge on
Carbon.
75.
OD
D D