You are on page 1of 27

Sri Chaitanya IIT Academy 28-12-19_Sr.

Icon All_GTM-5_CODE-A_Key & Sol's

Sri Chaitanya IIT Academy., India.


AP, TELANGANA, KARNATAKA, TAMILNADU, MAHARASHTRA, DELHI, RANCHI
A right Choice for the Real Aspirant
ICON Central Office , Madhapur – Hyderabad
Sec: Sr.Icon All GTM-05 Date: 28-12-19

Time: 09.00am to 12.00 CODE-A Max.Marks:300

Key & Solutions


MATHEMATICS
1 2 2 2 3 1 4 3 5 3
6 4 7 4 8 2 9 3 10 3
11 3 12 4 13 4 14 2 15 4
16 2 17 3 18 2 19 1 20 4
21 0005.00 22 0002.00 23 0009.00 24 1600.00 25 0056.25

PHYSICS
26 1 27 2 28 1 29 1 30 2
31 3 32 2 33 4 34 3 35 2
36 2 37 4 38 1 39 3 40 3
41 3 42 1 43 2 44 4 45 1
46 0000.33 47 0003.00 48 0002.00 49 0001.00 50 0002.60

CHEMISTRY
51 2 52 2 53 2 54 2 55 4
56 2 57 2 58 1 59 3 60 1
61 2 62 3 63 2 64 1 65 1
66 2 67 1 68 4 69 2 70 4
71 0004.00 72 2050.00 73 0100.00 74 0005.00 75 0004.00

Sec: Sr.Icon All 1


Sri Chaitanya IIT Academy 28-12-19_Sr.Icon All_GTM-5_CODE-A_Key & Sol's
SOLUTIONS
Mathematics

1. Given E   1 
cos 600  r 0 
59 
  
 cos r 0 
r 1  
 



59 sin 30  r  
r 1 cos r 
sin31.sin 32............sin89 cos1 cos 2 cos3....cos59
  1
cos1.cos 2............cos59 cos1 cos 2 cos3....cos59
2. E  2, A  2, R  1
T  1, H  1, Q  1,U  1, K  1
EEATQK
7!
2!
π
2 
sin 2 x sin 2 x
3. Let I      dx...........(1)
 1   2017  1   2017  x 
0 
π
2 π π 
2 sin     x 
   2 2  dx
π π
π 1   2017  +  x
 2 2
2
π
x
 2017  sin 2 x
2
I  dx...........(2)
x
π 1   2017 

2
(1)+(2)
π
1  2017  x  sin 2 x
2
 
 2I    dx
x
π 1

  2017 
2

Sec: Sr.Icon All 2


Sri Chaitanya IIT Academy 28-12-19_Sr.Icon All_GTM-5_CODE-A_Key & Sol's
π
2
 2 I  2  sin 2 x dx
0
π
 1  cos 2 x 
I   dx
 2 
0
 π π
1  sin x  2 
  x 02   
2  2 0 
 
1 π 1 
    0
22 2 
π
I 
4
z 1 w4
4. Given that  2and 2
z4 w 1

 z  w max  9, z  w min  1
5. Given that E  x 2017  y 2017  z 2017  2017 xyz
Use A.M  G.M.
x 2017  y 2017  z 2017  1
 1  ....  1 1

2017
2014 times

 z 2017
.y 2017 2017
.z 
.1.1............1 2017
 E  2014
n n
6. Given that  xi2  400 and  xi  100 ,
i 1 i 1
2
2  xi2   xi 
Use variance,  0   0
n  n 
400 10000
   0  n  25
n n2

Sec: Sr.Icon All 3


Sri Chaitanya IIT Academy 28-12-19_Sr.Icon All_GTM-5_CODE-A_Key & Sol's
π
7. Given point P  3sin θ  4cosθ,3cosθ  4sin θ  , θ 
8
x2 y2
Given ellipse equation is  1
16 9
Director circle of the given ellipse is x2  y 2  16
 Point P lie on director circle of given ellipse.
π
 Angle between tangents is .
2
x  3 y 1 z  a x2 y4 z5
8. Given lines are   and  
2 3 p 2 4 2
x  x1 y  y1 z  z1
The equation of the plane through the lines   and
a1 b1 c1
x  x1 y  y1 z  z1
x  x2 y  y2 z  z2
  is a1 b1 c1  0
a2 b2 c2
a2 b2 c2
5 5 5  a
 2 3 p 0
2 4 2
 60  30 p  14a  0 ................(1)
Since lines are perpendicular then
4  12  2 p  0 ...........  2 
From (1) & (2)
30
P  4, a 
7
30 2
a  p  4  
7 7
 xe3 x , x0
9. Given that f  x   
 x3  3x 2  x, x  0
If x  0
f ' ( x )  3e3 x x  e3 x
f ' ( x ) increasing function
 f " ( x)  0
 3e3 x  x.9.e3 x  3.e3 x  0
 6  9x  0

Sec: Sr.Icon All 4


Sri Chaitanya IIT Academy 28-12-19_Sr.Icon All_GTM-5_CODE-A_Key & Sol's
2
x
3
 2 
 x    ,0  .....(1) ( x  0
 3 
If x  0
f ' ( x)  3x 2  6 x  1
f ' ( x ) is increasing function
 f "( x)  0
 6 x  6  0
 x 1
But x  0
 x   0,1 ........(2)
From (1) and (2),
 2 
x    ,1
 3 
10. Given equation sin 1 x  cos 1 x 2  1  tan 1(tan y )  a...........(1)
Clearly sin 1 x  x  0, 1
 Possible value of x  1
π π
 Equation (1) becomes   tan 1 tan y  a
2 2
 π 3π 
 For solution a   , 
2 2 
 Integral values of a are 2, 3, 4
11. Given equation is 2 x  x 2

From graph, number of solutions are 3.

12. Let z be the event of 2 comes when the fair dice is thrown.
1 5
Pz 
6
P z  6
 P (2 comes in even trial)

Sec: Sr.Icon All 5


Sri Chaitanya IIT Academy 28-12-19_Sr.Icon All_GTM-5_CODE-A_Key & Sol's


 P zz or zz zz or ........... 
3
5 1 5 1
     .  .............
6 6 6 6
5 1
  a 
 6 6 
5  In G.Pseries, S  
2 11  1 r 
5
1  
6
cos ec 2 x
13. Let I   dx
9
 cos ecx  cot x  2
Put cos ecx  cot x  z
1
cos ecx  cot x 
z
 1 
2cos ec 2 x dx  1   dz
 z2 
1
1  9 13 
1 2 1
I    z dz    z 2 dz  z 2 dz 
2 9 2   
z 2  
 7 
11 
1z 2 z 2 
=  2 2  C
2   7   11 
 
7
 1 z 2 
2
= z   C
 7 11 
7  1 (cos ecx  cot x) 2 
  cos ecx  cot x  2   C
7 11 
 
7 2
1  cosecx  cot x  
  cos ecx  cot x  2     C (given)
  11 
  7
14. Given that  x cot y  ln cos x  dy   ln sin y  y tan x  dx  0
 x cot y dy  lnsin y dx  ln cos x dy  y tan x dx  0
  d  x ln sin y    d  y ln cos x    0
 x lnsin y  y ln cos x  c
Sec: Sr.Icon All 6
Sri Chaitanya IIT Academy 28-12-19_Sr.Icon All_GTM-5_CODE-A_Key & Sol's
x y
  sin y  . cos x   c
12 12
12 1211 11
15. Given that  12K. CK . CK-1   12K. CK-111CK-1
K 1 K 1
K
12 2  n n  n 1 
 12 2
 11
CK-1   Cr 
 r
Cr 1 

K 1
22!  (2n)! 
 122.  C02 +C12 +C22 +......+C2n 
11!11!  n!(n-r)! 
21.19.17.........3 12
 12. 2 .6
11!
12  21  19  17  .....  3 12
  2  P (Given)
11!
P  6

16. Given that f ( x )  x3  3x 2  3x  1 and g ( x) be the inverse of f ( x) .

1
3 2
 Required area, A   2  x  3 x  3 x  1 dx  
0
1

A    x3  3x 2  3x  1 dx 
0
1
 x4 3 3x
2  1
A   x   x   sq.units
 4 2 
 0 4

Sec: Sr.Icon All 7


Sri Chaitanya IIT Academy 28-12-19_Sr.Icon All_GTM-5_CODE-A_Key & Sol's
 p 1 3
 x sin    x x , x  0
17. Given that f  x    x
 0, x0

3
g  x   x x has 4 repeated roots
 g '' x  is continuous and differentiable at x  0
 p 1
 x sin x0
Consider f  x    x
 0, x0
1
h p sin
h  0 if p  1
 
f ' 0  lim
h 0 h
 f ' 0   0 for p  1
 p 1 1 1
 px sin  x p  2 cos x0
 f ' x    x x
 0, x0
1 1
php 1 sin  h p 2 cos
 
 f '' 0  lim
h 0
h
h
h 0

If p  3
 1 1
 f " x    
 p  p  1 x
p 4
 
 x p  4 sin  2 x p 3 cos
x
x
for x  0
 0, x0
 f '' x  to be continuous p   4,  
18.
p q p  q p  q  p  q q   q p  q  p   q  q
T T T T F F F
T F F T T F F
F T F T F F F
F F F T T F F
Given compound statement is always false. So it is a contradiction.
19. The normal at the extremities of focal chord meet at right angle. So orthocentre is the
point of intersection of normals
 2
 
2

If P at1 ,2at1 , q at2 ,2at2 then t1t2  1,
Point of intersection of normals

Sec: Sr.Icon All 8


Sri Chaitanya IIT Academy 28-12-19_Sr.Icon All_GTM-5_CODE-A_Key & Sol's


h  a t12  t22  t1t2  2 
k  at1t2  t1  t2 
 k  a  t1  t2 

 2
 h  a  t1  t2   t1t2  2 
  k 2 
h  a    3

 a  
 
 a  h  3a   k 2
 Locus of  h, k  is y 2  a  x  3a 
20. Given equation is ax  by  c  0  c  ax  by.....(1)
Since a, b, c are in A.P then
a  c  2b  a  2b  c  0
 a  2b  ax  by  0
 a(1  x)  b( y  2)  0
It represents family of concurrent lines.
 x  1, y  2
Let 1, 2    ,  
 Equation of the circle is

 x  12   y  2 2  
 x2  y 2  2 x  4 y  5    0.....(2)
It is orthogonal to x 2  y 2  4 x  4 y  1  0....(3)
 2 gg '  2 ff '  c  c '
 4  8  5   1
 8
      1  2  8  7
2 x4  14 x 2  8 x  49
21. Given that f  x  
x4  7 x2  4 x  23
3
f  x  2 
x 4  7 x 2  4 x  23

Sec: Sr.Icon All 9


Sri Chaitanya IIT Academy 28-12-19_Sr.Icon All_GTM-5_CODE-A_Key & Sol's
4 2
Let h  x   x  7 x  4 x  23
2

 x2  4   ( x  2)2  3

 h x  3
Range of h( x) is [3, )
 Range of f  x  is (2,3]
1
22. Given system of equation is x3  3x 2  2019 x  2017  sin 2 θ  and
2
1
y3  3 y 2  2019 y  2017  cos2 θ  adding two equations
2
1
 x  13  2016  x  1  sin 2 θ 
2
1
 y  13  2016  y  1  cos2 θ 
2
 x  13   y  13  2016  x  y  2  0
 ( x  y  2)[ x  1) 2  ( y  1) 2  ( x  1)( y  1)  2016]  0
 x  y  2  0  x  y  2
 x  y  2  2
23. Let ABCD have coordinates
O,   i  j  ,   j  k  ,   i  k  respectively
d1
 cosecθ  3
d
Where θ is angle between AB and normal of BCD

24. x6  2 x3  8   x   1  x   2  .....  x   6 
 2  6  2  2  3  8   2  1  2  1  .... 2   6 
2
On multiplying  40  g 1  g  2  ............g  6 
25. Given that a  7, b  3, c  5

Sec: Sr.Icon All 10


Sri Chaitanya IIT Academy 28-12-19_Sr.Icon All_GTM-5_CODE-A_Key & Sol's
Consider,
ab bc ac
 
 B C  A C  A C  A B  B C  A B
 tan  tan  tan  tan   tan  tan  tan  tan   tan  tan  tan  tan 
 2 2  2 2  2 2  2 2  2 2  2 2
ab bc ac
  
a b a c a c
. . .
r1 r2 r1 r3 r1 r3
 r1r2  r2r3  r3r1
 s2
2
abc
 
 2 
2
 7  35
 
 2 
2
  7.5 
 56.25
PHYSICS
26.

mg
Given
Length of cylinder= l
Depth= d
M
From diagram F  Mg   l  x  g  mxg
l
1
   F .dx
0
l
mg  x2 
  
l  2 
0

Sec: Sr.Icon All 11


Sri Chaitanya IIT Academy 28-12-19_Sr.Icon All_GTM-5_CODE-A_Key & Sol's

mg  l 2 
  
l  2 
mgl

2
  0.5mgl
27. Increasing b increases the torque due to each hand. So, increase b and l unchanged.
28. Horizontal component of velocity is decreased (or) due but vertical component remains
same.
29. Given
Length of rod= l

T cosθ

c
N
mg
θ
N  T cosθ  0
if N  0
T  0
So, answer is tensile force in the rod
30.
V A

+ -
r

Let r  internal resistance of the battery
We shall take the resistance for the ammeter to be equal to zero and that of voltmeter to
be R
Initially V    Ir

I
rR
R
So, V  .....1
rR
After the voltmeter is shunted

Sec: Sr.Icon All 12


Sri Chaitanya IIT Academy 28-12-19_Sr.Icon All_GTM-5_CODE-A_Key & Sol's
V r
 
RA R
 Voltmeter  ...... 2 
 r
RA  R
r 
and
RA R
  Ammeter  ..... 3
r r  R
RA  R
From (2) and (3we have
v n
 .... 4 
 rR
From (1) & (2) given the required reading
v 
 
  1

v 
 1

31. Given Magnetic field B  Bo ˆj
Current = i

By principle of superposition
Magnetic field exist at the centre of the second cube is  Bo  j   Bo  k   Bo   i 
 Bo   i  j  k 
32. Given
Mass of hydrogen m  1.0g
Root mean square speed of air molecules Vrms  500 m s
The average molecular mass of air molecules M  2.9g mol = 29  10 3 kg mol
We know that
3RT
Root mean square speed Vrms 
M
3RT
 500 
29  10 3

Sec: Sr.Icon All 13


Sri Chaitanya IIT Academy 28-12-19_Sr.Icon All_GTM-5_CODE-A_Key & Sol's

25  104  29  103
 RT 
3
25  29  10
 RT 
3
5
Total internal energy du  nRT
2
m 1
Where n  
M 2
5 1 25  29  10
 du   
2 2 3
25  29  25
 du 
6
du  3020.8
 du  3021J
33.
T


From relation
T T 1
 
sin  sin  sin 
T 1
(or)  
sin  sin 
 sin   sin 
 
 sin   sin 
 
    

Sec: Sr.Icon All 14


Sri Chaitanya IIT Academy 28-12-19_Sr.Icon All_GTM-5_CODE-A_Key & Sol's
34.

90-θ

90-θ

θ θ

From diagram , path difference


4
 1  cos 2θ   8sin θ=x
sin θ
 π 
 8  6    n  1 
 180 
 π 
 8  3   n
 180 
π
 83    41.88cm = 42cm
180
E
35. tan  θ  45  v
Er
36. Given
Capacitance = C
` Charge= Q
Q2
Total amount of energy lost U 
2C
2
Q
  Q2
 2
U  
2C 8C
37. Given
Wavelength = 
Distance= d
Electric field= E
We know KE  h  ho
 KE  Fd 
c
 F  eE    
 

Sec: Sr.Icon All 15


Sri Chaitanya IIT Academy 28-12-19_Sr.Icon All_GTM-5_CODE-A_Key & Sol's
hc hc
 eEd  
 o
1 1 
 eEd  hc   
  o 
eEd 1 1
  
hc  o
1 1 eEd
  
o  hc
1
 1 eEd 
 o    
  hc 
38. From relation
t
N  1 T
 e  t   
No 2
165
N  1  110
 
No  2 
1
N req  ; N o  x
2
165
1 1
N req   x  110
2 2
165
 21  x 2 110
3
1
 2  x2 2
3
1
 x  2  22
3 1
1
 x  22  22
 x  2  1.41ml
39. Given
Inductance= L
Unknown resistance= R
We know E  iR (From ohm’s law)
d  io  i 
Also, E  L
dt

Sec: Sr.Icon All 16


Sri Chaitanya IIT Academy 28-12-19_Sr.Icon All_GTM-5_CODE-A_Key & Sol's
d  io  i 
L  iR
dt
d  i  io  R
  dt
i L
Integrating on both sides
 d o
 i  i   R dt
i L
R
 log  io  i   t
L
R R
 t  t
 i  io  e L (or)  i  ioe L ....1
2
Now the total heat dissipation E   i Rdt
Li 2 R
E 1  0 
2R
1
 E  Li 2
2
40.
x l  x 
v3
A v1 B v2 C
From diagram
x x
t1  and t2 
v1  v2 v1  v3
lx
t 
v2  v3
So, if t2  t1 , particle B and C may collide at an instant t1  t2 .
41. Given mass of particle , m1  m
Velocity  v
Mass of stationary particle m2  2m
From Conservation of Momentum ,
m1u1  m2u2  m1v1  m2v2
 mv  2m  0    m  2m  v '
 mv  3mv '
v
v ' 
3
From law of conservation of energy,

Sec: Sr.Icon All 17


Sri Chaitanya IIT Academy 28-12-19_Sr.Icon All_GTM-5_CODE-A_Key & Sol's
2
1 1 v
Loss of kinetic energy  mv 2  m  
2 2 3
1 8 4
 mv 2    mv2
2 9 9
42. Work done = change in kinetic energy
W  K .E.
impulse, J East   mv f  mvi 
East

18  2  v f  5 
v f  4
J North   mv f  mvi 
North

v f ,n  3
vf  5
1 2
  
W  K .E.  m 5  5  0
2
2

43. Given
Weight of a body at the equator of planet is half of that at the poles
g
i.e.., g 
2
g
  g  R 2
2
g
 R 2  g 
2
g
 R 2 
2
 g  2 R 2
We know vo  R
The escape velocity ve  2 gR


 ve  2 R 2 R 2 
 ve  4 R 2 2
 ve  2 R  2vo
44. Newton’s laws
2T cosθ  mg
2T 'cosθ  f B  mg

Sec: Sr.Icon All 18


Sri Chaitanya IIT Academy 28-12-19_Sr.Icon All_GTM-5_CODE-A_Key & Sol's
45.  2  3  internal reflection
 2  1  light bends towards normal
46. Given Volume of cube  V
Pressure= Po
Temperature= T
We know that F  mg ....1
Also, F  Po A (Pressure  Area)


 F  Po a 2 .....  2   A  a 2 
From (1) & (2) , Po a 2  mg
mg
 Po 
a2
We know
Volume of cube V  a3
1
 a V 3
mg
 Po 
2
V 3
2
PV 3
 o m
g
Divide by M on both sides
2
Pv 3 m
 o  n
Mg M
2
PV 3
n  o
Mg
We know PV  nRT
2
P V 3 RT
PV  o
Mg
1
PV 3 RT
P o
Mg
1
x   0.33
3
47. Given radius of circular path R  20m
Radius of car wheel   25cm=0.25m

Sec: Sr.Icon All 19


Sri Chaitanya IIT Academy 28-12-19_Sr.Icon All_GTM-5_CODE-A_Key & Sol's
Length l  1.5m
Speed of midpoint of an axile is
5
vC  36km h  36   10m s
18
Vcm
We know  
r
l
    Vcm  l 
r
lv
  
Rr
1.5  10
  
20  0.25
a0

48. Given , height = h


Acceleration due to gravity= g
From text question,
v is maximum
Acceleration , a  0
gh
v 
2
49.
a
F
N

m
mg cosθ
mg sinθ  mg M

From Diagram
Constrain relations & Newton’s laws
F  F cosθ  N sinθ  ma.....1
F  mg sin θ  mg cosθ  mar ...... 2 
From (1) F  3a  F cosθ  N sin θ
F  F cosθ  N sinθ
(or) a  ..... 3
m
F  mg sin θ  mg cosθ
From (2) ar  ..... 4 
m

Sec: Sr.Icon All 20


Sri Chaitanya IIT Academy 28-12-19_Sr.Icon All_GTM-5_CODE-A_Key & Sol's
F 1  cos    mg sin θ.cosθ
By, solving , we get a 
M  m sin 2 θ
50. Given Energy density of electric field U E  2  107 J m3
Energy density of magnetic field U B  0.4J m3
Distance r  2cm = 2  102 m
1
We know Energy density of electric field U E   o E 2
2
1
 2  1017   8.85  1012  E 2
2
4  105
  E2
8.85
 E  2.13  103
B2
Also, U B 
2 o
B2
 0.4 
2  4π  10 7
 B 2  2  4π  0.4  107
ojr
We know B 
2
2B 2  10.23  104
 j 
or 4π  107  2  102
20.46  104
  0.81  105
25.12  109
 1
Now j   E   
 
E 2.13  103
 
j 0.8  105
   2.66  10 8 m

Sec: Sr.Icon All 21


Sri Chaitanya IIT Academy 28-12-19_Sr.Icon All_GTM-5_CODE-A_Key & Sol's
CHEMISTRY
Z  Z 2 2
51. A) LE  For MgO
rc  ra rc  ra
2 1
MgF2 so m.pt of MgO is greater than MgF2
rc  ra
B) Due to Pseudoinert gas configuration CdC 2 is more covalent and thus have low m.pt
than CaC 2
C) NaHCO3 is sparingly soluble due to polymeric H–bonding
D) For Sulphates of IInd group solubility decreases from top to bottom
52. a) Malachite is a green Copper Carbonate hydroxide mineral with a chemical of
Cu 2CO3  OH 2
b)Froath floatation method is used for the concentration of Sulphide ore. Sphalarite is
ZnS.
C)Haematatite Ore being Oxide Ore is Concentrated by gravity separation process using
hydraulic separator.The Oxide is being heavier settles to the bottom while impurities
come to the surface and is removed.
d).The Seperation of the alumina from the impurities in the bauxite Ore is usually
accomplished by the Bayer process.
53. A)  M  gly 3  has only 2 optical isomers. No geometrical isomers.
B)  M  gly  en  C , Br  is [ M  AB   CC  de ] type have 5 geometrical isomers.
c c c c d
A A B B A c
c c c c
B d A B c
d B e A e
e d e a e

C) M  gly 2  en   is  M  AB 2  CC   type have three geometric isomers only.
A B B
A B B A B c

B c c A A
A
c c c

D) [ M  en  C 2Br2 also have 3 geometric isomers.

Sec: Sr.Icon All 22


Sri Chaitanya IIT Academy 28-12-19_Sr.Icon All_GTM-5_CODE-A_Key & Sol's
C C Br

C Br C

Br Br C
Br C Br
54. Elements in their highest oxidation state can act only as oxidizing agents but in middle
oxidation states can act as both oxidizing and reducing agents.
55. SF6 has regular octahedral structure and XeF4 square planar structure. So in both all
bond lengths are equal. BrF5 has square pyramid, PC 5 has trigonal bi pyramid
structures in which all bond lengths are not equal. Due to distorted octahedral structure in
XeF6 all bond lengths are not equal.
56. With the increase in number of more electronegative bonded atoms positive charge on
central atom increases due to which EN increases.
57. Pollution is a foreign substance the makes something dirty, or impure, especially waste
from human activities while pollution is the act of polluting (or) the Stat of being polluted
especially the contamination of the environment by harmful substance
58.
12, 400
E=

12, 400
 eV=  1.83

12, 400
 eV=  1.83
3000
 4.13eV=  1.83
   2.3eV
A 4  4A
59. At initial 1 0
At equlibrium 1   4
Let a be the atomic mass of A
Thus mol mass of A 4  4A
r M2
From Graham’s Law 1 =
r2 M1
40 / a 4 4a
 
60 / 4a 1   a
16 8
 
6 1 

Sec: Sr.Icon All 23


Sri Chaitanya IIT Academy 28-12-19_Sr.Icon All_GTM-5_CODE-A_Key & Sol's
1 
 
3 1 
1
 
4
60. In closed insulated container a liquid is stirred with a paddle to increase the temperature,
therefore it be haves as a adiabatic process. so, for it q=0.
Hence, from first law of thermodynamics
E  q  w
If q = 0
E  w but not equal to zero
(or)
Work is done on the system  w  0 
Internal energy will increase  U  0 
61. More is the hydrophobic character in surfactant molecule, lesser is CMC in aqueous
solution.
62. Using Vander waal’s equation, get a quadratic equation from which pressure can be
found.
 a 
For 1 mole,  P    v  b   RT
 V2 
 a 
If b is neglible, then  P   V  RT
 V2 
RT a
Or P  
V V2
(Or) PV 2  RTV  a  0
 RT   RT 2  4aP
V
2P
As V we can have only one value at P & T, We must have
 RT 2  4aP  0
Or R 2T 2  4aP
R2T 2
Or P 
4a
63.
We know that
N M 
1   
a3  NA 
Where,

Sec: Sr.Icon All 24


Sri Chaitanya IIT Academy 28-12-19_Sr.Icon All_GTM-5_CODE-A_Key & Sol's
 = density
M= molar mass
NA = Avagadrols number = 6.023  1023
N = number of formula unit per unit cell
2  56 g
 1 
3 cc
 4r  30
   NA  10
 3
3a
(For BCC, Atomic radius, r  ) & N =2
4
4  56 g
 2 
3 cc
 
2 2. r  NA  1030
1
(For FCC, Atomic radius, r  ) & N =4
2 2a

 1  0.918
2
64.
ERP   0.059  P H
 0.059  7
 0.41V
65

NH 2 NH
NH

(I) (III)
(II) O
Aniline N-Phenye acetamide
N- Phenye-N-ethanamine
Basicity III > I > II.
66.

Sec: Sr.Icon All 25


Sri Chaitanya IIT Academy 28-12-19_Sr.Icon All_GTM-5_CODE-A_Key & Sol's
Ozonolysis O CHO
+

O CHO
Glyoxal
O
Ozonolysis + 2HCHO

O
Glyoxal
O
Ozonolysis
3
O
Glyoxal
67. All are primary halides. Rate of SN 2 is proportional to stability of transition state i.e.

stability of  charge on C.
68. Substitution not possible at bridgehead carbon.
69. 1)Mannose is a monosaccharide.
HO
CH 2
H O H
H
OH OH

OH OH
H H
2)A disaccharide is the sugar formed when two monosaccharide (simple sugar)are joined
by glycosidic linkage.Like monosaccharides, disaccharides are soluble in water.Three
common examples are sucrose lactose & maltose.
70
NO 2
O2N

CH I,K CO
3 2 3 H SO ,HNO
HO 
2 Me O 2 4 3  Me
 O
SN EAS

71. Cu, Hg, Pb, Ag produce NO gas with dil. HNO3 , Fe and Zn gives N2O , Sn produce
NH4 NO3 . Au has no reaction with dil. HNO3 .
72. Given, Initial Volume, V  V1
V
Final Volume, V2 = 1
3
Initial Pressure  750 – 100  650 mm

PV =  650×V =P ×V1
1 1 P2V 2 1 2
3
Sec: Sr.Icon All 26
Sri Chaitanya IIT Academy 28-12-19_Sr.Icon All_GTM-5_CODE-A_Key & Sol's
Initial Pressure, P1  750  100  650mmHg
Final Pressure, P2  ?
 Final Pressure, = 1950
 Final P total  1950  100  2050 mm  2050 torr.
73. 3  1011  3  101 :2  108  104 :2  1010  2  10 5
 9  1010 : 2  10 4 : 2  1010  2  103
 9  106 : 2 : 40
9  106 9000000
%  100   100  100.00%
9000042 9000042
74.
i, iii, iv, v, vi.

Rate of SN 2 is proportional to stability of transition state i.e. stability of  charge on
Carbon.
75.
OD

D D

Sec: Sr.Icon All 27

You might also like