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KEY SHEET
PHYSICS
1 B 2 D 3 C 4 A 5 A,D 6 A,B,C
7 A,C 8 B,D 9 A,C 10 A,B 11 A,D 12 A,B,D
13 50 14 1 15 9 16 4 17 2.7 to 2.9 18 2
CHEMISTRY
19 A 20 D 21 B 22 D 23 B,C,D 24 A,B
25 A,B,C 26 A,B,C 27 A,C 28 A,C,D 29 B,D 30 B,D
31 1 32 2 33 8 34 7 35 5 36 2
MATHEMATICS
37 D 38 D 39 D 40 B 41 ABCD 42 B,C,D
43 A,C,D 44 A,B,C 45 A,B,D 46 A,B,C 47 A,B,C 48 A,D
49 25 50 3 51 5 52 25 53 40 54 6
Sri Chaitanya IIT Academy 09-01-2022_Sr.Super60_Jee-Adv(2019-P1)_PTA-17_Key & Sol’s
SOLUTIONS
PHYSICS
1. So velocity of block when passing from its mean position is given as
3l k k
v A As
2 m m
If mass m1 is added to it and just after if velocity of combined block becomes v1 ,
from momentum conservation we have
mv m m1 v1
m 3l k
or v1
m m1 2 m
If this is the velocity of combined block at mean position, it must be given as
k
v1 A1 Now 1
m1 m2
Where A1 and 1 are the new amplitude and angular frequency of SHM of the
block. It is given that combined block just reaches the left wall thus the new
amplitude of oscillation must be l so we have
m 3l k k
. l1
m1 m2 2 m m m1
3 m
or 1
2 m m1
or 9m 4m 4m1
5
or m1 m
4
2. In equilibrium if spring extansion is h, we use
Mg 2 mg kh _____(1)
After displacing mass m down by x its equation of motion will be
T1 mg ma _____(1)
For pulley we write
k h x / 2 T1 T2 Mg Ma / 2 ____(2)
1 a
and T1 T2 r ' Mr 2
2 2r
From equation (1)
Ma
T2 ma mg
4
From equation (2)
x Ma Ma
kh k ma mg ma mg Mg
2 4 2
2
1
mg mg 02 cos t m 02 g sin 2 t
2
cos2 t sin 2 t 12
1
Tav mg mg 02
4
4. Location of centre of mass of the cavitied sphere is given by
4 3 R3 4 R3 R
R x
3 8 3 8 2
7 R
x density
8 16
R
x
14
Moment of inertia of the cavitied sphere about an axis ( r to plane of the figure)
through point of contact (P) is calculated as follows
Let M = mass of cavitied sphere
R 4 R3 M
Mass of sphere of radius is m
2 3 8 7
8M
Mass of sphere without cavity M 0 m M
7
Required moment of inertia
I = (moment of inertia of complete sphere without cavity about an axis through P)
(moment of inertia of the cavity about the same axis)
7 8M 2 47 M 2 177
R R MR 2
5 7 20 7 140
A purely rolling sphere can be considered to be is pure rotation about the point of
contact. Consider the sphere at a slightly displaced position , as shown.
ma0
Amplitude will be given by A x ma0 kx
k
2
1 2 1 ma0
Energy of oscillation will be E kA k
2 2 k
m2 a02
2k
7. Net force on the ball will be zero at 0
or h0 0
or h0 0
0
i.e., the mean position is at a depth h0
Net force at a depth h0 x will be
F 0 Vg
or F xVg
F is proportional to x
Thus, motion of the ball is simple harmonic
2 0
hmax 2h0
8. For first harmonic oscillator,
Mass = m
Sec: Sr. Super60 Page 6
Sri Chaitanya IIT Academy 09-01-2022_Sr.Super60_Jee-Adv(2019-P1)_PTA-17_Key & Sol’s
Angular frequency 1
Amplitude a
Total energy E1
Maximum momentum,
pmax b
1
E1 m12 a 2 _____(i )
2
pmax mvmax ma1 b ma1
a 1
_____(ii)
b m1
For second harmonic oscillator,
Mass m
Angular frequency 2
Amplitude R
Maximum momentum, pmax R
Total energy E2
1
E2 m22 R 2 ____(iii )
2
pmax mvmax m2 R
R m2 R m2 1____(iv)
From eqns.(ii) and (iv).
a 2
_____(v )
b 2
From eqns. (i) and (iii),
E1 12 a 2
E2 22 R 2
Sec: Sr. Super60 Page 7
Sri Chaitanya IIT Academy 09-01-2022_Sr.Super60_Jee-Adv(2019-P1)_PTA-17_Key & Sol’s
a a
If n 2 and n then from eqn.(v)
b R
2
n2
1
And from eqn.(vi)
E1 12
2 n2 1
E2 2 2
E E
1 2
1 2
9. At t 0 when particle is at extreme position then situation is shown in figure
t
A/ 2 1
From figure cos
A 2 3
At t 0 when particle is at mean position then situation is hown in figure
t
A/ 2
From figure sin
A 6
2
1 T 12 s
6 T
l
10. T 2 , independent of mass of bob:
g
Equation of motion is: 0 sin t
Calculation of 0 is from law of conservation of energy.
2
1 v
2m 0 2mg 1 cos0
2 2
11. In equilibrium of the cone Buoyant force = weight
2
1 h 1
A h w g AH w sg
3 H 3
v x
gx
vdv g
0 0
dx
2
v g x2
gx
2 2
At maximum displacement,
2 1
x 2 4 4m
2
17. If V0 is the speed at the mean position
1
mV02 20 10 3
2
1
0.2 V02 20 10 3 V0 0.2 m / s
2
If linear amplitude is A then V0 A 0.2
Sec: Sr. Super60 Page 10
Sri Chaitanya IIT Academy 09-01-2022_Sr.Super60_Jee-Adv(2019-P1)_PTA-17_Key & Sol’s
g
L 0 0.2 A L 0 where0 angular amplitude
L
0 gL 0.2
0.2
L 2.0m
3 2
10 100 10
L 2
T 2 2 3.14 2.80 s
g 10
18. At the instant shown, both particle are at their mean and moving in opposite
direction.
Phase difference 1800
GM
As is same for both particle the phase difference will be
R3
maintained through and they will never meet.
vmax A
v R 2
1
v2 R / 2 1
CHEMISTRY
C p ,m
19. and C p ,m Cv ,m R
CV ,m
R
Cv , m
1
Cv
Cv ,m and Cv m.cv
n
R m.cv
M
1 m
R
Cv
1 M
T P
20. S nC p ,m ln 2 nR ln 1
T1 P2
7 596 1
3 R ln 3 R ln
2 298 4
1
6.3cal K
21. For combustion of 1 mole of benzene
ng 1.5
H U ng RT
Enthalpy of hydrogenation of
357
119 kJ / mol
3
23. Conceptual
24. Extensive properties : Gibb’s energy, Entropy
25. Work done by system is negative
Work done by surrounding is positive
Heat absorbed by system is positive
Heat absorbed by surrounding is negative
26. U q w 0 w w
w n Cvm dT
nR
w T T
1 2 1
T T
w nR Pext 2 1
P2 P1
27. H U ng RT
a) ng 2 U H
1
b) ng U H
2
1
c) ng U H
2
d) ng 0 U H
28. G H T S
a) H ve, S ve at low temperature G ve
Ion H NH OH
4
7 kJ
sol . H
NaCl ( s) aq Na aq Cl (aq)
790
785
Na ( g )
Cl ( g )
35.
sol H 790 785 5
3 5
n1Cv ,m1 n2Cv ,m2 2 R 2 R
36. Average Cv ,m 2 2 2R
n1 n2 22
MATHEMATICS
37. Area of quadrilateral QCRI is
1
2 r s c r s c
2
s a s b s c 15
s 15
15.3.5.7 15 7
r 7
s
Required area 7 7
38. x , 1
2x
f x sin 1 2
2 tan 1 x
1 x
2 tan 1 x 2 tan 1 x
4 tan 1 x
1/ 4
Infinite G.P. 3 1
1 1/ 4
42. 2sin 2 A sin 2 B C sin C
Sec: Sr. Super60 Page 15
Sri Chaitanya IIT Academy 09-01-2022_Sr.Super60_Jee-Adv(2019-P1)_PTA-17_Key & Sol’s
2sin 2 A sin 2 A C C sin C Given that C
3
5 3
2sin 2 A sin 2A
3 2
3
2sin 2 A sin 2 A
3 2
1 3 3
2sin 2 A sin 2 A cos 2 A
2 2 2
3 3 3
sin 2 A cos 2 A
2 2 2
Divide by 3
3 1 1
sin 2 A cos 2 A
2 2 2
1
sin 2 A
6 2
2A A
6 6 6
2
B ,a
2 3
Now, verify.
43. Conceptual
1
44. f x tan 1 x 4 x 2 2 tan 1
4
2
1 2 1
tan x tan 1 2
2
1
For f to be surjective, tan 2 1
tan1
Now, verify the options
45. Conceptual
46. D0
p 2,5
a 3; b 4; c 5
Triangle is right angled triangle. Now verify
47. S 8
8 2 2 4 8 2
r 2
S
Sec: Sr. Super60 Page 16
Sri Chaitanya IIT Academy 09-01-2022_Sr.Super60_Jee-Adv(2019-P1)_PTA-17_Key & Sol’s
abc 6.6.4 9 9 2
R
4 4.8 2 2 2 4
2
R 36 a
AI 2 16 3 2
BI 4 2 6
AI : BI : CI 3 :1:1
CI 4 2 6
48. Clearly, f x and g x are defined if 1
x 1
x
0 x 1 and x I
0 x 1
x 0
x
A C 0,1 and f x 0 and g x x 0,1
2
B and D are co-domain
Need not to be singleton sets.
f x g x x 0,1
2
No.of integral solution = 0
49. a 11, ab 38, abc 40
2
a a ab 45
2
2 2 2
cos A a b c 45 9
a 2abc 80 16
1 x2 1 2 x
50. f x cos 1 2 sin 2
1 x 1 x