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Sri Chaitanya IIT Academy., India.

AP, TELANGANA, KARNATAKA, TAMILNADU, MAHARASHTRA, DELHI, RANCHI


A right Choice for the Real Aspirant
ICON Central Office , Madhapur – Hyderabad
Sec: Sr.Super60 PTA-17 Date: 09-01-2022
Time: 09.00Am to 12.00 2019_P1 Max.Marks:180

KEY SHEET
PHYSICS
1 B 2 D 3 C 4 A 5 A,D 6 A,B,C
7 A,C 8 B,D 9 A,C 10 A,B 11 A,D 12 A,B,D
13 50 14 1 15 9 16 4 17 2.7 to 2.9 18 2

CHEMISTRY
19 A 20 D 21 B 22 D 23 B,C,D 24 A,B
25 A,B,C 26 A,B,C 27 A,C 28 A,C,D 29 B,D 30 B,D
31 1 32 2 33 8 34 7 35 5 36 2

MATHEMATICS
37 D 38 D 39 D 40 B 41 ABCD 42 B,C,D
43 A,C,D 44 A,B,C 45 A,B,D 46 A,B,C 47 A,B,C 48 A,D
49 25 50 3 51 5 52 25 53 40 54 6
Sri Chaitanya IIT Academy 09-01-2022_Sr.Super60_Jee-Adv(2019-P1)_PTA-17_Key & Sol’s
SOLUTIONS
PHYSICS
1. So velocity of block when passing from its mean position is given as
3l k  k
v  A   As   
2 m  m
If mass m1 is added to it and just after if velocity of combined block becomes v1 ,
from momentum conservation we have
mv   m  m1  v1
m  3l k 
or v1   
 m  m1   2 m
If this is the velocity of combined block at mean position, it must be given as
 k 
v1  A1  Now 1  
 m1  m2 
Where A1 and 1 are the new amplitude and angular frequency of SHM of the
block. It is given that combined block just reaches the left wall thus the new
amplitude of oscillation must be l so we have
m 3l k k
.  l1
 m1  m2  2 m m  m1
3 m
or 1
2 m  m1
or 9m  4m  4m1
5
or m1  m
4
2. In equilibrium if spring extansion is h, we use
Mg  2 mg  kh _____(1)
After displacing mass m down by x its equation of motion will be
T1  mg  ma _____(1)
For pulley we write
k  h  x / 2   T1  T2  Mg  Ma / 2 ____(2)
1  a 
and  T1  T2  r '  Mr 2  
2  2r 
From equation (1)
Ma
T2   ma  mg
4
From equation (2)
x Ma Ma
kh  k  ma  mg   ma  mg  Mg 
2 4 2

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Sri Chaitanya IIT Academy 09-01-2022_Sr.Super60_Jee-Adv(2019-P1)_PTA-17_Key & Sol’s
kx
a 2
3
2m  M
4
For restoring tandency we use
 
 k 
a   x
3 
 4m  M 
 2 
Comparing with a   2 x
k
We get  
3
4m  M
2
3. Let the pendulum be at its positive extreme at t  0
 g
  0 cos  t  Where   
 
d
Angular velocity at time ' t ' is   0 sin  t 
dt
 velocity of the bob V   0  sin t 
Tension(T) is given by
mV 2
T  mg cos  

 2 
T  mg cos   m   sin t  mg 1    m 02 2  sin 2 t
2
0
2 2

 2
1
 mg  mg 02 cos  t  m 02 g sin 2 t
2
 cos2 t   sin 2 t   12
1
 Tav  mg  mg 02
4
4. Location of centre of mass of the cavitied sphere is given by
4  3 R3  4 R3 R
 R   x   
3  8  3 8 2
7 R
 x     density 
8 16
R
x
14

Sec: Sr. Super60 Page 3


Sri Chaitanya IIT Academy 09-01-2022_Sr.Super60_Jee-Adv(2019-P1)_PTA-17_Key & Sol’s

Moment of inertia of the cavitied sphere about an axis (  r to plane of the figure)
through point of contact (P) is calculated as follows
Let M = mass of cavitied sphere
R 4 R3 M
 Mass of sphere of radius is m    
2 3 8 7
8M
Mass of sphere without cavity M 0  m  M 
7
Required moment of inertia
I = (moment of inertia of complete sphere without cavity about an axis through P)
(moment of inertia of the cavity about the same axis)
7 8M 2  47 M 2  177
 R  R  MR 2
5 7  20 7  140
A purely rolling sphere can be considered to be is pure rotation about the point of
contact. Consider the sphere at a slightly displaced position  , as shown.

Restoring torque in this position is


R
  Mgx sin   Mg
14
R
 I   Mg
14
177 R
 MR 2   Mg
140 14
140 g
   
177  14 R
10 g
 2 
177 R

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Sri Chaitanya IIT Academy 09-01-2022_Sr.Super60_Jee-Adv(2019-P1)_PTA-17_Key & Sol’s
177 R
 T  2
10 g
5. The particle collides elastically with rigid wall.
V
e   1  V  0.5u0
0.5u0
i.e., the particle rebounds with the same speed. Therefore the particle will return to
its equilibrium position with speed u0 .

The velocity of the particle becomes 0.5u0 after time t. Using,


Equation V  Vmax cos t
0.5u0  u0 cos t
 2 T
  T  t 
3 t 6
m  m
The time period T  2 t 
k 3 k
The time taken by the particle to pass through the equilibrium for the first time
2 m
 2t 
3 k
The time taken for the maximum compression
 t AB  t BA  t AC
 m  m  m m 1 1 1 
     
3 k 3 k 3 k k  3 3 2 
7 m

6 k
The time taken for particle to pass through the equilibrium position second time
 m m m2  5 m
 2      1  
3 k k k 3  3 k
6. Fee body diagram of the block from non inertial frame of reference will be as
shown
This is similar to a situation when a block is suspended from a vertical spring.

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Sri Chaitanya IIT Academy 09-01-2022_Sr.Super60_Jee-Adv(2019-P1)_PTA-17_Key & Sol’s
Therefore, the block will execute simple harmonically with time period
m
T  2
k

ma0
Amplitude will be given by A  x   ma0  kx 
k
2
1 2 1  ma0 
Energy of oscillation will be E  kA  k 
2 2  k 
m2 a02

2k
7. Net force on the ball will be zero at    0
or  h0  0

or h0  0

0
i.e., the mean position is at a depth h0 

Net force at a depth h0  x will be
F     0 Vg
or F   xVg
F is proportional to  x
Thus, motion of the ball is simple harmonic
2 0
hmax  2h0 

8. For first harmonic oscillator,
Mass = m
Sec: Sr. Super60 Page 6
Sri Chaitanya IIT Academy 09-01-2022_Sr.Super60_Jee-Adv(2019-P1)_PTA-17_Key & Sol’s
Angular frequency  1
Amplitude  a
Total energy  E1
Maximum momentum,
pmax  b

1
E1  m12 a 2 _____(i )
2
pmax  mvmax  ma1  b  ma1
a 1
 _____(ii)
b m1
For second harmonic oscillator,
Mass  m
Angular frequency  2
Amplitude  R
Maximum momentum, pmax  R
Total energy  E2

1
E2  m22 R 2 ____(iii )
2
pmax  mvmax  m2 R
R  m2 R  m2  1____(iv)
From eqns.(ii) and (iv).
a 2
 _____(v )
b 2
From eqns. (i) and (iii),
E1 12 a 2

E2 22 R 2
Sec: Sr. Super60 Page 7
Sri Chaitanya IIT Academy 09-01-2022_Sr.Super60_Jee-Adv(2019-P1)_PTA-17_Key & Sol’s
a a
If  n 2 and  n then from eqn.(v)
b R
2
 n2
1
And from eqn.(vi)
E1 12 
 2  n2  1
E2  2 2
E E
 1 2
1 2
9. At t  0 when particle is at extreme position then situation is shown in figure

  t
A/ 2 1 
From figure cos     
A 2 3
At t  0 when particle is at mean position then situation is hown in figure

  t
A/ 2 
From figure sin    
A 6
 2
   1  T  12 s
6 T
l
10. T  2 , independent of mass of bob:
g
Equation of motion is:    0 sin t
Calculation of 0 is from law of conservation of energy.
2
1 v
 2m   0   2mg 1  cos0 
2 2
11. In equilibrium of the cone Buoyant force = weight
2
1  h   1
 A    h  w g   AH   w sg
3   H   3

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Sri Chaitanya IIT Academy 09-01-2022_Sr.Super60_Jee-Adv(2019-P1)_PTA-17_Key & Sol’s
1/3
1/3  27 
or h  H  s   4   3m
 64 
When the cone is pushed slightly downwards, it performs oscillations. Consider the
situation, when the cone is displaced downwards by x then, Buoyant force-weight-
Mass  Acceleration
2
1 h x 1 1
A   h  x   w g  AH  w sg   AH  w sa
3  H  3 3
3
h  x g  Hsg   Hsa
H2
3
h3  x 
 1   g  Hsg   Hsa
H2  h
h3  3 x 
1   g  Hsg   Hsa
H2  h 
[ x  h and approximating using Binomial theorem]
33  3 x   27   27 
 1   10    4    10   4  a
42  3   64   64 
270 27
 a
16 16
 a  10 x   10
2 2
T    1.98 s
 10
12. U  ax 3  bx 4
U
F  3ax 2  4bx 3
x
3a
F  0 at x  0 and x 
4b
For small displacement restoring force is given by,
9a 2
Fres  x
4b
13. F  20  10 x  10  x  2 
Hence, force constant is k  10; m  0.1kg
k
Angular frequency,    10 rad / s
m
vmax   A  50 m / s
14. Since, the sphere is moved down through a distance x , then elongation in the
spring  x cos300
 Restoring force  kx cos 2 300  3k x / 4

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Sri Chaitanya IIT Academy 09-01-2022_Sr.Super60_Jee-Adv(2019-P1)_PTA-17_Key & Sol’s
d 2 x 3
M  kx
dt 2 4
d2x  3k 
 2   x
dt  4 M 
2
d x
But 2
  2 x
dt
3k
   1 rad / s
4M
15. x  3sin100t  4  2cos 2 50t
 3sin100t  4 1  cos100t 
 4  3sin100t  4 cos100t
 
 4  5sin 100t  
 4
Clearly A  5 , and mean position is at x  4
 maximum displacement of the particle from origin, x  4  5  9
16. Al g  Ax  g  Al a
 gx
a b


v x
 gx
 vdv   g 
0 0
 
dx
2
v  g x2
  gx 
2  2
At maximum displacement,
2  1
x  2   4  4m
 2
17. If V0 is the speed at the mean position
1
mV02  20  10 3
2
1
 0.2  V02  20  10 3  V0  0.2 m / s
2
If linear amplitude is A then V0  A  0.2
Sec: Sr. Super60 Page 10
Sri Chaitanya IIT Academy 09-01-2022_Sr.Super60_Jee-Adv(2019-P1)_PTA-17_Key & Sol’s
g
L 0  0.2  A  L 0 where0  angular amplitude 
L
 0 gL  0.2
0.2
L  2.0m
3 2
10  100 10 
L 2
T  2  2  3.14  2.80 s
g 10
18. At the instant shown, both particle are at their mean and moving in opposite
direction.
Phase difference  1800
 GM 
As  is same for both particle    the phase difference will be
 R3 
maintained through and they will never meet.
vmax  A
v R 2
 1  
v2 R / 2 1

CHEMISTRY
C p ,m
19.    and C p ,m  Cv ,m  R
CV ,m
R
 Cv , m 
 1
Cv
Cv ,m  and Cv  m.cv
n
R m.cv
  M
 1 m
R
 Cv 
  1 M
T P
20. S  nC p ,m ln 2  nR ln 1
T1 P2
7  596  1
 3  R ln    3 R ln
2  298  4
1
 6.3cal K
21. For combustion of 1 mole of benzene
ng  1.5
H  U  ng RT

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Sri Chaitanya IIT Academy 09-01-2022_Sr.Super60_Jee-Adv(2019-P1)_PTA-17_Key & Sol’s
1.5  8.314  300
 3271  U 
1000
 U  3267.25 kJ
For 1.5 mole of combustion of benzene
U  3267.25  1.5  4900.88 kJ
22. Theoretical heat of hydrogenation of benzene = (Actual heat of hydrogenation) +
(Resonance energy)

 205  152  357

Enthalpy of hydrogenation of
357
  119 kJ / mol
3
23. Conceptual
24. Extensive properties : Gibb’s energy, Entropy
25. Work done by system is negative
Work done by surrounding is positive
Heat absorbed by system is positive
Heat absorbed by surrounding is negative
26. U  q  w  0  w  w
w  n  Cvm dT
nR
w T  T 
 1 2 1
T T 
w   nR Pext  2  1 
 P2 P1 
27. H  U  ng RT
a) ng  2 U  H
1
b) ng   U  H
2
1
c) ng   U  H
2
d) ng  0 U  H
28. G  H  T S
a) H  ve, S   ve at low temperature G   ve

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Sri Chaitanya IIT Academy 09-01-2022_Sr.Super60_Jee-Adv(2019-P1)_PTA-17_Key & Sol’s
b) H   ve, S   ve, G  ve at any temperature.
c) H  ve, S  ve, G   ve at any temperature.
d) H  ve, S  ve, G   ve at high temperature.
29. For spontaneous process
Ssystem  S surrounding  0
 G 
system T , P 0
2 2
30. 2 2  PV
PV 1 1
2
P2  V1 
 
P1  V2 
T PV V 1
Now, 2  2 2  1 
T1 PV 1 1 V2 3
300
 T2   100 K
3
H  nC p ,m T
5
 2  R   200 K   1000 R
2
or H  2k .cal .k 1
31. For reversible adiabatic process
P11 .T1  P21 .T2
1 1
T1  P2  
300  1  
  ;   ;
T2  P1  75  32 
1
 1
4  5 
2 
1
 1  
4 
 32 
1
1
 1 
4 
 32 
On solving   5 / 3  1.66
atomicity = 1
Atomicity = 1
32. Conceptual
33. 5H 2 O  CuSO4  s   aq 
 CuSO4  aq   70
CuSO4  aq  
 CuSO4 .5H 2O  s   aq  10
CuSO4  s   5H 2O 
 CuSO4 .5H 2O  80

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Sri Chaitanya IIT Academy 09-01-2022_Sr.Super60_Jee-Adv(2019-P1)_PTA-17_Key & Sol’s
H  80
For 0.1 mol: 80  0.1 mol : 80  0.1  8kJ
34. 50    Ion H  NH OH  57
4

  Ion H  NH OH
4
 7 kJ
 sol . H
NaCl ( s)  aq   Na  aq   Cl  (aq)

790
785

Na  ( g )
Cl  ( g )
35.
 sol H  790  785  5
3 5
n1Cv ,m1  n2Cv ,m2 2 R  2 R
36. Average Cv ,m   2 2  2R
n1  n2 22

MATHEMATICS
37. Area of quadrilateral QCRI is

1
2 r s  c  r s  c
2
s  a  s  b  s  c  15
 s  15
  15.3.5.7  15 7

r  7
s
Required area  7 7
38. x   , 1
 2x 
f  x   sin 1  2 
 2 tan 1 x
1 x 
   2 tan 1 x  2 tan 1 x
   4 tan 1 x

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Sri Chaitanya IIT Academy 09-01-2022_Sr.Super60_Jee-Adv(2019-P1)_PTA-17_Key & Sol’s
 1  x2 
1
g  x   sin  2 
 4 tan 1 x
 1 x 
2
 1  1  x 
  cos  2 
 4 tan 1 x
2 1 x 

   2 tan 1 x   4 tan 1 x
2

  6 tan 1 x
2
3
Now, f  x   g  x    10 tan 1 x
2
   
x   , 1 , tan 1 x   ,
 2 4 
 7 
So,  f  x   g  x     , 
 2 
39. Conceptual
40.  
tan 1 tan f  5   f  20   cos 1  f  10   f 17   
 
 tan 1 tan  2  3  cos1 1  2    tan 1  tan  5      tan 1  tan 5  5  2
n
 
    k 
1 1 3
41. 3   cot 1  2  r  
n 1   k 1
 
    r 1
  
 J 
2
k
3  k  k  1 
(1) r   
r 1  2 
1
(2) cot 1 x  tan 1  
x
1  1
 1  1   
J    tan       tan 1  k  1  tan 1 k 
  k 1 
 1  k  k  1     k 1 
1    1
 
  2 4  4
 n
1
T  3  
n 1  4 

 1/ 4 
Infinite G.P.  3   1
 1  1/ 4  
42. 2sin 2 A  sin  2 B  C   sin C
Sec: Sr. Super60 Page 15
Sri Chaitanya IIT Academy 09-01-2022_Sr.Super60_Jee-Adv(2019-P1)_PTA-17_Key & Sol’s

2sin 2 A  sin  2   A  C   C   sin C Given that C 
3
 5  3
2sin 2 A  sin   2A 
 3  2
  3
2sin 2 A  sin  2 A   
 3 2
1 3 3
2sin 2 A  sin 2 A  cos 2 A 
2 2 2
3 3 3
sin 2 A  cos 2 A 
2 2 2
Divide by 3
3 1 1
sin 2 A  cos 2 A 
2 2 2
  1
sin  2 A   
 6 2
  
 2A    A 
6 6 6
 2
 B  ,a 
2 3
Now, verify.
43. Conceptual
 1 
44. f  x   tan 1  x 4  x 2   2  tan 1  
 4 
2

1  2 1 
 tan   x    tan 1   2 
 2 
 
1
For f to be surjective, tan   2  1
   tan1
Now, verify the options
45. Conceptual
46. D0
p   2,5 
 a  3; b  4; c  5
Triangle is right angled triangle. Now verify
47. S 8
  8  2  2  4   8 2

r  2
S
Sec: Sr. Super60 Page 16
Sri Chaitanya IIT Academy 09-01-2022_Sr.Super60_Jee-Adv(2019-P1)_PTA-17_Key & Sol’s

abc 6.6.4 9 9 2
R   
4 4.8 2 2 2 4
2
R  36  a
AI  2  16  3 2
BI  4  2  6
 AI : BI : CI  3 :1:1
CI  4  2  6
48. Clearly, f  x  and g  x  are defined if 1 
 x  1
 x
 0   x  1 and  x   I

0  x  1 
 x  0
 x

 A  C   0,1 and f  x   0 and g  x   x   0,1
2
B and D are co-domain
Need not to be singleton sets.

f  x   g  x   x   0,1
2
 No.of integral solution = 0
49.  a  11,  ab  38, abc  40
2
 a    a    ab  45
2

2 2 2
cos A a  b  c 45 9
 a  2abc  80  16
 1  x2  1  2 x 
50. f  x   cos 1  2   sin  2 
 1 x   1 x 

Sec: Sr. Super60 Page 17


Sri Chaitanya IIT Academy 09-01-2022_Sr.Super60_Jee-Adv(2019-P1)_PTA-17_Key & Sol’s
   4 tan 1 x , x  1

0 , 1  x  0
f  x  
 4 tan 1 x , 0  x 1

  , 1 x
f  3   f   ln 2  f 1  f  ln 3    0      3
51. Conceptual
52. Since f  x  is onto hence range of f  x  equals co-domain
 1   9 
Now range of 4 x 2  3 x in  ,0  is  ,0 
 2   16 
 9
 
Hence, range of f  x   cos 1 4 x 2  3 x is  ,   cos 1 
2 16 
1 1 1  1 
53. B  A   2cot 1  2   3cot 1  3    cot 1    cot 1   
2  2 3  3 
1 1 1 1 1
 2  cot 1 2  cot 1 3    cot 1  cot 1   cot 1 
 3 2 3 6 2
  1 
  cot 1 3    tan 1 2
2 4 6 
 1  3 
  cot 1 3    tan 1 3
4 6 4 
 1
  cot 1 3  tan 1 3
8 6
 1 
  cot 1 3    cot 1 3 
8 6 2 
  1
   cot 1 3  cot 1 3
8 12 6
5 5 1
  cot 3
24 6
Hence, a  5; b  24; c  5; d  6
a  b  c  d  40
1 1 1
54. tan 1    tan 1    tan 1  
x  y 7
1 1
x y 1
1
 tan    tan 1  
1 1  7
 
xy 

Sec: Sr. Super60 Page 18


Sri Chaitanya IIT Academy 09-01-2022_Sr.Super60_Jee-Adv(2019-P1)_PTA-17_Key & Sol’s
x y 1
 
xy  1 7
 7 x  7 y  xy  1
  7  y  x  7 y  1
7 y 1 7 y  7  7 1
x 
y7 y7
50
 x 7
y 7
Here, y  8,9,12,17,32,57 are satisfy

Sec: Sr. Super60 Page 19

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