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Solutions to JEE Main - 6 | JEE-2022

PHYSICS
SECTION-1
2
1.(B) OC  OA  r 2   3r   2r

 OA  1  r 
Direction of resultant with OC ,   tan 1    tan    30º
 x   3r 
 OA  OC lies along OB  OA  OB  OC  2r  r  3r
     40
2.(B) v BA  v B  v A  40 j  30 i ; tan  
30


v BA  50 m /s

BD AB cos  6000
Required time     120 s
vBA vBA 50
3.(B) Since, ball gains constant velocity
Therefore, net force on the ball = zero
 Weight of the ball = Buoyant force + Viscous force ( Fv )
M  d 
 Mg   d 2  g  Fv  Fv  Mg  1  2 
d1  d1 
MX  m1x1 a 2 (0)  b 2 (c)
4.(B) X cm  
M  m1 a 2  b 2
cb 2
X cm 
(a2  b2 )

5.(B)

T – mg = ma
T = M(g + a)
T '  T  mg
= M(g + a) + mg

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6.(D) In reason c to d slope dx/dt is +ve, velocity is +ve

 dx   dx 
d  d 
dt dt d 2x
But   is –ve because slope decreasing so    2 is –ve,
dt dt dt
Therefore acceleration is –ve.
m
7.(D) Let  = mass per unit area 
( R 2  r 2 )
If we fill the hole with mass densities  and , then the system can be treated as a combination of
two discs of radii r and R and densities  and 
I  I1  I 2
1 1
 m1R12  m2 R22
2 2
1 1
 ( ) r 2 ( r 2 )  ( ) R 2 ( R 2 )
2 2
 4 4
 (R  r )
2
m( R 4  r 4 ) m 2 2
  (R  r )
2( R 2  r 2 ) 2
dv dv dx
8.(A) a  2v 2   2v 2 or   2v 2
dt dx dt
dv dv
v  2v 2   2v
dx dx
v v
dv v x
  2 dx   ln v v   2 x 0

v0
v 0 0

v
ln  2 x  v  v0 e 2 x
v0
9.(B) 10 kg will be accelerated by friction
f max  N  0.5  10 10  50 N

F  50  20a ……………..(1)
f  10a ……………..(2)
50  10a
 a  5 m /s 2 (maximum acceleration for blocks to move together)
Hence F  50  20  5  150 N
 Fmax  150 N
10.(C) Identify initial and final state and identify all forces
Wg  Wair res.  K
1 2
mgh  Wair res  m gh
2
  0

mgh
 Wair res.  
2

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11.(A) The projected speed is less than escape speed Ve  2 gRe . The body will not reach infinity.
At maximum height the kinetic energy becomes zero.
Using conservation of energy,
mV 2 GM e m GM e m
 
2 Re r
mgRe GM e m GM e m
   (GM e  gRe2 )
2 Re r
mgRe gR 2 m mgRe gRe2 m
  mgRe   e  
2 r 2 r
 r  2 Re (r  Re  h )  The height attained  Re
1 
12.(C) Extension  g  g '  
 r2 
2 (3Re )2 2
 2
 x  cm
x Re 9
13.(B) Initially the acceleration of rocket is 2g upward.
After time t0 , the speed of rocket will be
v  u  at or v  2 gt0 u  0 
2 gt02  1 
The height attained in this time   using s  ut  at 2 
2  2 
After time t0 , the engine is switched off. Now it will be a case of retardation g. The initial velocity
now will be 2gt0 .

 2 gt0 2  u2 
The height at which it will stop will be  using H max  
2g  2g 
Total height attained  gt02  2 gt02  3 gt02

14.(B) Horizontal velocity at point ' O '  u cos 

Horizontal velocity at point ' P '  v sin 
In projectile motion horizontal component of velocity remains constant throughout the motion

 v sin   u cos   v  u cot 

15.(C) Tangential acceleration,
dv d
at   (4t )  4 cm s 2
dt dt
v 2 (4) 2
ac    8 cm s 2
R 2
 a  at2  (4)2  (8) 2  4 5 cm s 2

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16.(C) Let v be the linear velocity of centre of mass of C and  its angular velocity about centre of mass.
v
Then,  
2R
1 1
K.E. of spherical body, K1  mv 2  I 2
2 2
 2 
1 1 v 3
 mv 2  (2mR 2 )  2   mv 2 ………………(i)
2 2  4R  4
Speed of the block will be
 v  3
v '  ()(3 R)  3R  (3R )   v
 2R  2
2
1 1 3  9
 K. E. of block K 2  mv '2  m  v   mv 2 ………………(ii)
2 2 2  8
K 2
From equations (i) and (ii), 1 
K2 3
17.(A) The height of water in the tank becomes maximum when the volume of water flowing into the tank
per second becomes equal to the volume flowing out per second.
Volume of water flowing out per second  Av  A 2 gh ………….(i)
Volume of water flowing in per second  70 cm3 / sec ………….(ii)
From (i) and (ii), we get
4900
A 2 gh  70  1  2 gh  70  1  2  980  h  70  h  2.5 cm
1960
18.(B) For the given situation, liquid of density 2 should be behind that  from right limb:
PA  Patm  gh
l l
PB  PA  a  Patm  gh  a
2 2
l 3
PC  PB  (2) a  Patm  gh  al …(1)
2 2
But from left limb:
PC  Patm  (2) gh …(2)
From (1) and (2)
3 3a
Patm  gh  al  Patm  2gh  h l
2 2g
2T 2T 2T 2T  4  P  P0 1
19.(B) PB  P0  , PA  PB  , PA  P0    2T   , B 
3R R 3R R  3R  PA  P0 4
20.(B) FBD of C kx1 = mg
FBD of B, T = 2 mg
FBD of A kx2 = mg + T
kx2  mg
When string is cut out T = 0
kx2  mg  ma A
3mg  mg  ma A  a A  2 g
For B
T  mg  kx1  maB
0  2mg  maB ; a B  2 g

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SECTION-2
21.(2) Resultant momentum  (2) 2  (2) 2  2 2
Momentum 2 2
Mass    2 kg
Velocity 2
22.(8) Angular momentum of particle moving in line AB is L = mvR
10  2 4
tan   
3 5 3
  53
R
In OAC , sin 53 
5/2
5 4
 R  2  L  1  4  2  8 Kg m 2 /s
2 5
v0
23.(5) Velocity of the centre  v0 and the angular velocity about the centre  . Thus v0  0 R . The
2R
sphere slips forward and thus the friction by the plane on the sphere will act backward. As the friction
is kinetic, its value is N  Mg and the sphere will be decelerated by acm  f /M .
f
Hence, v(t )  v0  t ………..(i)
M
This friction will also have a torque   fr about the centre. This torque is clockwise and in the
direction of 0 . Hence the angular acceleration about the centre will be
R 3f
 f 2

(2 / 3) MR 2 MR
3f v 3f
And the clockwise angular velocity at time t will be (t )  0  t 0  t
2 MR 2 R 2 MR
v 3f
Pure rolling starts when v(t )  R(t ) i.e., v(t )  0  t ………………….(ii)
2 2M
3 3 v 2 4
Eliminating t from (i) and (ii), v(t )  v(t )  v0  0 or v(t )   2v0  v0
2 2 2 5 5
Thus, the sphere rolls with linear velocity 4v0 / 5 in the forward direction.
24.(9.60) Here, velocity at the top most point is zero.
From energy conservation
v v
Let vB  v;   ; v A  l 
2l 2
1 2 1 v2 48 gl
mv  m  mg (2l )  mg (4l )  0  v  x  9.6
2 2 4 5
25.(60) Let the speed of the bullet be v. Let the common velocity of the bullet and the bob, after the bullet is
embedded into the bob, be V. By the principle of conservation of linear momentum,
(0.05 kg )v v
V 
0.45 kg  0.05 kg 10
The string becomes loose and the bob will go up with a deceleration of g  10 m /s 2 . As it comes to
rest at a height of 1.8 m, using the equation v 2  u 2  2ax , we get
2
 v 
 
10
1.8 m    2 or v  60 m /s
2  10 m /s

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Chemistry

SECTION-1
10.1
1.(C) Moles of KNO3  moles of NO3   0.1
101
 Density of H 2 O  1 g mL1
Weight of H 2 O  500 mL  1  500 g  0.5 kg

Moles of NO3 n NO

3
m  
NO3 Weight of solvent (H 2 O) in kg 0.5 kg
n NO
3
 0.3   n  0.3  0.5  0.15
0.5kg NO3
(required)

Moles of NO3 obtained from KNO3  0.1

Moles of NO3 required from Ba(NO3 ) 2  0.15  0.1  0.05
[2 mol of NO3 is obtained from 1 mol of Ba(NO3 ) 2 ]
0.05
 Moles of Ba(NO3 )2 
2
0.05
Weight of Ba(NO3 ) 2   261  6.5g
2
32 14
2.(C) (i) 1 molecule of O2  (ii) 1 atom of N 
6  1023 6  10 23
(iii) 1 mol of H 2 O  18g (iv) Weight of Fe  1010 g
So, the order is (C).

1 KE 2  1
3.(B)    1 or
KE KE1 2 0.99 1
KE1
 KE 2   1.02 KE1
(0.99)2
KE 2  KE1
% change in KE   100  2%
KE1
V Z n2
4.(A) Frequency   ; V  and r 
2 r n Z
Z Z Z2
  
n  n2 n3
  22 / 33 8  4 32
So He  2 3  
H 1 /2 27 27
Second excited state  n3

5.(D) The velocity of X-rays is same as that of microwaves.

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1/ 2
 3RT 
6.(D) CO gas, because root mean square velocity   
 M 
1/ 2
 1 
i.e., RMS   
M
CO has the lowest molecular mass; hence, it has the highest RMS velocity.
PM
7.(D) (A) Density of gas () 
RT
M M
Since B  A ,
TB TA
Therefore, at the same pressure A  B . But if pressure is different, then A  B .
(B) The pressure of the gases will be equal if their densities are equals, otherwise not
[as in case (A)]
3
(C) KE per mole  RT
2
Hence, it will be different for given gases.
3RT
(D) u rms 
MW
TA T
Since  B , u rms of A  u rms of B
MA MB
8.(D) Ideal gas cannot be liquefied at any value of P and T.
9.(D) b  4  volume occupied by the molecules in 1 mol of gas
4 4
 4    r 3  N A  4   3.14  (1  108 )3  6  1023  100.4  10 1  10 mL mol1
3 3
10.(C) VT 3  constant
Also V 1 T  constant for adiabatic expansion
1
1
V  T  1  constant or 3
 1
4
 , i.e., polyatomic gas
3
11.(B) In the process of formation, the compound must be formed from constituent elements in their standard
state.
12.(A) Stotal  Ssys  Ssurr  0

13.(C) H Θ  U Θ  n g RT
15
C6 H5COOH (s)  O 2  7CO 2 (g)  3H 2O()
2
15 1
n g  n P  n R  7  
2 2
 1 
 H Θ   321.30    300 K  R    321.30  150 R
 2 

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 CaO(s)  CO 2 (g)

14.(A) CaCO3 (s) 
K p  PCO2
Gº  2.303 RT log K p
Hº TSº  2.303 RT log K p
Hº S
log K P   
2.303RT 2.303R
Hº Sº
log PCO2    ………(i)
2.303RT 2.303R
y  mx  c
Graph (A) represents (i) and its slope will be used to determine the heat of the reaction.

15.(D)  H 2 (g)  I 2 (g)

2HI (g) 
 
At eq. 1  
2 2
2
 
 PT   PI  PH 2 
2 
Kp    K p  2 
(1   )2 PT2  (PHI ) 2 
 2 Kp
 2 Kp  
1  1 2 Kp

 Au ( )
16.(C) Au (s)  heat 
There is an increase in volume in the forward direction, hence the melting is favoured at low pressure.

17.(B) BF3  sp 2 hybridised

NF3  sp3 hybridized
% s character is more in hybrid orbital of BF3 than NH 3

18.(A) All given species have 14 electrons.

19.(B) Structure 

20.(C) Relation between H (enthalpy change) and E (internal energy change) is

H  E  n g RT
Where, n g  (moles of gaseous products)  (moles of gaseous reactants)
For the given reaction, n g  2  3   1

 1366.5  E  1  8.314  10 3  300

 E   1364.0 kJ mol1

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SECTION-2
21.(7.20) 1 mole of Na 3 [Fe(CN)6 ] contains  6 mol of C
0.1 mole of Na 3 [Fe(CN)6 ] contains  0.6 mol of C
 0.6  12  7.2g
22.(12) If each orbital can accommodate 3 electron, then atomic number of Ne will be 19
Its electronic configuration will be 1s 3 2s 3 2p 9
 Number of electrons having n  2 are 12
23.(0.34) Let the molecular mass of the mixture at equilibrium be M mix .
Applying the relation :
dRT 0.925  0.0821  900
M mix    68.348
P 1
Molecular mass of SO3  80
80
Vapour density of SO3 , D   40
2
68.348
Vapour density of mixture, d   34.174
2
Let the degree of dissociation be x.
Dd 40  34.174 5.826  2
x    0.34
(n  1) d  3  34.174
  1   34.174
2 
24.(0) From MO diagram.
25.(5) Except ClF3 , all are linear non-polar molecules.

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Mathematics

SECTION-1
1.(C) Let the mid-point of chords of circle be P(h, k).
Equation of this chord is T = S1
i.e., xh  yk  g  x  h   f  y  k   c  h 2  k 2  2 gh  2 fk  c

It passes through (0, 0) thus h 2  k 2  gh  fk  0

i.e., required locus is x 2  y 2  gx  fy  0

2.(A) Let P   a, 25  a  . Equation of chord AB is T = 0 i.e., xa  y  25  a   9 . If mid-point of chord AB

is C (h, k), then equation of chord AB is T = S1 i.e., xh  yk  h 2  k 2 . Comparing the coefficient of

like powers, we get
a 25  a 9 a  25  a 25
h

k
 2
h  k2

hk

hk
  
 9  h  k   25 h 2  k 2  25 x 2  y 2  9  x  y  
6
 2k  2k  
3.(D) S  i   cos  i sin 
k 1  7 7 
6
 2k  2k  
S  i   cos  i sin i
k 0  7 7 
0i i
4.(A) As 1, z  1,z  cos   i sin ,        0 , now


1

1

1  cos    i sin   1  cos    i sin 
1  z 1  cos   i sin  1  cos  2  sin 2  2 1  cos  
1 i   1 i   
  cot     tan   
2 2 2
  2 2 2 2
 
This shows that  lies on the line x = 1/2 and   arg    , Arg    0 , the maximum value of
2 2
Arg   is never attained.
5.(D) We have      p,   q

  
Now,    2   2     3 2   4   2   3  2
2
2  2          
2 2 2
        3  p 2  3q

6.(A) z1  z2  z3  1
z1z1  z2 z2  z3 z3  1
1 1 1 1 1 1
 z1  z2  z3       1
z1 z2 z3 z1 z2 z3
7.(C) Let P   a , 4  2a  . Equation of chord of contact is
x.a  y.  4  2a   1
 4 y  1  a  x  2 y   0
1 1
It will always pass through a fixed point whose coordinates are y  and x  2 y  .
4 2

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7 5

8.(D) The given expression is

 e   e   i 2 i3

ei 14 . ei 15

ei 29
 e i 47  cos 47  i sin 47
12 6 i 48 i 30 i 18
e   e   i4 i5 e e e

2 1
9.(C) zz  z  If z is of unit modulus, then zz  1 or z 
z
 1 z   1 z 
So, arg   becomes arg  1  1 z   arg  z   
 1 z   
10.(A) The equation of normal to the parabola y 2  12 x with slope 1 is
3
y   x  2  3 1  3  1  y  x  9  x  y  9
 k 9
Since, the focus of the parabola is (3, 0)
39 3
 p  2 p 2  36  3k 3  2 p 2  3  9   36  2223
2

11.(A) Centre of (, 2) and radius = 2


2
2  
 2    2  5
5 2 
2

2 5    42 5
2

12.(D) Vertex = (1, 1), Focus = (2, 2). So, the directrix is x  y  0 .
x y
Then, equation is   x  2 2   y  2 2   x  y 2  8  x  y  2 
2
 3
13.(A) Since, end of latus rectum is  2e, 
2  
 3
 y 
 3 x  2e  2
Normal at  2e,  is 
 2 2e 4 3
23
2  x  2e 

e

 2  y   4 1  e2   
 b2  a 2 1  e2  3  4 1  e2 
   
 2 x  4e  2ey  4e3  4e  2 x  2ey  4e3

  x  ey   2e3  x  ey  2e3  0
14.(C) Tangents at t and t meet on the point (x, y) given by
2 2
x  att   ak t . . . .(i)
and 
y  a  t  t   a k 2t   t  

 at  k 2  1  . . . .(ii)
From equations (i) and (ii),

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x
ak 2 . y 2

k 2 y2
 2
y 

ax k 2  1   1
 ax  k  
2

2 2
k2  k

a2 k 2  1  
a k 2 1 
x2 y2
15.(C) Given equation is 
2
1
16
16 11 
 16 
Thus, the parametric coordinates are  4 cos  , sin  
 11 
x cos  11 y sin 
The equation of tangent at this point is  1
4 16
This touches the circle x 2  y 2  2 x  15  0
cos 
1
4
 4
cos 2  11 sin2 

16 256
 cos 2  11 sin 2  
 cos 2   16  8 cos   256    
 16 256 


 
15 cos 2   11 1  cos 2   8 cos   16  0

 4 cos 2   8 cos   5  0
1  5   
 cos  
2  cos   2   
3
or 
3
 
16.(A) Parabola intersect y-axis at (0, 2), (0, 3)

17.(A) Equation of chord of contact ' AB '  hx  ky  1

AB is common chord also
 (  6) x  (8  21) y  2  0
  6 2  8 2 (2  12)  (2  8)
  
h k 1 2h  k
2 h  k  10
2 x  y  10  0

1
18.(D) Let the equations of circle be S1  x 2  y 2  4 x  4 y  4  0 and S2  x 2  y 2  x  y  0
4
Equation of common chord AB is S1  S2  0
 4x  4 y  5 . . . .(i)
4  2  4  2  5 11
Now, C1M   and r1  4  4  4  2
2 2 4 2
4 4
Also equation of line C1C2 is y = x . . . .(ii)
5 5
On solving equation (i) and (ii), we get : x  , y 
8 8
121 7
Radius of required circle, AM  AC12  C1m 2  4  
32 4 2

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19.(A) z   2  2 3 i  4
z 2 n  22 n  z n  2 4n  42 n   2 n  22 n  4 n   n  2 4 n

 4 2 n  2 n   n  1
 
0 , if n is not multiple of 3
 2n
3  4 , if n is multiple of 3
r r
20.(C) Given that, zr  cos
2
 i sin [where, r  1, 2 , 3,......, n ]
n n2
 
z1  cos  i sin
2
n n2
2 2
z2  cos  i sin
2
n n2
        
        
        
n 2
zn  cos  i sin
n2 n2
     2 2   n n 
 lim  z1 z2 .... zn   lim  cos
2
 i sin
2    cos 2  i sin 2  ....  cos 2  i sin 2 
n n   n n   n n   n n 
    
 lim cos  1  2  3  ......  n   i sin  1  2  3  ......  n  
n   2 2
n  n 
i
  n  n  1  n  n  1    2
 lim cos  i sin   cos  i sin  e
n   2 2 2 2
 2n 2n 
SECTION-2
2 2 2 2
21.(3) We have x  xx   a  b  c   a  b  c   a  b  c  a  b  c   b  c  a   c  a  b  ……(i)
2 2 2

Similarly y  a  b  a bw  cw2  b  cw2  a  c   a  b  ……….(ii)   
2 2 2

 a  b  c  a b  c 2  b c  a 2  c a  b 2     
 a  b  c   b  a  c   c  a  b  ……(iii)
2 2 2 2 2 2 2
And z  a  b  c
Adding (i) , (ii) and (iii), we obtain
2
x  y
2 2
z 3 a  b  c  2 2 2

2 2 2
x  y  z
 2 2 2
3
a b c

22.(12) z 2  z  1  0  z   , 2 .
Let z =  then
2 2 2 2 2 2 2
       2
 4    4
 8    5
 10  
 1 and  3   6    6
 12  4

Thus, S = 12.

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1 cos   2 sin 
23.(3)  i
x  iy 3 3
x  iy cos   2 sin 
 2 2
 i
x y 3 3
2 2
 x 2   y  cos 2   sin 2 
  2      
x y
2 3   x 2  y 2  9

x2  y2 4x 4 1
   
x 2
y 2 2
 
3 x y 2 2
 9 9

 3  4x  x2  y 2  0
24.(1) C1C2  r2  r1
 Circles touch internally
Hence, the number of common tangents is one.
x2 y2 x y
25.(8.08) Tangent to   1 is cos   sin   1 . If it is also tangent to the circle, then
25 4 5 2
1 100 3 25
16 
2 2

2
 sin 2   , cos 2  
cos  sin  4  21 sin  28 28

25 4
 5   2 
If the tangents meets the axes at A and B, then A   , 0  and B   0 , 
 cos    sin  
25 4 4 196 14
 AB 2    28  . 28   AB 
2 2 3 3 3
cos  sin 

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