Sec : XI_IIT_IC&IR Date : 20–11–2023

Time : 3 Hours CTA-3 Max. Marks : 198

JEE-ADVANCED
2020-P1-Model
KEY SHEET

PHYSICS
1 A 2 C 3 B 4 A 5 D 6 B

7 AD 8 ACD 9 AD 10 AD 11 AC 12 AC

13 3 14 2 15 2 16 5 17 2 18 8

CHEMISTRY
19 D 20 B 21 B 22 C 23 C

24 A 25 AB 26 ABC 27 D 28 BC

29 ABCD 30 ABD 31 20 32 -16.11 33 9

34 4 35 9 36 2.01

MATHEMATICS
37 B 38 B 39 C 40 A 41 C 42 B

43 ACD 44 BC 45 AC 46 ABC 47 AB 48 ACD

49 2 50 5 51 4 52 1 53 4 54 2
 SOLUTIONS
1. (A)
From l  m1r12  m2 r22 and m1r12  m2 r22 , we N 2  W  10 kg  10 m/s 2   100 N
get 200
The frictional force is, f  N1  N.
 mm  3
l   1 2  r 2.
 m1  m2  4. (A)
2. (C) Use linear momentum conservation.
 10 
    rad/s2 = 5 rad/s2 5. (D)
 2
Mass of the loop = M = L
1 2
I  MR 2   0.2   0.02 kg m2 Further, if r is the radius of the loop, then
2
L
  I   5  0.02  0.10 N m. 2r  L  r 
2
3. (B)
Moment of inertia about XX ’ is
The force acting on the ladder are as
3
shown in the following figure. The forces l  Mr 3
2
are its weight W, normal force N1 exerted
3 L2 3L3
by the vertical wall, normal force N2 l   L  2
 .
exerted by the floor and frictional force f 2  2  82
exerted by the floor. 6. (B)
Let h = height of ceiling from where ball was
drop
Speed by which ball hit the floor first time =
2 gh .
Speed after the first hit = e 2 gh .
Then, speed of the ball by which it hits the
Taking horizontal and vertical
floor for the second time = e 2 gh .
components, we get
N1 = f Speed after the second hit = e 2 2 gh .
(1) This speed is the initial speed u for upward
and N2 = W motion after second impact.
u2
(2) Now, the height attained = .
2g
Taking torque about B, we get 2
2
N1(AO) = W(CB) h  e 2 gh  e 4  2 gh 
  
CB 2 2g 2g
or N1  W
AO 1
e .
or 4
2

BO W 4 W  BO 4 7. (A, D)
  As  tan 53o  
AO 2 3 2  AO 3 Linear momentum is not conserved due to
(3) the force exerted by hinge.
The normal force by the floor is
8. (A, C, D)
Net external force on the system is zero. 11. (A, C)
Therefore, linear momentum will remain The following figure depicts the situation.
conserved. Initially both the particle have
equal momentum iun opposite directions.
Hence, the initial momentum is zero, that
is, final linear momentum is also zero or
velocity of centre of mass vc = 0. The momentum of the system is 1  3  3
Let  be the angular velocity about centre kg m/s; momentum of 3 kg after collision is
of mass. The net external torque on system 5  1  5 kg m/s. Thus, the kinetic energy
u is also zero. Hence, the angular of the centre of mass is
momentum about centre of mass will also 2
1  mu 
be conserved, that is,  m1  m2   1 
2  m1  m2 
Li  L f  2mva  4mva   l  2
1  1 3 
 1  5     0.75 J
2  6 
  6a 2 2

2
 8m   2m  a   m  2a    The total kinetic energy of the system is
 12  calculated as
1
 1 32  4.5 J.
6mva  24ma 2  2ma 2  4ma 2   2
12. (A, C)
  30ma  
2

v 13. (3)

5a l ml 2
mg  .
Finally, 2 3
1 1  v  3
2 14. (2)
E  l 2   30ma 2     mv 2 .
2 2  5a  5
9. (A, D)
L  mv0 r sin 

mg  T  ma (1)
T  R  l (2)
a
T R l
R
L  mv0b  constant
  mR 2 a Ma
r1  r 2  r T R   T  (3)
2 R 2
1 From Eq. (1), we get
Now, dA   v0 dt  r sin 
2  1
mg  ma 1  
dA mv0 r sin  L  2
   .
dt 2m 2m 3 2a
 mg  ma   a 
10. (A, D) 2 3
Kinetic energy changes during the
collision.
 M 2 g mg 18. (8)
Now, from the equation, T    ,
2 3 3
we get 19. (d)
0.6  10
T  2 N.  a 
3  p  2   V  b   RT
 V 
15. (2)
(a) If a = 0, for gas A
p  V  b   RT

(b)If b = 0, for gas B

a
pV   RT
V
Conservation of angular momentum about
pV a
O is  Z  1
RT RTV
 l1  l2     l1'  l2   '
ap  1 
2 2
1   p
 L L  RT  V 
  m    m   
  2   2   Thus, Z is dependent on p and is linear as
  L 2 L 
2
shown in B
  2m    m    
  2   2   (c) At low p, V is high, (V – b)  V
 3 2 a
 2   2 rad/s. And at high p,  p  2   p
3 3 V 
16. (5) pV pb
5  Z 1
I  MR 2 . RT RT
4
Thus, Z first decreases in low p range and

17. (2) then increases as p increases. At high p,

slope changes negative to positive. Thus,
incorrect.

For vertical forces : 20. (B)

Mg  T  Ma (1)
20 3 1 1 3 1
 rSO2  dm s  dm s
a (2) 60 3
2
V
Torque about A rO2  dm3s 1
30

Mg    l  rSO2 32 1 / 3 10
2    
rO2 64 V / 30 V
3g
 (3)
2 V  10 2  10  1.41  14.1 dm 3
From Eqs. (1), (2) and (3), we get
21. (B)
   3g
Mg  T  M   544
 2  2 From I G  SO 2    kJ mol1
2
Mg
T  2 N.
4
 293 Initial 1 0 0 0
From II G  ZnS    kJ mol1
2 x
At equil. 1  x  x x
480 2
From III G  ZnO    kJ mol1 2 1
2 Mole fractoin
3 3
G (elements) = 0 2p p
Partial pressure
 G  2G  ZnO   2G  SO2   2G  ZnS 3 3
1/ 2
 480  544   293  731kJ 1/ 2  2p  p 
  
K p  pCO2 . pO2    
 3  3 
22. (C)
1/2 3/2
nRT 0.5  0.0821 300  p  p  p
pH 2    2     2 
V 3.0  3  3   3

= 4.1 atm 25. (A, B)

2  0.0821  300 CO 2 , HgCl2 ,C2 H 2 are all linear.
PCO2   16.42 atm
3.0
26. (A) Cr   Ar   3d 5 4s1 , an exception to
Total = 4.10  16.42  20.52atm
aufbau principle.
Total volume = 3L as two vessels are
(B) For a given value of l, m can have any
connected.
value from  to  , so can have negative
H 2 and CO 2 are non-interacting gases.
value.
23. (C)
(C) Ag is incopper group with d10s1
By first law, E  q  W
configuration, ie, 46 electrons are spin
For isothermal expansion, E  0 paired.
 q  W
27. (A) Ti4   Mn 7  is the correct order of size
qirrev  W  pV
due lower positive charge on Ti4  .
 3  2  1  3Latm (B) 37
Cl  37 Cl : Isotopes with same
qirrev charge have same size because isotopes
Also, Ssurr 
T
differ in compositions of nuclei which do
 3  101.3 J 303.9
not affect the atomic/ionic radius.
 
300K 300
1
(C) K   Cl is the correct order. Among
 1.013JK
isoelectronic species, anion has greater size
24. (A)
than cation.
Ag 2 CO3  s   2Ag  s 
(D) P 3  P 5 is the correct order. For the
1
CO 2  g   O 2  g  same element lower the positive charge,
2
larger the ions.
28. (B, C)
pH of 108 M solution will be between 6
and 7 but never 8. The conjugate base of an
acid is formed by removing a proton  H  
 from acid. Therefore, HPO24  is a conjugate 32. (-16.11)

base of H 2 PO 4 . We make use of concept that heat of

formation is the enthalpy of any species
H 2 O  H   OH  H  0
 f H  x   H 0x
Increase temperature will increase
equilibrium constant of the above  6CO 2  g   6H 2 O   
C6 H12 O6  s   6O 2  g  

endothermic reaction.  C H  C6 H12 O 6   6 f H  H 2 O   +

At the mid-point of reaction. 6 f H  H 2 O 
29. (A,B,C,D)
 6  400  6  300   1300  0 
C2 H 4  H 2  C2 H 6 H  32.7 kcal
 2900 kJ mol 1
The above reaction is exothermic,
2900
increasing temperature will favour Thus,  C H   kJ g 1 = -16.11 kJ g 1
180
backward reaction, will increase the
Molar mass of glucose  C6 H12 O 6  =
amount of C2 H 4 . Decreasing pressure will
180 g mol1
favour reaction in direction containing
33. (9)
more molecules (reactant side in the
K SP of MOH = 1 1010 M 2 PH  ?
present case). Therefore, decreasing
pressure will increase amount of C2 H 4 . MOH is AB type of salt
 K SP  S2 , OH    S
Removing H 2 , which is a reactant, will
favour reaction in backward direction, S  K SP  1 1010 S  105 ,  OH    105

more C2 H 4 will be formed. pOH   log10  OH     log10 105  5

Adding C2 H 6 will favour backward
pH  pOH  14   14  5  9
reaction and some of the C2 H 6 will be
34. (4)
dehydrogenated to C2 H 4 . 2HI  g   H 2  g   I 2  g 
30. (A, B, D)
at t  0 0.2atm 0 0
31. (20)
Change  2x x x
Average atomic weight t  t eq  0.2  2x  x x


 Percentage of an isotope  atomic weight From question, 0.2  2x  0.04
100
2x  0.2  0.04  0.16; x  0.08
10.01x  11.01100  x 
 10.81  0.08  0.08
100 Kp  2
 0.04 
 x  20%
Therefore, natural boron contain 20% 35. (9)

(10.01) isotope and 80% other isotope. nRT an 2

P  2  10  1  9
V  nb v
36. (2.01)
Reversible work is maximum work.
V 
 w  2.303nRT log  2 
 V1 
16 25
 2.303   8.314  300 log 39. (C)
32 5
3 Chord with midpoint (h, k) is
 2.01  10 joule  2.01kJ
hk  ky  h 2  k 2 ….(i)
37. (B) Chord of contact of  x1 , y1  is
Let the orthocenter be H(5, 8).
xx1  yy1  2 ….(ii)
Comparing (i) and (ii), we get
2h 2k
x1  2 2
and y1  2
h k h  k2
Hence, CMH and BMD congruent.
Therefore, HM = MD  x1 , y1  lies on 3x  4y  10
D is the image of H in the line x – y = 0, or 6h  8k  10  h 2  k 2  .
which is D (8, 5). Therefore, the locus of (h, k) is
Thus, the equation of the circumcrircle is 3 4
2 2 2 2 x 2  y2  x  y  0
 x  2    y  3   8  2    5  3 5 5
i.e., x 2  y 2  4x  6y  27  0 Which is a circle with center P  3 /10, 4 /10  .
therefore OP = 1/2.
40. (A)

38. (B)
Let centre of the circles be C1 and C2
Clearly, OPCQ is cyclic quadrilateral, then
circumcircle of ΔOPQ passes through the
point C.
Since OP and OQ are tangents to the circle
they make perpendicular with CP and CQ
respectively. Also a circle inscribes two right
angled triangles which are COP and COQ in
this case. Thus for this circle, OC is a
diameter, then centre is midpoint of OC
41. (C)
which is (3/2, -1). 100
100   

z  1 i 3  100
2  cos  i sin 
 3 3
 44. (B, C)
The given circles
are x 2  y 2  2x  0, x  0 and
x 2  y 2  2x  0, x  0
From the above figure, the centres of the

required circles will be 0, 3 and 0,  3  
 The equations of the circles are
2
 x  0
2

 y 3   12

42. (B)
x, y and z are in G.P. hence,
y  xr, z  xr 2
Also, x, 2y, and 3z are in A.P. hence,
4y  x  3z 45. (A, C)
The point from which the tangents drawn are
 4xr  x  3xr2
at right angle lie on the director circle.
 3r2  4r 1  0
Equation of director circle is
  3r 1 r  1  0 x 2  y2  2 16  32
 r  1/ 3 Putting x  2, we get
(r  1 is not possible as x, y, z are distinct) y 2  28
 y  2 7
43. (A,C,D)
 The points can be
x 2  y 2  8x  10y  40  0
Centre of the circle is (-4, 5)  2, 2 7  or  2, 2 7  .
Its radius = 9 46. (A,B,C)
Distance of the centre (-4, 5) from the point From figure,
(-2, 3) is 4 4  2 2

a 0
b b
  4or  0
2a 2a
 b0
f 0  c  0
b
Also,   4 or 8a  b  0
2a
47. (A, B) 49. (2)
 sin x 
4
 cos x 
4
1 ab bc
  Given, b2  ac and x  ,y  .
2 3 5 2 2
Therefore,
4 6
3  6 cos x  5  cos x 
2
 . Let cos x = t a c 2a 2c
5   
x y ab bc
 25t 4  30t 2  9  0
2a  b  c   2c  a  b 

 a  b  b  c 
2ac  ab  bc
2
ab  ac  b 2  bc
2ac  ab  bc
2
2ac  ab  bc
 b2  ac 

3 2 2
 t2   tan 2 x 
5 3 50. (5)
4 | z  3  2i | 2
8 2 16
  sin x       z lies on or inside the circle radius 2 and
 5  625
4 center (3, 2)
8 3 81
  cos x    
 5  625
8 8


 sin  
 cos x  
1
8 27 125
48. (A, C, D)
n
C1  n 1C2  n  2 C3  ...  n  m 1C m
 n C n 1  n 1C n 1  n2
C n 1  ...  n  m 1C n 1
= Coefficient of
n n 1 n2
x n 1 in 1  x   1  x   1  x 
n  m 1
 ...  1  x  | 2z  6  5i |min.

 1  x  m  1   2 | z  3   5 / 2  i |min.
n 1 n
= Coefficient of x in 1  x    = 2 (minimum distance of any point on the
 1  x   1 
circle to the point (3, -5/2))
m n n
n 1 1  x   1  x  = 2(5/2) = 5
= Coefficient of x in
x 51. (4)
m n n k
= Coefficient of x n in 1  x   1  x   k k i
   k  cos  i sin e7
7 7
m n
 Cn  1 12  k 1  i k
12 i
Similarly, we can prove  |  k 1   k | e
k 1
7
e 7
k 1
 3
  4k 1  i  4k  2  i
3
m
C1  m 1C2  m  2 C3  ...  m  n 1C n  m n
Cm  1  |  4k 1   4k 2 |
k 1
e 7
e 7

k 1

12 k i
i 12
 e 7 e 7 1
k 1
1
k 1
  4k 2   i
 3
3 i
e 7
e 1 7 1
k 1
k 1
  k
i
 4k 2  
i  12 Now, the distance of this point from the line
 e 7
 e 7
 1  4 4x  3y  10  0 is 1. Therefore,
  3
 
| 4t  3  4  t   10 |
52. (1) 1
5
or |t + 2| = 5
i.e., t = 3 or t = 7
Therefore, the sum of values is 4
54. (2)
The point B is (2, 1). The image of A (1, 2)
on the line x – 2y + 1 = 0 is given by
x 1 y  2 4
 
1 2 5
Hence, the coordinates of the points are (9/5,
2/5).
Since this point lies on BC, the equation of
BC is 3x – y – 5 = 0. Hence, a + b = 2.

53. (4)
Any point on the line x + y = 4 is (t, 4 – t),
where t  R.