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Solutions to Mock JEE MAIN – 21 | JEE 2022

PHYSICS

1.(B) Y  A 1  cos  2kx  2t    2cos 2   1  cos 2 

 
Y  A  A cos  2kx  2t 
y  A cos  2kx  2t  [Put, Y-A = y]
 A  A
2 
f  
2 
2.(A) Having equal and opposite momenta, the two pieces of ice comes into rest and the loss of their
kinetic energies gets converted into heat to melt it into water.
i.e., Loss in K.E. = Latent heat + specific heat
1
 2  mV2  2mL  2m Sice   V  2  L  Sice  
2
 V  2  80  1000  0.5  1000  12  4.2m / s  850m / s

3.(B) For isobaric process : W  PV  nRT

5
For adiabotic process : W  U  nCV T   nRT
2
For a polytropic process PV x  constant
R
C  CV 
x 1
Multiplying by nT
nRT
nC T  nCV T 
x 1
As nC T  Q and nCV T  U

nRT
 W (As Q  DU  W )
x 1
For PV 2  constant, x  2
nRT
 W  nRT
2 1
P
For  constant, x  1
V
nRT nRT
 W 
1  1 2

4.(B) W  qE.S  qEi. PS

  
 qEi . ai  b j  qEa

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1
5.(C) I E (intensity due to electric field) = c0 E 2 ,
2
cB 2
I B (intensity due to magnetic field) =
2 0
1
c0 E 2
IE
 2
2
I B cB / 20
2  1 
 c2 
 
  00  E / B     c 2  1

 1 
 as c  and E / B  c 
  0 0 
 
6.(D) E ph  Ee

hc  h /  e 
2
h
  , momentum of electron 
 ph 2me e
c h
 
 ph 2e2 me
 ph 2ce me
 
e h
h
e 
2me Ee

 ph 2me 2  9.1 1031

 c c
e Ee 1020
 1.35  105  3  108  4  103
 ph   e
1 2
7.(D) AB  gt  5  60  60m  18km
2

(600)(600)
BC   18km, AC  36km
20

 0.02h; 0  h  18km

v 2   0.02(h  36);18km  h  36km
 0.02 (36  h); 36km  h  0km


8.(B) When the magnet approaches the coil, an induced current is set up in the coil. According to Lenz’s
law, a south pole is developed at the right end, so as to oppose the motion of the magnet towards
the coil. The direction of the induced current as seen from magnet side of the coil is clockwise.

9.(C) y-coordinate is maximum

When v y  0
v y  u y  a y t  0  5  5t  t  1

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1 1
x  uxt  axt 2  0  (10)(1)  5
2 2
1 1
y  u y t  a y t 2  5(1)  (5)(1)  2.5
2 2
10.(A) Wext  U  K
Wext  U [ K  0]
 U 2  U1
  MB cos 2  MB cos 1  MB  cos 1  cos 2   MB  cos 0  cos30 
 3
Wext  MB 1  
 2 
1
11.(D) K i  mu 2
2
By conservation of momentum mu = mv1 + nm v2
u = v1 + nv2 … (i)
v2 – v1 = u1 – u2
 v2 – v1 = u … (ii)
(i) + (ii)  2u = (n + 1) v2
2u
v2 
n 1
1 2n m u 2 Kt 4n
Kinetic energy transferred
2
K t  (nm)v2 , Kt  , 
2 (n  1) 2 K i (n  1) 2
12.(D) V  ir V  E  iR
E
i , R  internal resistance
rR
Er E E  E V
 V  rR r  R    1 r  R r
rR V V  V
hc 1240eV .nm
13.(C) max    121.57nm
10.2eV 10.2eV

R
14.(C) Gravitation potential at a distance of from the centre of earth is
2
GM  2 R 2  11 GM
V  3
 3R    
2R  4  8 R
Applying energy conservation
1 2 11 GMm 11 GM
mu  0u
2 8 R 4 R

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 kQ   a

Qa
15.(B) Ex  2 E cos   2   

 
 a 2  y 2  2  2 3/ 2
   a  y2 2
 20 a  y

Q
y  0, Ex  max  
20 a 2
y   , E x  0

16.(C) Vmax  A
2 g
 
T L
g
Vmax  A …(1)
L
m Vmax 
2
Tmax  mg  …(2)
L
A2  A2 
By (1) and (2), Tmax  mg  mg Tmax  mg 1  
L2  L2 

 i
17.(C) Magnetic induction due to AA´ and BB´ is given as B1  0
4R
Magnetic induction due to CC´ and DD´ is zero at O.
 i
Magnetic indication due to BA is given as B2  0
8R
0i
Magnetic induction due to CD is given as B3 
8R
0i
Thus net magnetic induction at O is given as B0  2 B1  B2  B3 ; B0 
2R
18.(C) Buoyant force arises due to pressure difference between lower and upper surfaces.
F2   P0  gR  R 2
2
F2  F1  R3g [ Buoyant force = F2  F1 ]
3

 R F  P R 2 1
F1   P0  g  R 2  1 0 
 3 F2  P0 R 2 3

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19.(B) E  eT 4  e  ET 4

 e   E  T 4  ;   MT 3 K 4

20.(D)

Work done by external agent = Gain in Gravitational potential energy

21.(62.50)
Let the number of moles of each gas be n and let the temperature be T
5
Total KE of Nitrogen molecules, K1  nRT
2
3
Total KE of Helium molecules, K2  nRT
2
K1
Therefore, the required percentage   100  62.5
K1  K 2

22.(2.50) Here, D  25cm, f0  2.0cm, fe  6.25cm

L  15cm.

For the eyepiece:

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1 1 1 1 1 1 1 1
  ,     (as ue   D  25 )
fe ve ue ue ve fe 25 6.25
1 1
or   or ue  5cm
ue 5
As v0  ue  L  15cm, v0  15  ue  15  5  10cm
For the objective:
1 1 1
 
f0 v0 u0
1 1 1
or  
2 10 u0
1 1 1 4
or   
u0 10 2 10
or u0  2.5cm
Thus, the object should be placed at a distance 2.50 cm in front of the objective.

I 2
23.(5) Moment of inertia of the part ADE about its own centroid is 0 as mass and (side) both are one-
16
fourth of the lamina ABC
I  I I
M.I. of lamina ABC about G, IG  3  0  Md 2   0  I 0  0  3Md 2
 16  16 4
I
 Md 2  0 , where M = mass of part ADE
4
d = distance between centroid of ADE and G.
I I I 5I
 M.I. of part ADE about G = 0  Md 2  0  0  0  N = 5.
16 16 4 16

24.(1.50) E1  7eV   x  1eV   x  6eV

x 6 3
E2  6eV   y  2eV   y  4eV   
y 4 2

25.(2.50) v = speed relative to rim.

v – R = speed relative to ground.
Li  L f as torque about axle of disc is zero.
M 2
 0  0  0  2m  v  R  R  R 
2
 4mv   4m  M  R  300v  750R
4R 5R
 2v  5R  
t t
4
  radians  N  2.50
5

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26.(15) I  1000mA  1A
75V  IR  Vz  75V  IR  60V  IR  15V  R  15
Vrms V0
27.(15) I rms    C  15 mA
XC 2
A 1
28.(2)  .
B 2
Initial activity must be equal.
i.e.,  A N A0   B N B0
N A0 
  B 2
N B0  A
29.(3) The first polaroid eliminates half the light, so the intensity is reduced by half: I1  I 0 / 2. The light
reaching the second polarizer is vertically polarized and so is reduced in intensity to

 
2 3
I 2  I1 cos300  I1.
4
Thus, I 2  3I 0 / 8.
 n=3
30.(16.67) Linear distance between two dots A and B, i.e.,
2.54cm
l  length of the arc AB =
300
Angular resolution of the eye,   5.08  104 rad
l l 2.54cm
Since   , z    16.67cm
z  300  5.08rad

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CHEMISTRY
1.(B)

2.(A)

3.(C)

According to IUPAC rule, name of compound is 4-Chloro-2-ethyl-1-methylcyclohexane.

4.(B) 3Cu  8dil.HNO3  3Cu  NO3 2  2NO 4H2O

(A)
2
Fe2  (aq)  NO  H 2SO4   Fe(H 2O)5 (NO)   H 2O
(conc.) (Brown)
2
The oxidation number of Iron in  Fe  H2O 5  NO    x   5  0   1  2  x  1
EAN of Fe = Atomic no. of metal – no. of electrons lost + no. of electrons gained from ligands
 26  1  12  37

5.(D) Critical temperature of gas depends upon strength of intermolecular force of attraction. In this
graph D shows more deviation from Z.
So D has highest critical temperature.

6.(C) Reactivity towards AgNO3 solution depends upon the stability of carbocation intermediate. Order
of stability of carbocation is (C) > (B) > (D) > (A).
7.(C) This option is correct statement if the emf. of a voltaic cell is negative, it means emf is positive for
reverse reaction and reverse reaction is spontaneous, and cell is working in reverse direction.

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8.(C) No. of geometrical Isomers

9.(B) The increasing stability of the peroxide or superoxide, as the size of the metal ion increases, is due
to the stabilisation of large anions by larger cations.

10.(C) Lysine contain - NH 2 group in its Zwitterion structure, so it will react with nitrous acid and
liberate nitrogen gas.

11.(A)

12.(A) (Fact)

13.(C) (Fact)

14.(C) (Fact)

15.(D)

Structure of Amylopectin which make the starch insoluble.

16.(D) This option is incorrect.

In isothermal process.
T  0
And change in internal energy depend upon change in temperature. In adiabatic expansion cooling
is observed,
Hence, U  nC v T  0.

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2
17.(D)  Ni  NH3 6 
 

2
Co  H2O  
 6

In both complex, Ni and Co have same hybridization.

5  5  1
18.(B) No. of spectral lines =  10
2
19.(B) The order of Bond dissociation energy is Cl2  Br2  F2  I 2 and thermal stability depends upon
Bond dissociation energy.

20.(B) At 20 min, Reaction is at the stage of equilibrium. Hence  r G  0.

R 2P
t=0 2 –
t = 10 2-x 2x (2–x = 2x)
 x  2/3
 4/3  4/3
rG0  RTln K
 22 
= RT ln   = RTln 4 = – ve
 1 
 
Q
At t = 10 min  r G  r G0  RT ln Q  RT ln
K

Q  4 / 3 1 2
1
 RT ln  RT ln  RT ln   ve
K  4 / 3   2  2 3

21.(5.02) A  3B
At t  0 a 0
At t  t a  x 3x
At time t,  a  x   3x
a  4x
2.303 4x 0.693 2.303 4
k log   log
t 3x t1/ 2 t 3
t1/ 2  5.02 min.

22.(4)

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460
23.(960) Moles of ethanol =  10
46
x
Moles of methanol =
32
10 320
 Moles fraction of ethanol = 
10 
x 320  x
32
 Vapour pressure of solution = Pethanol  Pmethanol
PT  PAo x A  PBo x B
 320   x 
72    48     80 
  320  x     320  x  

72 
 320  48  80x
 320  x 
x  960

24.(1) Tf  iK f  m
Tf
Hence, complex is Co  NH3 4 Cl2  Cl.
0.00732
i   1.96  2
k f  m 1.86  0.0020

25.(2.80) Meq of H 2O2  Meq of KMnO 4

w 1000 0.316
 1000
17 158/ 5
WH 2O2  0.17gm.

w 1000 0.17 1000

Normality of H2O2      0.5
E Volume (in ml) 17 20
Volume strength = N × 5.6  0.5  5.6  2.8

26.(56)  NH4 2 Cr2O7  N2  4H2O  Cr2O3

Heat

1 mole 1 mole
2 mole 2 mole
Mass of N 2  mole of N 2  molar mass of N 2
 2  28  56 g

27.(4) ABS Rubber, Plexiglass, Orlon, Teflon are addition polymer.

28.(5) The maximum prescribed concentration of Zn metal in drinking water is 5 ppm.

29.(4) Sodium hexametaphosphate  Na 6 P6O18  is known as calgon. When it is added to hard water the
following reaction takes place.
Na 6 P6O18  6 Na   P6O186 

3Ca 2   N6 P6O18  6 Na   Ca 3P6O18

3 mole 1 mole
12 mole 4 mole

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30.(3) On complete hydrolysis of the peptide give rise 3 distinct essential amino acid which are given
below.

Only valine, phenylalanine and leucine are essential amino acid.

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MATHEMATICS

 2 x  4 x3 
1.(A) x dx
1  x  x 
2 4 2

 1  1
 x 
2 4   dx
 1 x  x  1  x  x4
2

x 1 1  x2  1  x2
2  1  x2  x4
  dx
1  x2  x4
x 1 1  x2 1 1  x2
2  1  x2  x4 2  1  x2  x4
  dx  dx
1  x2  x4
 1 
1
1
   1  
x 1 x2 1  x 2  dx

1  x2  x4
 
2  1
2
dx  
2  1
2
 x    3  x   1
 x  x
 1  1 
 x   x  1 
tan 1 
x 1 1
x  log x
    C
2
1 x  x 4 1
2 3  3  4  x  1
   x 
2.(A) Midpoint of hypotenuse is circum centre which is equidistant from A, B, C.
AD=5
PD  152  52

PD  5 32  1  5 10

100  r 99  r
50 100  rC  C24
n 
 25 25 n n 1
3.(C)   Cr  r  Cr 1 
r 0
100  r 100  r  

1 50 99  r
 
25 r 0
C24

1  99
C24  98C24 ..... 49C24 
25  
1 100
C25  49C25 
25  

4.(A) p p is a fallacy so
(p  p)   p  q  is always true
So, S1 is tautology

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5.(A) f  x   cos x  sin x

 f ( x)   1
3/ 2
 1dx   x 3 / 2  3
3/ 2
So,
3 / 2

6.(C)

7
Sharp edge so not differentiable at x 
2
2
1 x x2
2
7.(A) f  x    a b c   x x2 1
x2 1 x

2 2
1 x x2 1 x x2

   
2 2
 1  x  x2 1 x2 1  1  x  x2 0 x2  x 1  x2
1 1 x 0 1 x x  x2

2
1 x x2
 
2
f  x   1  x  x 2 1  x  1  x  0  x 1  x
2 2

0 1 x

 
4
f  x   1  x3

  .3x2  0 x  0
3
f   x   4 1  x3 
 x 1

We have to find  2a1    2a2 

2 2
8.(A)

a1e1  a2 e2  10
10 10
and e1  ; e2 
a1 a2
a a a2 a
also 1  2  10 ; x  ; x 1
e1 e2 e2 e1

a12a2
 2  10 , a12  a22  100
10 10

4a12  4a22  400

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 Vidyamandir Classes: Innovating For Your Success

9.(D) f  x  
 x  1  x  x  1  x  dx
x 1 x
x
 x 1 
x dx
0
x2 x3 / 2
f  x  x
2 3/ 2
1 2 3 2 5
f 1  1   
2 3 2 3 6
1 1
10.(B) Roots of eqn. 2 x 2  3 x  p  0 are ,
 
1 1
and of 2 x 2  7 x  q are ,
 
1 1 1 1
and given , , , are in AP
   
1 1  3 1  1  7
  d and   2d     3d  
   2     2
1 1 1
 d and 
2  2
p 11 
   d
2  
p 1
 1
2 2
p 1
q 3
 2
2 2
q6  pq7

a 2 x b2 y
11.(A)   a 2  b2
x1 y1
x y
 2 Passing through (6,0)
x1 y1
6
 0  2  x1  3
x1

x12  y12  2

9  y12  2  y1   7
x y
So Eq. of Normal is  2
3 7

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 Vidyamandir Classes: Innovating For Your Success
12.(C) d  1 10, 11, 12
d=2 9, 11, 13
d=3 8, 11, 14
d = 10 1, 11, 21
1  2  3.....10  55

  
13.(A) Clearly 2 z  z  3 z  z i  0 
2 x  3 y  0 (a line)

z lies on intersection of L and line joining z1 and z2 i.e., y  1  3( x  2)

i.e., 3x  y  5 and 2 x  3 y  0
45 10
7 x  15 y  5
7 7
15 15 10
x ; z  x  yi   i
7 7 7
1
14.(B) x  1  x 2   1  y2  y …(1)
1  y2  y
1
y  1  y2   1  x2  x …(2)
1  x2  x
Adding (1) and (2) wegot
x  y  0  y  x
dy
 1
dx

15.(C) A  A2  A3  A4  A5  A6
 cos   cos 2  cos3  cos 4  cos5  cos6 sin   sin 2  sin 3  sin 4  sin 5  sin 6 
 
 [sin   sin 2  sin 3  sin 4  sin 5  sin 6] cos   cos 2  cos3  cos 4  cos5  cos6 

 1 0 
 
 0 1

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 Vidyamandir Classes: Innovating For Your Success
16.(A) Let A = families own a Car
B = families own a Scooter
C = families own a Bicycle
We have to find
 n  A´ B´C´  n U   n  A  B  C  = 100   n( A)   n( A  B)  n  A  B  C  

 100   60  80  40   90  x 
 100  90  x 
10  x
[Here x  n  A  B  C   0 and 0  x  10 ] So, possible answers is 7 %

      
17.(A)  12  22  42  52  7 2  82 ....  32  62  92... 30 terms 
 1  2 1  2    4  5  4  5    7  8  7  8  ...... 30 terms  9 12  2 2  32  ....30 2 
 
11  2  4  5  7  8.....
 3  9  15  ..... 30 terms
 2700 so 85095 – 2700 = 82395

xdy  ydx
18.(A)  2 xy  xdy  ydx 
x2
 y y
d    2 xy d  xy     xy   c
2
x x
1 1 c  c  0
y 1 1 1 1 65
  xy   y  ; y  2  y   
2
 23  8  
x x 3   2
2 3 8 8

19.(B) Mid-point of AB = (2, 6) (M say)

h1  h2  4
k1  k2  12
x1  x2  y1  y2  16

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10 10 10
r   2r 
20.(A)  r        
r 1 r 1   r 1  
7 7
10 11 1  2  3  4  5  6  0  1  2  3 2  4  6  1  3  5  0  2  4  6
  
2 7 7
21  6 21  12 27  33 60 385  60 445
 55    55   55   
7 7 7 7 7 7
21.(2) Here f  x   cos 1 x

2cos 1 x   0
Now lim   form LH Rule
x 0 x 0
2 2 f  x  
 lim  2  lim  +2
x 0 1  x 2 x 0 x
22.(2) OP  PA  PB  PC
1 1 1
P is  , , 
2 2 2
1 1 1
Distance of  , ,  from x  y  z  1  0 is
2 2 2
1 1 1
  1
1
D 2 2 2 
3 2 3
4 3 D2
4 3 2
23.(0)   1 1 3  4  4  15   3  4  6   2  5  2 
2 5 4
 44  30  14  0
So   0
1 3 2
Now, 1  4 1 3  1 4  15  3  16  18   2  20  6 
6 5 4
 11  3  34  2  26  0
  0, 1  0 So system is inconsistent no solution exist.

24.(7) Total no. of ways x  y  z  15

15 31C 17
31  C2
Favourable no of ways x3  y3  z3  6 6  31C31  8C2
8C
p 2  8 7  7
17 C 17  16 34
2

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25.(8) a0  1

a30  315

 
15
a0  a1x  a2 x 2  ...  a30 x30  1  2 x  3x 2

 
14
Diff both sides a1  2a2 x  3a3 x 2  ....  15 1  2 x  3x 2  2  6x 
Put x  0 we get a1  30

1  30  315 digit at unit place will be 1+ 0 + 7 = 8

26.(6)  cos4 x  2sin x cos2 x dx

  cos x cos2 x  2sin x dx

  cos x 1  2sin x  sin 2 x dx   1  2t  t 2 dx    t 2  2t  1  2 dt

 
1 t 1 t 
1  2t  t 2  sin 1 
2
  2  1  t  dt 
2

2 2  2
1  sin x  1  sin x 
 1  2sin x  sin 2 x  sin 1  c
2  2 
7
3 2
27.(3)    we here to get the greatest term.
5 5
7 7
 3   2 2
Let Tr 1 is greatest term   1   x
 5   3 3
| x |  n  1 2 / 3  7  1 16
m  
| x | 1 2
1 5
3
16 
r   m     3
5
So highest winning probability that India will win 3 matches.

28.(0) Domain of sin 1 x  cos1 x  tan 1 x is [– 1, 1]

        3 
So range is   ,     , 
2 4 2 4 4 4 
3
b
4
 b   2
Now no. of solutions of 1 | x | tan 1 x
2 solutions.

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29.(50) Using concept of rotation
i
 x  iy    3  4i   6  8i   3  4i  e 2
 
x  iy   3  4i    3  4i  i
 x  iy   3  4i 1  i 
x  iy  3  4i  3i  4
 7i
x  7, y  1 similarly, x = – 1, y = – 7
7 2  12  50

30.(4) Single digit 1-9 9

Double digit 10-99 2 × 90 = 180
Triple digit 100-999 3 × 900 = 2700
Four digit 1000-9999 4 × 9000 = 36000
Five digit 10,000 5
9 + 180 + 2700 + 36000 + 5 = 38894

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