Vidyamandir Classes

Solutions to JEE Advanced – 3 |JEE 2023 | Paper – 2

PHYSICS
1 k  1 k  1  k  1.71  k 2
1.(ABC) (A) Put t  x  1    1   
l l  e  l  2.71  l  2.71  l 3
dx d2x
(B)  v  kelt ,  a  lkelt put t = 0
dt dt 2
k
(C) Particle starts from x = 0 and maximum displacement achieved is at t   and x 
l
k
 Particle cannot go beyond x 
l
(D) Wrong
m  2 R   2m  5 R 
2.(BC) Location of c.m. is given by ycm  0, xcm   4R
m  2m
 c.m. is at the junction
I cm  I rod  I ring

m  4R 
2
28
  2  2m  R 2  mR 2
3 3
28 172
I z  I cm  (3 m) (4 R )2  mR 2  48mR 2  mR 2
3 3

3.(AD) The progression of velocities of A, B and C will be

3v, 2v, v  2v, 3v, v  2v, v, 3v  v, 2v, 3v
Number of collisions  3

4.(AD)

N cos   Ma
mg  N sin   mA

a
tan    A  a cot 
A

3 equations, 3 unknowns.

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 Vidyamandir Classes

5.(ACD) J  mv0 ….(i)

mR 2 0
J  h  R  ….(ii)
2
3R v
If h   0  0 (Disc starts Rolling)
2 R
If h  R
J
v0  , 0  0
m
Disc will start rolling after some time
mR 2 v
About P : L  mv0 R  mvR 
2 R
3v 2v 2J
v0  v 0 
2 3 3m
In the frame of center of mass bottommost point is moving backward & friction is also acting backward so W fric  0

6.(AD) Pressure at base  P  gh  Force on base  P  a 2  gha 2

Note that this force is exactly equal to the weight of cylindrical volume of water directly above the base [The
cylinder of radius a and height h]
The weight of the rest of the water is supported by the curved surface.
Total weight of water in bucket
W   [Volume of frustum, V]g.
h 2
V [a  ab  b 2 ]
3
Net force on curved surface  W  gha 2
Net force on bucket = W.

7.(D) Conserve angular momentum

1 1 1 M  R
2  32
MR    MR 2  
2
      
2 2 2 8  4  33
 
8.(C) Consider smaller disc, take radius = r and mass = m
Take ring shaped element of radius x and width dx.
 mg( 2 xdx )x
Torque due to friction on this ring element = d 
 r2
r r
2mg 2
 x
2
Total torque on smaller disc =   d   2
dx  mgr
r 3
0 0
2
2 mr 4g
  I  mgr    
3 2 3r
4g 32 8r 4 R
0  t    t   t 
3r 33 11g 11g

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 Vidyamandir Classes

9.(B) Let total volume be V.

Just after release, velocity is zero, so viscous drag force is zero
 
mg  B  ma  V  g  V  g  V  a  a  1  g.
  
10.(A) For the system of two spheres :
m1 g  m2 g  B1  B2  Fd1  Fd 2
4 4
 (8r 3  r 3 )  g   (8r 3  r 3 )  g  6 (2 r  r ) VT
3 3
4 2 (   ) gr 2
  (9r 3 ) g (   )  6 (3r )VT  VT 
3 3 
11.(B) GPE of elemental mass ‘dm’ is :
dU  ( dm) gR cos 
m 
dU   Rd   gR cos 
 
mgR 2
dU  cos d 

 Total GPE is : U  dU 
/ R
mgR 2
 U  
cos d 
0

mgR 2 
 U sin   i.e. option (B)
 R

12.(D) Consider an elemental length Rd  at an angle  with the vertical.

Using F  ma  (dm) g sin   dT  ( dm) aR
Integrating both sides,
dm m
 (dm) g sin    dT   dm aR ; 
Rd  
 0 
m m
  
gR sin d   dT  
aR Rd  ; aR  Constant
0 0 0

mgR m


1  cos    aR R[]

gR gR  


1  cos    aR  aR  
 
1  cos 
R
i.e. option (D)

1.(2) Au  a 2 gh
H2 t
 dh  dh a
 A     a 2 gh
 dt 
  
h
 A 2 g dt
H1 0

H2 a A 2
  2 h   2 gt  t [ H1  H 2 ]
  H1 A a g

A 2  H A 2  H  T1 2 1
Now, T1   H   and T2    0   H/ H 2
a g  9  a g  9  T2 3 3

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 Vidyamandir Classes

2.(4) In equilibrium : F1  F2  mg . . . . . (i)

After upper spring is cut F1 becomes zero but F2 remains unchanged
 mg  F2  m(6) . . . . .(ii)
If lower spring is cut, F2 becomes zero but F1 remains unchanged
 mg  F1  m(a )
From (i) and (ii), F1  mg  F2  6m  mg  6m  ma
a = g – 6 = 4m/s2

m  0   m  u  u
3.(5) At instant of projection, vcm  
2m 2
2
u  h
For CM, v 2     2   g      32  2  10  0.8  v5
2  2
4.(2) In orbit particle’s PE  mv 2
To take it to infinity it has to reach infinity with at least TE  0
So KE in orbit + PE in orbit should be zero.
 KE in orbit should be mv 2  n  2.
5.(5) Let 1 = density of water, 2 = density of oil and  = surface tension of water.
Equating pressure at the bottom of the capillary.
2 2
Patm   1 gh2  Patm   2 gh2  r
r (1  2 ) gh2

Solve to get r  5  104 m   5


6.(2) v cos  u cos   v  10m / s.
2
v2 10
Using an  , R  3R  2
R g cos30

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 Vidyamandir Classes

CHEMISTRY
1.(ACD)
NaOH  HCl 
 NaCl  H 2O
CO32  HCl 
 HCO3  Cl 
Now, methyl orange indicator is added and following reaction occurred further:
HCO3  HCl 
 H 2O  CO 2  Cl
Let solution has x mmol NaOH and y mmol CO32
 y = 15 and x + y = 35
 x = 20
 Total mmol of carbonate in 100 mL solution = 15
Total mmol of NaOH in solution = 20 = 0.80 g NaOH)
1.2
Mass % of M 2 (CO3 )3   100  60%
2
1.2
 Molar mass of M 2 (CO3 )3   240  240  2  M  60  3
5  103
And atomic weight of metal (M) = 30

2.(CD) Based on Le-Chatelier’s principle.

3.(ABC) PCl5 has trigonal pyramidal structure.

4 (ABCD) Fact

5.(BC) Since intermolecular forces are zero hence potential energy increases with decreasing distance, while Z
increases by increasing pressure.

6.(ABD)
G 0  H 0  TS0
Also G 0   RT ln K p

  RT ln K p  H 0  TS0

RT ln K P  TS0  H 0

1  0 H 0 
ln K p   S  ; Hence (A), (B), (D) is correct
R  T 
mol. mass of SO3 80
7.(C) D   40
2 2
40  30 10
8.(C)    0.66
(1.5  1)30 15

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 Vidyamandir Classes

9.(B) As S is a state function.

10.(A) A to C having constant volume therefore this process is isochoric

C to B having constant pressure therefore this process is isobaric.

11.(B), 12.(B)
Cu  4HNO3  Cu(NO3 ) 2  2NO 2  2H 2O Cu  4HNO3  Cu(NO3 ) 2  2NO 2  2H 2O
1 1.23 0.025 mole 0.1 mole
0.025 mole  0.05 4Zn  10HNO3  4Zn(NO3 ) 2  NH 4 NO3  3H 2O
0.082  300
= 0.025 × 63.5 0.005 mole 0.0125 mole 0.00125 × 80
= 1.5875g = 0.1g
1.5875 V3
 Percentage of Cu   100  82.92% Now, moles of HNO3 ,  0.1125
1.9145 1000
and Zn present = (1.9145 – 1.5875) = 0.327g  V = 37.5 mL
0.327
  0.005 mole
65.4

1.(344.80)
Work is done against constant pressure and thus irreversible.
V  4 lit
P = 1 atm
w  1 4 lit-atm  1 4 101.3  405.2 Joule
 E  q  w
 E  750  405.2
E  344.80 J
2.(30.60)
Z2 32
KE = 13.6  2  13.6  2  30.6 eV
n 2
3.(2763.60)
G  2.303RT log K P
= – 2.303×2×300 × log 102 = 2763.60 cal

4.(353.25)
u av  u rms
8RT1 3RT2

M M
8RT1 3RT2 8RT1 3R  300
 or 
M M M M
T1  353.25 K

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 Vidyamandir Classes

5.(80.32)
H  E  n g RT
1 8.314  298
 82.8  U   U  80.32
1000
6.(3)

MATHEMATICS
1.(BC)
At x  0, equation is satisfying.

 2  1 x   2 x  1 x  2 x  1  
2
x 2 1
 
Comparing coefficients

x 2  1,  2 x 1  1  0, & x  1
2

 
 x  1
 x  1, 0,1

 
n
2.(AC) We have 1  2 x  3 x 2  4 x3  ......

2 n
 1  x    1  x 
2n
 

 
n n
So, coefficient of x in 1  2 x  3 x 2  4 x 3  ......

 2n  !
= coefficient of x in 1  x 
n 2n 2n
 Cn  .
 
n !
2

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 Vidyamandir Classes

10 20
 1   1
3.(BC) We have  x2  2
 2   x  
 x   x
20 r
Tr 1  20Cr  x    x  r
20 2 r
Tr 1  20Cr  x   1r
10
 1
The value of constant term in the binomial expansion  x   , if
x  
20  2r  0  r  10
T101  20C10  1
10
 20C10

(A) Number of different dissimilar term in the expansion

 x1  x2  x3  .....  x10 10 10101 C101  19C9
 2  10 !
 10C0    10C1   10 C10  20!
2 2 2
(B)  ......     20C10
10!10! 10!10!

 n C1    n C2   n Cn  2n ! 
2 2 2
  ......  
n ! n ! 

Coefficient of x10 , in 1  x   20C10  1  20C10

20 10
(C)
(D) Number of linear arrangements of 20 things of which 10 alike of one kind and rest all are different,
20!
taken all at a time =
10!
4.(BCD)
We know that, distribution of n distinct objects into r different boxes, if empty boxes are not allowed or in
each box atleast one object is put  n  r  .
The number of ways
r 1 n
 r n  r C1  r  1  r C2  r  2   ......  1
n n
Cr 11 ….(i)

Hence, n  5, r  3
 number of ways in which the different books be distributed in 3 persons, so each gets at least one is

 3 5  3C1  2 5  3C2  243  3  32  3  150

(B) Number of parallelograms formed by one set of 6 parallel lines and other set of 5 parallel lines
6 C2 5 C2  15  10  150
(C) 5 different toys to be distributed among 3 children, so each gets at least one
  3   3C1  2   3C2
5 5

 243  3  32  3  150
(D) 3 mathematics professors are assigned five different lectures, so that each professor get at least one
lecture.
  3   3C1  2   3C2
5 5

 243  3  32  3  150

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 Vidyamandir Classes

5.(BD)
Case 1 When n people are sitting a row.
Let x be the number of persons to the left of the first person chosen, y be the number of persons between the
first and second, z be the number of persons between the second and the third and u be the number of
persons to the right of third person.

Then, x, u  0; y, z  1 and x  y  z  u  n  3
Now, Let Now, y1  y  1 and z1  z  1. Then, y1  0 and z1  0 such that x  y1  z1  u  n  5, where

x, y1, z1, u  0 .
 Total number of ways of selecting 3 people out of n
= Number of non-negative integral solution of x  y1  z1  u = n – 5

 n  5  n5 41 C41  n2C3

i.e. Pn  n2C3
Case II When n people are sitting in circle .
Let n persons be denoted by a1 , a2 ,...., an .
Now, we have to select 3 persons so that no two of them are consecutive. For this we first find the number of
ways in which 2 or 3 persons are consecutive. Now, number of ways in which 2 or 3 persons are
consecutive is obtained as follows, with a1 the number of such triples is

a1a2 a3 , a1a2 a5 , a1a2a6 ............a1a2an1.

[Note that we have excluded a1a2 an , since it will be repeated again for, if we start with an , then we shall get

triples : an , an a1a2 , an a1a3 ]

So, number of such triples when we start with a1 is  n  3 . Similarly, with a2 , a3 , a4 ,...................... we

shall get the same number of triples that is  n  3 .

But total number of triples is nC3 .

Thus required number of ways  nC3  n  n  3 

6.(ABD)

Tr 
 r  r  1  r !  r  1   r  2    r !   r  1   r  1! r ! r  2  
2


2

 
 r  3r  2 
2
 r  3r  2
2
  r  1 r  2  

Tr 
 r  1!  r!
 T  V V
r2  r  1 r r r 1
T1  V1  V0

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 Vidyamandir Classes

T2  V2  V1

Tn  Vn  Vn1
Sn  T1  T2  ......  Tn
Sn  Vn  V0

Sn 
 n  1!  1
n2 2
2  n  1 ! (n  2)
Sn  .
2(n  2)

7.(B)
az 2  bz  c  0 ….(i)

az 2  bz  c  0
a  z   bz  c  0
2

For purely imaginary root,
z  z
Then, az 2  bz  c  0 …(ii)
From eqs. (i) and (ii), we get
z2 z 1
 
bc  bc ca  ca ab  ab
bc  bc ca  ca
 z 
ca  ca ab  ab
  ab  ab  bc  bc    ca  ca 2  0
8.(D)
 az 2  bz  c  0

 az 2  bz  c  0
a  z   bz  c  0
2

Since, both roots are purely imaginary.
 z  z
Then , az 2  bz  c  0
Hence, Eqs. (i) and (ii) are identical
a b c
  
a b c

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 Vidyamandir Classes

9.(B) If curves intersect, the parameters are equal at the point of intersection.
Hence the curves intersect where
a 2  bt  c1  at 2  bt  c2

 2at 2  2bt  c1  c2  0 ….(1)

The equation has distinct roots if
4b 2  4.2a  c1  c2   0  b 2  2a  c1  c2 
dy a
10.(A) For the curve S1 , we have 
dx 2at  b
dy a
For the cure S2 , we have 
dx 2 at  b
The curves intersect orthogonally if, at the point of intersection,
a a
  1
2at  b 2at  b
 4 a 2t 2  4 abt  b 2  a 2  0
  2at  b  a  2at  b  a   0
a b ab
 t or 
2a 2a
a b ab
If the curve intersect then t  and t   must satisfy equation (1)
2a 2a
ab
So, for t  , from (1) we get
2a
2a  a  b  2b  a  b 
2

2
  c1  c2  0
4a 2a
 a 2  b 2  2a  c1  c2   0
ab
Similarly, for t  
2a
we get a 2  b 2  2a  c1  c2   0

 The curves intersect orthogonally if b 2  2 a  c1  c2  and a 2  b 2  2a  c1  c2   0

1 1 1.3
11.(A) Let C  1  cos 2  cos 4  cos 6  .........
2 2.4 2.4.6
1 1 1.3
and S  sin 2  sin 4  sin 6  .......
2 2.4 2.4.6
1 1 i 4 1.3 i 6
 C  iS  1  ei 2  e  e  .......
2 2.4 2.4.6

 
1/2
 1  cos 2  i sin 2 
1/2
 1  e 2 i

VMC |JEE-2023 | Paper – 2 11 Solutions |JEE Advanced – 3

 Vidyamandir Classes

1/2
  2 cos 2   i 2sin  cos  
 
  
 2 cos   cos   i sin  
1/2
  2    2 

  
 2 cos   cos  i sin 
 2 2
Equating real part

C  2 cos  cos  cos  1  cos  
2
a n  n  1 a 2
12.(A) Let C  1  n cos B  cos 2 B  .....
c 2! c 2
a n  n  1 a 2
S  n. sin B  sin 2 B  ......
c 2! c 2
a n  n  1 a 2 2iB
 C  iS  1  n eiB  e  ....
c 2! c 2
n n
 a   sin A
  1  eiB   1   cos B  i sin B  
 c   sin C 
n
 sin n C sin C  sin A cos B  i sin A sin B 
n
 sin n C sin  B  A  sin A cos B  i sin A sin B 
n
 sin n C sin B cos A  i sin A sin B 

sin n C cn
  cos A  i sin A  n   cos nA  i sin nA 
sin n B bn
cn
Equating imaginary parts S  sin nA
bn
1.(250) 1  x 
200
 200C0  200 C1 x  200 C2 x 2  200C3 x 3  ......... (i)
 1  x149 
and  
148 147 146
  x  x  x  ......  x  1  ……….(ii)
 1 x 
On multiplying and equating coefficient of x148 . we get
200
C0  200C1  200C2 .......  200C148

= coefficient of x 148

in 1  x  .
 200 
1  x149  
 1  x  
 

= Coefficient of x148 in  1  x 199 1  x149 

  
= Coefficient of x148 in 1  x 
199 199
 199C148 or C51 .

VMC |JEE-2023 | Paper – 2 12 Solutions |JEE Advanced – 3

 Vidyamandir Classes

2.(511) A rational number of the desired category is of the form

2021.x1 x2 .xk , where 1  k  9

and 9  x1  x2  ......  xk  1. we can choose k digits out of 9 in 9 Ck ways and arrange them in decreasing
order in just one way.
Thus, the desired number of rational numbers is
9
C1  9C2  .......  9C9  29  1

3.(1) The roots of the equation

n  n 2  4n 2 2
x may be integers if n  4n  I where I is an integer.
2
 n 2  4n  I 2  0 . . . (1)

 n  2 4 I2
Now n is an integer  4  I 2 should be an integer.
 4  I 2  k 2 where k is an integer .
 k2  I2  4
which is possible only when k  2, I  0.
putting I  0 in 1 ,

n 2  4n  0  n  0, 4. For both these values,

x 2  nx  n  0 has integral roots.
 n  0, 4  n 2  4n  0.
4.(1)
 2 2

 K 2  12   2  1

1 1
5.(2) Here, S      ....... 
k 1  3

 1 K 1 2 1
2
1
2
t  K2
 1        ...................
 2   3
k 1

 1  2  1 2  1  2  S S
S  t  2.          ........    2. 
2 4
      6  4 2

S S
 t  2
2 t
2
6.(3) k  z2  z  k  z2  k

 
arg z 2  arg  k 


 2 arg  z     arg  z   .
2

VMC |JEE-2023 | Paper – 2 13 Solutions |JEE Advanced – 3