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1
1
S1 0 a 2 p 1 …(1)
2
1
and S2 0 a 2( p 1) 1
2
1
a 2 p 1 …(2)
2
and 1
S 0 ap 2 …(3)
2
Adding equation (1) and (2)
1
S1 S2 a 2 p 1 2 p 1 2ap
2
Substituting the value of a from equation (3)
2S
S1 S 2 2 p
p2
p
S S1 S2
4
a) a = bt – c
b) a = –bt + c
c) a = c
d) a = –c
Ans. c)
Explanation:
S
2
Velocity is the slope of displacement-time graph. It is first
negative, then zero and finally, positive.
Hence, velocity continuously increasing so acceleration must
be always positive.
A B
2R
v
3
2v
2
R
Hence, ratio
2v v
R
c) v0e–2
d) v0(1 – e–2)
Ans. c)
Explanation:
dv v 2
dt R
vdv v 2
or
ds R
v S
R
dv dS
–
v
v 0
S
ln v v
v
0 R
v S
ln
v0 R
Hence, speed after one revolution
v = v0e–2R/R = v0e–2
4
6. A particle starts moving with velocity v ( y 2iˆ xjˆ) from
origin, where k is a constant. The general equation for its
path is
a) y x2/3
b) y x3/2
c) y x
d) y2 x
Ans. a)
Explanation:
Comparing vx = ky2
vy = kx
dy v y kx
and slope tan 2
dx vx ky
y x
y dy xdx
2
0 0
3 2
y x
3 2
y x2/3
5
Explanation:
2 m/s
1 kg
1 kg
1 kg 2 m/s
v
–2000iˆ 2000 ˆj
6
1 2
x at
4
vt
y
2
x y2, path is parabolic.
7
10.If Young’s modulus of a wire is Y = 1010 N/m2, and
strain on it is 0.001, then the energy stored in wire per
unit volume is
a) 10000 J/m3
b) 5000 J/m3
c) 2000 J/m3
d) Zero
Ans. b)
Explanation:
Energy density, u 1 y 2
2
1
1010 (0.001)2
2
= 5000 J/m3
mg
1
13.The amplitude of damped oscillation becomes in 2 s.
2
1
Its amplitude becomes in time after start
3
a) 3 s
b) 2 ln 2
ln 3
2 ln 3
c)
ln 2
3ln 2
d)
ln 3
Ans. c)
Explanation:
In damped oscillation
9
A = Ae–bt
A
bt ln
A
b × 2 = ln2 …(i)
b × t = ln3 …(ii)
ln 3
t2
ln 2
10
c) H.M.
d) None of these
Ans. c)
Explanation:
1 A A 2
L L
Req = R1 + R2
2L L L
eq A 1 A 2 A
21 2
eq
1 2
Magnetic moment ( M ) q
Angular momentum ( L) 2m
M q
I 2m
q mR 2
M
2m 4
qR 2 R 4
8 8
11
17.If coefficient of mutual induction of primary and
secondary coil of transformer is 5 H and in primary coil
is given as I = 10 sin4000 t. Then peak value of emf
induced in secondary coil is
a) 5 × 104 volt
b) × 105 volt
c) 2 × 105 volt
d) 5 × 106 volt
Ans. c)
Explanation:
Emf induced in secondary coil
Md I p
es
dt
d
5 10sin 4000t
dt
=– t
Peak value es 5 volt.
L
a)
2R
L
b)
R
L
c) ln 2
R
12
L
d) ln 2
2R
Ans. c)
Explanation:
Current in resistor is constant
I1
R
Current in inductor grows
Rt
I2 1 e L
R
I1
I2
2
Rt
1 e L
R 2 R
Rt
1
e L
2
Rt
ln 2
L
L
t ln 2
R
13
d
5 107
0.5 103
= 10–3 rad.
15
3R R 25
4 4 16
73R
64
73R
Req
Req R
% change 100 64 100
Req R
900
14.06
64
16
3
l2 e …(ii)
4
Dividing and substituting values of l1 and l2
20.1 e 1
, e
60.5 e 3
and for third resonance
5
l3 e
4
l3 = 100.9 cm
n 22
R
, n 2 R
R 1 R 1
17
27.First ionisation energy is lowest for
a) Carbon
b) Tin
c) Lead
d) Silicon
Ans. b)
Explanation: Sn has minimum first ionisation enthalpy.
28.Amongst BCl3, CO32 , NO3 , ClO3 , SO32 , BO32 , AsO32 and SO3, the
non-planar species are
a) AsO32 , BCl3 , NO3
b) NO3 , BCl3 , BO32
c) AsO32 , SO3 , BCl3
d) SO32 , ClO3 , AsO32
Ans. d)
Explanation:
BCl3, SO3, NO3 , CO32 , BO3 are planar species (sp2 hybridised).
AsO32 , SO32 , ClO3 are non-planar species (sp3 hybridised).
18
O
O O
H–O–S–O–O–H
H–O–S–O–O–S–O–H
O O O
Marshall's acid Caro's acid
O state of S = +6 O state of S = +6
P4O6 is O P O
So, P – O bonds are 12.
19
32.When hydrogen peroxide is added to acidified
potassium dichromate, a blue colour is produced due to
the formation of
a) CrO24
b) Cr2O72
c) Cr2O3
d) CrO5
Ans. d)
Explanation:
K2Cr2O7 + H2SO4 + 4H2O2 2CrO5 + K2SO4 + 5H2O
Blue-coloured compound
b) O O
c)
O O
20
Enol of O has anti-aromatic character which is least stable
i.e. unstable
OH
c) OH
d)
Ans. d)
Explanation:
OH
Ring
H
+
expansion
O O H OH
+
–H
OH
21
d) PQ4O4
Ans. c)
Explanation:
Number of oxide ions = O
1
Number of Q in octahedral voids 1 Q O1/4
4
1
Number of P in tetrahedral voids 2 P P1/4
8
So formula P1/4 Q1/4 O = PQO4
22
38.Which of the following complex has lowest value of
magnetic moment?
a) [Cr(NH3)6]+3
b) [Mn(CN)6]–4
c) [CoF6]–3
d) Ni(CO)4
Ans. d)
Explanation:
[Cr(NH3)6]+3 Cr+3 = 3d34s0 d2sp3 n = 3(unpaired
electrons)
[Mn(CN)6]4– Mn+2 = 3d54s0 d2sp3 n = 1(unpaired
electron)
[CoF6]–3 Co+3 = 3d64s0 sp3d2 n = 4(unpaired
electrons)
[Ni(CO)4] Ni(O) = 3d84s2 sp3 n = 0(unpaired electron)
b) O
C
Cl
NH
c) Cl
d) O
Ans. a)
Explanation:
Cl Cl Cl
NH2
OH SOCl2 Cl NH
O O O
Aniline is weak base so it substitutes chlorine at acyl group.
CH2 – Cl +
aq. KOH H O3
A B C NaOH
42. Zn/H2O
D(major product)
, D(major product)
is
CHO
a) CHO
b)
CHO
c) CHO
24
COONa
d) CH2OH
Ans. b)
Explanation:
CH2 – Cl CH2OH
KOH(aq) H
+
O3 CHO
Zn/H2O CHO
(A) (B) (C)
Aldol
CHO condensation
NaOH
(D)
O
C
CH3 Zn – Hg
43. HO HCl
A
. Identify ‘A’
a) HO
b) HO O
CH3
c) Cl
d) Cl
Ans. d)
Explanation:
O
CH3 Zn – Hg
HCl
HO Cl
alc KOH
O
NaOH O3
Zn/H2O
O O
Single final product
26
0.9 0.9 1000 900 9
1.12 M
800 800 800 8
1000
H 2 (g) 2H (aq) 2e
2e I2 (s) 2I (aq)
H 2 (g) I 2 (g) 2H (aq) 2I (aq)
0.0591 [H ]2 [I ]2
E cell E cell
o
log
2 PH 2
0.0591 [H ]2 (0.1) 2
0.7714 0.535 log
2 1
0.7714 0.535 2 log[H ]2 (0.1 0.1)
0.0591
27
1
48.PQ3(g) dissociates as PQ3 (g) PQ 2 (g) Q 2 (g)
2
When the initial pressure of PQ3 is 400 torr and the total
pressure developed at equilibrium is
450 torr. What percentage fraction of PQ3 (g) is
dissociated?
Ans. 25)
Explanation:
1
PQ3 (g) PQ 2 (g) Q 2 (g)
2
Initial 400 0 0
P
At eq. 400 – P P
2
P
400 P P 450
2
P
450 – 400 50
2
P = 100
100
% of PQ3 dissociated 100
400
= 25%
28
3 3 4
Total Kinetic energy of He gas nRT 120 180 J
2 2 4
P C
A
V 3V
Volume
a) 5PV
b) 10PV
c) 4PV
d) 12PV
Ans. 5)
Explanation:
Work done in the cyclic process = Area bounded (ABCA)
1
6P – P (3V – V)
2
1
5P 2V 5PV
2
29
Ans. c)
Explanation:
x2(2 + 22 – 5) + x(22 – 2) + (2 + 2 – 3) = 0
2 + 22 = 5, 22 –2 = 0, 2 + 2 – 3 = 0
which gives, = ±1, 2
k 1
= c3n2(2n2 –1)
30
53. If = e–2i/3, a, b, c, x, y, z are non-zero complex
numbers such that a + b + c = x, a + b + c2 = y and a +
2 2 2
2 x y z
b + c = z, then 2 2 2
a b c
a) 6
b) 4
c) 1
d) 9
Ans. d)
Explanation:
Put a = b = c
x = 3a
y = a(1 + + 2) = 0
z = a(1 + 2 + ) = 0
| x |2 | y |2 | z |2
| a |2 | b |2 | c |2
=9
31
Since, x > 0
therefore, p > 0
32
d) 2ln2 sq. unit
Ans. a)
Explanation:
1
cot
1
A x tan 1 x dx
0
1
2 tan 1 x dx
2
0
Let g ( x)
f (t )dt
0
g (3) g (2) g (2) g (1) g (1) g (0)
g (3)
3 2 2 1 1 0
= g() + g () + g()
= 3[2f(3) + 2f(3) + 2f(3)]
33
58.Given that f satisfies |f(x) – f(y)| |x – y| for all x and y in
b
16
b) 17 Cr
r 1
18
c)
r 1
17
Cr 1
16
d) 17 Cr 1
r 1
Ans. c)
Explanation:
34
det(2ABTC) = 23 det(A)·det(BT)·det(C) = 23·22·(22)2·(24)2 =
217
61. If the function f(x) = x3 + ex/4 and g(x) = f–1(x), then the
value of g(1) =
a) 2
b) 1
4
1
c)
2
d) 4
Ans. d)
Explanation:
f(g(x)) = g(f(x)) = x
gf(x)) f(x) = 1
g f ( x) 1
f ( x)
x = 0, g
35
62. Equation of common tangent with positive slope to the
circle (x – 4)2 + y2 = 42 and hyperbola
4x2 – 9y2 = 36 is
a) 5 y 2 x 4 0
b) 2 y 5 x 4 0
c) 5 y 2x 20 0
d) 2 y 5 x 4 0
Ans. a)
Explanation:
Let equation of tangent be y mx 9m2 4 , m > 0
Also, it is tangent to the circle,
4m 9m 2 4
therefore, 4
1 m2
m2 4
5
m 2
5
36
xh yk 1 …(i)
9 1
Making equation of ellipse homogeneous with the help
of equation (i), we get
2
xh
x 9 y 9 ky
2 2
9
37
65. In a PQR, if medians from P and Q are perpendicular,
then minimum value of cotP + cotQ is
a) 2
3
1
b)
3
3
c)
4
1
d)
4
Ans. a)
Explanation:
P
2x
y T
2y
2 x
1
Q S R
x
tan 1
2y
2x x
tan 2
2y y
x x
2y y
tan Q
x2
1 2
2y
3x 2 y 2
2 2
2y 2y x
3 xy
2
2 y x2
2 y 2 x2
cot Q
3 xy
2 x2 y 2
Similarly, cot P
3 xy
x2 y 2 2
cot P cot Q
3 xy 3
38
66. Three normals can be drawn from a point (sin + 3,
cos) to the parabola y2 = 4a(x – 3), then value of a lie in
the interval
a) 1 , 1 0
2 2
1
b) 2 , 1
1
c) 2 , 0
1
d) , 1
2
Ans. a)
Explanation:
Equation of normal is given by y = m(x – 3) – 2am – am3
am3 + (2a – m
For three real roots 3am2 + (2a – sin) < 0.
x 2 y 1 z 2
67. If the line lies in the plane x + 2y + z –
3 5 2
= 0, then (, ) equals
a) (4, 8)
b) (–8, 4)
c) (–4, –8)
d) (8, –4)
Ans. c)
Explanation:
2 + 2(–1)+ 2 – = 0
and 3+ 10 + 2 = 0
= –4 and = –8
39
68.There are three bags B1, B2 and B3·B1 contains 2 red
and x2 – 6x + 13 black balls. B2 contains 3 red and x2 –
6x + 12 black balls and B3 contains 4 red and x2 – 6x +
11 black balls. A ball is drawn at random from at random
chosen bag. Then the maximum probability such that the
drawn ball is red, is
a) 1
3
1
b)
2
1
c)
4
2
d)
9
Ans. b)
Explanation:
1 9
Required probability 2
3 x 6 x 15
3
x 3 2 6
3 1
Maximum probability
6 2
69.Let x(0, 4) and yR, then number of ordered pairs (x,
y) which satisfy the equation
2 1
2cosec x y 4 y 2 1 is
2
a) 4
b) 8
c) 12
d) 16
Ans. b)
Explanation:
40
1
cosec2x = 1 and y2
2
cosecx = ±1 and y
1
2
x , 3 , 5 , 7 and y
1
2 2 2 2 2
Tr 1 10Cr
1
x r /3 Term independent of x = 10C6 =
10 r
x1/2
10C10–6 = 10C4
5r
5
10
Cr x 6
5r
5 0
6
r = 6
41
NUMERICAL TYPE QUESTIONS
differential equation t 2 y(t )dt x3 y( x) (x > 0) is x2y = c. find
0
the value of c.
Ans. c)
Explanation:
dy
x 2 y ( x) 3x 2 y ( x) x3
dx
x3 dy 2 x 2 y
dx
dy
2
dx
y x
x2y = c
c=2
Therefore, required curve is x2y = 2
42
73. If x, y and z are unit vectors such that
2 2 2
x y yz zx 9, then 3x 5 y 5 z
Ans. 2)
Explanation:
2 2 2
x y yz zx 9
x yz 0
x yz 0
3x 5 y 5 z 2
2
15 4 x 2 x 2
6
75. Let I dx , then I
e6( x 1) 1 49
0
Ans. 2)
Explanation:
2
15 4 x 2 x 2
I
0
e6( x 1) 1
dx
2
e6( x 1) (15 4 x 2 x 2 )
I
0
1 e6( x 1)
dx
43
2
2I
15 4x 2x dx
2
2 I 15 2 8 16
3
I 98
49
6 3
44