28-12-23

PHYSICS MAX.MARKS: 100

SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer,
out of which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -1 if not correct.
1. Two coherent sources of light interfere. The intensity ratio of two sources is 1: 4 . For this
I max  I min 2  1 
interference pattern if the value of is equal to , then will be
I max  I min  3 

A) 1.5 B) 2 C) 0.5 D) 1

2. Two satellites A and B, having masses in the ratio 4 : 3, are revolving in circular orbits
of radii 3r and 4r respectively around the earth. The ratio of total mechanical energy of
A to B is.

A) 9 : 16 B) 16 : 9 C) 1 : 1 D) 4 : 3

3. An infinite current carrying uniform wire passes through point O and in perpendicular to
the plane containing a current carrying loop ABCD as shown in the figure. Choose the
correct option(s)

A) Net force on the loop is zero

B) Net torque on the loop is zero

C) As seen form ‘ O ' ’, the center of mass of the loop moves towards ‘O’.

D) As seen from ‘ O ' ’, the center of mass of the loop moves away from ‘O’.

4. The amplitude of electric field at a distance r from a point source of light of power P is
(taking 100% efficiency)

P P P P
A) B) C) D)
2 r 2c 0 4 r 2c 0 8 r 2c 0 2 r 2 c 0
5. An iron rod of length L and magnetic moment M is bent in the form of a semicircle.
Now its magnetic moment will be
2M M
A) M B) C) D) M 
 
6. In a football game, a player wants to hit a football from the ground to one of his
teammates, who is running on the field. Take hitter position as origin and receiver’s
initial positions as 2iˆ  3 ˆj , where iˆ and ĵ are in the plane of field. Football’s initial
velocity vector is 2iˆ  5 ˆj  25kˆ and in the subsequent run receiver displacement is 5iˆ and
8 ˆj , then 2iˆ  4 ˆj and then 6 ˆj . How far is the receiver from the football when football

lands on ground? (assume g  10kˆ )
A) 10 B) 17 C) 26 D) 13
7. In the given circuit diagram, switch was connected to position 1 for long time. At t = 0,
switch is shifted from position 1 to position 2. Find the final charge on capacitor 2C.

CV CV 2CV 4CV
A) B) C) D)
6 3 3 3

8. STATEMENT – 1: Two teams having a tug of war always pull equally hard on one
another. (Ignore mass of rope)
STATEMENT – 2: The team that pushes harder against the ground, in a tug of war,
wins.
A) Statement – 1 is True, Statement – 2 is True; Statement – 2 is a correct explanation
for Statement – 1.
B) Statement – 1 is True, Statement – 2 is True; Statement – 2 is NOT a correct
explanation for Statement – 1.
C) Statement – 1 is True, Statement – 2 is False.
D)Statement – 1 is False, Statement – 2 is True
9. A bag is gently dropped on a conveyor belt moving at a speed of 2 m/s. The coefficient
of friction between the conveyor belt and bag is 0.4. Initially, the bag slips on the belt
before it stops due to friction. The distance travelled by the bag on the belt during
slipping motion, is :

[Take g = 10 m / s 2 ]

A) 2 m B) 0.5 m C) 3.2 m D) 0.8 ms

10. The voltage time (V – t) graph for triangular wave having peak value V0 is as shown in
figure.

T
The rms value of V in time interval from t = 0 to is :
4

V0 V0 V0 2V0
A) B) C) D)
3 2 2 

11. A hollow spherical shell at outer radius R floats just submerged under the water surface.
27
The inner radius of the shell is r. If the specific gravity of the shell material is w.r.t
8
8
water, the value of r is : (Given 3 19  )
3

8 4 2 1
A) R B) R C) R D) R
9 9 3 3

12. A very long solenoid of radius R is carrying current I(t) = Kteat  k  0 , as a function of

time  t  0 . Counter clockwise current is taken to be positive. A circular conducting coil

of radius 2R is placed in the equatorial plane of the solenoid and concentric with the
solenoid. The current induced in the outer coil is correctly depicted,
 A) B)

C) D)

13. For a nucleus ZA X having mass number A and atomic number Z

A. The surface energy per nucleon  bs  = a1 A2/3

Z  Z  1
B. The coulomb contribution to the binding energy bc  a2
A4/3
C. The volume energy bv  a3 A
D. Decrease in the binding energy is proportional surface area.
E. While estimating the surface energy, it is assumed that each nucleon interacts with 12
nucleons,
( a1 , a2 and a3 are constants)
Choose the most appropriate answer form the options given below;
A) C , D only B) B , C, E only C) A , B , C , D only D) B , C only
14. In a Vernier calipers having 10 VSD, the Vernier constant is 0.1 mm. when the jaws are
closed, zero of Vernier lies to the left of zero of main and 7th VSD coincides with a main
scale division. When a cylinder is placed between the jaws the main scale reading was
7.7 cm and Vernier scale read 8 divisions. What is the diameter of the cylinder?
A) 78.1 mm B) 77.5 mm C) 77.8 mm D) 78.5 mm
15. Two cylindrical vessels of equal cross – sectional area 16 cm2 contain water upto heights
100 cm and 150 cm respectively. The vessels are interconnected so that the water levels
in them become equal. The work done by the force of gravity during the process, is
[Take , density of water = 103 kg/ m3 and g = 10 ms 2 ]
A) 0.25 J B) 1 J C) 8 J D) 12 J
 3RT
16. In the expression for Vrms of a mixture of 2 gases at same temperature, Vrms  , the
M
molecular weight M is
A) Arithmetic mean of molecular weights
B) Harmonic mean of molecular weights
C) Geometric mean of molecular weights
D) Larger Molecular weight of the two
17. A particle executing SHM is given by equation x  A cos t    . When particle is at half
the amplitude with positive velocity initially, the initial phase  is
  5 5
A) B) C) D)
6 3 3 6
18. A monatomic ideal gas sample is given heat Q. One half of this heat is used as work
done by the gas and rest is used for increasing its internal energy. The equation of
process in terms of volume and temperature is
V2 V2
A) 3 = constant B) = constant C) VT 3 = constant D) V 2 T = constant
T T

19. Five point charges each + q , are placed on five vertices of a regular hexagon of side L.
The magnitude of the force on a point charge of value – q placed at the centre of the
hexagon (in newton) is
3 q2 q2 q2
A) Zero B) C) D)
4  0 L2 4  0 L2 4 3 0 L2

20. A disc has mass 9 m and radius R. A hole of radius R/3 is cut from it as shown in the
figure. The moment of inertia of remaining part about an axis passing through the centre
‘O’ of the disc and perpendicular to the plane of the disc is :

40 37
A) 8m R 2 B) 4m R 2 C) m R2 D) m R2
9 9
 SECTION-II
(NUMERICAL VALUE ANSWER TYPE)
This section contains 10 questions. The answer to each question is a Numerical value. If the Answer in the
decimals , Mark nearest Integer only. Have to Answer any 5 only out of 10 questions and question will be
evaluated according to the following marking scheme:
Marking scheme: +4 for correct answer, -1 in all other cases.
21. In the circuit shown below, the Zener diode is ideal and the zener voltage is 6V. The
output voltage V0 (in volts) is _______________

22. The energy (in eV) that should be added to an electron, to reduce its de – Broglie
wavelength from 110 9 m to 0.5 109 m will be x times the initial energy.

23. The X – Y plane be taken as the boundary between two transparent media M 1 and M 2 .
M 1 in Z  0 has a refractive index of 2 and M 2 with Z < 0 has a refractive index of 3.
A ray of light travelling in M 1 along the direction given by the vector

A  4 3 iˆ  3 3 j  5kˆ , is incident on the plane of separation. The value of difference
between the angle of incident in M 1 and the angle of refraction in M 2 will be
__________ degree.
24. A body of mass 500g moves along x axis such that its velocity varies with displacement
x according to relation v  10 x m/s. Force acting on the body is _____________ N

25. The disc of mass M with uniform surface mass density is shown in the figure. The centre
xa xa
of mass of the quarter disc (the shaded area) is at the position , where x is .
3 3
(Round off to the Nearest integer) [a is the radius of disc as shown in the figure]
26. A progressive wave travelling along the positive x - direction is represented by y  x , t  =

A sin  kx  t    . Its snapshot at t = 0 is given in the figure.

x
For this wave, if the phase  is then x is ___________.     0, 2
2

27. A circular disc reaches from top to bottom of an inclined plane of length ‘L’. When it
slips down the plane (without friction) , it takes time ‘ t1 ’. When it rolls down the plane

t2 3
with pure rolling , it takes time t2 . The value of is . The value of x will be ______.
t1 x

28. A thin rod having a length of 1 m and area of cross section 3 106 m 2 is suspended
vertically from one end. The rod is cooled form 210C to 160C . After cooling , a mass
M is attached at the lower end of the rod such that the length of rod again becomes 1 m.
Young’s modulus and coefficient of linear expansion of the rod are 2 1011 Nm2 and
2 105 K 1 , respectively. The value of M is _________ kg. (Take g = 10 m s 2 )

29. A uniform heating wire of resistance 36  is connected across a potential difference of

240 V. The wire is then cut into half and potential difference of 240 V is applied across
each half separately. The ratio of power dissipation in first case to the total power
dissipation in the second case would be 1 : x , where x is ___________.

30. M grams of steam at 100C is mixed with 200 g of ice at its melting point in a thermally
insulated container. If it produces liquid water at 40C [heat of vaporization of water is
540 cal/g and heat of fusion of ice is 80 cal/g], the value of M is ____________ grams.
CHEMISTRY MAX.MARKS: 100
SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer,
out of which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -1 if not correct.
31. In which of the following arrangements the order is NOT according to the property
indicated against it?

A) Al 3  Mg 2  Na   F   increasing ionic size

B) B  C  N  O  increasing first ionization enthalpy

C) I  Br  F  Cl  increasing electron gain enthalpy (with negative sign)

D) Li  Na  K  Rb  increasing metallic radius

32. Assertion : PbI 4 doesnot exist

Reason : Pb  I bond initially formed during the reaction does not release enough energy
to unpair 6S 2 electrons

A) Both Assertion and Reason are correct and the Reason is a correct explanation of the
Assertion

B) Both Assertion and Reason are correct but Reason is not a correct explanation of the
Assertion.

C) The Assertion is correct but Reason is incorrect

D) The Assertion is incorrect and Reason is correct

33. The incorrect order among the following is

A) Bond dissociation enthalpy (kj/mole): Cl2  Br2  F2  I 2

B)Melting point /K : I 2  Br2  Cl2  F2

C) Melting point/K : HF  HI  HBr  HCl

D) Electron gain enthalpy (kj/mole): Ne  Ar  Kr  Xe  He

34. Which of the following is not arranged in correct sequence?

A) MO, M 2O3 , MO2 , M 2O5  decreasing order of basic nature (M = d-block metal)

B) Sc, Ti,V , Cr , Mn  increasing order of highest possible oxidation state

C) d 5 , d 3 , d 1 , d 4  increasing magnetic moment

D) Mn 2 , Fe2 , Cr 2 , Co 2  decreasing stability

35. Which of the following is incorrectly matched? (Accoring to CFT)

Complex Number of unpaired electrons

I)  FeF6 
3
5

2
II) Cr  en 3  2

3
III) Co  NH 3 6  4

2
IV)  Mn  H 2O 6  5

A) III B) I C) IV D) II

36. The correct order of dipole moment is:

A) NH 3  NF3  CH 4  H 2O B) CH 4  NH 3  NF3  H 2O

C) H 2O  NF3  NH 3  CH 4 D) CH 4  NF3  NH 3  H 2O

37. The correct order of acidic strength character of the following compounds is
OH COOH COOH COOH

NO2 CH3
CN
I
II III IV

A) IV > III > II > I B) III > II > I > IV

C) II > III > IV> I D) I > II > III > IV

38.

 i C H CO O ,HBr

ii
6 5

2 2
CoF2
P

Br (major product)

Major product ‘P’ of above reaction, is:

A) B) C) D)

39.

(P)
Cl2 / hv

Cl2 / AlCl3

(Q)

Identify major product of both reactions P and Q respectively

CH2 Cl
Cl

B)
A)
Cl
Cl

Cl Cl

D)
C)

Cl Cl
Cl
40. Which of the reagents shown below would accomplish the following transformations?

OH
Br
1. A

2. B

a) A is H 3O  ; B is BH 3  THF ; H 2O2 / NaOH

b)A is NaOH ; B is BH 3  THF ; H 2O2 / NaOH

c) A is HBr in ether ; B is Hg  OAC 2 / H 2O; NaBH 4

d) Ais NaNH 2 ; B is Hg  OAC 2 / H 2O; NaBH 4

41.

OH
O
||
PBr3 1V
W 
 X  Mg

2 H3O
ether
Y C
H3CCl
 Z

Na2CrO
2 7

Product Z of above reaction is :

O
|| O
OCCH3 ||
OCCH3

A) B)

O
O ||
|| OCCH3
OCCH3

C) D)
42. The products of the following reaction are,

CH2OD CH2OH

A) B)

OD

COOD
C C

C) D) HO

A)A,B B) A,C C) A,D D) C,B

43. Consider the following sequence of reactions,

COOH
1.AlCl3
SO
 Cl2
 A2.
 
H O
BC ZnHg

onc.HCl, heat
C
3

CH2C6H5

The end product ( C ) is :

O
A) B) O

C6H5
C6H5

C) D)
44. The compound X  C7 H 9 N  reacts with benzene sulphonyl chloride to give
y  C13 H 13 NO2 S  which is insoluble in alkali. The compound X is :

NH2

NHCH3
CH3
A) B)

NH2
NH2

C) D)
H3C
CH3

45. The amino acid that cannot be obtained by hydrolysis of proteins is-
CH2COO

H NH3

A) HOOCCH 2CH  N H 3  COO 


B) SH
 

H2CCH COO

NH3
NH

C) N D) N H 3  CH 2 4 CH  NH 2  COO

46. A certain amount of a reducing agent reduces x mole of KMnO4 and y mole of K 2Cr2O7 in
different experiments in acidic medium. If the change in oxidation state in reducing
agent is same in both experiments, x : y is

A) 5:3 B) 3:5 C) 5:6 D) 6:5

47. The ionisation enthalpy of H atoms is 1.312  106 J / mol the energy required to excite the
electrons in the one of mole of hydrogen atoms from n  1 to n  2 is
A) 9.84  105 J / mol B) 8.51 105 J / mol
C) 6.56  105 J / mol D) 7.56  105 J / mol
 1 3
48. x2  y2  xy3 ; H r  30kJ
2 2

Entropies of x2 , y2 and xy3 are 60,40 and 50J K 1mol 1 respectively for the reaction. The
temperature in kelvin at which the above reaction attains equilibrium.

A)750 B) 650 C) 550 D) 880

49. Match the following if the molecular masses of X,Y,Z and W are same

[Solutions]

Column-I Column-II

(Solvent and its boiling point) (Molal elevation constant, Kb )

A) X 100 C 
0
P) 0.68

B) Y  27 C 
0
Q) 0.53

C) Z  253 C  0
R) 0.98

D) W 182 C 
0
S) 0.79

A) A  P; B  Q; C  R; D  S B) A  Q; B  P; C  R; D  S

C) A  P; B  Q; C  S ; D  R D) A  S ; B  Q; C  R; D  P

50. A solution is 0.1M in Cl  and 0.001M in CrO42 . Solid AgNO3 is gradually added to it.
Assuming that the addition does not change in volume and
Ksp  AgCl   1.7 1010 M 2 and Ksp  Ag2CrO4   1.9 1012 M 3. Select correct statement from the

following

A) Ag2CrO4 precipitates first because the amount of Ag  needed is low.

B) AgCl precipitates first because its K sp is high

C) AgCl will precipitate first as the amount of Ag  needed to precipitate is low.

D) Ag2CrO4 precipitates first as its K sp is low.

 SECTION-II
(NUMERICAL VALUE ANSWER TYPE)
This section contains 10 questions. The answer to each question is a Numerical value. If the Answer in the
decimals , Mark nearest Integer only. Have to Answer any 5 only out of 10 questions and question will be
evaluated according to the following marking scheme:
Marking scheme: +4 for correct answer, -1 in all other cases.
51. Percentage of aniline hydrochloride hydrolysed in its M/40 solution at 250 C is

2.303 RT
Given ;  EC H NH .HCl / H  0.18V ; 
 0.06 
 6 5 2 2
F 

52. How many compounds will give positive Lassaigne’s test ?

OH NH2 NH2 NH2 SH

O O

Cl I NH2
NH2

53. ----------- is the magnetic moment of a di valent ion in aqueous solutionswith atomic
number 26. (nearest integer)

54.

CH2 OH

CHOHCH3MgBr xCH4

CH2 SH (Excess)

What is the value of ' x ' in the above reaction?

55.

HO OH
O
O
||
CH3 CCH3 xHCHOK
OH

 C
HO
HO HO OH

x moles of HCHO consumed .

Value of  x  will be
56. a) Glycine b) Valine c) Leucine d) Cysteine

e) Arginine f) Methionine g)Lysine h) Try Ptophan

Sulphur containing amino acid x

Basic amino acid  y

Essential amino acid  Z

Find the value of

57. NaClO3 is used, even in spacecrafts, to produce O2 . The daily consumption of pure O2 by

a person is 492 L at 1atm, 300K. How much amount of NaClO3 , in grams, is required to
produce O2 for the daily consumption of a person at 1 atm,

300K?  Na  23gm / mol, Cl  35.5gm / mol  According to the following reaction.

NaClO3  s   Fe  s   O2  g   NaCl  s   FeO  s 

R  0.082 L atm mol 1K 1

58. Consider the following reaction

Na3 PO4   NH 4  2 MoO4  HNO3  dil   ' X '  canary yellow PPT  then calculate total number of
atoms of 15th group elements which are SP 3 hybridized in compound ‘X’.

59. How many grams of sucrose (mol. Wt. = 342) should be dissolved up to the nearest
integer in 100 gm water in order to produce a solution with 1050C difference between the
freezing point & boiling point temperature at 1 atm?
Unit : k f  2 K .kg mol 1; kb  0.5K .kg mol 1 

60. At a certain temperature equilibrium constant  Kc  is 16 for the reaction.

SO2 g   NO2 g   SO3 g   NO g  .If we take one mole each of all the four gases in one litre

container, then the % moles of NO2 at equilibrium is

MATHEMATICS MAX.MARKS: 100
SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer,
out of which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -1 if not correct.
61. If z is a complex number satisfying the equation z  i  z  i = 8, on the complex plane
then maximum value of z is

A) 2 B) 4 C) 6 D) 8

62. The system of equations

px+(p+1)y+(p-1)z = 0

(p+1)x+py+(p+2)z=0

(p-1)x+(p+2)y+pz=0 has a non – trivial solutions for

A) Exactly two real values of p. B) no real value of p.

C) Exactly one real value of p. D) infinitely many real value of P.

63. If two whole numbers are randomly selected and multiplied then the chance that the unit
place in their product is 0 or 5, is

A) 20% B) 16% C) 61% D) 36%

64. Consider the word ‘HALEAKALA’. The number of ways the letters of this word can be
arranged if

Column-I Column-II
a) All ‘A’ are separated p) 5
Keeping the position of each
b) q) 60
consonant fixed
c) All the vowels occur together r) 300
d) No two vowels are consecutive s) 900
Code:
A) a  s, b  p, c  p, d  r B) a  q, b  r , c  s, d  p
C) a  s, b  p , c  r , d  q D) a  q, b  r , c  s, d  s
65. Statement-I: Out of 21 tickets with numbers 1 to 21,3 tickets are drawn at random,
10
the chance that the numbers on them are in A.P is .
133

Statement-II: Out of  2n  1 tickets consecutively numbered, three are drawn at random,

the chance that the numbers on them are in A.P is  4n  10  /  4n 2  1 .

A) Statement- I is true, Statement-II is true, Statement-II is correct explanation of for

statement-I
B) Statement- I is true, Statement-II is true, Statement-II is not correct explanation of for
statement-I
C) Statement- I is true, Statement-II is false
D) Statement- I is false, Statement-II is true
66. A cubic polynomial y = f(x) is such that A(-1, 3) and B (1, -1) are the relative a
maximum and relative minimum points respectively. The value of f(2) is

A) 6 B) 4 C) 0 D) 3

67. If the surface area of a sphere of radius r is increasing uniformly at the rate 8cm2/sec,

then the rate of change of its volume is

A) Proportional to r B) Constant

C) Proportional to r D) Proportional to r2
 ^ ^ ^  ^ ^ ^
68. If V1  i  j  k; V2  ai  b j  c k where a, b, c  {-2, -1, 0, 1, 2}, then find the number of non-
 
zero vectors V2 which are perpendicular to V1

A) 18 B)24 C) 21 D) 12

69. Let L be the line passing through the point P (1,2) such that its intercepted segment
between the Co-ordinate axes is bisected at P. If L1 is the line perpendicular to L and

passing through the point  2,1 then the point of intersection of L and L1 is

 3 23   4 12   11 29   3 17 
A)  ,  B)  ,  C)  ,  D)  , 
 5 10  5 5   20 10   10 5 
70. Let f : R  R be defined by f ( x)  x3  3x  1 and g is the inverse of ‘f’ then the value of

g  (5) is equal to

A) 1 B) 1 C) 1 D) 1
6 36 6 36


1
x  x16  x8  2 x16  3x8  6  dx   2x  3x16  6 x8    C (Where C is constant of
1/8
71. If 24 24


integration and  ,  are coprime numbers) then the value of       is…

A) 51 B) 61 C) 71 D) 81
x

72. Let y = y(x) satisfy the equation y( x)   y(t )dt  x2 . The value of y(e) is equal to
1

A) 2e-2+e1-e B) 2e-1+e1-e C) 2e+2+e1-e D) 2e+1+e1-e

73. If the roots of the equation 72 x3  108 x2  46 x  5  0 are in A.P, then the difference between
largest and smallest root lies in the interval

1 1 1   1 
A)  0,  B)  ,  C)  ,1 D) 1, 2 
 2  2 2  2 

74. If the mean deviation about the median of the numbers a, 2a,…… 50a is 50, then
a equals:

A) 1 B) 2 C) 3 D) 4
13
1
75. The value of 
k 1    k  1     k 
is equal to
sin    .sin   
4 6  4 6 

A) 3  3 B) 2  3  3  C) 2  3  1 D) 2  2  3 

76. Suppose A1, A2, ….., A30 are thirty sets each having 5 elements and B1, B2, ….., Bn are n
30 n
sets each with 3 elements, let  Ai   B j  S and each elements of S belongs to exactly
i 1 i 1

10 of the Ais and exactly 9 of the Bj s . Then, n is equal to

A) 40 B) 54 C) 45 D) 27
  1 1 1
77. Let A be a non- singular matrix such that A1   4 6 8  , then the value of
100 100 99 
 
det  Adj  2 A    det  2 A  is

A) 8 B) 12 C) 16 D) 28

78. Let  ,      be the roots of the quadratic equation x 2  x  4  0 . If Pn   n   n . n  N

P15 P16  P14 P16  P152  P14 P15

then is equal to
P13 P14

A) 15 B) 16 C) 17 D) 18

79. Let f  x    x   1  x for 1  x  3 where [x] is the integral prat of x. Then the number
of value of x in [-1,3] at which f is not continuous is .

A) 0 B) 1 C) 2 D) 4

80. cos 1  cos  5    sin 1  sin  6    tan 1  tan 12   is equal to :

(The inverse trigonometric functions take the principal values)

A) 3  11 B) 4  9 C) 4  11 D) 3  1

SECTION-II
(NUMERICAL VALUE ANSWER TYPE)
This section contains 10 questions. The answer to each question is a Numerical value. If the Answer in the
decimals , Mark nearest Integer only. Have to Answer any 5 only out of 10 questions and question will be
evaluated according to the following marking scheme:
Marking scheme: +4 for correct answer, -1 in all other cases.
2 i
81. Let   e 3
and a, b, c, x, y, z be non – zero complex number such that

a+b+c=x

a + b  + c  2 =y

a + b  2 +c  =z
2 2 2
x  y  z
Then the value of 2 2 2
, is equal to
a b c
82. If f  x   ax3  9 x 2  9 x  3 is strictly increasing on R, then find the number of
integralvalues of ' a ' , a   5,100

x  0 y 1 z 1
83. The shortest distance between the lines x = y = z and   is then  =
1 1 0 

84. The locus of image of the point ( 2 , 2 ) in the line mirror x–y+1= 0 where  parameter is

 x  a  b  y  c  where a, b, c  I, then find the value of (a + b + c).

2

85. Two vertices of an equilateral triangle are (-1,0) and (1,0), and its third vertex lies above
2y
the x – axis. If the equation of its circumcircle is x2+y2-   =0, then find the value of
3
.
1 1 1 1
86.  1  x  4 dx   1  x  7 dx is equal to
7 4

0 0

87. Find the area of the region bounded by y   x  4  , y  16  x2 and the x  axis.
2

88. Let a and b are two positive real numbers such that a2 + b = 2, then the maximum value
of term independent of x in the expansion of (ax1/6 + bx-1/3)9 is

89. If lim x  x 2  x 4  1  2 x  exist and has value non – zero finite number L, then find
x   

the value of 2 .
L

90. Let A  1, 2,3, 4 and B  1, 2,3, 4 . If f : A  B is an one – one function and f  x   x for
all x  A , then the number of such possible functions, is
 Date: 28-12-23
Time: 3 HRS Max. Marks: 300
KEY SHEET
PHYSICS
1 B 2 B 3 A 4 A 5 B
6 B 7 B 8 B 9 B 10 A
11 A 12 A 13 A 14 A 15 B
16 B 17 C 18 A 19 C 20 B
21 5 22 3 23 15 24 25 25 4
26 2 27 2 28 60 29 4 30 40

CHEMISTRY
31 B 32 A 33 C 34 C 35 A
36 D 37 C 38 D 39 C 40 D
41 B 42 B 43 D 44 A 45 B
46 D 47 A 48 A 49 A 50 C
51 4 52 5 53 5 54 3 55 6
56 5 57 2130 58 4 59 68 60 10

MATHEMATICS
61 B 62 C 63 D 64 C 65 C
66 D 67 C 68 A 69 B 70 B
71 C 72 A 73 B 74 D 75 C
76 C 77 B 78 B 79 D 80 C
81 3 82 97 83 6 84 4 85 1
86 0 87 64 88 84 89 96 90 9
 SOLUTIONS
PHYSICS
1. I max  I1  4 I1  2 I1 4 I1  9I1
I min  I1  4 I1  2 I1 4 I1  I1
I1  I1 10 5 2  1
  
9 I1  I1 8 4   1
  2  1
 2
  2
 1
1
2. Total mechanical energy = - (potential energy)
2
[for circular orbits under central forces]
SQ T .M .E.A :T .M .EB
GMm1 GMm2
= : 
2r1 2 r2
= m1r1 : M 2 r2 = (4m) (4r) : (3m) (3r) = 16 : 9
 
3. F AB  F CD
1
4. I   0cE 2
2
 2 L  2M
5. New magnetic moment M '  m  2 R   m  
  

  
2u 50
6. Time of flight =  = 5 sec
g 10

r  f
foot ball
 
 2iˆ  5 ˆj  5 = 10iˆ  25 ˆj

r  f
player
   
 5iˆ  8 ˆj  2iˆ  4 ˆj  6 ˆj  2iˆ  3 ˆj = 9iˆ  21 ˆj

distance = 12  42 = 17
C
7. V2  , Q2  2C V2
C  2C
8. Conceptual
9.

N – mg = 0, f= N
f = ma  a =  g = 4 m / s2
22  02
u=0, =2  2  u 2 = 2as  s  = 0.5 m
2 4
 V0 4V0
10. (i) V  t V t
T /4 T
1/ 2
 T /4 2 
4V0  0
 t dt 
 V0
 Vrms = V 2  =  T /4  =
T  3.
dt 
 0 
11. In equilibrium, mg = Fe
FB  V 0 g and mass = volume x density
4 4
  R 3  r 3  0 g   R3  w g
3 3
 27
Given , relative density, 0 
w 8
  r 3  27
 1     W  W
  R   8
r3 8
 1 3 
R 27
r3 8 r3 8 19
1 3   3  1 
R 27 R 27 27
8
 r = 0.89 R = R.
9
12.   BA   0 ni  A = 0 n  kt e  t  A
d d
e   0 nAk  te t 
dt dt
= - 0 nAk t   a  e  e  t  = - 0 nAk  e  t 1   t  
 t

e  0 nAk  t
i=   e 1  t  
R R 
At t = 0 ,i  - ve
at t = 1 sec ,i  0

13. Surface energy per nucleon,

r 2 A2/3 1 a1
bs  
A A
 1/3  1/3
A A
 r  r0 A1/3 
A is incorrect
Contribution to binding energy by columbic forces is given by
a Z  Z  1
bc  2 1/3
A
B is incorrect
Volume energy, bv  A
C is correct
For (D), if we consider only surface energy contribution then option is correct.
Contribution then option is correct.
For € only 3 interactions contribute to surface energy.
14. Zero error = - (10 – 7) x 0.1 = - 0.3 mm diameter = 77.0 + 8 x 0.1 – (- 0.3) = 78.1 mm
15.

Effectively , 25 cm column of water from top of right vessel entered the left a = mgh
(h is height reduced of the COM)
= (16) (25) 10 3 g (25) x 10 2 = 1J
16. In the case of Vrms  of mixture,
N1  N 2
M mix  ( N1 , N 2 are number of molecules of gaseous 1 and 2) which is Harmonic mean
N1 N 2

M1 M 2
m  m2 n1M 1  n2 M 2
But M mix  1  which is the Arithmetic mean is used in velocity
n1  n2 n1  n2
of sound expression.
17. If the particle covers a further phase of 60C , it will be at the extreme.
  = 360 – 60 = 300 .
18. PdV = nCv dT
nRT
 dV = nCv dT
V
3 dT
=
2 T
 V 2 = CT 3 , where C is a constant.
1 q1 q2
19. F
4 0 r d2
9mR 2  mR 2 4mR 2  9mR 2  mR 2  1  
20. = -  
9 
= -    4 
2  18 2  9  2 
9mR 2  mR 2  9   9mR 2 mR 2 8mR 2
= -   2   =  = = 4m R 2
2  9  2 2 2
21. In the given circuit we can find the voltage across Zener diode which is reverse
biased

10 1K
Voltage across Zener diode (V) V  = 5 Volt
1K  1K
Thus the voltage across the Zener diode is less than the breakdown voltage
(given as 6V) i.e. V  VZ So, VO  V = 5 Volt
h h
22.  
p 2mE
 
23. A  4 3iˆ  3 3 ˆj  5kˆ

As incident vector A makes I angle with normal z – axis and refracted vector R makes r
. angel with normal z – axis with help of direction cosine
 
1  Az  1
 5 
i  cos    cos  
 A
   
2 2
 4 3  3 3  52 
 
 5 
cos 1    i  60
 10 
By shell’s law, we have
2 sin 60 = 3 x sin r  r = 45
Difference between i and r = 60 - 45 = 15
dV
24. V 2  100 x ; 2V = 100
dx
dV
V = a = 50 , F = ma
dx
25. Mass of element,
1  R 2 d
dm   R  Rd  dm 
2 2
 /2
R 2
 2R 
 x dm  2
d 
 3
cos  

xcm  = 0  /2
 dm R 2

0 2 d 
  /2

2R  cos  d 2R 2
 0
 /2
=  
3 3  
 d
0

4R
=  x = 4.
3
26. At t = 0 , x  0 , y = 0 , and velocity of particle is positive
 =  rad
27. When disc slides then acceleration , a1 = g sin  and, distance travelled
1 1
S  ut1  a1t12 = g sin  .t12 … (i)
2 2
Again , when disc do pure rolling
g sin  2  1 
a2  = g sin   I disc  mr 2 
I 3  2 
1 2
mr
1 1 2 g sin  2
 S = ut2  a2t22 = . g sin  .t22 = t2 … (ii)
2 2 3 3
From equation. (i) & (ii),
S g sin  t12 g sin  t22
=1= /
S 2 3
t 3
 2 =
t1 2
28. We have li  l f
Mgl YA T
 l  T   M=
YA g
2 1011  3106  2 105  50
 M=
10
 M = 60 kg
2
29. P  240
36
2
P1  240
18
2
P2  240
18
2
Ptotal  P1  P2  240
9
P 1

Ptotal 4
30. Using the principal of calorimetry
M ice L f  mice  40  0  Cw  mstream Lv  mstream 100  40  Cw
 M  540   m 1 100  40  = 200  80  200 1 40
 600M = 24000
 M = 40g
 CHEMISTRY
31. IP1 of Nitrogen is more than Oxygen
32. Reason: Pb  I bond initially formed during the reaction does not release enough energy to unpair
6S 2 electrons
33. Melting point/K : HI  HF  HBr  HCl
34. Magnetic moment more for d 5 configuration.  d1 ,d 3 ,d 4 ,d 5 
3 5 2
35. I) Fe  3d II) Cr  3d 4 III) Co
3
 3d 6 IV) Mo
2
 3d 5
36. CH 4  0,  NF3   NH 3   H 2O
37.
OH
COOH COOH COOH

NO2 CH3
CN I
IV
II III

Electron with drawing nature: -NO 2 > -CN

38.

39. Formation of (P) allylic substitution; Formation of (Q) electrophillic aromatic substitution
40. Elemination with NaNH 2 , followed by reaction with Hg  OAC 2 / H 2O; NaBH 4
41.
O

OH Br MgBr
  
V
eth
 er

  
OMgBr
P
Br3
  Mg
ether


W  X
Na2CrO
2 7

O
O H3O
CH3 OCl

O
OH
 Z O C CH3
V Y
42.

43. Formation of A – Nucleophilic substitution

B – EAS, Formation of C = Clemenson’s reduction.
44. 20 amines reacts with Hinsberg’s reagent forms alkali insoluble product
45. Protein is formed by  -amino acid, B is not amino acid
46. x5  y6  x : y  6 :5
47.
E1  1.312  106 J / mol
E1 1.312 106
E2   J mol 1
22 4
E   E2  E1 
1 3  1 3 
48. S  S xy3   S x2  S y2   50    60   40   40 Jk 1mol 1
2 2  2 2 
G  H  T S
H
G  0  T   750 k
S
49. Higher the B.P of solvent, normally higher is its K b value
50.  Ag   C     k sp ,  Ag   0.1  1.7  1010  Ag    1.7  109
2 2
k sp   Ag    cro42  ,1.9  1012   Ag   103  Ag    1.9  109  1.9  103
In AgCl  Ag   is low  so AgCl undergoes ppt.
0.06 PH 2
51. E  E0  log 2 
 Assu min g 2 H   2e   H 2 
n  H 


0.06 1
0.18  0  log 2
2  H  
 H    103 M

C6 H 5 N H 3  H 2O  C6 H 5 NH 2  H 3O 
C  x  M xM
3
x 10
h   0.04
C 1
40
 h  4%
52.
O

Cl I
NH2 SH H2N NH2
53. 4.9  5
54. RMg X reacts with acidic hydrogens forms alkane
E.g: OH ,  SH , COOH ,  NH 2 , C  CH

55. For each CH 2OH one mole of HCHO is consumed

56. Sulphur containing amino acid =2
Basic amino acid =2
Essential amino acid  6
226
M 5
2
1 492
57. Mole of O2 consumed   20 Mole of NaClO3 required = 20
0.082  300
Mass of NaClO3  20 106.5  2130 gm
58. X   NH 4 3 PO4 .12 MoO3
15th group and SP 3 hybridized atoms in X  4,  3, N  atoms  1 P  atom 
59. TB  TF  105
TB  100    0  TF   5
Tb  TF  5 Kb m  K F m  5
5 5 w  1000
m  2 ; w  68.4 gm
K b  K F 2.5 342  100
60.
SO2 g   NO2 g   SO3  NO g 
t0 1 1 1 1
t  eq 1  x 1 x 1  x 1 x

Kc 
 SO3  NO   16  1  x 2
 SO2  NO2  1  x 
2

3
 x  moles  0.6 mole
5
At equi nSO2  0.4nNO2  0.4 nSO3  1.6 nNO  1.6
0.4
% of nNO2   100  10%
4
 MATHS
61. If z  i  z  i = 8,

PF1 + PF2 = 8  z max  4

62. Has non – trivial solutions
  0
p p 1 p 1
  p 1 p p2 0
p 1 p  2 p
R2  R2  R1 ; R3  R3  R1
p p 1 p 1
1
 1 1 3 0  p
2
1 1 1
 Exactly one real value of p.
63. n(S )  100
n( E )  36
36
 PE   36%
100
64. A ' s  4 ; L ' s  2; E ' s  1; K ' s  1; H ' s  1
5!
a) 6 C4
2!
5!
b)
4!
c) AAAAELLKH
5! 5!

2! 4!
4! 5!
d) 
2! 4!

65. Total ways  2 n 1 C3 

 2n  1 .2n.  2n  1  n  4n 2  1
1.2.3 3
Let the three numbers a,b,c are drawn, where a  b  c and given a,b and c are in AP.
 2b  a  c....  i 
It is clear from Eq. (i) that a and c both are odd or both are even
 Favorable ways  n 1 C2  n C2


 n  1 n  n  n  1  n 2
1.2 1.2
n2 3n
 Required probability  
n  4n  1  4n 2  1
2

3
 Statement -2 is false
 In statement 1, 2n  1  21
 n  10
3  10 30 10
 Required probability   
4 10   1
2
399 133
 Statement -1 is true.
66. Let f ( x )   ( x  1)( x  1)   ( x 2  1)
Integrating on both sides, we get
 x3 
f ( x)     x   c
 3 
2
Now, f (1)  1  1  c …… (1)
3
2
Similarly, f (1)  3  3  c ….. (2)
3
 From (1) and (2) , we get
2c = 2  c = 1 and  = 3

 x3 
 f ( x)  3   x   1  x 3  3x  1
 3 
dS dr 1
67. S  4 r 2 ; 8 
dt dt  r
4 dv dr dv
Now, v   r 3   4 2  4r   r
3 dt dt dt
68. We have
 
V1.V2  a  b  c  0
But a, b, c  {-2, -1, 0, 1, 2}
Now (i) if a = 1, b = -1, c = 0, number 3!=6
(ii) if a = 2, b = -2, c = 0, number = 3!=6
3!
(iii) if a = 1, b = 1, c = -2, number = 3
2!
3!
(iv) if a = -1, b = -1, c = -2, number = 3
2!
Total = 18
70. g(5) = 1 f(1) = 5
f  1
g   5   
 
 f  1 
3

x  x16  x8  2 x16  3x8  6  dx

24 1/8
71.
Put 2 x 24  3 x16  6 x8  t
   54 ,   9 ,   8
72. Differentiate with respect to x.
y  x   y  x   2 x
dy
 y  2x
dx
I .F  e x
ye x  2 xe x dx

ye x  2  xe x  e x   C
y  2  x  1  ce  x
At x = 1, y(1) = 1,  c = e
Y = 2(x-1) +e1-x
73. 72 x3  108 x 2  46 x  5  0
Let root be a  d , a, a  d
3 1
3a  a
2 2
5 1
a  a2  d 2   d 
72 3
2
Difference .
3
74. Mean of a, 2a, 3a, ….. 50a
25a  26a 51
Median =  a
2 2
 xM  50  a 
51 51
 2a  a
50 2 2
51 51
+ ..... 25a  a  26a  a  .....
2 2
51  49a 47 a 45a a
 50a  a 2    ....    2500
2  2 2 2 2
(1  3  ....  49)a  25
25
1  49 a  25
2
25x25a=25
A=4
  k      
sin       k  1   
13
 6 4   6 4 
75. 2
    k 
k 1
sin    k  1  .sin   
4 6 4 6 
   13   
 2 cot  cot   
 4  6 4 
2  
3 1 .
76. If elements are not repeated, then number of elements in A1  A2  A3 .....  A30 is 30x5
30  5
But each elements is used 10 times, so S   15
10
If elements in B1, B2, ….., Bn are not repeated, then total number of elements is 3n but each elements
3n 3n
is repeated 9 times, so S   15 
9 9
n = 45.
78. Pn  Pn 1   n   n    n 1   n 1 
  n  2  2      n  2   2   
 4  n  2   n  2 
 Pn  Pn 1  4 Pn  2
 P15  P14  P16  P15   16
P13 P14
80.  4 tan 2 1

x   a  b  c  a  b  c 
2
81.
2 2 2 2
x  a  ab  ac  ab  b  bc  ca  cb  c ….. (1)
y   a  b  c 2  a  b 2  c
2
 
2 2 2 2
y  a  ab 2  ac  ba  b  bc 2  ca 2  cb  c ----- (2)
z   a  b  c 2  a  b  c 2
2
  ---- (3)
2 2
 x  y  z 3 a  b  c
2
 2 2 2

(As (1+  +  2 =0)
2 2 2
x  y z
 2 2 2
3
a b c
82. We have f  x   ax3  9 x 2  9 x  3
 f   x   3ax 2  18 x  9  3  ax 2  6 x  3
As f  x  is strictly increasing on R, So a  0 and Disc < 0  36 -12 a  0  a  3
So, a  [3,  )
Hence, number of integral values of a, a  [-5, 100] are 98.
x y z x y 1 z
83. The lines are   ,  
1 1 1 1 1 0

S .D 

C  a . bd  
bd

h   2 k  2 2    2  1
2

84.  
1 1 2
h  1  2 ----- (1)
k  2 1 ---- (2)
Put value of  from (1) and (2)
 2
 h 1 
 ; 4  y  1   x  1 .
2
k 1  
 2 
Hence, a = -1, b = 4 and c = 1.
85.

Let ABC be the given equilateral triangle. Then C must lie on the y – axis.
Let C   0, a  , Also, AC = AB. Therefore,

1  a2  2 or 1+a2 = 4 or a  3
 1 
Then, the centroid of ABC is  0, .
 3
But in an equilateral triangle, the circumcenter coincides with the centroid. Therefore, the
 1 
circumcenter is  0, .
 3
Also, Radius of circumcircle = C1B
2
 1  1 2
 1  0    0 
2
  1 3 
 3 3
Therefore, the equation of circumcircle is
2 2
 1   2 
 x  0   y     
2

 3  3
2y 1 4
or x 2  y 2   
3 3 3
2y
or x 2  y 2  1  0
3
1 1 1 1

 1  x7  4 dx   1  x  7 dx
4
86.
0 0

y  f ( x)  (1  x 7 )1/4  y 4  1  x7   x  1  y 4 
1/7

Hence functions are inverse of each other

1 1 1 0
I   f  x  dx   g  y  dy   f  x  dx   xf   x  dx
0 0 0 1
 1

Hence I    f  x   xf   x   dx  xf  x ]10  f 1  0

0

Aliter:
b b

As,  f ( x)dx   g  y  dy   bd  ac  where g  f 1

a c

(property of definite intergral)

  = 0.
1 0 1

 1  x7   7 1  x4  0   1  x7  7 1  x 4
4 4
So,
0 1 0

87. Clearly required area

0 4

 16  x  dx    x  4
2 2
 dx
4 0

4
 x  4
0 3
 x3 
 16 x   
 3 4 3
0

64 64
 64    64 square units.
3 3
3 r
88. Tr 1 9 Cr a 9 r b r x 2

 r  3 (for term independent of x)

 Term independent at x is equal to
9
Cr a 6 b 3
To get the maximum value of a6b3 use AM  GM

 a2   b 
3   3  1
3  3   a 
6 3 3
b
i.e,.    6 
6  3 
  a 6b 3  1  Answer = 9 C3
max

89. lim x
a x 2
 x4  1  2x2 
x 
x  1/ 2
2
 x4  1  2x

 lim x
a  x4  1  x2 
 2
  
x  1/ 2
4
 x  x 1  2x 
 
  1 
 1 4  4
a
 x 
 lim x 1 1/ 2

x 
 1 
1  1  4   2
 x 
1  1 1
 1 
 lim x 1  . 4  ........  1
2 2 x 
 2 x 
 For limit to exist and has value non – zero, we must have   1  4    3
1 1 1
and L   
2 2 2 4 2
1
L2 
32

  3  32  96
L2
90. Derangement
So, D (4) = 9