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PART A PHYSICS
1. Find the electric potential, at the centre of uniformly charged circular ring having charge Q and radius R.
Q
(a) Zero (b)
4 0R 2
Q Q
(c) (d)
4 0R 8 0R
2. A particle crosses the topmost point C of a vertical circle with critical speed; then the ratio of velocities at
points A, B and C is : C
(a) 3 : 2 : 1
(b) 5 : 3 :1 O B
90o
(c) 52 : 32 : 12
(d) 5: 3: 1 A
(c) 3 amp
1
(d) none of the above
6V
4. In the circuit below, A and B represent two inputs and C represents the output,
A
(c) 16 cm
(d) 20 cm Object
m2 A B
moment of inertia of the rod about A is ,
3
the initial angular acceleration of the rod will be
mg 3
(a) (b) g
2 2
3g 2g
(c) (d)
2 3
12. Two satellites of earth A and B each of mass m, are launched into circular orbits about earth’s centre.
Satellite A has its orbit at an altitude of 6400 km and B at 19200 km. The ratio of their potential energies
UA
is:
UB
(a) 1 : 1 (b) 1 : 2
(c) 2 : 1 (d) 3 : 1
13. The potentiometer wire AB shown in the adjoining figure is 100 cm long when AD = 30 cm, no deflection
occurs in the galavanometer. The value of R is:
6 S R
G
D
A B
(a) 6 + – (b) 9
(c) 14 (d)15
14. The magnetic field at point P due to an infinite hollow tube carrying a steady current of i ampere at all
points inside and outside along the periphery of the tube is:
0i
(a)
2r
i i
0i r
(b) P
4 r r1
r2
0i 1 1
(c)
2 r1 r2
0i 1 1
(d)
2 r1 r2
15. In the LCR series circuit, the voltmeter and ammeter reading are-
400 V 400 V
V
R = 50 C
100V, 50 Hz
A ~
A.C. generator
Intensity
and Q. The ratio of areas under the two curves P
and Q will be
(a) 1 : 16
(b) 4 : 9
(d) 16 : 81 D
21. An infinite current carrying wire passing through point ‘O’ and
C
perpendicular to the plane containing a current carrying loop
ABCD as shown in fig. The wire at ‘O’ carries an outward
current choose the correct option regarding the situation
P
(a) net torque on the loop is zero
O
(b) seen from ‘O’ the loop experiences clockwise torque about line OP B
(c) seen from ‘O’ the loop experiences anticlockwise torque about line OP A
(d) Direction of torque remains same if the direction of current in the wire at ‘O’ is reversed
22. A number of tittle droplets of water of surface tension T, all of same radius ‘r’ combine to form a single
drop of radius R and the energy released is converted into kinetic energy of the bigger drop. The final
velocity acquired by the bigger drop is than
6T(R r ) 2 Rr
(a) (b)
Rr 3 Rr
6T(R r ) 2 R r
(c) (d)
Rr 3 Rr
23. A tube of uniform cross section in the form of a semicircle of radius R is kept in a vertical plane. An ideal
fluid is in equilibrium subtending an angle ‘2’ at the centre ‘C’ of the circle. Angular frequency of small
oscillations of the liquid is given by :
g sin g sin
(a) (b) R 2
R R
g sin( 2) g sin
(c) (d)
R 2R
24. A uniform rod of mass ‘M’ and length a lies a smooth horizontal plane. A particle of mass ‘m’ moving at
a
a speed ‘v’ perpendicular to the length of the rod strikes it at a distance from the centre of the rod
4
and stops after the collision. The velocity of the centre of the rod
m M
(a) V (b) V
M m
m M
(c) V (d) V
M m Mm
25. A particle is projected at time t = 0 from a point ‘P’ with speed V 0 at an angle of 45 to the horizontal. The
v0
magnitude of angular momentum of the particle about the point ‘P’ at time t = is
g
mv 3
0 mv 3
0
(a) (b)
2g g
mv 3
0 mv 3
0
(c) (d)
2g 2 2g
26. When the tension in a metal wire is T 1 , its length is 1. when tension is T2 , its length 2 . The natural
length of wire is .
T2
(a) 1 2 (b) T1 1 T22
T1
T21 T12 T21 T12
(c) (d)
T2 T1 T2 T1
27. A charge ‘Q’ is divided into two parts which are then kept some distance apart. The force b/w them will
be maximum if the two parts are
Q Q 3Q
(a) each (b) and
2 4 4
Q 2Q
(c) and (d) e and Q – e where e = electronic charge
3 3
5 4
28. If one mole of a mono atomic gas is mixed with one mole of a triatornic gas . The
3 3
value of r for the mixture is
(a) 1.40 (b) 1.44
(c) 1.53 (d) 3.D
29. The radius of n’the Bohr orbit of hydrogen like atom of atomic number ‘Z’ is given by
n2h2 nh
(a) (b)
4 2kzme 2 4 kzme 2
2
n2h2 nh
(c) (d)
22kzme 2 2kzme 2
30. For hydrogen – like systems magnetic moment is n corresponding to the motion of an electron along
the n’th orbit. The ratio of the magnetic moment to the angular momentum is
2e e
(a) (b)
m 2m
e
(c) (d) none
m
PART B CHEMISTRY
31. The ionic strength of solution obtained by mixing 100 mL of 0.1 M Al 2(SO4)3 and 100 mL of 0.2 M
Na2SO4 is
(a) 2.1 (b) 1.05
(c) 0.21 (d) 0.105
32. An ideal gas at pressure P 0 in a vessel. If the masses of all the molecules are halved and their rms
speeds doubled, the resulting pressure P will be
(a) 4P0 (b) 2P0
P0
(c) P0 (d)
2
33. The radii of two of the first four Bohr’s orbits of the hydrogen atom are in the ratio 1: 4. The energy
difference between them may be
(a) either 12.09 eV or 3.4 eV (b) either 2.55 eV or 10.2 eV
(c) either 13.6 eV or 3.4 eV (d) either 3.4 eV or 0.85 eV
34. Two elements P and Q have half lives of 10 and 15 minute respectively. Freshly prepared sample of
mixture containing equal number of atoms is allowed to decay for 30 minutes. The ratio of number of
atoms of P and Q left in mixture is
(a) 0.5 (b) 2
(c) 3 (d) 1
35. The oxidation number of S in Na2S4O6 is
(a) +2.5
(b) +2 and +3 (two S have +2 and other two have +3)
(c) +2 and +3 (three S have +2 and one S has +3)
(d) +5 and 0 (two S have +5 and other two S have 0)
36. A gas X at 1 atm is bubbled through a solution containing a mixture of 1 MY and 1 MZ at 25C. If the
reduction potential of X > Y > Z, then
(a) Y will oxidise X and not Z (b) Y will oxidise Z and not X
(c) Y will oxidise both X and Z (d) Y will reduce both X and Z
37. The correct order of bond angles is
(a) PF3 < PCl3 < PBr3 < P3 (b) PF3 < PBr3 < PCl3 < P3
(c) P3 < PBr3 < PCl3 < PF3 (d) PF3 > PCl3 < PBr3 < P3
38. The species having bond order different than CO is
(a) NO– (b) NO+
–
(c) CN (d) N2
39. The relationship between osmotic pressure at 272 K when 10 g glucose (P 1), 10 g urea (P 2) and 10 g
sucrose (P3) are dissolved in 250 mL of water is
(a) P1 > P2 > P3 (b) P3 > P1 > P2
(c) P2 > P1 > P3 (d) P2 > P3 > P1
40. At 40C, the vapour pressure (in torr) of methyl alcohol (A) and ethyl alcohol (B) solution is represented
by:
P0
B
P = 120 XA + 138; where, XA is mole fraction of methyl alcohol. The value of X and
B
lim X A 0
P0
A
X are
A lim XB 0
(a) 138, 258 (b) 258, 138
(c) 120, 138 (d) 138, 125
41. A hypothetical reaction, A2 + B2 2AB follows the mechanism as given below;
A2 A+A ……(Fast)
A + B2 AB + B …….(Slow)
A + B AB …….(Fast)
The order of the overall reaction is
(a) 2 (b) 1
1
(c) 1 (d) Zero
2
42. What will be the order of reaction and rate constant for a chemical change having log t 50% s. log
concentration (a) curves as?
log t50%
(a) 0, 1
(b) 1, 1
(c) 2, 2 45
(d) 3, 1
43. For N2 + 3H2 2NH3, one mole of N2 and threelogmol
a
of H2 are at pressure of 4 atm. Equilibrium
pressure is found to be 3 atm. Hence, KP is
1 1
(a) 3 (b)
(0.5) (0.15) (0.5) (1.5) 3
33
(c) (d) none of these
(0.5) (1.5) 3
44. In an aqueous solution of volume 500 mL, when the reaction of 2Ag + + Cu Cu2+ + 2Ag reached
equilibrium the [Cu ] was xM. When 500 mL of water is further added, at the equilibrium [Cu 2+] will be
2+
(a) 2 x M (b) x M
(c) between x M and x/2 M (d) less than x/2 M
45. The pKa of acetyl salicylic acid (aspirin) is 3.5. The pH of gastric juice in human stomach is about 2-3
and the pH in the small intestine is about 8. Aspirin will be
(a) unionized in the small intestine and in the stomach
(b) completely ionised in the small intestine and in the stomach
(c) ionised in the stomach and almost unionised in the small intestine
(d) ionised in the small intestine and almost unionised in the stomach.
46. A reaction is A + B C + D. Initially we start with equal concentrations of A and B. At equilibrium we
find that the moles of C is two times of A. What is equilibrium constant of the reaction
(a) 1/4 (b) 1/2
(c) 4 (d) 2
47. A closed flask contains water in all its three states, solids, liquid and vapour at 0C. In this situation the
average K.E. of the water molecule will be
(a) maximum in vapour state (b) maximum in solid state
(c) greater in the liquid than in vapour state (d) same in all the three states
48. Starting with the same initial conditions, one mole of an ideal monoatomic gas expands reversibly from
volume V1 to V2 in two different ways. The work done by gas is w 1, if the process is purely isothermal, w 2
if purely isobaric and w3 if purely adiabatic, then
(a) w2 > w1 > w3 (b) w2 > w3 > w1
(c) w1 > w2 > w3 (d) w1 > w3 > w2
49. The heat of atomistion of PH 3(g) is 228 kcal mol–1 and that P2H4(g) is 355 kcal mol–1. The energy of the
P–P bond is (in kcal):
(a) 102 (b) 51
(c) 26 (d) 204
50. Product
(a) (b)
O
OH
(c) (d)
OH
OH
51. Possible products have been written against the following reaction
Me
CH2 HBr Me
Br
Me
Me
CH2 OH
H SO 4
+ H2O 2
O
52.
H2N O P
The main product is
O H
N
HO O O
(a) (b)
HO
O O
NH2
O
53. An inorganic mixture was treated with excess of dil. H2SO4. Effervescenses were produced. The solution
was heated till effervescences ceased. After this a small pinch of MnO 2 were added. Fresh
effervescences were produced. Select the correct statement/s
(a) Mixture contains CO32 ions only (b) Mixture contains C2O42 ions only
(c) Mixture contains SO32 ions (d) Mixture contains both CO32 and C2O42 ions
H (catalyst)
54. product is :
2 moles
CH3
(a) (b)
C=C
(c) (d)
57. Which of these compounds represents the major monochlorination isomer formed in the following
reaction?
CH3 Cl2
CH ?
CH3 hv
CH3
Cl
CH3
CH3
C
CH
(a) (b) CH3
CH3
Cl CH3
H3C
CH3 CH3
CH3 CI
(c) CH (d)
CH3 CH(CH3)2
Cl
A: CH(CH3)2
1 1 1
61. Let f1(n) = 1 + + +…..+ , then f1(1) + f1(2) + f1(3) + … + f1(n) is equal to
2 3 n
(a) nf1(n) – 1 (b) (n+1)f1(n) – n
(c) (n+1)f1(n) + n (d) nf1(n) + n
62. Reflection of the line a z a z = 0 in the real axis is
(a) az + a z = 0 (b) a z az = 0
(a) az a z = 0 (d) none of these
63. If P is a point on the rectangular hyperbola x2 y2 = a2, C is its centre and S, S are the two focii, then
(a) SP SP = CP2 (b) SP S' P = CP
(c) SP SP = PC2 (d) All of these
a2 1
64. If x2 + ax – 3x – (a + 2) = 0 has real and distinct roots, then the least value of is
a2 2
(a) 1/2 (b) 1/4
(c) 0 (d) 1
π 4
tan
r
65. Let Ir = x dx then I2 + I4, I3 + I5, I4 + I6, I5 + I7, …… are in
0
(a) A.P. (b) G.P.
(c) H.P. (d) A.G.P.
n log3 8
1 1
66. The last term in the binomial expansion of 3 2
is . Then 5th term from the
2 3
3. 9
beginning is
(a) 10
C6 (b) 2. 10 C 4
1 10 1 10
(c) C4 (d) C4
2 4
67. If b > a then equation (x – a) (x – b ) – 1 = 0 has
(a) both roots in (a, b) (b) both roots in , a
(c) both roots in (b, ) (d) one root in , a and the other in (b ,
).
68. The arithmetic mean of the roots of the equation 4 cos 3 x 4 cos2 x cos ( + x) 1 = 0 in the interval
[0, 315] is equal to
(a) 49 (b) 50
(c) 51 (d) 100
69. If a sin1 x b cos1 x = c, then a sin1 x + b cos1 x is equal to
π ab c(b a)
(a) 0 (b)
ab
π ab c(a b)
(c) /2 (d)
ab
70. The sum of the rational terms of (21/5 + 3 )20 is
(a) 71 (b) 85
(c) 97 (d) None of these
71. If the equations of the sides of a triangle are arx + bry = 1; r = 1, 2, 3 and the orthocentre is the origin
then
(a) a1a2 + b1b2 = a2a3 + b2b3 = a3a1 + b3b1
(b) a1a2 + b1b2 = a2a3 + b2b3 = a3a1 + b3b1 = 0
(c) a1a2 + b1b2 + a2a3 + b2b3 + a3a1 + b3b1 = 0
(d) None of these
72. If the lines ax + y + 1 = 0, x + by + 1 = 0 and x + y + c = 0 (a, b and c being distinct and different from 1)
1 1 1
are concurrent then the value of is
1 a 1 b 1 c
(a) 2 (b) 3
(c) 1 (d) 0
73. If points P (5, 3) and Q ( cos , sin ) lie on the same side of the line 2x + 4y = 8 then lies between
(a) ( 0, 2 ) (b) (, )
(c) 0, (d) None of these
2
74. The length of the latus rectum of the parabola 169[(x 1)2 + (y 3)2] = (5x 12y + 17)2 is
28 25
(a) (b)
13 13
27 26
(c) (d)
13 13
75. If , are complex numbers, then the maximum value of is
| |
(a) 1 (b) 2
(c) > 2 (d) < 1
76. If the maximum number of trials required to open all locks when there are n locks and n keys is 105,
then n =
(a) 13 (b) 15
(c) 35 (d) none of these.
77. In a certain test there are n questions. In this test 2 nk students gave wrong answers to atleast k
questions, where k = 1,2,…n. If the total number of wrong answers given is 2047, then n equals
(a) 8 (b) 10
(c) 15 (d) none of these.
78. The means of five observations is 4 and their variance is 5.2. If three of these observations are 1,2 and
6, then the other two are
(a) 2 and 9 (b) 3 and 8
(c) 4 and 7 (d) 5 and 6
79. Which of the following is a contradiction?
(a) (p q) (p q) (b) p (p q)
(c) (p q) p (d) None of these
80. The relation R on the set Z of all integers defined by (x, y) R x y is divisible by n is
(a) not reflexive (b) not symmetric
(c) not transitive (d) equivalence
1 125
81. Let the sequence < bn > of real numbers satisfy the recurrence relation: bn1 2bn ,b 0,
2 n
3 b
n
then nlim
bn
is equal to
(a) 0 (b)
2
(c) 5 (d)
3
x
2
1 1 1
82. lim e t dt
equals
x 0 x5 x 4
3x 2
0
1 1
(a) (b)
5 10
(c) 0 (d) 1
(b) Statement I is true, Statement II is true; Statement II is not a correct explanation for Statement I