JEE MAINS MODEL PRACTICE TEST

GRAND TEST - 1
(KEY SHEET)

PHYSICS

01) 4 02) 4 03) 2 04) 1 05) 4

06) 3 07) 1 08) 1 09) 2 10) 3

11) 4 12) 2 13) 3 14) 1 15) 1

16) 1 17) 4 18) 1 19) 1 20) 3

21) 3 22) 1 23) 2 24) 1 25) 1

CHEMISTRY

26) 4 27) 1 28) 3 29) 3 30) 1

31) 4 32) 1 33) 4 34) 2 35) 3

36) 1 37) 2 38) 4 39) 3 40) 1

41) 3 42) 4 43) 1 44) 4 45) 2

46) 2 47) 4 48) 3 49) 1 50) 3

MATHEMATICS

51) 3 52) 2 53) 2 54) 4 55) 4

56) 3 57) 3 58) 3 59) 4 60) 3

61) 1 62) 1 63) 4 64) 3 65) 2

66) 4 67) 1 68) 2 69) 2 70) 4

71) 4 72) 3 73) 4 74) 2 75) 1

 Mass of sphere without cavity,
PHYSICS HINTS & SOLUTIONS
      4
01. Sol: J  Pi  Pf  J  Pf  Pi M1   R 3
3

J  m [v 2  ( v1 )]  m [0.2v 1  v 1] Mass of portion which is removed,
 3
J  2  1.2  2  20  10  48 kgms1 . 4 R
M2      
3 2
02. Sol: I  nE  E
nr R
2 2
So I is independent of n. 2 2 R R 
I  MR   M2    M2    I  57 MR.2
2

5 5 2  2   140

05. Sol: Writing voltage equation from A to B,
dx
di q
VA  L   VB or 2  1 (1)  q  5
x dt C C
03. Sol.
 q  20 C .

1
06. Sol. As box is having power factor of and
A moving charge corresponds to an electric 2
current, using this concept we can overall circuit is having point of 1, so it
 means the box is inductive in nature.
determine the B at centre of disc. Consider
an elemental ring of radius x and thickness 1
dx on the disk. Charge on this elemental ring For box, cos   so tan   1
2
is,
X
dq  ( 0 x)  2xdx  20dx  x 2  tan   1  X  R
R
This elemental ring is equivalent to current
Since overall power factor is 1,
carr ying ring, having current
1 1
dq dq X X R
I  C C
T 2    x 2dx
0
 So impedence of box,

Magnetic field at centre of disk due to this 2 2

 1   1  2
 0I  0  0  Z  X  R   C    C   C
2 2

elemental ring is, dB    xdx

2x 2
2
R  0 0     R2 Z .
B   dB    xdx  0 0  100 C
0 2 2 2

 0 0R 2 V
 dE 0    A
. 07. Sol. ID 0 EA d
4 dt 0 t  t
12 4
0 VA 8.85  10  400  (60  10 )
 
td 106  (2  103 )

 1.062  102 A .
R/2 M1 R/2
 Z  0 0 0
R R M2 08. Sol:    [M L T ]
 k 
04. Sol.
 k 
[]   
Z
   2 
Further [p]    a    x
   64 

    k  Comparing with a  2 x we get

 []      
 p   Zp  2  2
  T  16s
Dimensions of k are same as that of energy.. 64 8 
 ML2T 2  T
Hence, []   1 2 
 [M0L2T 0] . There is a time difference of between t  2s
 LML T  2
09. Sol. Conceptual/Basic Question. to t  10s . Hence particle is again passing
10. Sol. PE of system when point mass is at A is, through the mean position of SHM where its
speed is maximum at t  10s .
GMm
Ui  
2R 4 2 32 2
 Vmax  A  4 2  A   m.
PE of system when point mass is at B is, /8 
GMm 16. Sol. The maximum error in the measurement
Uf   will be equal to least count of the instrument.
5R
Work done by gravity force on point mass as it V  bh
moves from A to B is, Taking log and differentiating on both sides
we get.
GMm  1 1 
Wgravitation  dU  (U f  U i )   V  b h 0.1 0.1 0.1 0.7
R  5 2        
V  b  10 20 5 20
From work energy theorem,
V 0.7
K  0  Wgravitational force  Wexternal %   100  3.5% .
V 20
GMm  1 1  17. Sol. Carrier frequency is always greater than
Wexternal   Wgravity    .
R  2 5  modulating frequency (i.e., audio frequency),
so option D is appropriate carrier frequency.
11. Sol. As the energy of incident particle is less
18. Sol.
than 20.4 eV  2 Emin so the collision would
be an elastic one and hence the KE of neutron P
after collision is zero. B(3T0)
3P0 C(6T0)
12. Sol. A  A 0e t
P0 A
A0 D(2T0)
After 1 Hour,  A 0e  (T0)
3
V0 2V0 V
4  A
After 4 hours, A  A 0e  0.
9 Monoatomic
13. Sol. Let  is the density of material of sphere, 3 5
then from equilibrium equation,  f  3  CV  R , CP  R
2 2
4 3 2 2 Wnet  Area of ABCDA
r g  r 3  13.6g  r 3  0.8g
3 3 3
Wnet  2P0 V0  2nRT0
   7.2gm / cc .
Qinput  QBC  Q AB
14. Sol. Pmax  VzIz (max)
 nCP (6T0  3T0 )  nCV (3T0  T0 )
P 3
Iz (max)  max  364  10  40 mA .
Vz 9.1 5  3 
 Qinput  n  R  (3T0 )  n  R  (2T0 )
2  2 
15. Sol. Acceleration of particle is
 Wnet 2nRT0 4 VZ 50
   3) Load current IL  R   5  103 A
Qinput 21 nRT 21 . L 10  103
0
2
Vin  VZ
 u  1 9.5 u Current through R  i 
19. Sol.  A   10u    R
 2f f
70
  14  103 A
 u  1 10.5 u 5  103
 B   10u   
 2f f
According to the Kirchhoff’s first law I  IL  IZ
 A 19  Zener current,

 B 21 .
I Z  I  I L  14  103  5  103  9  103  9 mA .
20.Sol: In the figure shown, the cycle is 23. Sol. The fish can obser ve the sky only if
clockwise, thus net work is done by the refraction takes place. If TIR takes place then
gas. As in a cyclic process no change in image of sky can’t be observed.
internal energy takes place thus heat
supplied is equal to the work done by the 
gas in one complete cycle so in this case i  ic & ic  45 . So angle subtended  .
2
heat supplied to the gas is given as
24. Sol: Heat given out when 5 g water ar 30°C cools
Q = Work done by the gas W down to 5 g water at 0°C
= Area of ellipse  ab
H1  5  1  30  150 cal
Where ‘a’ and ‘b’ are semi major and semi-
Heat required by 5 g ice to melt to water at
minor axis of the ellipse which are given
from figure as 0°C H2  (5  0.5  20)  (5  80)

a  1.0  105 N / m and b  100  106 m3  50  400  450 cal

Thus area of ellipse is Since this much heat is not available, the
temperature of mixture = 0°C.
Q  W    1.0  10 5  100  10 6
25. Sol. Let the ball hits the n th step then using
 3.14  10  31.4 J . equation of trajectory
21. Sol: In steady state the circuit would be like as 1 gx 2
shown in figure y  x tan  
2 u2 cos2 
2
I 12V 1 10(100  n)2
We have n  (100  n) 
2 (15 5 )2  1
2

I
Solving we get n  6.05 . Hence ball will hit 7th
6
step.

12 3 CHEMISTRY HINTS & SOLUTIONS

I  A 26. Sol. In ACB process, AC process is isochoric, so
8 2
Potential difference across capacitor is, WAC  0 .
V  6I  9 volt . So, EBC  qBC  WBC
q  18 C . 30  qBC  (20)
22. Sol. 1) Output voltage across the load will be
qBC  50 J
same as that across the zener diode and the
voltage across zener diode remains constant Now, q AB  q AC  qCB
equal to its zener voltage. So, output voltage,
70  q AC  50 (since for path BDA,
VZ  50V
2) Voltage drop across series resistance E A  E B  q  W  60  10  50 J and
WACB  20J .
R  Vin  VZ  120  50  70 V
So, qAB  E AB  WACB  50  20  70 J ) qAC  20 J .
27. Sol. P is related to sp3 - hybridised C-atom, Q is second layer (diffused layer).

related to sp2 -hybridised C-atom and R is 34. Sol. 2NaBH4  I2  B2H6  2NaI  H2
(X) (Y) (Z)
related to sp-hybridised C-atom.
28. Sol. For first order reaction, 450 K
2BF3  6NaH   B2H6  6NaF
(X) (P)
2.303 a 2.303 400
k log  log
t (a  x ) 200 25 4BF3  3LiAH4  2B2H6  3LiF  3AF3
(Q) (R)
.
(X)
2.303
  1.204  0.01386 s1  1.386  102 s1 . 35. Sol. One CHO is oxidised to COO and one CHO
200
is reduced to CH2OH . Thus, it is not a
29. Sol. For an ideal solution,
disproportionation reaction. It is intramolecular
(i) G  0 ; for mixing
redox reaction. Thus, options (a) and (b) are
(ii) Ssystem  0 ; because disorder increases CHO
(iii) S surr  0 ; no heat is exchanged in case of true and is reducing as well as oxidising
CHO
ideal solution
agent. Thus, (d) is also true. Thus (c) is
(iv)  mix  0 . incorrect.
30. Sol. Reactivity  stability of carbocation. 36. Sol. Au  2CN   H2O  1 / 2O2
31. Sol. (i) Since A gives characteristic colour with
[Au(CN)2] ( X)  2OH ;

aqueous FeC 3 so it contains a phenolic group.
(ii) Since A when treated with Br2 forms 2[Au(CN)2]  Zn  [Zn(CN)4 ]2 (Y)  2Au .

C7H5OBr3 (ppt.) and considering the molecular 37. Sol.1 & 4 are reducing sugar as one
monosaccharide has free reducing group
formula of A, it is most likely to be cresol.
because glycosidic linkage is (1, 4). Whereas
CH3 in 2 & 3 both the reducing groups are involved
C6H4 in glycosidic bond formation.
OH
38. Sol. NHCOCH3 Is more activating than isopropyl
(iii) Since A on bromination forms tribromo group.
CH3
39. Sol. Conceptual/Basic Question.
derivative so, it is m-cresol i.e. 40. Sol. Solubility of sulphate decrease down group
OH
2 with decrease in hydration energy.

The reaction are: 41. Sol. CO2 is an acidic oxide, Co is neutral and BeO
is an amphoteric oxide.
NaHCO3 Cresol is a weak acid so no 42. Sol. Conceptual/Basic Question.
Weak base reaction
CH3 43. Sol. If CFSE ( o )  P (Energy required for
NaOH CH3 pairing), the electrons do not pair up and fourth
C6H4 (Soluble in NaOH)
Strong base ONa
OH
electron goes to e g of higher energy. Hence,
A CH3 high spin complex is formed. Pairing of
Br Br
Bromination electrons does not take place in case of weak
field ligands.
OH
Br
44. Sol. Plastics are non-biodegradable, hence are
not environmental friendly.
Distance travelled by substance from base line (x)
32. Sol. Rf 
Distance travelled by solvent from base line (z) 45. Sol.  2Na  replaced by one Sr 2 ;

x y 1 mole of NaC contain 107 mole of Sr 2

For x : R f  ; For y : R f  .
z z 7
 Number of cationic vacancies  10  N A .
33. Sol. As excess of KI has been added, I  ions are
adsorbed on AgI forming a fixed layer (and 46. Sol. pH  5 , [H ]  105 M
giving it a negative charge). It then attracts the
105
counter ions (K+) from the medium forming a After dilution   108 M
1000
 Total [H ]  108  107  1.1  107 T1  273 K T2  273  20  293 K

pH   log[H ]   log(1.1  107 )  6.96 . P1V1 P2 V2

Applying ideal gas equation, T  T
1 2
47. Sol: Total number of electrons  2n2
If n  4 , number of electrons = 32 1  0.1867 0.987  V2

1 273 293
Total number of electrons with ms  will be
2 293 1  0.1867
V2    0.2030 L  203 mL .
16. 0.987 273
48. Sol. 100 mL gaseous mixture contain 20 mL C3H 8 MATHEMATICS HINTS & SOLUTIONS
So, volume of CH4 and CO  (100  20)  80 mL 51. Sol: Conceptual/Basic Question.
52. Sol: Conceptual/Basic Question.
C3H8  5O2 
 3CO2  4H2O 53. Sol: Conceptual/Basic Question.
1 54. Sol: Conceptual/Basic Question.
 CO2  2H2O ; CO  O2 
CH4  2O2   CO2 55. Sol: Conceptual/Basic Question.
2
80 mL ( CH4 and CO) will produce 80 mL CO2; 56. Sol: Let xy  yz  zx   . Then, x 2  y 2  z2  

C3H 8 will produce  3  20  60 mL 1

 [(x  y)2  (y  z)2  (z  x )2 ]  0
Total CO2 produce  80  60  140 . 2
49. Sol. At equilibrium  1   0

0.0591 [Cu ]2 Again, (x  y  z)2  x 2  y 2  z2  2  1  2

0
E 
1 log10
1 [Cu ]  1  2  0 .
2 2
0.0591 104 57. Sol:  y  x  1  y  (x  1)
 log  0.254
1 2.02 Change x by –x, then required image is
2 2
E10  E0Cu2 /Cu  E0Cu /Cu and y 2  ( x  1)2  y  x  1  2x

E0Cu2 /Cu  ECu

0 or x 2  y 2  2x  1  0 .

E0Cu2 /Cu  /Cu

2 2 1
58. Sol: tan2 x   ( 2  1)2
0 0 0
So, E1  2ECu2 /Cu  2ECu  /cu 2 1

E0Cu /Cu  0.457   

 tan2  tanx  tan    .
8  8
E0Cu/Cu   0.457 . 59. Sol: Required limit
50. Sol; The reaction between aluminium and caustic
 sinx 2 2 
soda is  sin2x 2x x  x  2 5
 lim    x2   1  .
2A  2NaOH  2H2O  2NaAO2  3H2 x 0
 2x 3x sinx 3
3 3
2  27  54g  3
 x 3 
3  22.4 L at STP  x 

 54 g of A produces H2 at STP  3  22.4 L 60. Sol: Curves are y 2  4x ––––– (1)

0.15g of A will produce H2 at
and x 2  y 2  6x  1  0 ––––– (2)
3  22.4
STP   0.15  0.186 L . dy 2
54 From (1), 
dx y
At STP Given conditions P1  1atm
P2  1 bar  0.987 atm dy 3  x
From (2), 
dx y
V1  0.186 L V2  ?
 dy For even divisor at least one 2 should be selected.
At (1, 2), for curve (1)  1  m1 (say)
dt  Required number  3(2  1)(1  1)  18 .

dy 9!
and for curve (2)  1  m2 (say) 65. Sol: n(S)  and n(E)  3!
dt 4! 3!2!
Since m1  m 2 , therefore the two curves have a (3!)(4!)(3!)(2!) 1 .
 P(E)  
common tangent at (1, 2) i.e., they touch each 9! 210
other at (1, 2).
sinx 1 dx
n 66. Sol: I   dx  
 1  sin4x 4 cos x  cos2x
61. Sol: The last term  nCn    
 2
1 cosx
  dx
log 3 8 4 (1  sin x )(1  2sin2 x )
2
 1  (from the question)
 3 
 3 9  Putting t  sinx  dt  cos x dx

1
n/2
 1 
log 3 8 1 dt 1  2 1 
 ( 1)n      5/3  I
4  (1  t2 )(1  2t2 ) 4   1  2t2 1  t2 
  dt
2 3 
5 5 1
 3log 3 2 5  1 t
3 3
 3log3 2  25    1 dt 1 dt 1 1 1 1 t
 2  1 2     ln 2  ln C
2
4 2 1
4 2  t 4 1t  t 8 1 t
 n  10 . 2

62. Sol: For non-trivial solution, we must have

1 1  2 sinx 1 1  sinx
2a 2 3  ln  ln C.
4 2 1  2 sin x 8 1  sinx
1 a 2 0
2 0 a 2 dy
67. Sol: Since, xy  c  x y 0
dx
 2a(a 2  0)  2(a  4)  3(0  2a)  0 Thus D.E. of orthogonal trajectory is,
 2a 3  2a  8  0  6a  0  2a 3  4a  8  0 dx
x  y  0  y dy  x dx  0  y 2  x 2  a .
 a 3  2a  4  0 dy

 a 3  2a 2  2a 2  4a  2a  4  0 xh yk
68. Sol: Equation of tangent at P(h, k) is  1
 a 2 (a  2)  2a(a  2)  2(a  2)  0 a 2 b2

h2 k 2
 (a  2)(a 2  2a  2)  0  a  2 . Where   1 , i.e., b 2h2  a 2k 2  a 2b 2
a 2 b2
63. Sol: [cot1 x]  2[tan1 x]  0 Solving it with circle, we get
1 1
 [co t x]  0 , [tan x]  0 
2
yk  a 4
y 2   1  2   2  a2
or [cot 1 x]  2 , [tan1 x]  1  b  h

If [cot 1 x]  0 , then x  (cot1,  )  y2 (b4h2  a4k2 )  2ya4b2k  a2b2 (a2b2  b2h2 )  0

Since, it’s roots are y1 and y 2 , thus

If [tan1 x]  0 , then x  [0, tan1)
1 1 2a 4 b2k 2a 4 b2k 2
 [cot1 x]  [tan1 x]  0  x  (cot1, tan1)   2 2 2 2  2 2 2 2

2 2
y1 y 2 a b (b h  a b ) a b  a k k
If [cot 1 x]  2 , then x  (cot 3, cot2)
x 7 2
If [tan1 x]  1 , then x  [ tan1, 0)  tan  .
2 3
Since, no such x-exists thus the solution set is 69. Sol: D is the root of altitude drawn fro C to side
(cot1, tan1) . AB. Since triangles BAA 1 and BDC are similar
64. Sol: 504  23  32  71 therefore,
 C
x
It is clear that graphs y  2  x and y  3 cuts
A1
at four points.
 No. of solutions is 4.

B A D
74. Sol: If both positive, then

AD  AB  C x  y  1  2x  y  1  1  3x  2y  3

BA 2c AD x y
cosB   cos(   A)    1
BA1 a , AC 1 3/2
If first positive and second negative, then
c 2c c
  cos A   cos A  cosB   (x  y  1)  (2x  y  1)  1
b a b
 x  1  0  x  1
2bc  ac c
  (2b  a) . If first negative and second positive, then
ab ab
(x  y  1)  (2x  y  1)  1
   
70. Sol: (3a  b)  (a  4b)
Y
2    2 3
 3 a  11a  b  4 b
2
3 /2
 3.36  11.6.8 cos   4.64  0
 
 Angle between a and b is acute 3x  2y  1 3x  2y  3

1 /2
 The longer diagonal is given by
       X'
1 O 1/3 1
X

  (3a  b)  (a  4b)  4a  3b 1

 2   2 2  2   Y'
Now,   4a  3b  16 a  9 b  24a  b
 x 1  0  x  1
 16.36  9.64  24.6.8 cos   16  144 If both negative, then
  (x  y  1)  (2x  y  1)  1
 4a  3b  48 .
x y
NUMERICAL VALUE QUESTIONS:  3x  2y  1  0   1
1/ 3 1/ 2
f(x  h)  f(x )  Required area
71. Sol: f '(x )  lim
h 0 h
  14  1 2
   2  3     2    1
f(x )  f(h)  f(x ) f(h) 2  2 3  2 3
 lim  lim
h0 h h 0 h
4 1
2
(2h  3h)g(h)  3   3  1  2  0  2 sq. units
 lim  lim(2h  3)g(h) 3 3
h 0 h h 0
Alternative method:
 (0  3)g(0)  3g(0)  3  3  9 . 1  3 1 3x 
Required Area     x      dx
72. Sol: iz  z1  i(z  i)  z1  1 1
 2   2 2 

 i(z  i)  z1  1  z  i  z1  1 1 1 1
  1 dx  x dx  2  0  2 sq. units .
1 2 1
 2  4  3i  2  5  7 .
75. Sol: For the two circles to intersect orthogonally,
x x
73. Sol: 3  2  x  1 or 2  x  3  y (say) 2  1  0  2  k  k  6  k  2k 2  k  6  0
y 3
 k  2 or  .
2
2
y  2 x
1 ***THE END***
x
y 3
x' x
2 O
y'