JEE MAINS MODEL PRACTICE TEST

JR.GRAND TEST
(KEY SHEET)

PHYSICS

01) 4 02) 2 03) 2 04) 2 05) 1

06) 1 07) 2 08) 2 09) 2 10) 1

11) 2 12) 1 13) 2 14) 3 15) 4

16) 2 17) 2 18) 2 19) 2 20) 4

21) 3 22) 1 23) 4 24) 4 25) 1

CHEMISTRY

26) 1 27) 3 28) 2 29) 1 30) 4

31) 1 32) 2 33) 4 34) 2 35) 1

36) 4 37) 2 38) 3 39) 3 40) 3

41) 2 42) 1 43) 2 44) 3 45) 1

46) 1 47) 3 48) 3 49) 2 50) 3

MATHEMATICS

51) 3 52) 3 53) 2 54) 2 55) 1

56) 3 57) 3 58) 3 59) 3 60) 3

61) 2 62) 1 63) 3 64) 2 65) 3

66) 3 67) 3 68) 4 69) 4 70) 2

71) 2 72) 3 73) 4 74) 1 75) 4

PHYSICS HINTS & SOLUTIONS
1 1
01. Hint: mv 2  f  s  f  N  s  at2 .
2 2

u2
02. Hint: H1  H2  30  H1  H2  .
2g
03. Hint: It is moving with uniform velocity. Net force is zero.

B B
04. Hint: (C  x )2 is equal to workdone, C is displacement.   ML2 T 2
2
(C  x )
 W y
05. Hint:   heat absorbed  100 mg sin   khy  I  sin   tan   .
h

W  Area under p-v Diagram 1 1  k2 

19. Hint: Total energy T.E  kx 2  mv 2  1  2 
2 2  r 
Heat absorbed  Q AB  QBC
d(E)
3 0
QAB  nc v1 dT  nR(TB  TC ) ; dt
2
k
5  a x
QBC  ncpdT  nR(TC  TB ) .  k2 
2 m 1  2 
 r 
5nR
06. Hint: Q AB  ncpdT  (2T0  T0 )  k2 
2 m 1  2 
 r .
1 T  2
QBC  nR2T0 n    WBC k
2
20. Hint: Shearing stress  sin 2
QBC  nR2T0 n2 .    45 .
21. Hint: mg sin    N
T2 50 500
07. Hint:   1    1  T1  1000K mg sin    mg cos  .
T1 100 T1
v 2  v1 60  20
60 T 22. Hint:   t  t  40  30 .
  1 2 . 2 1
100 1000
23. Hint: F  30  mg(40)
x  ( 10) 40 F  3920 N .
08. Hint:  .
90  ( 10) 100
p  2
09. Hint: 2(90   )    0 24. Hint: V  ;   1   .
  f
10. Hint: Heat lost by the hot body = Heat gained
Q KA( 1  2 )
by the cold body. 25. Hint:  .
t 
2AT
11. Hint: F  ; m  v  ( Ad)
d
CHEMISTRY HINTS & SOLUTIONS
12. Hint:
L L L   L 2L   L 3L   L 2L  L L  L Number of moles of solute  1000
m   m     m     m     m    m   
2  2 10   2 10   2 10   2 10   2 10  2
26. Sol: Molarity 
x cm 
7m
Volume of solution (in mL)

 1 M H2SO4 contains 1 mole of H2SO4 in 1000

u cos 
u u mL of solution

13. Hint:  0.02 M H2 SO4 in 100 mL of solution contains
u sin  u sin 
0.02  100
  2  103 mol
  v x2  v y2 1000
20
 2  10 3  6.022  1023  12.044  10 molecules .
v x  u sin  ; v y  eucos  27. Sol: Conceptual/Basic Questions.
490 28. Sol. If Qc  K c , reaction is in equilibrium.
14. Hint:  mgh .
2
29. Sol. (i) is a dimer of BeC 2 in vapour phase.
16. Hint: T 2  r 3 .
(ii) is a chain structure of BeC 2 in solid state.
17. Hint: y  A sin t .
30. Sol: Conceptual/Basic Questions.
18. Hint:   I for small angular displacement
‘’
  NH 4OH  HC
44. Sol: NH4C  H2O 
31. Sol: 3B2H6  6NH3  3 [BH2 (NH3 )2 ] [BH4 ]
(X)
Heat Ch2
kh  k h is constant
2B3 N3H6  12H2
1 h
(Y)
kh
1 h  1 k h  Ch2 h
32. Sol: Ionisation enthalpy of B  C but N  O C
due to half-filled orbitals in N which have extra as 3 increases h decreases.
stability. Electron gain enthalpy of C  F due
 Answer is (3).
to bigger size and lesser electronic repulsion.
45. Sol: Conceptual/Basic Questions.
33. Sol: Conceptual/Basic Questions.
46. Sol: Let atomic mass of X is ‘a’ amu
34. Sol: V1  68.6 mL , P1  756 mm , T1  300 K ,
(4a  96)g X 4O6 –––––––– 4a g X
V2  ? , P2  760 mm , T2  273 K
 4a  10 
P1V1 P2 V2  10g X 4O6 ––––––––  g X
  4a  96 
T1 T2
4a  10
At NTP, volume of N2 ,  5.72  a  32 .
4a  96
P1V1 T2 756  68.6 273 47. Sol:
V2      2NO2(g )
N2O4(g ) 
T1 P2 300 760  62.09 mL
Initial conc. 18.4 0
Percentage of nitrogen in organic
No. of moles 18.4
 0.2
28 V 92
  2  100
22400 w
At equilibrium 0.2  0.1 2  0.1
28 62.09  0.1  0.2
compound    100  14.93% .
22400 0.52
35. Sol: For hydrogen bonding, the size of the 0.2  0.2
atom should be small. Kc   0.4 .
0.1
36. Sol: 48. Sol: Vander Waals equation is
 a 
4n  2  4 or 4n  4  2  2 , n  0.5 .  P  2  ( V  b)  RT
 V 
37. Sol: Conceptual/Basic Questions.
As given that b  0 ;
Br
a a
PV   RT  PV  RT 
HBr V V
Mark addn.
A Comparing with y  mx  c , Intercept (c) = RT,,
38. Sol: Slope (m)  a
HBr, h
Anti. Mark addn.
Br y 2  y1 20.1  21.6
Slope    1.5 .
B x 2  x1 32

39. Sol: 2KMnO4  3H2SO4  K 2SO4  2MnSO4  3H2O  5[O] Thus, a  1.5 .
[H2O2  O  H2O  O2 ]  5 49. Sol: Here n2  5 and n1  2 . So longest
Hence, 1 mole of KMnO4 requires 5/2 moles wavelength means least energy difference
H 2O 2 transition i.e., n2  5 to n1  4
40. Sol: Conceptual/Basic Questions. 1  1 1 
41. Sol: Conceptual/Basic Questions.  R H (1)2  2
 2 
  (4) (5) 
42. Sol: Conceptual/Basic Questions.
43. Sol: Conceptual/Basic Questions. So,   4  10 6 m .
  2Z
50. Sol: X  3Y   
 cos2  sin2  cos   2 
S  2  50  (60  3  40)  80 kJ 2 

G  H  TS when G  0  One solution is 2 


 2
2
H 1000
T  40   500 K .
S 80 
or     .
4
MATHEMATICS HINTS & SOLUTIONS 57. Sol: Given ( 3  1)cos   ( 3  1) sin   2
51. Sol: Given Df  (0, 1)  0  x  1
Here a  3  1 , b  3  1 , c  2
x
 0  e  1 and 0  ln x  1
 a 2  b2  2 2
   x  0 and 1  x  e
c 1 
 cos1  cos1 
 x  ( , 0) and x  ( e,  1)  (1, e) a b2 2
2 4
 x  ( e,  1) .
1
52. Sol: Let ‘A’ be a square matrix then we can 1
b 3 1 3
tan    
1 a 3 1 1 1
rewrite A  ((A  A T )  ( A  A T ))
2 3
T
Here, A  A T is clearly symmetric and A  A  tan(45  30 )  tan15
is skew symmetric.

1 1 1    15 
2
53. Sol: Given equation is (x  9) 2 x 2 0
7 6 x    2n    cos1 c  .
2 2
 2n  
a b 12 4
[R1  R1  R 2  R 3 ] 1 1 1
58. Sol: f(x )  sin x  tan x  sec x
2
 ( x  9)[(x  12)  (2x  14)  (12  7x )]  0
Clearly, the domain of f(x ) is x  1
2
 (x  9)(x  9x  14)  0
 3 
 (x  9)(x  2)(x  7)  0  x  9, 2, 7 . Thus, range is {f(1), f( 1)} , i.e.,  , .
4 4 
    
54. Sol: a  b  c  x , taking dot with x on both 59. Sol: c12  c22  2c1c2 cos2A
sides we get;
         2  c12  c22  2c1c2 (2cos2 A  1)
x a  x b  x c  x  x  x  4
 (c1  c2 )2  4c1c2 cos2 A
3     3
1  x c  4  x c   4b2 cos2 A  4(b2  a 2 )cos2 A  4a 2 cos2 A .
2 2
 
If '  ' be the angle between c and x , then 60. Sol: 3a  2b  5c  0  3 a  2 b  c  0
5 5
  3 3 1  3 
x c cos    cos      cos   . Thus, the line ax  by  c  0 passes through
2 4 4
  3 2
55. Sol: Work done  F  AB the point  ,   .
 5 5

 (10i  5j  7k)

  ( 2i  4j)
 61. Sol: Slope of line RQ  2  tan 
R
 20  20  40 . 45°
2x  y  3
2
56. Sol: Given, 2sec2  tan   cot  
sin 2 45°
P(2, 1) Q
 Slope of lines making an angle of 45° with cos 
y  a(sin    cos  )  
tan   1 2  1 1 sin 
QR are tan(   45 )    ,3
1  tan  1  2 3
[x  a(cos    sin  )]
Equation of PQ and PR (not necessarily in
or x cos   y sin   a  0
1
that order) are y  1   (x  2) and
3 00a
 p  a.
y  1  3(x  2) cos2   sin2 
or x  3y  5  0 and 3x  y  5  0 66. Sol: In this case PA must be normal to the given
Hence, their combined equation is curve.
( x  3y  5)(3x  y  5)  0 dy x
For x 2  4y, 
or 3x 2  3y 2  8xy  20x  10y  25  0 . dx 2
Thus, equation of normal at P( x 1 , y 1 ) is
62. Sol:  0  cos2 (n! x)  1
 x12  2
If 0  cos2 (n! x )  1  y     (x  x1 )
 4  x1
Then, f( x )  lim lim{1  (cos 2 ( n ! x )) m }  1  0  1
m  n
It must pass through (0, 4)
2
When x is irrational and if cos (n! x)  1
 x2  2
  4  1    x1  2  x1   8
r  4  x1
 n! x  r  x   rational
n!
Apart from this, y-axis is also a normal to the
Then, f( x )  lim lim{1  (cos2 (n! x ))m }  1  1  2 cur ve passing through A(0, 4) and
m  n 

corresponding x 1  0 .
2, x is rational
Hence, f(x)   .
If x 1  0 , then P(0, 0)
1, x is irrational
 PA  4
63. Sol: f (log e x )  log e (log e x)
If x1   8 , then P(  8, 2)
 df (loge x )  1  1 .
dx loge x x  PA  8  4  12

1 Thus, P  (  8, 2) .
 
 x2  1  1
 1  x2  67. Sol: Suppose p is the quantity of petrol burnt
64. Sol: Let y  sec1  2   sec  
 x 1 1 3
1 2  in one hour. Then p  kv . Let the distance of
 x 
the journey be s km.
1 s
 2tan1   Duration of the journey  hours .
x v c
 Total petrol burnt for the whole journey
dy 2  1  2
    2  . sp skv 3
dx 1  1  x  1  x2  
x2 v c v c

dx v3
65. Sol:  a(  sin   sin    cos  )  a  cos  Take u  (sk  constant) ,
v c
d
dy du (v  c)3v 2  v 3 v 2 (2v  3c)
 a(cos   cos    sin )  a  sin   
d dv (v  c)2 (v  c)2

3c 3c
 dy  tan  du
0 v  , is found to give a
dx dv 2 2
Equation of normal at point ‘  ’ is minimum for u.
 3c consistent and since here no two equations
 Most economical speed  km / h . are identical, therefore number of solutions
2 is one.
68. Sol: f '(x )  3x 2  2ax  b  3(x  x1 )(x  x 2 ) 72. Sol: If radius of circle is r, then
where x 1  x 2 A4
Clearly, f '(x )  0  x  ( x 1 , x 2 ) and
An O
f '(x )  0  x  ( , x 1 )  (x 2 ,  ) A3

Thus, x  x 1 is the point of local maxima and

x  x 2 is the point of local minima. A1 A2
Thus, bigger root of f '(x )  0 must be
negative.   2 
A1A 2  2rsin   , A1A 3  2r sin  
n  n 
Hence, a 2  3b  0 , a  0 , b  0 .
69. Sol: Given cur ves are x 3  3xy 2  a and  3 
A1A 4  2rsin  
 n 
3x 2 y  y 3  b –––––– (1)
For curve (1), 1 1 1
  
A1 A 2 A1 A 3 A 1 A 4
dy x 2  y 2
  m1 (say)
dx 2xy 1 1 1
  
  2
   3 
For curve (2), 2r sin   2r sin   2r sin  
n  n   n 
dy 2xy
 2  m2 (say)
dx x  y2  2   3   3    
 sin   sin    sin   sin  
 n   n   n  n
Since m1m 2  1 , hence the two cur ves
intersect at an angle of 90°.  2    
 sin   sin  
x y z  n  n
70. Sol: Let the plane be   1
a b c  2    3       3   
 sin    sin    sin     sin   sin  
 n   n   n   n  n
1 1
 1, 1  a  b 1
a b  2   2      3  
 sin    2cos   sin    sin   sin  
 n   n  n  n  n
1 1

 a b  4   3    
Also, sin   sin    sin    sin    0 
4 1 1 1  n   n  n 
2
 2 2 11
a b c
4 3
  r  ( 1)r ,
1 n n rI
c
2 4 3
  r  ( 1)r for r  1 , n  7 .
Thus direction ratios are n n
73. Sol: Shifting the origin at (1, 3), we get
(1, 1, 2 ) or (1,1,  2 ) .
x'  y'  1
NUMERICAL VALUE QUESTIONS:
Which represent a square of area 2 sq. units.
0 1 1
sin{log(1  x)}
71. Sol: Here,   1 0 2 74. Sol: lim
x 0 log(1  sin x)
1 2 0

 1( 2)  1(2)  0 . sin{log(1  x )} log(1  x)

 x
log(1  x) x
Hence, given system of equations is  lim 1
x 0 log(1  sin x ) sin x .
. x
sin x x
 dy  
75. Sol:  2cos2x  2sin  2x  
dx  2

d2 y    
 2
 2 cos  2x    22 sin  2x  2  
dx  2  2

d6 y  
6
 26  sin  2x  6    26 sin  2x  3 
dx  2

 d6 y
At x  , 0.
2 dx 6

***THE END***