IIT JEE (M + A) ENTHUSIAST COURSE

(PHASE - 1 & 2)
INTERNAL TEST - 03 DATE: 13.07.2022

SYLLABUS

PHYSICS : Electrostatics, Gravitation, Current Electricity, Thermal Physics,

Heat Transfer (Upto Thermal Radiation)

CHEMISTRY : Solution, Solid State, Electrochemistry, Coordination Chemistry

(Upto Naming of Some Special Complexes and of Complexes
With Bridging Ligands)

MATHS : Functions, Inverse Trigonometric Functions, Limits &

Continuity (Complete)
 TARGET : JEE (M + A) : 2023
CLASS : ENTHUSIAST (XII) (PHASE - 1 & 2)

Time : 3 Hours Maximum Marks : 300

SOLUTION
PART 1 – PHYSICS 1
(A) 1 (B) 
SECTION - I 2
1. A thin spherical shell of radius R has a charge Q spread (C) 2 2 (D) – 1
uniformly over its surface. Which of the following
Ans. C
graphs most closely represents the electric field E(r)
produced by the shell in the range 0  r   , where r Sol. Q2 , Pg 62
is the distance from the centre of the shell ? Q q
E r  E r 

q Q
(A) (B)

r r k Qq kQ2
O R O R 2
a2 2 a2

E r  E r  Q
2 2
q
But nature of charges Q and q is opposite

(C) (D) Q
 2 2
q
r r
O R O R 3. An infinite, uniformly charged sheet with surface
charge density  cuts through a spherical Gaussian
Ans. A surface of radius R at a distance x from its center, as
Sol. Q1 , Pg 62 shown in the figure. The electric flux  through the
Inside shell Gaussian surface is :
E=0
Outside shell 
1
E
r2 R
2. A charge Q is placed at each of the opposite corners x
of a square. A charge q is placed at each of the other
two corners. If the net electrical force on Q is zero,
Q
then q equals
R 2  2  R 2  x 2  
(A) (B)
0 0
 R  x2   R2  x2  (A) 24 a 0 (B) 6 a 0
(C) (D)
0 0 (C) 24 a 0 r (D) 6 a 0 r
Ans. D Ans. B
Sol. Q3 , Pg 53 Sol. Q3 , Pg 67

q in A   R  x  d
 ar 2  b   2ar
2 2

   E
0 0 0 dr
Let   kr n

   R 2  x2  
0 r
kr n  4r 2 dr
2ar  4r 2  
4. The maximum electric field at a point on the axis of 0 0
a uniformly charged ring is E0. At how many points
on the axis will the magnitude of electric field be 4k r n 3
8ar 3 
E0 / 2 0 n  3
(A) 1 (B) 2 n  0
(C) 3 (D) 4
k  6a 0
Ans. D
7. Three concentric metal shells A, B and C of
respective radii a, b and c (a < b < c) have surface
charge densities ,  and  respectively. The
E0 potential of shell B is :
E0
  a 2  b2    a 2  b2 
2
(A)   a  c  (B)   b  c 
0   0  
A B
Sol. C D
E0   b2  c2    b2  c2 
2 (C)   b  a  (D)   c  a 
E0 0   0  
Ans. B
5. In the figure a hemispherical bowl of radius R is  Qa Q b Qc 
Sol. Vb  k   
shown. Electric field of intensity E is present
 b b c 
perpendicular to the circular cross section of the
hemisphere. The electric flux through the hemisphere  4a 2 4b2 4c 2 
is  k   
 b b c 

  a 2  b2 
   c
0  b 

8. Let E1  r  , E 2  r  and E 3  r  be the respective

electric fields at a distance r from a point charge Q,
(B) E  R 
2
(A) 0 an infinitely long wire with constant linear charge
density  , and an infinite plane with uniform surface
(C) E  2R  (D) E  3R 
2 2
charge density  . If E1  r0   E 2  r0   E 3  r0  at a
Ans. B given distance r0 , then
6. The electrostatic potential inside a charged spherical (A) Q  4r02
ball is given by   ar  b where r is the distance
2

from the centre ; a, b are constant. Then the charge 

(B) r0 
density inside the ball is : 2
 (C) E1  r0 / 2   2E 2  r0 / 2 

(D) E 2  r0 / 2   4E 3  r0 / 2  P
R2
a
Ans. C R1
kQ   O
Sol. r 2  2 r  2 
0 0 0 0

9. Charges Q, 2Q and 4Q are uniformly distributed in

three dielectric solid spheres 1, 2 and 3 of radii R/2,

R and 2R respectively, as shown in figure. If (A) E is uniform, its magnitude is independent of
magnitudes of the electric fields at point P at a 
distance R from the centre of spheres 1, 2 and 3 are R2 but its direction depends on r

E1 , E2 and E3 respectively, then (B) E is uniform, its magnitude depends on R2 and

its direction depends on r
P

(C) E is uniform, its magnitude is independent of a
R P 
but its direction depends on r
R 
Q 2Q (D) E is uniform and both its magnitude and direction

R/2 depend on a
Ans. D
Sphere 1 Sphere 2

b 
P c

R a
4Q Sol.

2R
 
 c b
Sphere 3 E 
3 0 3 0

(A) E1  E 2  E 3 (B) E 3  E1  E 2   

30

cb 
(C) E 2  E1  E 3 (D) E 3  E 2  E1

Ans. C a

kQ k  2Q k  4QR 3 0
Sol. E1  2
; E2  2
; E3 
R R 8R 3 11. Figure shows elliptical path abcd of a planet around
10. Consider a uniform spherical charge distribution of 1
radius R1 centred at the origin O. In this distribution, the sun S such that the area of triangle csa is the
4
a spherical cavity of radius R2 , centred at P with
distance OP = a = R1 – R2 (see figure) is made. If area of the ellipse. (See figure) With db as the
 semimajor axis, and ca as the semiminor axis. If t1 is
the electric field inside the cavity at position r is the time taken for planet to go over path abc and t2
 

E r , then the correct statement(s) is (are)
for path taken over cda then :
 13. Consider two solid spheres of radii
c
R 1  1m, R 2  2m and masses M 1 and M 2 ,
d s b respectively. The gravitational field intensity due to
M1
sphere (1) and (2) are shown. The value of M is :
2
a
(A) t1  4t 2 (B) t1  3t 2

Gravitational field E
4
(C) t1  t 2 (D) t1  2t 2
3 (2)
Ans. B
Sol. Law of Areas 2
(1)
A A 1

t1 2 4
 3
t2 A
0 1 2 3 4 5 radius R
4
12. A test particle is moving in a circular orbit in the 1 2
gravitational field produced by a mass density (A) (B)
2 3
k
r  . Identify the correct relation between the 1 1
r2 (C) (D)
3 6
radius R of the particle's orbit and its period T :
Ans. D
(A) T / R2 is a constant (B) TR is a constant
(C) T2 / R3 is a constant (D) T / R is a constant GM1
Sol. 2
Ans. D R12
k GM 2
Sol.   3
r2 R 22
2
M1 2  1  1
   
R M2 3  2  6
14. A wire is in the form of a tetrahedron. The resistance
of each edge is r. The equivalent resistances between
R corners 1–2 and 1–3 are respectively
k
E  4 R 2  4  G   4 r 2 dr
0 r 2
4

ER 2  4GkR
1 3
4Gk R
E 2
R
2
4 Gk mv 2
m   v  4 Gk r r
R R (A) , (B) r, r
2 2
2R
T TR r r
v (C) ,r (D) r,
2 2
Ans. A
 4 Ans. B
Sol. P  I 2
V
Sol. 3 I1 
2R
1 2 V 2V
I2  
1 1 1 1 R 3R
   R
req 2r 2r r 2
I2 V
r I3  
req  2 3R
2
17. In the circuit shown, current (in A) through the 50V
15. In the given potentiometer circuit length of the wire and 30V batteries are, respectively :
AB is 3m and resistance is R  4.5 . The length
AC for no deflection in galvanometer is 5

E = 5V r  0.5 20
50V 30V
10

5
R  4.5
A B (A) 3 and 2.5 (B) 3.5 and 2
C
(C) 4.5 and 1 (D) 2.5 and 3
Ans. C
G
E1 = 3V r1
5 2 1
(A) 2m (B) 1.8m 2.5 3
(C) Dependent on r1 (D) None of these 20
Sol. 50V 30V
Ans. A 10
5 x 4.5
Sol.   4.5  3
0.5  4.5 3
5 2 1

x =2 18. The variation of lengths of two metal rods A and B

16. If X , Y and Z in figure are identical lamps, which of with change in temperature is shown in figure. The
the following changes to the brightness of the lamps A
occur when switch S is closed ? ratio of  is :
B

106
Z
s
B
x
length(cm)

104
A
100
Y
(A) X stays the same, Y decreases
(B) X increases, Y decreases 0 T
(C) X increases, Y stays the same temp(°C)
(D) X decreases, Y increases
 3 2 SECTION - II
(A) (B)
2 3 1. Two particles of masses m and 2m having same
charge q each are placed in a uniform electric field
4 3 E and allowed to move for the same time. Find the
(C) (D)
3 4 ratio of kinetic energies of m to 2m.
Ans. B Ans. 2
 A L0 T 4 qE qE
Sol.  L T  6 Sol. a1  and a 2   a1  2a 2
B 0 m 2m
19. Bars of two different metals are bolted together, as 1 1 1 
K1  m1v12  m1  a1t  , K 2  m 2 v 22  m 2  a 2 t 
2 2
shown in figure. The distance x does not change with 2 2 2 2
temperature if :
K1 m1a12 m 4 2
lA  2
  
K 2 m 2 a 2 2m 1 1
A A
B B x 2. Figure shows two conducting thin concentric shells
lB of radii r and 3r.

lA  A lA  B
(A) l   (B) l  
B B B A

l A2  A l A2  B r 3r
(C) 2  (D) 2 
lB  B lB  A
Ans. B K

Sol. x  l A 1   A T   lB 1   B T 
The outer shell carries charge q and inner shell is
x  l A  l B    A l A   B l B  T neutral. The amount of charge which flows from
inner shell to the earth after the key K is closed is
  Al A   B l B
equal to 1 / n  of the charge on outer shell. What
th
20. A metal rod of Young's modulus Y and coefficient of
thermal expansion  is held at its two ends such is the value of n ?
that its length remains invariant. If its temperature is Ans. 3
raised by t°C, the linear stress developed in it is : Sol. Let charge appearing on inner sphere be x,
t Y
(A) (B) q
Y t
1 x
r
(C) Yt (D)  Yt 

Ans. C
3r

Sol. Y

l Y l T Now potential of inner sphere is zero, i.e
  YE  Y 
l l kq kx
  0  x  q / 3
3r r
Now charge which flows from the inner shell to the
earth shall be  x  q / 3
3. In the figure, find the ratio of the linear charge
densities 1 (on semi-infinite straight wire) and A 11 18 10 A
 2 (on semi-circular part), that is, 1 /  2 so that 12 9
6
5 2
the field O is along y direction. 19 17
3 B 1
13 16
y 7 4 8
2
x A 14 20 15 A
O
R
The resulting circuit can be drawn as shown below.

1 r/8 r/8 r/8 1,2,3,4

r/4
Ans. 2 A B
Sol. Electric field due to semicircular part :
r/8 5,6,7,8
r/4
2 9,10,11,12
E2 
20 R 13,14,15,16
17,18,19,20

2 E1y 21 21 80
Solve to get R AB  r  R AB    6
E2 40 40 7
E1x 5. Two circular rings of identical radii and resistance of
R
36 each are placed in such a way that they cross
1 other's centre C1 and C2 as shown in the figure.
Conducting joints are made at intersection points A
Electric field due to straight part : and B of the rings. If the power delivered by a 20 V
1 cell connected between A and B is 100n watt, then n
E1x  E1y  is :
40 R
For the net field to be along the y-axis : A

2 1 
E 2  E1x    1 2 C1 C2
20 R 40 R 2
4. A finite square grid, each link having resistance r, is
fitted in a resistanceless conducting circular wire. B
Determine the equivalent resistance between A and Ans. 1
B (in  ) if r   80 / 7   Sol. The resistance of four sections are shown in the
figure.
A

24 12 12 24

B

A B
Ans. 6 Hence, the equivalent resistance R across AB is
Sol. If we connect battery between A and B, then different 1 1 1 1 1
points will be at the same potentials.      R  4
R 24 12 12 24
(1,2,3,4) ; (5,6,7,8) ; (9,10,11,12,13,14,15,16) and
Power  V 2 / R  202 / 4  100W
(17,18,19,20)
6. A bubble of conducting liquid is charged to potential 8. A particle of mass m is subjected to an attractive
V. It has radius a and thickness t <<a. It collapses to central force of magnitude k / r 2 , k being a constant.
1/3 If at the instant when the particle is at an extreme
 a  position in its closed elliptical (not circular) orbit, at a
form a droplet. Potential of the droplet, is V   .
 Kt  distance a from the centre of force, its speed is
Find K.
 k / 2ma  , if the distance of other extreme position
Ans. 3 is 'b'. Find a / b. (where a > b)
Sol. Let q be the charge on the bubble, then Ans. 3
Kq  1  Va
V  Here K 
a 

40 
q 
K
k / 2ma 
b
Let, after collapsing the radius of droplet becomes
a
R, then equating the volume, we have Sol.

 4pa  t  43 pR  R   3a 2 t 
1/3
2 3
Vb

Kq k
Now, potential of droplet will be V  a  m  Vb  b  m
R 2ma
Substituting the values, we have 1 ka
Vb 
b 2m
 K  
Va 

V   K  or 1 k k 1 m ka k
m   
 3a t 
1/3
2
2 2ma a 2 b2 2m b
a
a 
1/3
Let x
V  V   b
 3t 
3 x2
7. 2 kg of ice at –15°C is mixed with 2.5 kg of water at   x
4 4
25°C in an insulating container. If the specific heat
capacities of ice and water are 0.5 cal/g°C and x 2  4x  3  0
1 cal/g°C, latent heat of fusion is 80 cal/gm find the x = 1, 3
amount of water present in the container ? (in kg 9. The density of a newly discovered planet is twice
nearest integer) that of the earth. The acceleration due to gravity at
Ans. 3 the surface of the planet is equal to that at the surface
of the earth. If the radius of the earth is R and the
Sol. Energy released by water from 25°C to 0°C
radius of the planet is R  . Then what is the value of
 2500  1 25  62500cal
R / R ?
Energy to bring ice to 0°C Ans. 2
1 GM 4 R 3
 2000   15  15000cal Sol. g   G
2 R2 3 R2
Energy used to melt ice of m gram = m80 cal
4
g  GR  g  R
 62500  15000  3
 Ice melt m   80
  593.75g
  g   R     2
So, mass of water = (2500 + 593.75) g
g
= 3093.75 g  3kg 1
g

R
2
R
10. The variation of potential with distance R from fixed (A) 8 NA (B) 40 NA
point is shown in the figure. Find the electric field at (C) 4 NA (D) 2 NA
R = 5 m. (in v - m)
Ans. C
M M
2 2
Sol. p  NA NA
 6.17 
a3 (3  108 cm)3
Potential in

10  M = 50 gm/mol
8 w 200
6
Volts

No   NA   N A  4N A
4 M 50
2
4. Copper crystallises in fcc with a unit length of
O 361 pm. What is the radius of copper atom?
1 2 3 4 5 6
(A) 181 pm (B) 128 pm
Distance in m (C) 157 pm (D) 108 pm
Ans. 5 Ans. B
Sol. In FCC
dV  10 
Sol. E   5 2a  4r
dx 2
 2  361  4r
PART 2 - CHEMISTRY 5. Among the following the INCORRECT statement
SECTION - I is:
1. A compound alloy of gold and copper crystallizes in (A) Density of crystals remains unaffected due to
a cubic lattice in which gold occupy that lattice point Frenkel defect
at corners of the cube and copper atom occupy the (B) In BCC unit cell the void space is 32%
centres of each of the cube faces. What is the (C) Electrical conductivity semiconductors and
formula of this compound. metals increases with increase in temperature
(A) AuCu6 (B) AuCu (D) Density of crystals decreases due to Schottky
(C) AuCu3 (D) Au2Cu3 defect
Ans. C Ans. C
Sol. Fact based
1
Sol. Au  8   1 6. Osmotic pressure of 30% solution of glucose is
8
1.20 atm and that of 3.42% solution of cane sugar
1 is 2.5 atm. The osmotic pressure of the mixture
Cu  6  3 containing equal volume of the two solutions will be
2
(A) 2.5 atm (B) 3.7 atm
 AuCu3
(C) 1.85 atm (D) 1.3 atm
2. The appearance of colour in solid alkali metal halides Ans. C
generally due to:
(A) Frenkel defect (B) F-centres Sol. f Vf  1V1  2 V2
(C) Schottky defect (D) Interstitial position 1.2V  2.5V 3.7V
Ans. B f  
2V 2V
Sol. Theory based
 f  1.85atm
3. A diatomic molecule X2 has a body centred cubic
(bcc) structure with a cell edge of 300 pm. The
density of the molecule is 6.17 g cm–3. The number
of molecules present in 200 g of X2 is (Avogadro
constant (NA) = 6 × 1023 mol–1)
7. A sample of air is saturated with benzene (vapor Ans. B
pressure = 100 mm Hg at 298 K) at 298K, 750 mm
Hg pressure. If it is isothermally compressed to one Tb i.m  k b
Sol. 
third of its initial volume, the final pressure of the Tf i  m  k f
system is
2 11 k b
(A) 2250 torr (B) 2150 torr 
2 1 2  k f
(C) 2050 torr (D) 1950 torr
Ans. C kb = 2kf
Sol. Pressure of air = 750 – 100 = 650 mm of Hg 11. 12g of a nonvolatile solute dissolved in 108g of water
produces the relative lowering of vapour pressure
on compressing Pf = 650 × 3 mm of Hg = 1950 mm of 0.1. The molecular mass of the solute is:
of Hg
(A) 60 (B) 80
So, PT = (1950 + 100) = 2050 mm of Hg (C) 40 (D) 20
8. The cryoscopic constant of a solvent (x) is 3.6 K Ans. D
kg/mol. A solution of 1 g of a hydrocarbon in 100 g
Sol. R.L.V.P = xsolute
of 'x', freezes at 16.14°C instead of the usual
16.60°C. The hydrocarbon contains 92.3% carbon. n solute
The molecular formula of hydrocarbon is CXHY then 
n solute  n solvent
Y + X is
(A) 12 (B) 6 n solute

(C) 14 (D) 2 n solvent (for dil. solution)
Ans. A 12 / M
0.1 
Sol. Tf  i  K f  m 108 / 18
M = 20
1 / M solute
0.46  1  3.6  12. Analysis shows that oxide of 'Ni' has the formula
0.1
Ni0.98O. The percentage of 'Ni' present as Ni+2 &
 M solute  78g Ni+3 respectively will be
E.f. = C92.3/12 H7.7/1 = C1H1 (A) 96%, 4% (B) 97%, 3%
 M.F.  (C1H1 ) 6 (C) 98%, 2% (D) 99%, 1%
9. CsCl crystallises in body centred cubic lattice. If 'a' Ans. A
is its edge length then which of the following Sol. Ni+2 = x, Ni+3 = 98 – x
expressions is correct? 2x + 3 (98 – x) = 200
x = Ni+2 = 94 Ni+3 = 4
3a
(A) rCs  rCl  3a (B) rCs  rCl  94
2 %Ni 2   100  96%
98
3 % Ni+3 = 4%
(C) rCs  rCl  a (D) rCs  rCl  3a
2 13. An element 'X' with an atomic mass of 60 g/mol
Ans. C has a density of 6.23 g/cm3. If edge length of the
Sol. As CsCl forms body centred cubic lattice, Cs+ and unit cell is 400 pm. The type of unit cell is
Cl– touch each other along body diagonal. Hence (A) Simple cubic (B) BCC
(C) FCC (D) May be FCC & BCC
a
rCs  rCl  3 (a is edge length). Ans. C
2
Sol. Mass of unit cell = V × d
10. Elevation in the boiling point for 1 molal solution of
= (400 × 10–10)3 × 6.23
glucose is 2K. The depression in the freezing point
of 2 molal solutions of glucose in the same solvent Z M
is 2K. The relation between Kb and Kf is: d
N A  vol
(A) Kb = 0.5 Kf (B) Kb = 2 Kf
Z = 4  it is FCC
(C) Kb = 1.5 Kf (D) Kb = Kf
14. KCl can be used in salt bridge as electrolyte in which 18. The standard electrode potentials (E oM  / M ) of four
of the following cells
metals A, B, C & D are –1.2 V, 0.6 V, 0.85 V &
(A) Fe | FeSO4 || AgNO3 | Ag – 0.76 V respectively. The sequence of deposition
(B) Pb | Pb(NO3)2 || Pb(NO3)2 | Pb of metals on applying potentials is
(C) Cu | CuSO4 || AuCl3 | Au (A) D, A, B, C (B) C, B, D, A
(D) Zn | ZnCl2 || Pb(NO3)2) | Pb (C) B, D, C, A (D) A, C, B, D
Ans. C Ans. B
Sol. As Cl– forms precipitates of AgCl or PbCl2 in other Sol. As reduction potential  ,
cells
15. Pick out CORRECT statement tendency to get reduced  :
(A) As temperature increases, resistance of 19. Conductivity of saturated solution of BaSO4 at
metallic conductor increases 315 K is 3.648 × 10–6 ohm–1 cm–1 & that of water is
(B) As temperature increases, resistance of 1.25 × 10–6 ohm–1 cm–1. Ionic conductance of Ba+2
electrolytic conductor decreases & SO42 are 110 & 136.6 ohm –1 cm 2 mol –1
(C) The product obtained during electrolysis respectively. Calculate solubility of BaSO4 in g/lit
depends on charge density flowing during (molar mass of BaSO4 = 233)
electrolysis
(A) 2.26 × 10–3 g/L (B) 9.72 × 10–6 g/L
(D) All of these
(C) 5.62 × 10–7 g/L (D) 56.2 × 10–5 g/L
Ans. D
Ans. A
Sol. Theory based
16. The reduction potential of hydrogen half cell will be Sol.  om BaSO4   om Ba 2   mo SO42
negative if = 110 + 136.6 = 246.4 ohm–1 cm–1 mol–1
(A) PH 2 = 1 atm & [H+] = 2 M K BaSO4  K BaSO4 (Solution)  K water

(B) PH 2 = 1 atm & [H+] = 1 M = 3.648 × 10–6 – 1.25 × 10–6

= 2.398 × 10–6 ohm–1 cm–1
(C) PH 2 = 2 atm & [H+] = 1 M
K  1000
 om 
(D) PH 2 = 2 atm & [H+] =2M Solubility
Ans. C = 9.72 × 10–6 mol/L
0.0591 PH1/ 2 = 9.72 × 10–6 × 233
Sol. E H /H2  E H / H2 
o
log 2 = 2.26 × 10–3 g/L
2 [H ]
20. Which of the following pair contains only
17. Two faraday of electricity is passed through a ambidentate ligands?
solution of CuSO4. The mass of Cu deposited at
the cathode is [atomic mass of Cu = 63.5 a.m.u] (A) CN– & H2O (B) en, F–
(A) 0 g (B) 63.5 g (C) NH3 & SCN– (D) NO2 & SCN 
(C) 2 g (D) 127 g Ans. D
Ans. B
Sol. NO2 & SCN  these can ligate through two
Sol. Charge (Q) = 2F
different atoms
M 63.5
Eq.mass of Cu    31.75
2 2
Amount of copper deposited = 2 × eq. mass
= 2 × 31.75
= 63.5 g
 SECTION - II 7. Find the coordination number of
1. How many effective number of atoms are present Na in Na2O
in a cubic unit cell having one atom at each corner Ans. 4
& two atoms on each body diagonal?
Sol. Na2O (Antiflurite)
Ans. 9
coordination number = 4 : 8
1
Sol. 1. 8  (corner)  1  
8 8. The ratio of    for Ca3(PO4)2 will be equal to
m

2. 4 × 2 = 8  eq 
Total no. of atoms 1 + 8 = 9 _____
2. If the density of some lake water is 1.25 g/ml & Ans. 6
contains 92 gm of Na + ions per kg of water. m
Calculate the molality of Na+ ions in the lake. Sol.  e 
n  factor
Ans. 4
9. How many among the containers are not used to
92 store FeSO4 safely?
Sol. n Na   4
23 Pb, Ag, Al, Cu, Zn
4 Ans. 2
molality  4
1 Sol. Zn & Al are more reactive than Fe
3. What is the Van't Hoff factor for glucose? 10. The difference in packing efficiency & void space
Ans. 1 (%) of simple cubic unit cell is ____% (nearest
Sol. Van't Hoff factor for non electrolyte = 1 integer value)
4. How many among the following are Monodentate Ans. 5
ligands?
P.E  52.3%
Difference  4.6%
Void space  47.7%
 2   Sol.
en, Br , C2 O , Gly , H 2 O,CN ,CO, NO
4

Ans. 5
PART 3 - MATHEMATICS
Sol. Except en, C2 O42 & Gly 1
SECTION - I
5. How many given parameters are CORRECT for
Hexane + Heptane solution mixture?
1. f (x)  sin 1 x  cos1 x  tan 1 x, then domain is

H mix  0, H mix   ve, H mix   ve, (A)   2, 2  (B) [0, 1]

Smix   ve, (C) [– 1, 1] (D) R
Vmix   ve, Vmix  0, G mix   ve Ans. C

Ans. 4 Sol. f (x)  sin 1 x  cos 1 x  tan 1 x

Sol. Ideal solution   
1  x  1   1  x  1  x  R
H  0, V  0
So x  [1, 1]
G   ve, S   ve
2. Value of
6. If there are 3 moles of atoms are present in the
packing pattern of ABC ABC. The number of moles sin 1  sin 8   tan 1  tan10 
of Tetrahedral voids are equal to ___  cos 1  cos12   sec 1  sec9   cot 1  cot 6 
Ans. 6
Sol. No. of T.V = 2Z (A)   10 (B) 11  33
=2×3=6 (C) 9  2 (D) 6  2
Ans. B
Sol.  3  8   10  3   4   12   9  2   6     x 2  1  ax  x  1  b  x  1 
Sol. x  
lim
x 1


 11  33  

 2x  3  x 1   x 2 1  a   x   b  a   1  b  
3. lim lim    0
x 1
 2x 2
 5x  3
x 
 x 1 
So, 1 – a = 0 and –b–a=0
3 5 a=1 and b=–1
(A) (B)
5 3
tan x  sin x
5 5 6. lim
(C)  (D)  x 0 x3
2 4 (A) – 1 (B) 0
Ans. C
1 1
(D) 
 2x  3  x  1 (C)
2 4
Sol. lim
x 1  x  1 2x  3 Ans. C

 1 
 2x  3  x 1  Sol. lim
sin x 
 cos x
 1

 lim
x 1
 x 1  
x  1  2x  3 x 0 x3

sin x 1  cos x 
5 5 lim
  x 0 cos x  x  x 2
2x  1 2
lim sin x 1  cos x 1
1  x 3  4 1  2x
3
x 0 2

4. lim x x cos x
x 0 x  x2
1 1
1  1 1 
(A) 0 (B) 2 2
2
ex  1  x
(C) 1 (D) None 7. lim 
x 0 x2
Ans. B
Sol. x  0  h  
(A) (B)
2 4!

lim
1  h  3 1/3
 1  2h 
1/ 4
1 1
h 0 h  h2 (C)  (D) 
2 4
 h2 1  Ans. A
h3 h
1 1 h  3  2 1/ 2 1
lim 3 2  lim     
 1  x 
x2 
 ....   1  x
h 0 hh 2 h  0 h 1  h  1 2
2! 1 1
Sol.    
2
x 2! 2
 x2 1 
5. lim   ax  b   0, then (a,b) is
x 
 x 1   21/ x  1
 ; x0
8. If f (x)   21/ x  1 ; then
(A) 0, 1 (B) 1, – 1
0 ; x 0
(C) 1, 0 (D) 0, 0 
Ans. B (A) Continuous at x = 0
(B) Discontinuous at x = 0
(C) Limit exists at x = 0
(D) None
Ans. B
 3a  4b  4a  4b
a   f a   g a   a   
Sol. f  0 

 7  7
x=0+h  3a  4b  3b  3a
 b  f  b  g b  b   
 1   7  7
21/ n 1  1/ n 
21/ n  1  2  1 0   a     b   0 &   x  is continous.
lim 1/ n  lim
h 0 2  1 h 0  1   1
21/ n 1  1/ n  1  0
 2  Hence one solution (but line   x  even degree
polynomial so at least two solution)
f  0 
x=0–h
 0 at x0
21/n  1 0  1  1 1
lim 1/ n   1   x  [x] if 0x
h 0 2 1 0 1
 2 2
LHL  RHL  1 1
11. If f (x)   if x
 L.D.N.E  2 2
 2 1
 Discontinuous.  3  x if
2
 x 1

x  [x]  1 if x 1
9. Let f (x)  , x R (where [.]denotes the
1  x  [x]
Then f (x) is
greatest integer function). Then the range of f is
1
 1 (A) Continuous at x =
(A) (0,1) (B) 0,  2
 2 (B) Continuous at x = 1
(C) Continuous at x = 0
 1 (D) Discontinuous at x = 0
(C) [0,1] (D) 0, 
 2 Ans. D
Ans. B 1 1 1
Sol. lim f (x)  lim  x  [x]   0  [0 ] 
Sol. y = x–[x]={x}   0,1 x 0 x0 2 2 2
f(0) = 0
 1+{x}  [1,2)
 f  x  is discontinuous at x = 0
x  [x] {x}  1 
 f (x)    0,  2  2 1 1
1  x  [x] 1  {x}  2  Since, xlim f (x)  lim1   x    
2
1 x 2   3  3 2 6
f  x    x  a   x  b   x and
2 2
10. Let function  f  x  is not continuous at x = 1/2
3a  4b
gx  , then number of solution of 2  1
lim f (x)lim   x     f (1)
7 x 1 x 1  3  3
f x  g x
 f  x  is not continuous at x = 1.
(A) No solution
cosec x
(B) At least one solutions  1  tan x 
12. If f  x    is to be made continuous
(C) Minimum two solutions  1  sin x 
(D) At least 4 solution at x = 0, then f  0 should be equal to
Ans. C (A) e 2 (B) e
Sol. Let   x   f  x   g  x  1 1
(C) (D)
e e2
Ans. D Sol. f (x  1)  f (x  1)  2f (x) , f (0)  0
Sol. If f  x  is continuous at x = 0, then lim f  x   f  0 Putting x  1, f  2  f  0  2f 1 ,  f  2  2f 1
x0

  tan x  sin x 
lim  Let f  k   kf 1 for k  n
1 sin x  .sin x 
 f  0  lim f  x   e
x 0 

x0 Then f  n  1  f  n  1  2f  n 
1 cos x 
lim
1 sin x  .cos x
 f (n  1)  2(nf (1))  f (n  1)
e  e2
x0

 2nf (1)  (n  1)f (1)  (n  1)f (1)

13. lim

cos 1 2x 1  x 2  is equal to  f  n   nf 1 for all n  N.
1 1 15. If f (x)  x 3  3x 2  10x  2sin x , then range of the
x
2 x
2 function is
(A) 2 (B) 2 2 (A) (0, 2) (B)  , 
(C) 2 2 (D) Does not exist (C)  ,0 (D)  0,
Ans. D Ans. B
1 1  Sol. f (x)  x 3  3x 2  10x  2sin x ;  
Sol. Let cos x   i.e., as x  ; 
2 4
 x 3  3x 2  10x   as a cubic polynomial.
RHL  lim
cos 1
 sin 2  So,   x 3  3x 2  10x  2sin x  
 1
 cos  
1  x  1 
4 2
2  
16. If for x 1, cos  x 2  1 
   
cos 1  cos   2  2   2x   2x  
 2  2 sin 1   tan 1  2   , then x is equal
 lim  lim 2
 1  1 1 x   x  1 3
 cos   
4 cos  
4
2 2 to
(A)  3 (B)  2
2
 lim  2 2 (C) –2 (D) None of these
  sin 

4 Ans. A
cos 1  sin 2  1
LHL  lim– Sol. For, x  1  1  0
 1 x

4 cos  
2  1 
  1
x 2
 1  x 2   2 tan 1  1 
   cos 1  2   cos 1   
cos 1  cos   2  
 2  x  1 1  x
 2   1  2 

 lim–  lim– 2 x
 1  1

4 cos   
4 cos  
2 2  2 
 2x     1
2 sin 1  2   sin 1  x   2 tan 1  
 lim– 2 2  x  1 1  x
  sin   1  2 

4 x
14. If f (x  1)  f (x  1)  2f (x) and f(0) = 0, then f(n), 2
n  N, is  2x  x  1
tan 1  2   tan 1  2 tan 1  
 x  1 1  x
(A) nf 1 (B) f 1
n 1 2
x
(C) 0 (D) None of these
 1 
Ans. A  2 tan 1     x   3
 x 3
  1 x2  Sol.   lim f x
1  x 0
17. If cos  2
 , then
1 x  3
   3x    3x  ......
3 5

 lim   3x   
 1 1   1 1  x 0
  3! 5!
(A) x    ,  (B) x    ,  
 3 3  3 3
  2x   2x  
1 5
 1   A  2x   
(C) x   0,  (D) None of these 
 3  3! 5! 
Ans. B
 x3 x5 
 1 x2   8 x   ..... / x5
Sol. We have, cos 1  2
  3! 5! 
1 x  3
 3  27  8A  B  x5 5 x3 
 x  3  2A  B   x     3  2 A  B  ... 
5
  1  x2  
 0  cos 
 3!  5! 7
   cos 1   1
  lim 
3  1  x 2  3 x 0 x5

 2A  B  3 ; 8A  B  27
1 x2  1 1  x2
 0  cos 1    1
1  x2 3 2 1  x2  A  4 ; B  5


 1  x2  2 1  x2  2 1  x2     
243  128  5
1
1 1 1 120
 0  x2    x
3 3 3 x n  sin x n
20. Consider f  x   lim ; x  0 ; x  1 and
n  x n  sin x n
1 x  3 1 x
18. If f  x   is continuous function, f (1) = 0 then
x
then f(0) is equal to : (A) f is continuous at x = 1
(B) f has a finite discontinuity
1
(A) 2 (B) (C) f has an infinite discontinuity at x = 1
4
(D) f has a removable type discontinuity at x = 1
1 1 Ans. B
(C) (D)
6 3
Ans. C sin x n
1
Sol. f  x   lim x n  '1'  x  1
1 1

Sol. lim
1  x  2
 1  x  3 n 
1
sin x n
x  x xn
1
1  x  2 1 1  x  3  1
1
0 : 0  x  1
 lim  
x  1  x   1 f  x  0 : x  1
1  x  1 1 : x  1

1 1 1
    1    1 
 2  3 6

19. If f  x   sin 3x  Asin52x  Bsin x is continuous at

x
x = 0 then f (0) is.
(A) 1 (B) 2
(C) –1 (D) 0
Ans. A
 SECTION – II 4. If n is a natural and 1  n  100, then the number of
2
8x  3
 2x 2  3   n   n   n  31n
1. Value of lim   is solutions of          (where [.]
x  5x 2  3
   2   3   5  30
denoted the greatest integer function) is
Ans. 0
Ans. 3

2 Sol.
Sol.    0
5 n n n n n n
2  3  5  2  3  5
ln  x 2  e x       
2. Value of lim is
x  ln  x 4  e x   n n   n n   n n 
                0
Ans. 1  2  2   3  3  5  5 

  x2   n  n  n 
ln  e x 1  
       0
 ex   2 3 5
Sol. lim  (where {.} is a fractional part)
x   x x4  
ln  e 1   But each of the fraction part function is
  ex  
positive and their sum is zero. Hence, each of
the fraction part function is zero.
  x2   n n n
 ln  1  x  2  Consequently, each of , , is an integer..
e x 2 3 5
ln e x    2   x 
 x e  The L.C.M of 2,3,5 is 30.
 
 e x
 Therefore we can take n = 30k, where k is an
lim integer. Hence the number of solutions such
x    x2  
 ln 1  x   4 that 1  n  100 is 3 (n = 30, 60, 90)
e x 
ln e    4    x 
x
5. If f (x)  2f (1  x)  x 2  1 x  R then f(3) is
 x  e 
 x  Ans. 0
 e 
Sol. f  x   2f 1  x   x  1; _______(i)
2

1 0
 lim 1
x  1 0  f(1 x)  2f(x)  (1 x)2 1  x2  2x  2_(ii)
 Solving (i) & (ii) we get,
 x 2  16
 ; x4 3f (x)  x 2  4x  3
3. f (x)   x  4 , is continuous at x = 4,
a ; x4  f (3)  0

then a = ? 8 8

Ans. 8 6. If  sin 1 x i  4, then

i 1
x
i 1
2
i 

x 2  16 Ans. 8
Sol. lim a
x 4 x4 10

lim  x  4   a  8  a
Sol.  sin
i 1
1
x i  4  8.
2
x 4

 10
 sin 1 x i  ,  i   x i2  8
2 i 1
 n  10. If there exists a continuous onto function
7. If cot 1  , n  N, then the maximum positive
 6 f :  0,1  0,10 then how many continuous onto
integral value of n is
function g(x) exist(s) such that
Ans. 5
g  x  :  0,1   0,10 
n 
1  n 
Sol. cot   cot  cot 1   cot Ans. 0
 6    6
Sol. Since g (x) is continious over [0, 1]


n
 3  n  3   5.5 (nearly).  g  x   [min, max]

 for onto range = co-doman
So, the maximum value of n is 5.
 [min, max]   0,10  (Proper subset )
3 1
8. If f  u   ,u ; then number of
2u  5u  3
2
x2 Hence cannot be onto.
point at which f (x) discontinuous
Ans. 3
1
Sol. u  ; x  2
x2

3 x  2 3 x  2 
2 2

f x  
2  5  x  2   3 x  2 3x 2  7x
2

7
x  0,
3
9. Let function f  x  : R   R  be an increasing

f  4x  3
function with lim  1 then
x  f  2x  1

f  3x  2 
lim 
x  f  2x  1
Ans. 1

 2x  1   4x  3 
Sol. x  0 ;  2x  1   4x  3
2
f  2x  1  f  3x  2   f  4x  3

 f  3x  2  f  4x  3  
lim 1   
x 
 f  2x  1 f  2x  1 

f  3x  2 
1  lim 1
x  f  2x  1