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(II) Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only, if
more than 5 questions attempted, First 5 attempted questions will be considered.
∎ The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest
Integer value (Example i,e. If answer is above 10 and less than 10.5 round off is 10 and if answer is from
10.5 and less than 11 round off is 11).
To cancel any attempted question bubble on the question number box.
For example: To cancel attempted question 21. Bubble on 21 as shown below
.
Question Answered for Marking Question Cancelled for Marking
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
6. Use Blue / Black Point Pen only for writing particulars / marking responses on the Answer Sheet. Use
of pencil is strictly prohibited.
7. No candidate is allowed to carry any textual material, printed or written, bits of papers, mobile phone
any electron device etc, except the Identity Card inside the examination hall.
8. Rough work is to be done on the space provided for this purpose in the Test Booklet only.
9. On completion of the test, the candidate must hand over the Answer Sheet to the invigilator on duty in
the Hall. However, the candidate are allowed to take away this Test Booklet with them.
10. Do not fold of make any stray marks on the Answer Sheet
PHYSICS : Kinematics and Energy of a general linear Simple Harmonic oscillator, Time
period of spring-block system and related problems (EXCLUDE : Problems
other than spring block systems, angular SHM, Simple and physical
pendulum).
CHEMISTRY : Reactions of alkenes with KMnO4 (cold as well as hot), Reaction with OsO4,
Epoxidation - hydrolysis, Ozonolysis ,Hydroxylation reactions; Oxidative
cleavage - KMnO4, ozonolysis; allyl substitution, allyl oxidation;
Isomerization; Reaction with carbenes and carbenoids.,Dienes: Preparation
and reactions of cnjugated dienes, 1-2 and 1-4 addition reactions, Addition
of HX and H2O to cummulenes, Addition of HX and X2 to conjugated dienes
,Addition of HX and X2 to conjugated diene,Alkynes: Physical properties,
Preparation from CaC2 and conversion of acetylene to higher
alkynes,Preparation of alkynes from polyhalogen compounds,Formation of
metal acetylides from terminal alkynes,Eelctrophilic addition reactions: X2,
HX, H2O, Alkynes:hydroboration-oxidation, HOX (X = halogen), linear
polymerization of acetylene,Eelctrophilic addition reactions: X2, HX, H2O, ,
linear polymerization of acetylene,Reactions of alkynes with KMnO4 (cold as
well as hot), Ozonolysis
MATHEMATICS : 3D-Geometry: Distance Formula, Section formula, Direction Ratios & Cosines
of a line, Angle between two lines, Angle between two lines by using D.Cs
and D.Rs, D.Cs and D.Rs of angular bisectors of two lines.
x2 10 sin 5 t 3 cos 5 t . The ratio of the amplitudes of the two motions is
3
1) 0.5 2) 1 3) 0.25 4)
2
2. The equation of simple harmonic motion of a particle is a 4 2 x 0 where a is the
instantaneous linear acceleration at displacement x. The frequency of motion is
1
1) 1Hz 2) 4 Hz 3) Hz 4) 4 Hz
4
3. The amplitude and time period in SHM are 0.8 cm and 0.2 sec respectively. If the initial
phase is radian, then the equation representing SHM is
2
1) y 0.8 cos10 t 2) y 0.8sin t
3) y 3 0.8 sin t 4) y 0.8sin10 t
4. The shortest distance travelled by a particle (performing S.H.M.) from mean position in 2
3
seconds is equal to of its amplitude. Find its period.
2
1) 11 s 2) 12 s 3) 13 s 4) 14 s
5. A small mass executes linear SHM about O with amplitude a and period T. Its
displacement from O at time T/8 after passing through O is
1) a/8 2) a / 2 2 3) a/2 4) a / 2
6. The acceleration- displacement graph of a particle executing simple harmonic motion is
shown in the figure. The frequency of oscillation is
2.5 1 1 1 1
1) S 2) 2 10S 3) 5 S 1 4) 20 S 1
2 2
2 A 2 A
1) 2) 3) Zero 4) A 2
2 2
11. A particle is executing SHM with amplitude A and has a maximum velocity V0 . The
displacement at which its velocity will be ( V0 /2) and the velocity at displacement A/2 are
A V0 A V0 3 3V0 A V0
1) , 2) , 3) A, 4) ,
2 2 3 3 2 2 2 2
12. The velocity time graph of a harmonic oscillator is shown in the figure. The frequency of
oscillation is
1) 25 Hz 2) 50 Hz 3) 12.25 Hz 4) 33.2 Hz
m 2m 3m 3m
1) 2 2) 2 3) 2 4)
3k 3k 2k 2k
15. A particle at end of a spring executes simple harmonic motion with a period t1 , while the
corresponding period of another spring is t2 . If two springs are connected in series then
time period is T, then which one is true?
2 2 2 1 1 1 2 2 2
1) T t1 t2 2) T t1 t2 3) T t1 t2 4) T t1 t2
16. Two springs are joined and attached to a mass of 16 kg. The system is then suspended
vertically from a rigid support. The spring constant of the two springs are k1 and k2
k1 k2 k1 k1 k2 k1 k2
1) 8 2) 3) 4)
k1k2 2 k2 8 2
k1 k2 k1 k2
1) A 2) A 3) A 4) A
k2 k1 k1 k2 k1 k2
19. A uniform spring of normal length l has a force constant k. If is cut into two pieces of
length l1 and l2 such that l1 nl2 where n is an integer. Then the value of k1 (force
kn k (n l ) k (n l ) kn
1) 2) 3) 4)
(n l ) n n (n l )
20. Assertion: If the amplitude of simple harmonic oscillator is doubled, its total energy
becomes four times.
Reason: The total energy is directly proportional to the square of amplitude of
oscillations.
1) Assertion and reason are true and reason is the correct explanation of assertion.
2) Assertion and reason are true but reason is not the correct explanation of assertion.
3) Assertion is true but reason is false
4) Assertion and reason are false.
The hydrocarbon is
1) 2, 5-dimethyl-3-hexene 2) 1-octene
3) 3,6-dimethy1-1,4-cyclohexadiene 4) 3,6 - dimethylcyclohexene
32. An organic compound C6 H 8 (molecular formula) on reductive ozonolysis given 2 moles
of CHOCH 2CHO . The possible structure of organic compound will be
1) 2)
3) 4)
33. Assertion: Alkynes are less reactive than Alkenes in electrophilic addition reaction
Reason: Terminal Alkynes have acidic Hydrogen
1) Assertion and Reason are true, reason is explanation of Assertion
2) Assertion and Reason are true, reason is not explanation of Assertion
3) Assertion is true but Reason is false
4) Assertion is false but Reason is true
34. How many compounds are formed upon oxidative ozonolysis of the following compound
1) 3 2) 4 3) 5 4) 6
Sia2 BH
CH3 COOD Product
1) 2)
3) 4)
36. The reagents used to convert in this reaction is/are
1) 2)
3) 4)
2 P 2 Catalyst Ni B
1) CH 3 C C CH 3 H 2
2 1) Sia BH /THF
2) CH 3 C C CH 3
2) CH COOH
3
3 Li in liq. NH
3) CH 3 C C CH 3
3 Li in liq . NH
4) CH 3 C CH CH 3 CH CH 2
39.
List-I List-II (Reagent)
A) CH 3 C C CH 3 Cis 2 Butene 1) Na / NH 3
C ) CH 3 C C CH 3 1 Butyne 3) Sia2 BH / H 2 O2 , OH
D) CH 3 C C CH 3 2 Butanone 4) NaNH 2 /
CH 3 CH CH Br and CH 3 CH 2 CH
1) Br
CH 3 C CH 2 and CH 3 CH CH 2
2) Br Br Br
3)
4)
2) O
4) O
H O
2
2 Hg 2 / H / H O
42. Mg 2C3
CH 3 C CH 3
1) 2) O
3) 4)
Br (i ) alc. KOH
43. 2
CCl
4( ii ) NaNH
2
A ; Product ( A)is :
major
1) CH 3 CH 2 CH CH 2 2) CH 3 C C CH 3
3) CH 3 CH 2 C CH 4) CH 3 CH C CH 2
44.
Hydrogenation of the above compound in the presence of poisoned palladium catalyst
gives:
1) an optically active compound 2) An optically inactive compound
3) a racemic mixture 4) a diastereomeric mixture
45. Which of the following is used for the conversion of 2-hexyne into trans-2-hexene?
1) H 2 / Pd / BaSO4 2) H 2 , PtO2 3) NaBH 4 4) Li.NH 3 (l )
46. Which of these compounds on oxidation with hot KMnO4 gives only butanoic acid?
1) Oct-3-ene 2) Oct-4-ene
3) Oct-2-ene 4) 3-methylhept-3-ene
H 2O Re d hot Cu tube
47. CaC2 ( A) ( B) Product ( B) of the reaction is :
Calcium carbide
KMnO4
HO cold
1) 2)
3) 4)
53. How many reagents from the list below would give effervescence/liberated gas when
reacted with 1-Pentyne?
NaOH 1 , CH 3CH 2ONa II , CH 3CH 2 MgBr III , NaH IV , NaNH 2 V , Na VI , NaHCO3 VII ,
CH 3CH 2 Li VIII , C6 H 5 Li IX
Red hot Cu
54. CH 3 C CH X . The no. of methyl groups in X is/ are
55. How many reagents from the list below can be used to remove hydrogen as proton from
terminal alkyne?
CH 3 MgBr , NaH , NaNH 2 , Na, NaHCO3 , KNH 2 , CH 3CH 2 Li
56. Acetylene reacts with hydrogen cyanide (1 equivalent) to give an addition compound ‘A’.
The number of bonds present in a molecule of ‘A’
OH
Con.H SO
2 4 Baeyer ' s
A(major )
reagent
Pr oduct ( S )
58.
Total diols formed after final reaction will be:
59. Acetylene can be prepared by heating iodoform with silver powder.
How many moles of silver iodide will be produced for the formation of 39 gm of
acetylene?
60.
NBS
2 1 7 8 7 8 9
1) , , 0 2) 6, 9,12 3) , , 3 4) , ,
3 3 3 3 3 3 3
65. If the foot of the perpendicular drawn from the point 1, 0,3 on a line passing through
2 7 17
, 7,1 is , , then
3 3 3
1) 1 2) 2 3) 3 4) 4
66. A 3, 2, 1 , B 4,1,1 , C 6, 2,5 and D 3,3,3 are four points. G1 , G2 , G3 and G4 respectively are
the centroids of the triangles BCD, CDA, DAB and ABC. The point of concurrence of
the lines AG1 , BG2 , CG3 and DG4 is
1) 4, 2, 2 2) 2, 4, 2 3) 2, 2, 4 4) 2, 2, 2
68. A 4,3,5 , B 0, 2, 2 and C 3, 2,1 are three points. The coordinates of the point in which the
69. If the midpoints of the sides AB, BC, CA of a triangle are 1,5, 1 , 0, 4, 2 , 2,3, 4
respectively, then the length of the median drawn from C to AB is
1) 29 2) 27 3) 5 4) 5
70. Assertion(A): If 1,3, 2 and 5,3, 2 are respectively the orthocenter and Circumcentre of
76. If the line joining 2,3, 1 and 3,5, 3 is perpendicular to the line joining A 1, 2,3 and
B , , then a possible point for B is
1 1 1 1
1) cos1 2) cos1 3) cos 1 4) cos 1
8 3 4 6
1) 13 2) 13 3) 2 13 4) 169
84. Let A 3, 2, 4 and B 9,8, 10 be two points. Let P1 divide AB in the ratio 1:2 and P2
divide AB in the ratio 2:1. If the point P , , divides P1P2 in the ratio 1 : 1, then
2 2
2
90. If the volume of regular tetrahedron OABC of unit edge is cubic units then is