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KEY SHEET
PHYSICS
1 C 2 A 3 A 4 C 5 A 6 A
7 CD 8 BC 9 AC 10 ABCD 11 AD 12 BC
13 2 14 2 15 3 16 3 17 2 18 0.75
CHEMISTRY
19 A 20 B 21 C 22 D 23 C 24 A
31 4 32 4 33 2 34 4 35 3 36 500
MATHEMATICS
37 A 38 D 39 B 40 A 41 C 42 B
43 BD 44 BD 45 ABCD 46 D 47 ABCD 48 BC
49 4 50 8 51 6 52 4 53 8 54 3.14
Sri Chaitanya IIT Academy 21-01-24_Sr.Super60_Elite,Target & LIIT-BTs_Jee-Adv(2020-P1)_GTA-12_Key& Sol’s
SOLUTIONS
PHYSICS
1. The system can be redraw as
A
4m
4m
4mg g
üa ý ý ý 5 m / s2
8m 2
ü v ý u at ý 2 ô 5 ý 10 m / s
2
dU 1 ö öy ö dKE
2. ý T÷ ÷ ý
dx 2 ø öx ø dx
mv 1
3. Rý Rõ
Bq B
4.
V
at
aC
a
tan 30 ý T ----------- (1)
aC
at ý 3 t
ö 3 2ö
aC ý ÷ t ÷
ø 2 ø
t ý ø 2ù
2/3
5. Distributing the currents in the circuit according to Kirchoffs law is shown in the figure.
In ideal voltmeter current = 0. Applying Kirchoffs law in mesh ABCDA
D A C
I
12V
i.e., I1 ý 6 A
Now apply Kirchhoffs law in AFBA
B ø I I1 ù ô 10 6 3I1 ý 0
2 13
i.e., 10 I 13I1 ý 2 or Iý ô 6 ý 8A
10 10
6.
y 18+N
MSD
Vernier
x
M
x M VSD ý ø18 N ù MSD
50VSD ý 47 MSD
47
1VSD ý MSD ý 0.94MSD
50
Given x ý 0.62mm
ø18 N ù MSD MVSD ý 7.62mm
18 N M ø 0.94 ù ý 0.62
M must be an integer
Now option A N ý 8, M ý 27
Option B N ý 2, M ý 20.65 øWrong ù
OptionC N ý 3, M ý 21.7 øWrong ù
Option D N ý 1, M ý 19.55 øWrong ù
ö k k' ö
7. Sol: fR øt ù ý ÷ ÷ f øt ù
÷ k k' ÷ i
ø ø
y
x y
R
a H
mg x
Sec : Sr.Super60_ Elite, Target & LIIT‐BTs Page 4
Sri Chaitanya IIT Academy 21-01-24_Sr.Super60_Elite,Target & LIIT-BTs_Jee-Adv(2020-P1)_GTA-12_Key& Sol’s
dy 1 dv
v= mg-ρL . πx 2 y.g=m.
dt 2 dt
dv πx 2 ygρ L ρ x 2 yg dv ρ
=g- g g- L × v. =g- L gy 2
dt πR 2H ρs R 2 H dy ρs
2ρs
2
0 H
ö ρL 2 ö gρ L ρL
vdv= ø ρs ø
÷ g- gy ÷ dy o=gH-
3ρs
H
ρs
=3
0 0
12. Sol: Zero error ý ø 2.00 0.04 ù ý 1.96 mm
Thickness ý 8.04 1.96 ý 10.00mm
ò
13. Angular fringe width ñ ò ý ý
D d
According to the given condition
ð 6 ô 107 ô 180 ô 60
ó dü
d 180 ô 60 ð
d max ý 2.06 ô 103 m
d max ý 2.06 mm
14. Conceptual
15. Disc will move translationally if line of action of force passes through c.m of
semicircular disc
ycm ý
y dm 3ð R
ý So value of K=3
dm 16
16. Conceptual
17. Initially let number of molecules of A ý N A and that of B ý N B
NA 25 2
ý ü100 N A ý 25 N A 50 N B N A ý N B
N A 2 N B 100 3
N B e t
2
ý N Aet ý N B et
' 2 3 75 3
Now, N A ý ý
3 2 t 2 t 100 4
N B e 2 N B e
3
ln ø 9 ù 2ln ø 3ù
1 ý 9et et ý 9 So, t ý
1 3
ý hr ý ý 2hr
1 3e t 4 ln ø 3 ù
m 3l 3
18. Sol: F ý 2 ô ý m 2l
2 4 8
CHEMISTRY
19. Ans: A
SOL- For Li 2 ,n ý 6 to n ý 3 For He , the similar transition is 4 to 2
It means when electron of He absorbes energy at n=2 it will go to n=4
22
Energy of 4th orbit of He ý 13.6 ô ý 3.4 eV
42
20. Ans: B
Sol : Iodo lactonisation followed by dehydrohalogenation
21. Ans: C
Sol : Intramolecular aldol condensation gives 6 membered ring as major product
22. Ans: D
Sol : O
OH
HO
+
H
HO O
23. Key:C
Hint: CO: Bond order = 3 and NO : bond order = 2
24. Key:A
2
Hint: ùû Ni ø CO ù4 ùû : Ni0 : sp3 ùû Ni ø CN ù4 ùû : Ni 2 : dsp 2
25. Conceptual
26. Conceptual
27. C-leaving group present in equatorial position , E2 elimination will not takes place.
28. Conceptual
29. MnO 4 - coloured ; TcO 4 and Re O 4 are colourless as the energy required for the charge
transfer process corresponds to absorption in the UV.
30. NCl3 ø106.8 ù þ PCl3 ø100.3ù
31. Ans-4
øøö 2 Bi 3 3S 2
Sol Bi2 S3 ÷øø
2 3 3 3
K sp ý ù Bi 3 ù ù S 2 ù 1056 ý (0.1) 2 ù S 2 ù 1054 ý ù S 2 ù
û û û û û û û û
ù S 2 ù ý 1018 mole / l øøö 2 H S 2 û Ka ý
H 2 S ÷øø
û û
2 2
ù H ù ù S 2 ù ù H ù ô 1018
Ka ý û û û û 1021 ý û û
û H 2S ý 0.1
ù H ù ý 102 Molar ûü x ý 2ý 1
M .eq of HCl ý ô m.es of Na2CO3
û û 2
1
102 ô 1 ô 4000 ý ô y ô 2 ô 20 y ý 2 ANS(x+y) =4
2
Sec : Sr.Super60_ Elite, Target & LIIT‐BTs Page 6
Sri Chaitanya IIT Academy 21-01-24_Sr.Super60_Elite,Target & LIIT-BTs_Jee-Adv(2020-P1)_GTA-12_Key& Sol’s
32. ANS-4
SOL-1) CH 3 CHO 2) CH 3 CH 2 CHO
O
H
5) 6)
OH O
33. ANS-2
SOL- X=4
Y=6
COOH
COOH
O COOH
NO 2 CF3
Y= H C OH , COOH , , , Picric acid, 2,4- dinitro phenol
H2N C NH
N NH2
X= H , ,, p-anisidine, m-toluidine
34. Key:4
Hint: ùûCu ø NH3 ù4 ùû SO4 4CH3COOH CuSO 4 4CH3COONH 4
2CuSO4 K 4 ùû Fe ø CN ù6 ùû Cu 2 ùû Fe ø CN ù6 ùû 2K 2SO 4
35. Key:3
2 2
Hint:(i) ùCo ø H 2O ù ù
û 6û
4Cl û CoCl4 ý 6H 2O, H ý ve
ø pink ù ø blue ù
(iii) Mn 2 : acts as auto catalyst
(vii) SO 2 decolourises the pink colour of acidified KMnO 4
36. ANS-500
SOL-
A 2B C
t ý 0 4a 0 3a
t ý t 4a x 2x 3a x
From the question
ø 4 a x ù ø 40 ù 2 x ø10 ù ø 3a x ù ø 30 ù ý 0
7
üx ý a
5
1 4a 1 20
Now, t ý K ô ln 7
ý
0.001
,ln
13
ý 500 min
4a a
5
MATHEMATICS
dx dy x 2dy y 2dx
37. ý0
x y ø x yù 2
dy dx
dx dy y 2 x 2
x y 1 1 ý0
y x
1
log x log y ýc
1 1
y x
38. abcý7/4
ö 1 ö
39. Any point on ø t 2 ùø x y ù ý 1is ÷ ñ , ñ ÷
ø t2 ø
Equation of chord of contact is 4 xñ 16 y
ö 1 ö
÷ ñ ÷ ý1
øt 2 ø
ö 16 ö
ñ ø 4 x 16 y ù ÷ y 1÷ ý 0
øt 2 ø
ö 16 ö
The chord of contact passes through the intersection of x 4 y ý 0 and ÷ y 1÷ ý 0
øt 2 ø
öt 2 t 2ö
üThe point of intersection is ÷ , ÷
ø 4 16 ø
2 2
öt 2ö öt 2ö
It lies inside the ellipse if 4 ÷ ÷ 16 ÷ ÷ 1 ü 0
ø 4 ø ø 16 ø
ö 4 ö ö 4 ö
=÷ 2÷ ü t ü ÷ 2 ÷ t ý 3, 1
ø 5 ø ø 5 ø
(0,2)
F1
E1 E2
F2
ø ù ø
F1 1, 3 and F2 1, 3 ù
Tangent at E1 : 3 x y ý 4
Tangent at E2 : 3 x y ý 4
ü E5 ø 0,4 ù
Tangent at : F1 : x 3 y ý 4
Tangent at F2 : x 3 y ý 4
ü F5 ø 4,0 ù
And similarly G5 ø 2,2 ù
ø 0,4 ù , ø 4,0ù and ø 2,2ù lies on x yý4
ý ÷
4 ø ø
t 3 ö
ù 16 ö
sin y 3 9 y y 2 ÷ dy
3ø
Notice sin ø y3 9 y ù is an odd function in y, we have
4
ù y 3 16 y ù
I ø7ù ý
4 ö
4 ÷ø
3
ø ù
2 16 ö
sin y 9 y y ÷ dy ý
3ø
4 ö 2 16 ö
4 ÷ø
y ÷ dy ý ú
3ø úû 3
ú
úû
ý0
4
For t þ 7, we have
dI ø t ù
dt
ø ù
ý sin y 3 9 y y 2
16
3
2 16
y ýt 3 ó 1 ø t 3ù
3
19
þ 42 þ 0
3
This means I ø t ù is strictly increasing on û 7, ù and I ø t ù þ I ø 7 ù ý 0 whenever t >7.
As a result, 7 is the largest t where I ø t ù ý 0
43. If n=m then equation becomes z n =z m and it has infinite solution because any z real
n m m
will satisfy it. If n m , let n>m, then, z n ý z m z ý z z z
nm
1 ý 0 ø ù
z ý 0 or z ý 1, z ý 0 z ý 0 i 0 z ý 1 z ý eiñ eø
m n ùñ i
ý1 z ý1 ø
1/ m n ù
(iv) (v)
In case (i), there are four lines, each containing five points. Hence there are
ö5ö
4 ô ÷ ÷ ý 40 collinear triplets. In case (ii) and case (iii) combined, there are nine lines
ø 3ø
ö 4ö
altogether, each containing four points. Hence there are 9 ô ÷ ÷ ý 36 collinear triplets. In
ø 3ø
case (iv) and case (v) combined, there are eight lines altogether, each containing three
ö 3ö
points. Thus there are 8 ô ÷ ÷ ý 8 collinear triplets. Thus the answer is
ø 3ø
1140 ø 40 36 8ù ý 1056
45. 8 4
ø 4 2
x +x +1= x +x +1 x -x +1 ùø 4 2
ù
ø ùø ù ø
Also x 4 +x 2 +1= x 2 +x+1 x 2 -x 2 +1 and x 4 -x 2 +1= x 2 3x 1 x 2 3x 1 ùø ù
46. Conceptual
ð
47. Let x ý r cosñ & y ý r sin ñ ,0 ü ñ ü , then z=r and
4
1
5r 2 cos 2 ñ 4r 2 sin ñ cosñ r 2 sin 2 ñ r 2 ý
2cos 2ñ 2sin 2ñ 3
dr sin 2ñ cos 2ñ
r ý2
dñ ø 2cos 2ñ 2sin 2ñ 3ù2
ð ð
Now r is increasing if sin 2ñ þ cos 2ñ tan 2ñ þ 1 üñ ü .
8 4
ð
And r is decreasing if sin 2ñ ü cos 2ñ tan 2ñ ü 1 0 ü ñ ü .
8
ð
Now for ñ ý
8
1
,r2 ý
3 2 2
ø ù
i.e. 3 2 2 hence r ý 2 1.
ñò ñ ò ñ ò ñ ò ö ñ ò ö
48. 2sin cos ý sin øñ ò ù 2cos cos ÷ cos 0÷
2 2 2 2 ø 2 ø
ñ ò ñ ò ñ ò
sin ý 2sin cos 2
2 2 2
ñ ò
2cos 2 1 ý 0
2
cos øñ ò ù ý 0 ñ ò ý 90
ý 90 ý cot 1 ø 0 ù
ü0 x ü a
49. Use Srk ø x 0 ù ý ý
þ1 x ó a
N th
50. The class interval containing or 25th item is 20-30. Therefore, 20-30 is the median
2
class. We know that
N
C
Median ý l 2 ôh
f
Here l ý 20, C ý 13, f ý 15, h ý 10 and N ý 50
25 13
Therefore, Median ý 20 ô 10 ý 20 8 ý 28
15
Thus, Mean deviation about median is given by
1 6 1
M.D. (M) ý õ fi xi M ý ô 508 ý 10.16
N i ý1 50
1 r 1ö 1 1 ö
51. Use ý ÷ n1 n ÷
n
Cr 1 r ÷ø Cr Cr ÷
ø
52. N = 1980.6!.7!.10!
ö1 1 ö ö 1 1 ö ö 1 1 ö 9d
53. ÷ ÷ ÷ ÷ ....... ÷ ÷ý
ø 1
a a2ø ø 2a a3ø ø 9
a a10 ø 64
a a 9d
10 1 ý a1a10 ý 64
a1a10 64
ö 1 1 ö a1 a10 ö 1 1 ö
Also ø a1 a10 ù ÷ ...... ÷ý ÷ ..... ÷
ø a1a10 a10a1 ø 10 ø a1 a10 ø
ö1 1 ö a1 a10 ö 1 1 ö
2 ÷ ..... ÷ý ÷ ..... ÷ a1 a10 ý 20
ø a1 a10 ø 10 ø a1 a10 ø
54.
ü ð ðü
f ø x ù ý sin 1[t ] sin 1 øût ý 1ù ý , ý
þ 2 2þ