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Sri Chaitanya IIT Academy.,India.

 A.P  T.S  KARNATAKA  TAMILNADU  MAHARASTRA  DELHI  RANCHI


A right Choice for the Real Aspirant
ICON Central Office - Madhapur - Hyderabad
Sec:Sr.Super60_Elite, Target & LIIT‐BTs Adv-2020-P1-Model Date: 21-01-2024
Time: 02.30Pm to 05.30Pm GTA-12 Max. Marks: 198

KEY SHEET
PHYSICS
1 C 2 A 3 A 4 C 5 A 6 A

7 CD 8 BC 9 AC 10 ABCD 11 AD 12 BC

13 2 14 2 15 3 16 3 17 2 18 0.75

CHEMISTRY
19 A 20 B 21 C 22 D 23 C 24 A

25 ABCD 26 ABD 27 BCD 28 BC 29 BCD 30 ABC

31 4 32 4 33 2 34 4 35 3 36 500

MATHEMATICS
37 A 38 D 39 B 40 A 41 C 42 B

43 BD 44 BD 45 ABCD 46 D 47 ABCD 48 BC

49 4 50 8 51 6 52 4 53 8 54 3.14
Sri Chaitanya IIT Academy 21-01-24_Sr.Super60_Elite,Target & LIIT-BTs_Jee-Adv(2020-P1)_GTA-12_Key& Sol’s

SOLUTIONS
PHYSICS
1. The system can be redraw as

A
4m

4m
4mg g
üa ý ý ý 5 m / s2
8m 2
ü v ý u  at ý 2 ô 5 ý 10 m / s
2
dU 1 ö öy ö dKE
2. ý T÷ ÷ ý
dx 2 ø öx ø dx
mv 1
3. Rý Rõ
Bq B
4.
V

at
aC

a
tan 30 ý T ----------- (1)
aC
at ý 3 t
ö 3 2ö
aC ý ÷ t ÷
ø 2 ø
t ý ø 2ù
2/3

5. Distributing the currents in the circuit according to Kirchoffs law is shown in the figure.
In ideal voltmeter current = 0. Applying Kirchoffs law in mesh ABCDA

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Sri Chaitanya IIT Academy 21-01-24_Sr.Super60_Elite,Target & LIIT-BTs_Jee-Adv(2020-P1)_GTA-12_Key& Sol’s
F
ø I  I1 ù
8V
 10
V
ø I  I1 ù 
3
A B
I1 G 6V

D A C
I
12V
i.e., I1 ý 6 A
Now apply Kirchhoffs law in AFBA
B  ø I  I1 ù ô 10  6  3I1 ý 0
2 13
i.e., 10 I  13I1 ý 2 or Iý  ô 6 ý 8A
10 10
6.
y 18+N
MSD

Vernier

x
M
x  M VSD ý ø18  N ù MSD
50VSD ý 47 MSD
47
1VSD ý MSD ý 0.94MSD
50
Given x ý 0.62mm
ø18  N ù MSD  MVSD ý 7.62mm
18  N  M ø 0.94 ù ý 0.62
M must be an integer
Now option A  N ý 8, M ý 27
Option B  N ý 2, M ý 20.65 øWrong ù
OptionC  N ý 3, M ý 21.7 øWrong ù
Option D  N ý 1, M ý 19.55 øWrong ù
ö k  k' ö
7. Sol: fR øt ù ý ÷ ÷ f øt ù
÷ k  k' ÷ i
ø ø

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Sri Chaitanya IIT Academy 21-01-24_Sr.Super60_Elite,Target & LIIT-BTs_Jee-Adv(2020-P1)_GTA-12_Key& Sol’s
ö 2k ö
fT ø t ù ý ÷ ÷ fi ø t ù
ø k  k' ø
8. Force on the sheet due to the point charge=charge density electric flux passing through
the sheet
9. When shell strikes the ball and gets stuck with it, combined body of mass 2m starts to
move to the right. Let velocity of combined body (just after collision) be v1 . According
to law of conservation of momentum.
v
ø m+m ù v1=mv0 or v1= 0 =3ms-1
2
As soon as the combined body starts to move rightwards, thread becomes inclined to the
vertical. Horizontal component of its tension retards the combined body while trolley
accelerates rightwards due to the same component of tension.
Inclination of thread with the vertical continues to increase till velocities of both
(combined body and trolley) become identical or combined body comes to rest relative to
trolley. Let velocity at that instant of maximum inclination of thread be v. According to
law of conservation of momentum.
ø 2m+M ù V=2m.v1 or v=1ms-1
During collision of ball and shell, a part of energy is lost. But after that, there is no loss of
energy. Hence, after collision, kinetic energy lost is used up in increasing gravitational
potential energy of the combined body.
If maximum inclination of thread with the vertical be θ then according to law of
conservation of energy.
1 1
ø 2m ù v12 - ø 2m+M ù v2 =2mg ø -cosθ ù ü cosθ=0.8or θ=37°
2 2
Force xAò g
10. Sol: Stress in the element ý ý ý xò g
Area A
Now, elastic potential energy stored in the wire is
1 ø Stress ù
2
1
dU ý ø Stress ùø Strain ùøVolume ù ý . øVolume ù
2 2 Y
1 ø xò g ù
2
1 ò 2g 2 A 2
dU ý . Adx ý . x dx
2 Y 2 Y
1 ò 2g 2 A L 2 ò 2 g 2 AL
Y 0
Total elastic potential energy= . x dx ý
2 6Y
H 2
11. Let Y=ax 2 (A parabola) Y= x (from given data)
2
R
Fup

y
x y
R
a H
mg x
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Sri Chaitanya IIT Academy 21-01-24_Sr.Super60_Elite,Target & LIIT-BTs_Jee-Adv(2020-P1)_GTA-12_Key& Sol’s
dy 1 dv
v= mg-ρL . πx 2 y.g=m.
dt 2 dt
dv πx 2 ygρ L ρ x 2 yg dv ρ
=g- g  g- L × v. =g- L gy 2
dt πR 2H ρs R 2 H dy ρs
2ρs
2
0 H
ö ρL 2 ö gρ L ρL
 vdv=  ø ρs ø
÷ g- gy ÷ dy o=gH-
3ρs
H
ρs
=3
0 0
12. Sol: Zero error ý  ø 2.00  0.04 ù ý 1.96 mm
Thickness ý 8.04  1.96 ý 10.00mm
ò 
13. Angular fringe width ñ ò ý ý
D d
According to the given condition
 ð 6 ô 107 ô 180 ô 60
ó dü
d 180 ô 60 ð
d max ý 2.06 ô 103 m
d max ý 2.06 mm
14. Conceptual
15. Disc will move translationally if line of action of force passes through c.m of
semicircular disc

ycm ý 
y dm 3ð R
ý So value of K=3
 dm 16
16. Conceptual
17. Initially let number of molecules of A ý N A and that of B ý N B
NA 25 2
ý ü100 N A ý 25 N A  50 N B  N A ý N B
 N A  2 N B 100 3

 N B e t
2
ý N Aet ý N B et
' 2 3 75 3
Now, N A ý ý
3 2 t 2 t 100 4
 N B e  2 N B e
3
ln ø 9 ù 2ln ø 3ù
 1 ý 9et  et ý 9 So, t ý
1 3
 ý hr ý ý 2hr
1  3e t 4  ln ø 3 ù
m 3l 3
18. Sol: F ý  2 ô ý m 2l
2 4 8

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Sri Chaitanya IIT Academy 21-01-24_Sr.Super60_Elite,Target & LIIT-BTs_Jee-Adv(2020-P1)_GTA-12_Key& Sol’s

CHEMISTRY
19. Ans: A
SOL- For Li 2 ,n ý 6 to n ý 3 For He  , the similar transition is 4 to 2
It means when electron of He absorbes energy at n=2 it will go to n=4
22
Energy of 4th orbit of He ý 13.6 ô ý 3.4 eV
42
20. Ans: B
Sol : Iodo lactonisation followed by dehydrohalogenation
21. Ans: C
Sol : Intramolecular aldol condensation gives 6 membered ring as major product
22. Ans: D
Sol : O
OH
HO

+
H

HO O

23. Key:C
Hint: CO: Bond order = 3 and NO : bond order = 2
24. Key:A
2
Hint: ùû Ni ø CO ù4 ùû : Ni0 : sp3 ùû Ni ø CN ù4 ùû : Ni 2  : dsp 2
25. Conceptual
26. Conceptual
27. C-leaving group present in equatorial position , E2 elimination will not takes place.
28. Conceptual
29. MnO 4 - coloured ; TcO 4 and Re O 4 are colourless as the energy required for the charge
transfer process corresponds to absorption in the UV.
30. NCl3 ø106.8 ù þ PCl3 ø100.3ù
31. Ans-4
øøö 2 Bi 3  3S 2
Sol Bi2 S3 ÷øø
2 3 3 3
K sp ý ù Bi 3 ù ù S 2 ù 1056 ý (0.1) 2 ù S 2 ù 1054 ý ù S 2 ù
û û û û û û û û
ù S 2 ù ý 1018 mole / l øøö 2 H   S 2 û Ka ý
H 2 S ÷øø
û û
2 2
ù H  ù ù S 2 ù ù H  ù ô 1018
Ka ý û û û û 1021 ý û û
û H 2S ý 0.1
ù H  ù ý 102 Molar ûü x ý 2ý 1
M .eq of HCl ý ô m.es of Na2CO3
û û 2
1
102 ô 1 ô 4000 ý ô y ô 2 ô 20 y ý 2 ANS(x+y) =4
2
Sec : Sr.Super60_ Elite, Target & LIIT‐BTs Page 6
Sri Chaitanya IIT Academy 21-01-24_Sr.Super60_Elite,Target & LIIT-BTs_Jee-Adv(2020-P1)_GTA-12_Key& Sol’s
32. ANS-4
SOL-1) CH 3  CHO 2) CH 3  CH 2  CHO
O
H

5) 6)
OH O

33. ANS-2
SOL- X=4
Y=6
COOH
COOH

O COOH
NO 2 CF3
Y= H C OH , COOH , , , Picric acid, 2,4- dinitro phenol

H2N C NH
N NH2
X= H , ,, p-anisidine, m-toluidine
34. Key:4
Hint: ùûCu ø NH3 ù4 ùû SO4  4CH3COOH  CuSO 4  4CH3COONH 4
2CuSO4  K 4 ùû Fe ø CN ù6 ùû  Cu 2 ùû Fe ø CN ù6 ùû  2K 2SO 4
35. Key:3
2 2
Hint:(i) ùCo ø H 2O ù ù
û 6û
 4Cl  û CoCl4 ý  6H 2O, H ý  ve
ø pink ù ø blue ù
(iii) Mn 2  : acts as auto catalyst
(vii) SO 2 decolourises the pink colour of acidified KMnO 4
36. ANS-500
SOL-
A  2B  C
t ý 0 4a 0 3a
t ý t 4a  x 2x 3a  x
From the question
ø 4 a  x ù ø 40 ù  2 x ø10 ù  ø 3a  x ù ø  30 ù ý 0
7
üx ý a
5
1 4a 1 20
Now, t ý K ô ln 7
ý
0.001
,ln
13
ý 500 min
4a  a
5

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Sri Chaitanya IIT Academy 21-01-24_Sr.Super60_Elite,Target & LIIT-BTs_Jee-Adv(2020-P1)_GTA-12_Key& Sol’s

MATHEMATICS
dx dy x 2dy  y 2dx
37.   ý0
x y ø x  yù 2

dy dx

dx dy y 2 x 2
 x  y  1 1 ý0

y x
1
log x  log y  ýc
1 1

y x
38. abcý7/4
ö 1 ö
39. Any point on ø t  2 ùø x  y ù ý 1is ÷ ñ , ñ ÷
ø t2 ø
Equation of chord of contact is 4 xñ  16 y
ö 1 ö
÷ ñ ÷ ý1
øt 2 ø
ö 16 ö
 ñ ø 4 x  16 y ù  ÷ y  1÷ ý 0
øt 2 ø
ö 16 ö
The chord of contact passes through the intersection of x  4 y ý 0 and ÷ y  1÷ ý 0
øt 2 ø
öt 2 t 2ö
üThe point of intersection is ÷ , ÷
ø 4 16 ø
2 2
öt 2ö öt 2ö
It lies inside the ellipse if 4 ÷ ÷  16 ÷ ÷ 1 ü 0
ø 4 ø ø 16 ø
ö 4 ö ö 4 ö
=÷   2÷ ü t ü ÷  2 ÷  t ý 3, 1
ø 5 ø ø 5 ø
(0,2)
F1
E1 E2

40. (-2,0) (2,0)

F2

Co-ordinates of E1 and E2 are obtained bysolving y ý 1 and x 2  y 2 ý 4


ø
ü E1  3,1 and E2ù ø 3,1 ù
Co-ordinates of F1and F2 are obtained by solving
x ý 1 and x 2  y 2 ý 4

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Sri Chaitanya IIT Academy 21-01-24_Sr.Super60_Elite,Target & LIIT-BTs_Jee-Adv(2020-P1)_GTA-12_Key& Sol’s

ø ù ø
F1 1, 3 and F2 1,  3 ù
Tangent at E1 :  3 x  y ý 4
Tangent at E2 : 3 x  y ý 4
ü E5 ø 0,4 ù
Tangent at : F1 : x  3 y ý 4
Tangent at F2 : x  3 y ý 4
ü F5 ø 4,0 ù
And similarly G5 ø 2,2 ù
ø 0,4 ù , ø 4,0ù and ø 2,2ù lies on x yý4

ù a11 a12 a13 ù ù a12  a13 a11  a13 a11  a12 ù


41. Let A ý úú a21 a22 a23 úú B ý úú a22  a23 a21  a23 a21  a22 úú
úû a31 a32 a33 úû úû a32  a33 a31  a33 a31  a32 úû
Now A ý 1
ù c11 c21 c31 ù ù a12  a13 a11  a13 a11  a12 ù
1 ú
1
A B ý úc12 c22 c32 úú úú a22  a23 a21  a23 a21  a22 úú
A
úû c13 c23 c33 úû úû a32  a33 a31  a33 a31  a32 úû
ù0 A A ù ù0 1 1 ù
1 ú ú
ý úA 0 A ú ý ú1 0 1 ú
A ú ú
úû A A 0 úû úû1 1 0 úû
 n ý A1B ý 2
ù xù ù x ù ù6ù ù3ù
1 ú ú1 ú ú ú ú ú ú
Now A B y ý A y ý 4 ý 2
ú ú ú ú ú ú ú ú
ûú z ûú ûú z ûú ûú8 ûú ûú 4 ûú
ù0 1 1 ù ù x ù ù 3ù y z ý3
ú1 0 1 ú ú y ú ý ú 2 ú  x  z ý 2
ú úú ú ú ú
úû1 1 0 úû úû z úû úû 4 úû x  y ý 4
3 5 1
x ý , y ý ,z ý
2 2 2
ü 2 ø x  y  z ù  n ý 9  2 ý 11
42. only STATEMENT-I and II are true.
Let x ý y  3, the integral at hand can be rewritten as
t ö
1ø ø ù 11 ö
I ø t ù def ý  ÷ sin x3  9 x 2  18  x 2  6 x  ÷ dx

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Sri Chaitanya IIT Academy 21-01-24_Sr.Super60_Elite,Target & LIIT-BTs_Jee-Adv(2020-P1)_GTA-12_Key& Sol’s

ý ÷
4 ø ø
t 3 ö
ù 16 ö
sin y 3  9 y  y 2  ÷ dy

Notice sin ø y3  9 y ù is an odd function in y, we have
4
ù y 3  16 y ù
I ø7ù ý
4 ö

4 ÷ø
3
ø ù
2 16 ö
sin y  9 y  y  ÷ dy ý

4 ö 2 16 ö
4 ÷ø 
y  ÷ dy ý ú
3ø úû 3
ú
úû
ý0
4
For t þ 7, we have
dI ø t ù
dt
ø ù
ý sin y 3  9 y  y 2 
16
3
2 16
y ýt 3 ó 1  ø t  3ù 
3
19
þ 42  þ 0
3
This means I ø t ù is strictly increasing on û 7, ù and I ø t ù þ I ø 7 ù ý 0 whenever t >7.
As a result, 7 is the largest t where I ø t ù ý 0
43. If n=m then equation becomes z n =z m and it has infinite solution because any z  real
n m m
will satisfy it. If n  m , let n>m, then, z n ý z m  z ý z z z
nm
1 ý 0 ø ù
 z ý 0 or z ý 1, z ý 0  z ý 0  i 0 z ý 1  z ý eiñ  eø
m  n ùñ i
ý1 z ý1 ø
1/ m  n ù

 number of solutions is m+n+1


ö 20 ö 20  19  18
44. There are ÷ ÷ ý ý 1140 ways to choose three points. But not all of these
ø3ø 3!
triplets form non-degenerate triangles. We need to find how many triplets are collinear.
We consider the five cases shown in following figures.

(i) (ii) (iii)

(iv) (v)
In case (i), there are four lines, each containing five points. Hence there are
ö5ö
4 ô ÷ ÷ ý 40 collinear triplets. In case (ii) and case (iii) combined, there are nine lines
ø 3ø
ö 4ö
altogether, each containing four points. Hence there are 9 ô ÷ ÷ ý 36 collinear triplets. In
ø 3ø
case (iv) and case (v) combined, there are eight lines altogether, each containing three
ö 3ö
points. Thus there are 8 ô ÷ ÷ ý 8 collinear triplets. Thus the answer is
ø 3ø
1140  ø 40  36  8ù ý 1056

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Sri Chaitanya IIT Academy 21-01-24_Sr.Super60_Elite,Target & LIIT-BTs_Jee-Adv(2020-P1)_GTA-12_Key& Sol’s

45. 8 4
ø 4 2
x +x +1= x +x +1 x -x +1 ùø 4 2
ù
ø ùø ù ø
Also x 4 +x 2 +1= x 2 +x+1 x 2 -x 2 +1 and x 4 -x 2 +1= x 2  3x  1 x 2  3x  1 ùø ù
46. Conceptual
ð
47. Let x ý r cosñ & y ý r sin ñ ,0 ü ñ ü , then z=r and
4
1
5r 2 cos 2 ñ  4r 2 sin ñ cosñ  r 2 sin 2 ñ  r 2 ý
2cos 2ñ  2sin 2ñ  3
dr sin 2ñ  cos 2ñ
r ý2
dñ ø 2cos 2ñ  2sin 2ñ  3ù2
ð ð
Now r is increasing if sin 2ñ þ cos 2ñ  tan 2ñ þ 1  üñ ü .
8 4
ð
And r is decreasing if sin 2ñ ü cos 2ñ  tan 2ñ ü 1  0 ü ñ ü .
8
ð
Now for ñ ý
8
1
,r2 ý
3 2 2
ø ù
i.e. 3  2 2 hence r ý 2  1.

ñò ñ ò ñ ò ñ ò ö ñ ò ö
48. 2sin cos ý sin øñ  ò ù 2cos cos ÷ cos  0÷
2 2 2 2 ø 2 ø
ñ ò ñ ò ñ ò
sin ý 2sin cos 2
2 2 2
ñ ò
2cos 2 1 ý 0
2
cos øñ  ò ù ý 0  ñ  ò ý 90
  ý 90 ý cot 1 ø 0 ù
ü0 x ü a
49. Use Srk ø x  0 ù ý ý
þ1 x ó a
N th
50. The class interval containing or 25th item is 20-30. Therefore, 20-30 is the median
2
class. We know that
N
C
Median ý l  2 ôh
f
Here l ý 20, C ý 13, f ý 15, h ý 10 and N ý 50
25  13
Therefore, Median ý 20  ô 10 ý 20  8 ý 28
15
Thus, Mean deviation about median is given by
1 6 1
M.D. (M) ý õ fi xi  M ý ô 508 ý 10.16
N i ý1 50

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Sri Chaitanya IIT Academy 21-01-24_Sr.Super60_Elite,Target & LIIT-BTs_Jee-Adv(2020-P1)_GTA-12_Key& Sol’s

1 r  1ö 1 1 ö
51. Use ý ÷ n1  n ÷
n
Cr 1 r ÷ø Cr Cr ÷
ø

52. N = 1980.6!.7!.10!
ö1 1 ö ö 1 1 ö ö 1 1 ö 9d
53. ÷  ÷  ÷  ÷  .......  ÷  ÷ý
ø 1
a a2ø ø 2a a3ø ø 9
a a10 ø 64
a  a 9d
 10 1 ý  a1a10 ý 64
a1a10 64
ö 1 1 ö a1  a10 ö 1 1 ö
Also ø a1  a10 ù ÷  ......  ÷ý ÷  ..... ÷
ø a1a10 a10a1 ø 10 ø a1 a10 ø
ö1 1 ö a1  a10 ö 1 1 ö
 2 ÷  .....  ÷ý ÷  .....  ÷  a1  a10 ý 20
ø a1 a10 ø 10 ø a1 a10 ø
54.
ü ð ðü
f ø x ù ý sin 1[t ]  sin 1 øût ý  1ù  ý , ý
þ 2 2þ

Sec : Sr.Super60_ Elite, Target & LIIT‐BTs Page 12

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