Narayana IIT Academy 07-12-16 Sr.

IIT-IZ-CO-SPARK_Jee-Adv_(2015_P2)_Key Sol’s

NARAYANA IIT ACADEMY

INDIA
Sec: Sr.IIT-IZ-CO-SPARK RPTA-13 DATE : 07-12-16
TIME : 02:00 PM TO 05: 00 PM 2015_P2 MAX MARKS : 240
KEY & SOLUTIONS

PHYSICS
1 4 2 7 3 2 4 3 5 0

6 2 7 4 8 4 9 A 10 ABCD

11 BD 12 B 13 BCD 14 D 15 AC

16 AC 17 AC 18 C 19 AC 20 ACD

CHEMISTRY
21 8 22 3 23 8 24 1 25 7

26 4 27 4 28 9 29 ABCD 30 AB

31 ACD 32 ABCD 33 A 34 AB 35 AB

36 ABC 37 A 38 C 39 C 40 D

MATHEMATICS
41 8 42 6 43 0 44 8 45 4

46 6 47 5 48 1 49 ABCD 50 BC

51 BCD 52 AD 53 ACD 54 ABCD 55 AD

56 BCD 57 C 58 D 59 A 60 C

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Narayana IIT Academy 07-12-16 Sr.IIT-IZ-CO-SPARK_Jee-Adv_(2015_P2)_Key Sol’s
SOLUTIONS
PHYSICS
1.
Q Q Q Q
  
2 2 2 2

imax

Let Q  CV0 . At an instant when current in circuit is maximum emf across inductor
will be zero. Net potential difference across two capacitor will be zero
instantaneously.
  Q 2 
 
1 2 1 Q 2  1  2  
L imax   2
2 2 C 2 C 
 
 

2 Q2  1 
imax   
LC  2 

2 CV0
imax 
2 LC

2.

~
Let independence of upper and lower branch z1 and z2 .
 
z1  10, z2  10 , current upper branch i1  2 sin   t  
 3


Current in lower branch i2  2 sin   t  
 6

 
Current through source i1  i2  2sin   t  
 12 

V0 i0  
Pavg  cos  
2  12 
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Narayana IIT Academy 07-12-16 Sr.IIT-IZ-CO-SPARK_Jee-Adv_(2015_P2)_Key Sol’s
 5 2  0.96 

 6.8
x7
3. Net flux passing through complete loop is a 2 B
dB 
Emf induced in loop is  a 2    20a
2

 dt 

20a 2
Current in loop i  ;  is resistance per unit length.
12a
i  2 amp

4. Ratio of area of  OCD to  OAB is the ratio of emf in reach CD and AB.
5. Flux through each plane is zero.
0 I  Rb
6. Magnetic flux through conducting loop  a ln  
2  R 
0 I 0a  5 
emf  ln   cos1000 t
2 4
0 5
Maximum emf   I 0   ln  a
2  4

 5
 2 107 10 1000  ln  a
 4

5
 2 10 3 ln   a
4

7. Current in circumferential direction per unit axial length of tube is  I 0 cos

    0 I 0 cos  sin  t  A

emf  0 I0 A cos  cos  t

2
erms
Average rate of heating 
R
2

P
 0 I 0 A  cos 2 
2R

5
8. z R  X C2  R 2
2
1 R
XC  
C 2
RC  4
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Narayana IIT Academy 07-12-16 Sr.IIT-IZ-CO-SPARK_Jee-Adv_(2015_P2)_Key Sol’s

9. I  mv (1)
Emf in rod e  Blv (2)
e
Current in loop i  (3)
Rloop

1 3
10    2
i 2 3  2 amp
5
l
Potential difference across terminals of rod is B v  iR  16V
2
10. Induced electric field lines must form close curves. But in confined finite space field
may be uniform.
11.
i1
x

i3
z
y
i2

Current i3  i1  i2  5 2 sin 100 t 


Potential of junction at z is VZ  5 2 sin 100 t  
 2

 
VZ  25 2 sin 100 t  
 2

 
Potential at x; Vx  i1 R  VZ  50sin 100 t    25 2 sin 100 t  
 4  2

3 
Potential at y; V y  i2 X C  VZ  50sin  100 t   
  20 2 sin  100 t  
 4   2

 
V xy  100sin  100 t  
 4

Net heat is getting released across resistor   irim 2 . R  125W

t
  
12. Charge built up on capacitor in initial 0 to  sec q  2CV0 1  e RC
  CV0 .
 

Let charge left on capacitor at the time instant t  2 is q.

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Narayana IIT Academy 07-12-16 Sr.IIT-IZ-CO-SPARK_Jee-Adv_(2015_P2)_Key Sol’s
 CV0  q  
ln  
 CV0  CV0  RC

q0

So in process charge buildup up to CV0 and decreases to O in each one period of

oscillation.
1 3
Heat released in charging process  2V0  CV0   CV02  CV02
2 2
1 3
Heat released in discharging process  CV02   CV0 V0  CV02
2 2
Net heat released in one oscillation  3CV02
2
3CV02   ieffective  R  2 

3CV02
ieff 
2 RI

Average reading of d.c. volt meter will be zero

13. Reactance of capacitor and inductor are 2k , and 1k respectively. Current is reading
over voltage so circuit must be capacitive in nature.
14. M . changes its sign.

15. X Z  2 R, X C  R , and resistance of resistor  3 R

2
Z  R2   3R   2R


Current lags behind voltage by
6
V3  V0 sin  t

V0  
I3  sin   t  
2R  6

Vs


Is

I s cos  is active component and I s sin  is a reactive component of current.


Wattles current IW   I s sin   sin   t   .
 2
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Narayana IIT Academy 07-12-16 Sr.IIT-IZ-CO-SPARK_Jee-Adv_(2015_P2)_Key Sol’s
16. Flux lines of one passes through other in opposite direction. Let current passing
through copper branch is i
Ldi Ldi
   iR   2i  R  0
dt dt
V
i 1  e 6 Rt / L 
3R 

Current through cell is  2 P  11  e 300 t  A

V2
Resistance of each bulb   50 
R
Safe current across each bulb = 2amp
Maximum allowed supply voltage = 150 volt
17. After magnetic field is turned on due to torrents force a circular component of current
gets generated. If battery supply is kept constant effective potential difference across
annulus in reduced due to this radial current in annulus as well as across battery
reduces, due to this power supply by battery reduces so heating in annulus reduces.
In another case when radial current in kept constant for this supply emf should be
increased. So power supply increases hence heating in annulus increases.
18. Current is metallic annulus in due to motion of free electrons. Figure shows net
electric, magnetic force and manner of motion of one free electron moving from outer
rim to inner rim.

VC eVC B

Vr
eVr B

++ + ++

19. resistivity of liquid nitrogen cooled ring will be very low so I r increases hence jump
height will be more Because of ferromagnetic substance in core magnetic field Bs
increases heavily so jump height will be more.
20. less resistance and less weight represents more jump height.

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Narayana IIT Academy 07-12-16 Sr.IIT-IZ-CO-SPARK_Jee-Adv_(2015_P2)_Key Sol’s
CHEMISTRY
21.
KE1  E ph  BE1  H  atom
KE2  E ph  BE2 He  ion 
KE2  KE1  12.75  BE1  BE2
 1 22 
12.75  13.6  2  2 
1 n 
n8

22.
hc hc
2E  E  ;E 
1 1
4E hc
E
3 2
E hc 3hc hc
 E 
3 2 2 1
2
 3
1

23. 1s 2 , 2s 2 , 2 pz 2 3s 2

24. Angular node or nodal plane for 4p is 1

25. 2 p z 2 ,3s 2 ,3 px 2 , 3d 1 xy

26.

 1 1 
48.3  13.6  z 2  2  2 
2 n 
1 1 
18.13  13.6  z 2   2 
9 n 
48.3 n 2  4 9n 2
  n4
18.13 n 2  9 4n 2
48.3 8
 z2 
13.6 36
2
z  16
z4

3 1000
27. Millimoles of N 2 H 4 .H 2o taken=  60
50

Millimoles of IO3 reacted = 20  0.1 10  20

Millimoles of N 2 H 4 .H 2O reacted = 60  20  40

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Narayana IIT Academy 07-12-16 Sr.IIT-IZ-CO-SPARK_Jee-Adv_(2015_P2)_Key Sol’s
x
1 millimole of M   m  n  millimoles of N 2 H 4 .H 2O

10 millimoles of M x  =40 millimoles of N 2 H 4 .H 2O

40
m  n  4
10
28. Distance between 92U 238 and 2 He4 neuclei
=radius of U 238 nucleus+radius of 2 He 4 nucleus
1 1
13 13
= 1.4 10   238  3  1.4 10  4  3 cm
1.0899 10 12 cm

z1 z 2e 2
Coulombic barrier =
d
2
92  2   4.8 1010 
=
1.0899 10 12
= 3.889 105 erg
29. (Text book reference)
Conversion of o/w to w/o emulsions and viceversa is inversion of phase
Argyrol is colloid of Ag used as an eye lotion
Basic dye stuffs are positively charged colloids
30. (Text book reference p-139)
Scattering of light is observed at right angles to induced light. Increase in size of
colloids increases tyndall effect
31. FeCl3 added to excess of hot water gives positively charged colloid

32. Electronic configuration table page no;-37

(Academy text book-1)
33. In P orbital  2 is zero at plane where two lobes touches each other

(Academy text book pageno:-30,31)

z2
th 13.6 
 13.6
34. BE of 4 state= n2
z  4
16
Energy of e in 3rd state= 13.6   25ev
9
For ‘C’ option

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Narayana IIT Academy 07-12-16 Sr.IIT-IZ-CO-SPARK_Jee-Adv_(2015_P2)_Key Sol’s
1 1 
E1  13.6 16     40.8ev
 4 16 
1 1 
E2  13.6  4     40.35ev
1 9 
For ‘D’ option
1 1 
E1  13.6 16     10.57ev
 9 16 
1 1 
E2  13.6     10.2ev
1 4 

35. Radical probability distribution curves for 1s orbital indicates electron probability
maximum at a distance of 0.53 A0
36.
 2  2  2 8 2 m
   2  E V   0
x 2 y 2 z 2 h
8 2 m
 2   E  V   0
h2
E  K V
k  E V
1
k  Mv 2
2
2
v2   E  V 
m
4 2 m 2 v 2
 2  0
2
4 2 m 2 v 2
 2  
2
4 2
 2  2 

HINT: for 37 & 38

Only Fe 2 is oxidized and MnO4 is reduced to Mn2

25  M  Fe2    25  0.02  5  MnO4 

M = 0.10M
Total Fe 2 in second part (including that of from Fe3 )-
25  y  40  0.02  5

y = 0.16 M = 0.16 N

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Narayana IIT Academy 07-12-16 Sr.IIT-IZ-CO-SPARK_Jee-Adv_(2015_P2)_Key Sol’s
Fe = 0.16 – 0.10( Fe 2 )
3

= 0.06 M
25mL of 0.10 M Fe 2 = V1 mL of 0.02 M K 2Cr2O7
 V1  0.02  6 N K 2Cr2O7

V1 = 20.83 mLs
MATHS
41. cauchy-schwarz
2
a  b 2 sin x  c sin 2 x   a 2
 b 2  c 2 1  2sin 2 x  sin 2 2 x 

  13  
 a  b 2 sin x  c sin 2 x  10   1, 
  2  
 5 13
 max.value  5 13  R.V  13  5  8
42. We know that tan 200  tan 800  tan 400  3 3
Squaring on both sides

tan 2 200  tan 2 800  tan 2 400  2 tan 20 0 tan 800  tan 800 tan 40 0  tan 400 tan 200 =27 
Upon simplification we get K=33
43. let z  cos60  i sin 60
2z 2iz 2 2iz 4 2iz 8
G.E  2
 4
 8
 16
  z15  i   z  i   0  z15  i 
z 1 z 1 z 1 z 1
2 2

44.
1  tan    1  tan  
2 2

tan 2  tan 2 

1  tan 4  1  tan 4  tan 2  2 tan 2 

   2 
tan 2  tan 2  tan 2  tan 2 

2 tan 2  2 tan 2  2 tan 2  2 tan 2 

    8
tan 2  tan 2  tan 2  tan 2 

 
4   1  tan 2 
 7
45. 

1  tan 2
7

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Narayana IIT Academy 07-12-16 Sr.IIT-IZ-CO-SPARK_Jee-Adv_(2015_P2)_Key Sol’s
2
4 cos  / 7 1
 
2 2
cos cos
7 7
2
1  2 cos
 7
2
cos
7
2 4
2sin  2sin
 7 7
4
sin
7
3 
4sin cos
 7 7
4
sin
7

= 4 cos
7

 k4

46. cos k  R.P of  eik  and proceed

 ln 6  .ln sin x , clearly f 0  

47. Let f  x   1     
 ln 2  ln 3
f     
Also f  x   f   x 

f 1  x 
 ln 6  .cot x
 ln 2  ln 3
 
0 x   0,  
 2  
 f   1
   2
0 x   , 
 2  
 ln 2  ln 3

f  x   0  ln  sin x   
 ln 2  ln 3  x  sin 1  e  ln 6


 ln 6  



   lnln2 6ln 3   lnln26ln 3  
   ,   sin  e    
  ,    sin  e
1 1

    
    

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Narayana IIT Academy 07-12-16 Sr.IIT-IZ-CO-SPARK_Jee-Adv_(2015_P2)_Key Sol’s
 ln 2  ln 3
 
 ln 6 
       2sin 1  e 
 
 

  lnln26ln 3    lnln26ln 3 
1      2.cos  e   
1
 2.   sin  e
 2    
   

  2 &   1  3    5
48. Form equation having roots as cos  , cos  and sin  ,sin 
50. Man value of f(x) is 13
F(x) is even with fundamental period as  / 2
51. Using 7th roots of unity
1  cos   cos 2 ___ cos 6  0

sin   sin 2 ___ sin 6  0

  
1  z  z 2 ___ z 6  z  ei z  ei 2 ___ Z  ei 6  

1  z  z 2 ___ z 6  z  ei  z  e  ____  z  e 
i 2 i 6

Put z=1 and apply modules on both sides we get sin  / 2 sin  sin 3 / 2  7 / 8
Let
2 4 8
S  sin  sin  sin
7 7 7
Upon squaring we get
S2  7 / 4  7 / x

3tan   tan 3 
52. tan 3   k  say 
1  3tan 2 

 
 tan 6   3 3  2 k 2 tan 2   k 2  3 3k 2  2 tan 4   
Comparing with given equation k   3

   200  or  400
n
1
53. 2 log 2    n , n  I  x  2 2 , n  z
 x
 1 1 1 1 
For x   0,2   x 1, , , , ,...., 2, 4, 8, 16, 32,.... 
 2 4 8 16 
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Narayana IIT Academy 07-12-16 Sr.IIT-IZ-CO-SPARK_Jee-Adv_(2015_P2)_Key Sol’s
Integers of x  1,2,4   0,2 


54. for   0,  0  sin   cos   1
 4

55. AD
cos z cos z
56. E  cos x sin y cos z  sin  x  y   sin  x  y     cos z  sin  x  y  
2 2 
1
 cos 2 z
2
1 1  
 1  cos 2 z   1  cos 2   
4 4  12  

1 3 2 3
 1  
4 2  8
1 5 7 11 13 17 19 23
57, 58. The fractions are , , , , , , ,
24 24 24 24 24 24 24 24
59. Least positive solution is  / 6
60. Solution is possible
 
4 
cos 2  sin x  2 cos 2 x  =1 & 2 tan 2
x
4
tan 2 x  0


4
 
sin x  2 cos 2 x  K 

sin x  2 cos 2 x  4 K Possible only if K=0

1
 sin x  or 2
2

n   
 x  n   1  
 4 

 3
The possible solution are ,
4 4

Sec: Sr.IIT-IZ-CO-SPARK Page 13