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Sri Chaitanya IIT Academy., India.

AP, TELANGANA, KARNATAKA, TAMILNADU, MAHARASHTRA, DELHI, RANCHI


A right Choice for the Real Aspirant
ICON Central Office , Madhapur – Hyderabad
Sec: Sr.Super60 CTA-02 Date: 01-11-20
Time: 05:10Pm to 08:10 Pm 2018_P2 Max.Marks: 180

KEY SHEET

PHYSICS
1) ACD 2) BD 3) AC 4) AC 5) BD 6) BC 7) 100 8) 1.42 to 1.44 9) 20

10) 0.46 to 0.48 11) 0.5 12) 12.5 13) 3.75 14) 10 15) B 16) C 17) B 18) B

CHEMISTRY

19) ABC 20) BCD 21) BC 22) BCD 23) BCD 24) ABC 25) 52 26) 13.00 27) 3

28) 5 29) 6 30) 3 31) 2.00 32) 14.90 33) C 34) D 35) D 36) B

MATHEMATICS

37) BCD 38) ABCD 39) ABCD 40) ABCD 41) ABCD 42) ABCD 43) 7 44) 5 45) 2

46) 1 47) 1 48) 50 49) 3 50) 1 51) D 52) A 53) D 54) D


Sri Chaitanya IIT Academy 01-11-2020_Sr.Super60_Jee-Adv(2018-P2)_CTA-02_Key&Sol’s
SOLUTIONS
PHYSICS
1. (a) Process AB: PT = const.  nRT2 = kv (k is constant)

dT

2.

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Sri Chaitanya IIT Academy 01-11-2020_Sr.Super60_Jee-Adv(2018-P2)_CTA-02_Key&Sol’s
yb
3. x 
d
b
.b b2
x  2 =
d 2d

If certain wavelength are missing then they are making minima.


 1
x   n    for minima
 2
2
b 3 b2
n = 1,  , 
2d 2 3d
2
b  b2
n = 0,  , 
2d 2 d
The deviation produced by a glass slab is zero. Hence the cavity will not have any
4.
effect on the deviation.
B
A

C
D
 A
sin  min 
 2 
2
A
sin  
2
o
 min  30

5. For such an expansion the pressure is decreasing:


P1V1
P
isotherm

P2 V2

V
P1V1  nRT P2 V2  nRT
Since V2  V1 and temperature is same.
 P2  P1
Sec: Sr.Super60 Page 3
Sri Chaitanya IIT Academy 01-11-2020_Sr.Super60_Jee-Adv(2018-P2)_CTA-02_Key&Sol’s
Temperature first increases and then decrease.
6. The combination behaves as a converging mirror. So we can have possibilities
like

7. P2 V2  P1V1
V1  20000CC P1  105 Pa

v2  Ax
Kx
P2  P0 
A
 1000x 
 105  20000  106  105  100x  104
 100  10 4 
 2000  1000  x 1  x  
x2  x  2  0
x = 100 cm
8. We have,
d
  k    0 
dt
Where 0 is the temperature of the surrounding and  is the temperature of the
body at time t. suppose   1 at t=0.
Then,
 t
d
   0  k 0 dt
1

  0
or, ln   kt
  0
or,   0   1  0  e  kt …(i)
The body continues to lose heat till its temperature becomes equal to that of the
surrounding. The loss of heat in this entire period is
Qm  ms 1  0 

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Sri Chaitanya IIT Academy 01-11-2020_Sr.Super60_Jee-Adv(2018-P2)_CTA-02_Key&Sol’s
This is the maximum heat the body can lose. If the body loses half this heat, the
decrease in its temperature will be,
Q m 1   0

2ms 2
If the body loses this heat in time t1 , the temperature at t1 will be
1  0 1  0
1  
2 2
Putting these values of time and temperature in (i),
1   0
 0   1   0  e  kt1
2
Solving, z=10/7
9. Figure shows that on segments, 1-2 and 3-4, pressure is directly proportional to
the temperature. It follows from ideal gas equation that gas volume remains
unchanged in this case and the gas does no work. So, we must find the work
done only in isobaric processes 2-3 and 4-1.
The work W23  P2 (V3  V2 ) and W41  P1 (V1  V4 )
Total work done by the gas during the cycle is, W  P2 (V3  V2 )  P1 (V1  V4 )
The equation of state for three moles of ideal gas, PV 1 1  3RT1 , PV
1 4  3RT4

2 2  3 RT2 , PV
PV 2 3  3RT3

Putting these values, we get: W  3R(T3  T1  T2  T4 )  20kJ .


10. Since, pressure remains unchanged, hence according to charles’ law, we get:
V2 T2 273  50 V1 323
  or 
V1 T1 273  12 V 285
V  323 17
 V2   V
285 15
17 17
Out of the volume V , ( V  V ) escaped, leaving volume V inside the flask.
15 15
17
But mass of V  4 g
15
 17  2V
 mass of  V  V  , i.e.,
 15  15
4 2V 8
   g  0.471g .
17
V 15 17
15
11. If intensity due to S1 & S2 each at screen 1 is I each then intesnsity at S3 & S4

each is 4I cos 2 2I & if now intensity due to S3 & S4 each at O is I0, then I1
2
= 4I0

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Sri Chaitanya IIT Academy 01-11-2020_Sr.Super60_Jee-Adv(2018-P2)_CTA-02_Key&Sol’s

S1  S3
4
O

S2 S4

 1  2

intensity at S4=4I intensity S3 = O hence intensity at O due to S3 is zero now & due
to S4 is 2 times the value before i.e 2I0
1m

S1  S3
2
O

S2 S4

 1  2

so I 2  2I0
I2
 0.5
I1
12. We know that a thin silvered lens is equivalent to a combination of two lenses
and a mirror. This equivalent system is working as a mirror whose focal length is
given by:

1 2 2 25 1 2 2 9
   ( where f L  20cm and f M   cm) Or    
F f L fM 2 F 20 25 50

10 cm

Let  is the image distance from lens. Then


1 1 1
 
 10 50 / 9
1 1 9 4
or   
 10 50 50
   12.5 cm

13.
Sec: Sr.Super60 Page 6
Sri Chaitanya IIT Academy 01-11-2020_Sr.Super60_Jee-Adv(2018-P2)_CTA-02_Key&Sol’s
1 1 1 1 1 1
From,  = ;   =
v u f f u f
f 5f
For lens, v =  2f   =
 2 2
1 1 1 1 1 1
From,  = ;  =
v u f 5f / 2 u f /2
5f
u=  ;
8
Final image is f in front of lens
So answer is 3f/8
1 1 1 
14. For lens, = ( – 1)   
f  R1 R2 
Here, R2 = +60 cm and R1 = +20 cm
1 1 1
= (1.5 – 1)   
f  20 60 
1 1 1
  
60 v 80
v = 240 cm
1 
Shift due to slab, s = 3 1  = 1 cm
 1.5 
for final image to form at O, ray should retrace its path after reflection from
mirror. So I2 should be at centre of curvature of mirror i.e. 7 + 3 + x = 20
x = 10 cm
15. When the strip is y below the mid plane its acceleration is given by,
buyant force  weight
a=
mass
 
 V0  1  4y   V0 g 0 
  g  4gy
V0 g 0
Similarly when strip is y above mid plane a = 4gy clearly its medium is SHM
2
When T   1sec
4g
16. A) at t = 0
Optical path difference due to glass slab
=   2  1  t  15t  3m  n 0
3m
n  300
100A 0
 0 D 100A 0  1m
So y  300     0.2m
d  20  2mm
So y  300  75m

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Sri Chaitanya IIT Academy 01-11-2020_Sr.Super60_Jee-Adv(2018-P2)_CTA-02_Key&Sol’s
B) At t = 5 sec
  1 (as R.I cannot be less than 1 as given in paragraph)
So optical parth difference due to galss slab
   2  1  t  4t  0.8m  n 0
0.8
n  80
100A 0
 0 D 100A 0  1m
So y  80     5m
d 1 2mm
y  80    400m
C) Central maximal is at geometral center when
 medium   glass  5 i.e at t = 3.75 sec
D) At t = 3.75 sec
  20  3.75  4   5
D
  0  1m
d
17. d = 2mm
d = 2m
I  I0  I0  2I0 cos 
 yd 
 x  
 D
2
 x

(b)
18.
(p) Rays will become parallel to principal axis after reflection. Therefore
diameter of spot will be D.
1 1 1 f
(q)   v
v  f    f  2
y D
If diameter of the spot is y then  or, y = 5 D
 5f   f 
   
 2   2

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Sri Chaitanya IIT Academy 01-11-2020_Sr.Super60_Jee-Adv(2018-P2)_CTA-02_Key&Sol’s

1 1 1
r)    v  f
v  f   f 
  
 2
y D 3D
Diameter of the spot is given by  or, y
3f
  f 2
 
 2 

y D
(s) Diameter of the spot is given by  or y  3D
3d d

CHEMISTRY:
19. Angular nodes are directional and dependent on angular part of polar
coordinates.
20. total energy of the electron is negative
21. it forms fcc lattice
22. Intermolecular forces turned into repulsive at high pressures.
23. order of the reaction can be integer or fractional value.
24. A) Addition of NaOH will decrease [H3O+].
(B) Addition of water will decrease the concentration of both.
(C) Acetic acid is a weak acid
(D) Increase in temperature increases the reaction rate.
25. 4CuSCN + 7KIO3 + 14HCl = 4CuSO4 + 7KCl + 4HCN + 7ICl + 5H2O
26. Actual unit cell composition: Cu2.66Pt1.33

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Sri Chaitanya IIT Academy 01-11-2020_Sr.Super60_Jee-Adv(2018-P2)_CTA-02_Key&Sol’s
3
V=A
a  380 pm  3.80  108 cm
3
V   3.80  10 8   54.87  10 24 cm3

m  2.66   A w  Cu    1.33   A w  Pt    / N A
d 
V 54.87  1024 cm3
 2.66   63.54   195.1  1.33 / 6.02  10 23
 24
 12.97 g/cm3
54.87  10
27. Lyman series corresponds to n1.
28. Crystalline solids: Mohr’s salt, Benzoic acid, potassium nitrate, copper, silicon
Amorphous solids: Polyurethane, Teflon, cellophane, polyvinyl chloride, fiberglass
and plastic sulphur.
29. VT
V nR
K
T P
log V  log T  log K
y  mx  c
 nR 
C  log K  log  
 P 
 0.0821 
C  log  n 
 0.0821 
For gas 1 : C  log n
0.4771  log n  log 3
For gas  2  : 0  log n  log1
n 1
For gas  3   log x  0.30
 log 2  log n
 log 2 1  log n
1
log    log n
2
1
n  mole
2
neq SO2  neq HClO3

30.
V 16.9
Or 2   6  V  13.44 L
22.4 84.5
Now n  PV  2   5  13.44   3
RT 0.0821  546

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Sri Chaitanya IIT Academy 01-11-2020_Sr.Super60_Jee-Adv(2018-P2)_CTA-02_Key&Sol’s
RT
V  B  2.058L . Also, for the given equation
31. P
16
32. 8O  4 2 He 4
m  15.9944  4  4.0026  0.016 u

∴ Energy required in separation  0.016  931.5  14.904 MeV


Radial node = (n-l-1), Angular node = l.
33. 4s, 5px, 6dxy having 3 radial node. Angular node in all ‘s’ orbital in zero.
34. Ideal gases cannot be liquefied.
35. NCERT examples lattice point is occupied basis
36. Units of rate constant are defined over, rate per unit concentration of reactant
terms

MATHS:
37. AD must pass through the incentre of the triangle.
15 15
Circum centre  , 
8 8 
5 5
Incentre =  , 
2 2
 5 25 
D , 
4 4 
38. Given circle is circum circle of excentral triangle ABC of triangle PQR. Orthocentre
of the excentral triangle is the in centre of the triangle. Image of ortho center in
any side lies on the circumcircle. Hence the required locus is
x 2  y 2  6 x  14 y  38  0 .
39. The reflection of the focus of the parabola w.r.t a tangent to the parabola lies on
the direction of the parabola and also the line passing through the point of
intersection tangents and mid point of the segment joining point of contact of
the tangents is parallel to the principle axis of the parabola.

40. PA+PB=4, QA+QB=4          8


 3   3   3   3        
and      3   3   3   3  32
4  4 
41.

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Sri Chaitanya IIT Academy 01-11-2020_Sr.Super60_Jee-Adv(2018-P2)_CTA-02_Key&Sol’s
B

P
A
O

C
P  (1, 2) Q  (1,  2)
Slope of PA = - 1
Slope of QA = 1
Equation of PA, QB are x  y  3  0, x  y  3  0 on solve with parabola
B   9, 6  C   9,  6 
1
Area of trapezium PBCQ is 12  4  8  64 units
2
1
In radius of  PAQ   2 1
S1

In radius of  ABC  2  3( 2  1)
S2
2x y
42. Equation of the normal at ‘  ’ on the ellipse is   3 if it passing through
cos  sin 
4cos sin 
' ' , then  3
cos  sin 
2
16cos 2   sin  
  3  
cos2   sin  
 16 1  6sin 16
 sin 2   2  2   9 0
 cos  sin   sin  cos 2 
 9cos2   16   7  9sin 2  
 sin  sin   sin 2   2 2

  sin    sin   2

16sin   cos   1  15sin  
43. Clearly x  y  2  0
x  y  1  0 are perpendicular to each other
BAC  900
A

 1, 1
900
D 900
900 E
 2,1
900

B C
P
 A is the ortho centre of  ABC le

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Sri Chaitanya IIT Academy 01-11-2020_Sr.Super60_Jee-Adv(2018-P2)_CTA-02_Key&Sol’s
1 3
Mid point of BC  P  Circum centre =  , 
 2 2 
2 2
 PA  DE  9  4  13
44. Let A   0, 0  , B   4, 0  , C  0, 3
5
Circum centre S is  2,3/ 2  and circum radius =
2
25
Equation of S is  x  2 2   x  3/ 2 2  ..... 1
4
2 2
If circle S1 and S touch internally   r1  2    r1  3/ 2   r1  5 / 2
2
 r1  2r1  0  r1  2
If S2 is having radius r2 and touching AB and AC  centre of S2 =  r2 , r2 
2 2 2
S 2 touches S externally   r2  2    r2  3/ 2    r2  5 / 2 
 r2 2  12 r2  0  r2  12  r1r2  24
45. Slope of PQ + slope of AB =0.
46.     
P at12 , 2 at1 , Q at22 , 2at2 , R at32 , 2at3 
Then T   at1t2 , a (t1  t2 ) 
P1   at1t3 , a(t1  t3 ) 
Q1   at2t3 , a(t2  t3 ) 
T P1 t3  t2 TQ1 t1  t3
Now  , 
T P t1  t2 TQ t1  t2
TP1 TQ1
  1
TP TQ
47. Ellipse 16 x 2  25 y 2  400
x2 y 2
  1
25 16
Let the points on ellipse be P(5 cos 1 , 4sin 1 ) and Q 5 cos 2 ,4 sin  2  .
Circle described on PQ as diameter touches x  axis 3,0 . Then
 cos1  cos 2   sin 1  sin 2 
5    3 and 4    r
 2   2 
4     r
 tan  1 2  
5  2  3
    5r
 tan  1 2  
 2  12
4  
 Slope of PQ   cot 1 2
5 2
48
  1
25r
48. (1,  4) lies on common chord of the circles 6 x  14 y  c  d  0  c  d  50

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Sri Chaitanya IIT Academy 01-11-2020_Sr.Super60_Jee-Adv(2018-P2)_CTA-02_Key&Sol’s
SQ
49. e 2
SP
50. The line L is common chord of x 2  y 2  61 and the circle with P as centre and
radius 10 Then L  5 x  6 y  11  0
51. Conceptual.
52. A) e1 < 1 < e2  f(1) < 0   > 3
B) Both roots are greater than 1  D  0    2 and f 1  0    3 and also

 1    2    2,3
2
1 1 2  4
C) 2  2  1   1    2 2 & D  0    2 .
e1 e2 4
3
53. Equation of such ellipse is x 2  4 y 2  4    x  1  0 with area =
2
54. Apply tangent condition for the given curves.

Sec: Sr.Super60 Page 14

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