Sri Chaitanya IIT Academy., India.: Physics

Sri Chaitanya IIT Academy., India.
AP, TELANGANA, KARNATAKA, TAMILNADU, MAHARASHTRA, DELHI, RANCHI

A right Choice for the Real Aspirant
ICON Central Office , Madhapur – Hyderabad
Sec: Sri Chaitanya-Sr.Chaina-I(L-I&II) PTA-12 Date: 01-12-19
Time: 09:00 AM to 12:00 Noon 2017_P2 Max. Marks:183
KEY SHEET
PHYSICS
1 D 2 D 3 B 4 A 5 D
6 B 7 C 8 AD 9 BD 10 ABC
11 C 12 ABC 13 B 14 BCD 15 B
16 D 17 C 18 A
CHEMISTRY
19 A 20 C 21 C 22 C 23 C
24 D 25 C 26 ABCD 27 ABCD 28 ABCD
29 BCD 30 ABCD 31 ABC 32 ABD 33 B
34 D 35 D 36 C
MATHS
37 B 38 A 39 C 40 C 41 B
42 D 43 A 44 ABC 45 ABD 46 ABCD
47 ABCD 48 AD 49 AB 50 AB 51 B
52 B 53 D 54 C
Sri Chaitanya IIT Academy 01-12-19_Sri Chaitanya-Sr.Chaina-I_Jee-Adv(2017_P2)_PTA-12_Key & Sol’s
PHYSICS
SOLUTIONS
PHYSICS
1. Momentum conservation MV  mV ' (V ' =Velocity of man)
1 2
A) KEboat  mV
2
2 2
1 2 M V
B) KEman  mV ' 
2 2m
D) Work done by boat on man + Work done by man on himself = KEman
2 2
M V
 Work done by man on himself 
2m
2. Statement I: Work done by gravity is same for motion from A to Z and B to
M for equal mass. So K.E. will be equal.
Statement II: Acceleration = g sin 
tan  A > tan B
Statement III:
W g + W ext = 0 (Because moved slowly)
W ext = – W g
W g is positive so W ext < 0
3.
B move in a circle in frame of A

2
T  mg  m.
 2V 
l
And T = mg to lift A
gl
V 
2
Using energy cons.
1 2 1 2
mu   2m V  mgl
2 2
2 2
 u  2V  2 gl
 u  3gl
4.
Sec: Sr. Chaina-I Page 2

1 2
f  x1  x2   K  x1  x2 
2
2f
  x1  x2  
K
5. J  5 m  V cm
In the COM frame, particles will be in circular motion.
VA,cm A
m
4l/5
Vcm
C
4m
B
2
 J 
2 m 
m (V A,cm )  5m  J2
T  
(4l / 5) ( 4l / 5) 20 ml
2R
6. If we treat the train as a ring of mass ‘M’ then its COM will be at a distance from

the centre of the circle. Velocity of centre of mass is:
Vcm  Rcm .
2R 2R  V   V
 .       
  R R
2V
 Vcm 

2MV
 MVcm 

As the linear momentum of any system = MVcm
2MV
The linear momentum of the train =

7. For anti-clockwise motion, speed at the highest point should be . Conserving energy at
(1) & (2):

1 2 R 1
mva = mg  m( gR )
2 2 2
 va2 = gR + gR = 2gR  va = 2gR
For clock-wise motion, the bob must have atleast that much speed initially, so that the
string must not become loose any where until it reaches the peg B.
At the initial position:
2
T + mgcos600 = mvc ; VC being the initial speed in clockwise direction.
R
For VC min : Put T = 0 ;
gR
 VC =
2
gR
 VC/Va = 2 = 1
2 gR 2
 VC : Va = 1 : 2
8.
2 2
FL  A V0  V  FR  2A V0  V 
FL  FR  V0  V   V0  V  2
V 
V0  2 1 
 
2 1
9. Options (B) & (D) are correct.
10.

V1 cos   V2 cos   eV0 cos 
 V1  V2  eV0 1
mV1  2mV2  2mV0
 V1  2V2  2V0  2
Solving (1) & (2), V1  V0
V0
V2  
2
11.
Minimum velocity configuration at highest point

1 2
 1  V  2
Using every conservation : mV  2  m     mg  2 L
2  2  2 
 V  8 gL
12.
Configuration when ball is at highest point.

Equation for M:
2
T  2mg  2m
 3V '
, T 0
L
gL
V ' 
9
Using energy cons. just after collision:
2 2 2
1 V  1 V  1  V
2 m    m   2V '  2 m  V '   2mg.2l
2  2 2 3  2  3

2 2 2
V V  V 
    2V '  2   V '  8 gL
2 3  3 
2 2
V V 2
   6V '  8 gL
2 3
2
V 6 gL
   8 gL
6 9
2
 V   48  4 gL  V  52 gL
13. Just after collision:
V2+V3 = V as collision is elastic.

V
V1  2 (rod constraint)
2
(Momentum cons.) V2  V3  V1 2  V
2V
Solving, V2 
3
V
V3 
3
V 2
V1 
3
14. After second collision, both blocks move with a common velocity V0 towards left with
spring undeformed.
15&16.

Acceleration of A and B along C and will be equal (as V=0 at this instant)
 a '  2a
T T
Equation for B along horizontal is  Ma and vertical is Mg   Ma '  2 Ma
2 2
g 10
Solving a  
3 3
20 2 40
T  Ma 2  
3 3 2
17 & 18.
Just after first collision,
Just before collision between C and D
From COM frame it can be seen that time interval between above two events is
T  m T V m
  and displacement of C is L  Vcm  .
2 k 2k 2 2 2k
After second collision both B and C come to rest with spring at natural length for above
value of L.
CHEMISTRY
19. Ca, Sr and Ba ions produce colour when introduced into Bunsen flame which is
characteristic of that metal ion. By using the intensity of the colour, the concentration of
the metal ion can be determined using flame photometric method.
20. Fullerene consists of 5 & 6-membered rings due to which it contains two types of
C – C bond lengths. In the remaining species, all bond lengths are equal.
21. Diamond is stable even at high pressures but can convert into graphite only on heating
to high temperatures at high pressure. Due to more electronegativity of oxygen, carbon
in CO2 has more positive charge than in CS2 and can accept lone pair easily. Zeolites
2
are frame work (Honey comb 3D) alumino silicates. Due to high basic character of C2 ,
it takes up H+ ion from water forming C2H2 and Ca(OH)2.
22. At low temperatures, tin converts into brittle crystalline allotropes.
23. BeCl2, BH3 and AlCl3 exist as dimer in gas phase as Be2Cl4, B2H6 and Al2Cl6. BeF3
exist as monomer only.
24. CaF2 cannot accept fluoride ion to form of complex.
25. Silicones contain organic groups such as alkyl group which are water repellent but
silicones do not have such groups.
26. The difference in terminal bridge B – H bonds is 133 – 119 = 14 pm while in that of
B2H6 is 221 – 206 = 15 pm. If percentage difference is calculated, it will be 12% in
B2H6 and 7% in Al2Cl6. This is due to weaker 3c – 2e B – H – B bond compared to
3c – 4e Al – Cl – Al strong bond.
27. (A) AlF3 is ionic, insoluble in water but on mixing with NaF forms soluble Na3 AlF6
complex.
(B) BF3 react with NaF forming NaBF4 before BF3 hydrolyses since B – F bond
stronger than B – OH bond.
(C) Due to small size of boron, it cannot coordinate with 4 Cl atoms and hydrolyse to
give H3BO3 since B – Cl bond is weaker than B – OH bond.

(D) Since BF3 is stronger Lewis acid it removes F ions from Na3AlF6 forming AlF3
which is insoluble white solid.
Na3AlF6 + 3BF3  AlF3 + 3NaBF4
28. (A) Due to back bonding, the order of Lewis acidic character of boron halides is in the
order BF3 < BCl3 < BBr3 < BI3. Though in silicon there is back bonding, due to bigger
size and difference in energies of 3d orbital in silicon and p-orbitals of halogens, it is
very weak.
(B) BCl3, BBr3 and BI3 hydrolyse completely in water but due to strong B – F bond,
BF3 hydrolyse partially.
(C) In boron as the outer most orbit is second orbit which can accommodate only 8
electrons, its coordination number is restricted to 4. In silicon, the 3rd orbit is valance
shell that contains vacant d-orbitals and can accept more than one electron pair.
(D) All boron and silicon halides are non-polar.
29. With increase in oxidation state (B in +3) positive charge developed on central atom
increases. So it can attract lone pair easily. Statements C & D are also correct.
30. Compared to Sn2+, Pb2+ ion is larger and polarizable easily. So compounds like PbCl2
are more covalent than Sn2+ compounds. Hence ionization of Sn2+ compounds in water
is more and Sn2+ hydrolyses easily. Due to inter-pair effect, Pb2+ is stable and cannot act
as reducing agent.
 2
31. Compared to Cl ion O attract more number of water molecules due to small size and
more charge. So that heat of solution of CaO is more than CaCl2 and can act as stronger
22
drying agent than CaCl2. The lattice energy of CaO is while that of CaCl2 is
rc  ra
21
. This indicates L.E of CaO is more and have high melting point. Substances
rc  ra
which can be dried such as C2H5OH, NH3 etc with CaO cannot be dried with CaCl2
since CaCl2 form addition compounds. Also CaO react with water forming Ca(OH)2
which is highly exothermic reaction where as CaCl2 form only hydrated molecules.
32. SiF4 + (CH3)4NF  (CH3)4NSiF5

 
(CH3)4NF is quaternary ammonium salt ionizes to give (CH3)4 N and F . F is accepted

 
by SiF4 to give SiF . (CH3)4 N have tetrahedral structure and SiF5 have trigonal
5

bipyramid shape. The product is formed by accepting a lone pair from F , it is Lewis
acid-base neutralization.
33. Due to elongation along the chain axis distortion occur at the tetrahedral Be atom.
34. Due to elongation along the chain axis Cl – Be – Cl angle decreases while
Be – Cl – Be angle increases.

35. All the above three factors combinedly effect in the existence of dimeric B2H6 and
monomeric BX3.
36. Of large size of chlorine atom there will be steric hindrance.
MATHEMATICS
624 624
37. Let A   25  r , B   25  r and a  b  2 ab  a  b (a, b >0)
r 1 r 1
2
Let a + b = 50, ab = r  a, b are the roots of x  50 x  r  0 .
 a  25  625  r , b  25  625  r  Assume a  b
624 624
 2 A   50  2 r   125  625  r  25  625  r
r 1 r 1
 A B
 A  2 1 B 
38. Consider g(x) = 12x5+15ax4+20bx3+30cx2+60dx+k=0 has 5 positive real roots.
By Rolle’s theorem g’(x) = 0 has four positive real roots.
f(x) = 0 has four positive real roots , ,  ,  such that
                      16,
  4
 
4 1 1 1 1
  
   
 A.M .  H .M .       
4 4
 f  x    x     f  x   f  2   2     1
 2    1 or  1    1 or 3
2
5 2 1
39. a0  
2 2
4
2 17 2  1
a1  a0  2   2 4
4 2 x 1 2
n 1
8 4
Let an  2
, x  2 ,
2 1 4 1 x
a2  2  2
2 4
 n
 1  ak  1 
  1    lim
k 0 
 
ak  n k 0  ak 

a 1 a 1 a 1
 lim 0 , 1 ,......, n
n  a a2 an
0
2 2 2
2  2  1 4  4  1 16  16  1  x2  x  1 
 lim 2 . 2 . 2
...... 2 
n  2 1 4 1 16  1  x 1 
2 4 2
2 1 x  x 1 3
 lim 2 4

n  2  2  1 x 1 7

2019
 1
40. f  x    x  i  
i 1  i 
2019 2019
f 1        w    w 
2 2
 i  i  1 i i
i 1 i 1
  2019  2019
f  1
     1     w   w 
2 2
i i i i
i 1 i 1

   361
P   w P  w
2
P  w P  w 
2
327
41. Let a be the integral root of P(x)
P ( x)  Q( x)( x  a )
P (2)  Q(2)(2  a)  13, P (10)  Q(10)(10  a )  5
This is possible only if a = 15
Therefore Q(2)  1, Q (10)  1
Here Q(x) is a polynomial having integral coefficients so it cannot have integral root
Hence P(x) has only one integral root.
4 3 2
42. x  x  3x  8   x    x   x    x   
3 2
1 1 1 1 4 x  3x  6 x
     4  f  x say
x   x   x   x   x  x3  3 x 2  8
1 1 3
 2   f  2  f  4  
  6  8 2 10
2 2p p4
43. x  x 0
p5 p5
f  0  0, f  2  0, f  3  0
m m  i 1 1 1
44.   
 m  i !  m  i !  m  i  1!  m  i !
n
1 1 1
m   ..........1
i 1  m  i ! m!  m  n !
1 1
lim  f  m,n     ....... 2 
n  m.m! m!
1 1 1 m 1
f  m,m     ......   
 m  1!  m  2 !  m  m ! m!  m  1!
45. f ( x)  x 3  2 x 2  10 x  20  f is  f ( x)  0 has only one real root and f(x)=0 has
no rational root.
2 2
46. P
1  2  3  .....  2020  1  2020  2021 
  
2 2 2 
2
  ai  1
47. S   a1  a3  ......  a2  a4  ....    
 2  4

2
48.  ,  are roots of x  x  1
ar  2  ar 
 r 2

r2
   r

r
   r 2 r
     r 2

r

   

r
 2
  1    1  r
 2
       
r r r 1

r 1
 ar 1
     
 ar  2  ar 1  ar
n 2 2
 
  ar  an  2  a2  an 2   an  2       an 2  1
r 1  
  n n
 

an  
 
n 1 10
    
n 1 10
Now  n 
n 1 10  
 
10  10
   
1 1 
10 10  10   10    10 10
 
   10   10   89
 
 
bn an1  an1 12
 n   n  10  10 
n 1 10 10   89
n 1 1 1
10 10
Further, bn  an1  an1

 n 1

n 1
   n 1

n 1

 
as   1   n 1
   & 
n n 1
 
n

n n
           n n
  
 
1 1 1
1 1 1  
49. A.M.  H.M. for , , , we get a b c 3
a b c 3 6
1 1 1 3
   
a b c 2
2 2 2 2 2
 1  1  1  1 1 1  3
 a     b     c   a b c 6
b c a  b c a  2
Now,    3 
3 3
   

2 2 2
 1  1  1 75
 a     b     c   
b c a 4
 3
f 
 2 f  3
50. 0& 0
 5 f 1
f 
 2
abc  f 1 
51.  2
b  f 1  f  1 
 
 1 
 2 
 1  f  1 
 f 1 
abc f  1
Minimum of  2 as  0.
b f 1
52. H  x    x    x  1 x  2 x  3  x
 H  1   1    2 3 4  1  24 1     1
H  5   5    4  3  2  5  24  5     5
H  1  H  5  148
Similarly H(0) + H(4) = 28.
53.   2 ,M  5   5,M  2
log 5 N  2   log 2 N  5  
2  5
N 5 N 2
N  25,125 N  32 ,64
Maximum integral value of N = 124.
54.  ,M  3,5   5, M  3
  3, M  5 log3 N  5  
N 125,625 N  243,729
Maximum integral value of N = 728.

Sri Chaitanya IIT Academy., India.: Physics

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Sri Chaitanya IIT Academy., India.

AP, TELANGANA, KARNATAKA, TAMILNADU, MAHARASHTRA, DELHI, RANCHI

24 D 25 C 26 ABCD 27 ABCD 28 ABCD

29 BCD 30 ABCD 31 ABC 32 ABD 33 B

42 D 43 A 44 ABC 45 ABD 46 ABCD

B move in a circle in frame of A

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Minimum velocity configuration at highest point

Configuration when ball is at highest point.

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V2+V3 = V as collision is elastic.

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Just before collision between C and D

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