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2. Assuming all compounds are in the liquid phase, which of the following has the
compound with the greater surface tension listed first?
A. benzene (C6H6), H2O C. CH3Cl, CH4
B. CH3OCH3, CH3CH2OH D. Br2, I2
3. Antimony has a normal boiling point of 1860 K and ΔHvap = 77.14 kJ/mol. What happens
to the vapor pressure of antimony when the temperature is increased to 1950 K?
A. The vapor pressure exceeds 760 torr.
B. The vapor pressure is 760 torr.
C. The vapor pressure falls between 760 and 380 torr.
D. The vapor pressure falls below 380 torr.
4. Sublimation is
A. the phase transition from solid to liquid.
B. the phase transition from gas to solid.
C. the phase transition from liquid to gas.
D. the phase transition from solid to gas.
5. How much heat is required to convert 9.01 g of ice at −100.0 °C to liquid water at 0.0 °C?
7. What type of crystalline solid has a low melting point and is held together by dispersion
forces only?
A. molecular solid C. ionic solid
B. nonbonding atomic solid D. network covalent solid
12. What is the freezing point of an aqueous 2.23 m ethylene glycol solution? The freezing
point constant, Kf, of water is 1.86 °C/m.
A. 1.14 °C C. −4.15 °C
B. 5.48 °C D. −2.23 °C
13. Which of the following 0.100 M solutions will have the lowest osmotic pressure?
A. CaCl2 C. (NH4)3PO4
B. C6H12O6 D. NaNO3
14. If H2(g) appears at a rate of 1.00 M/s at a particular moment in the reaction below, what
is the rate of CH4(g) consumption at the same instant?
A. Reaction 1 C. Reaction 3
B. Reaction 2 D. Reaction 4
17. When the Kelvin temperature of a reaction is reduced by half, the value of the rate
constant, k
A. doubles.
B. increases, but doesn’t necessarily double.
C. decreases by half.
D. decreases, but not necessarily by half.
18. The reaction, 2 Cl(g) → Cl2(g), is known to be catalyzed by N2(g). The following
mechanism has been proposed for the catalyzed reaction.
19. Which one of the following is the equilibrium constant expression, Kc, for the reaction
below?
2 ZnS(s) + 3O2(g) ⇌ 2 ZnO(s) + 2 SO2(g)
A. C. 2[ ZnO] + 2[SO 2 ]
[SO ]2
2 2[ ZnS] + 3[O 2 ]
[O ]3
2
B.
[O ]2
D. [ ZnS ][O 2 ]2
2 [ ZnO] [SO 2 ]3
[SO ]3
2
20. What is Kp for the overall reaction that converts propane (C3H8) and steam to carbon
dioxide and hydrogen gas (H2) at 1200 K given the following information?
2 NO2(g) ⇌ N2O4(g)
At equilibrium, the partial pressure of NO2 is 0.12 atm. Determine the partial pressure of
N2O4 at equilibrium.
A. 15 atm C. 1.2 atm
B. 0.096 atm D. 0.16 atm
23. Given the following reaction, initially at equilibrium, which change will cause the
greatest shift in the equilibrium to favor product formation?
25. Which one of the following acids has the lowest percent ionization at 0.100 M?
A. HCN, Ka = 4.9 × 10−10 C. HC9H7O4, Ka = 3.3 × 10−4
B. HC2H3O2, Ka = 1.8 × 10−5 D. HCl, Ka >> 1