FIRST SEMISTER CHEMISTRY FINAL EXAMINATION FOR GRADE 12 TH

CHOOSE THE CORRECT ANSWERS

1. If the solute-solvent interactions are greater than the solute-solute and solvent -solvent interactions, what will be
the total vapor pressure of the solution?
A. greater than that calculation from Raoult's law B. less than that calculted from Raoult's law
C. The same as calculated from Raoult's law D.Raoult's law cannot be applied for such interaction
2. What is the freezing point of a solution of 250g of CaCl2 in 1.0kg of water (Kf for water =1.86 ℃ kg/mol) A -1.3
℃ B. -6.5℃ C. -9.0℃ D. -12.55℃
3. .What is the molarity of a 5 g of hydrogen peroxide in 100mL solution that is used for hair bleaching A.0.015M
B. 0.15M C. 1.5M D. 3M
4. What is the osmotic pressure ,in atm ,of a 0.30M solution of glucose in water that is used for intravenous infusion
at body temperature ,37℃ ?
A. 0.911 atm B. 773.2atm C. 7.6atm D. 76atm
5. Given the unbalanced equation
KMnO4+KI+H2SO4 → K2SO4+MnSO4+I2+H2O .How many grams of KMnO4 are needed to make 500mL of
0.250N solution? A. 3.95g B. 1.49g C. 1.58g D. 63.2g
6. In which of the following cases will the dissolution of sugar be the most rapid?
A. Sugar crystals in hot water B. Sugar crystals in cold water
B. Powdered sugar in hot water D . Powdered sugar in cold water
7. Which of the following is not a colligative property
A. Osmotic pressure B. Vapour pressure C. Boiling point D. Freezing point depression
8. What is the normality of a 1M solution of H3PO4 given the following reaction
H3PO4+2NaOH Na2HPO+H2O A 3N B.2N C. 6N D.1N
9. A given solution contains 100g of NaCl and 900g of water .what is the mole fraction of NaCl
A. 0.0331 B. 0.9669 C. 0.3 D. 0.7
10. A0.029m aqueous solution of K2SO4 has a freezing point of -0.14 ℃ . what are the value of I factors (kfH2O
=1.86℃ /m) A. 2 B. 4 C. 2.3 D. 2.6
11. Which of the following combination never form a buffer solution
A. HF/F- B. HCOOH/HCOO- C. HCO3-/CO3-2 D. HNO3/NO3-
12. Which one of the following are true about The graph of weak acid and strong base
A. The PH is equal to 7 at equivalence point B. The graph indicates the titration of strong base with strong acid
C. The PH is greater than 7 at equivalence point D. at half neutralization PH =Pka
13. A solution in which propionic acid is 0.94% ionized has a PH of 2.85. what is the values of the acid ionization
constant (ka) for propionic acid A. 4.2X10-4 B. 6.8X10-4 C. 1.3X10-5 D. 8.7X10-5
14. The acid-base indicator bromocresol green is a weak acid. The yellow acid and blue base forms of the indicator
are present in equal concentrations in a solution when the PH is 4.68 .what is the Pka of bromocresol green A.
4.48 B. 4.68 C. 5.68 D. 6.68
15. For the step wise dissociation of aqueous H3PO4 .which of the following is not conjugate acid -base pair A.
HPO42- and H2PO43- B. H3PO4 and H2PO4- C. H2PO4- and HPO42- D. H2PO4- and PO43-
16. To 0.2M solution of a weak monoprotic acid HA ,enough quantity of its sodium salt ,NaA, was dissolved to give
a concentration of 0.2M of the salt .what will be the acid concentration [H3O +] in the final solution (ka of HA
=1.8x10-5) A. 1.8x10-5M B. 1.8x10-4 M C. 2.8x10-5 D. 2.8x10-4
0.0057M B. 0.057M C. 0.57M D. 5.70M
17. Consider the following equilibria I. HCO3-+H2O=====H2CO3+OH-, II. NH4+ +H2O===H3O+ +NH3,
III .HSO3- +H3O+========H2O+H2SO3 In which of the equilibrium does water acts aas a Bronsted-lowry base?
A .I only B. II only C. II and III D. I ,II,III
18. To a 50ml of a buffer solution that is 0.25M in HF and 0.1M in NaF ,if 5ml of 0.05M NaOH is added ,what is
the final PH of this buffer solution , PKa HF=3.17 A .2.77 B. 2.80 C. 2.74 D. 3.17
19. When sodium acetate is added to an aqueous solution of acetic acid its PH
A. increases B. Decreases C. Remain constant D. may increases or decreases
20. How is a buffer solution prepared A. By mixing a weak acid and strong acid B. By mixing a weak acid and its
conjugate base C. By mixing a strong acid and its conjugate base D. By mixing strong base and its conjugate
acid
21. Which one of the followings are not Intensive properties A. color B. length C. density D. melting point
22. What are the standard enthalpy change for the following reaction 10N2O(g0+C3H8(g) 10N2(g)
+3CO2(g)+4H2O(g). the standard enthalpy formation for N2O(g) ,C3H8(g) ,CO2(g) and H2O(g) are 82 ,-104, -
393.5 and -242 Kj/mol respectively A. -2864.5Kj B. +2864.5Kj c. 28.645J D. 0.28645J
23. Based on the following information given in the table below what is the enthalpy change for the reaction Based on
the following information given in the table below what is the enthalpy change for the reaction 2H 2O2(g) +S(s)
SO2(g)+2H2O(g)
substance ∆ H of(KJ/mol)
2H2O2(g) -150
SO2(g) -300
H2O(g) -250
S(s) 0
A. -500KJ B. -200KJ C.200KJ D. 400KJ
24. How much work in KJ is done when gas expands from 5 L to 15 L under a constant pressure at 2 atm A.-
20.0KJ B. -2.03KJ C. +2.03KJ D. +20.0KJ
25. what is the enthalpy for the reaction C2H6(g)+2.5O2(g) 2CO2(g)+3H2O(l) given the following reaction
1. 2C(s)+3H2(g) C2H6(g) ∆ H° f = -84.7kJ/mol
2.C(s)+O2(g) CO2(g) ∆ H° f = -393.5kJ/mol
3. H2(g)+1/2O2(g) H2O(l) ∆ H° f = -285.8kJ/mol
A. -764KJ B. -1560KJ D. -1664KJ D. -312KJ
26. Which of the following statement is not true according to first law of thermodynamics
A. Entropy can neither be created nor destroyed although it can be changed from one to another
B. the total energy of the universe is constant
C. the change is the internal energy of a closed system is equal to the sum of heat absorbed by the system
and work done by the system
D. the change in internal energy of a system is zero in all process
27. Under what conditions will the enthalpy change of a process equals the amount of heat transferred in to or out of
the system A. under constant volume B. under constant pressure
C. under constant pressure and volume D. under constant pressure and temperature

28. Consider the following gaseous reaction at 25℃ CH4(g) +2O2(g) CO2(g) +2H2O(g) ∆H = -
802kJ.which energy change would occure if 3.2 mole of CH4 is completely combusted ?
A. 2.57x102kJ will be released B. 2.57x102 kJ will be a absorbed C. 6.43x103 kJ will be released
D. 6.43x103kJ will be absorbed
29. In a certain chemical process both ∆ H and ∆ S have values greater than zero. Under what conditions, the reaction
would not be spontaneous? A. ∆ H =T∆ S B. T∆ S – ∆ H >0 C. ∆ H >T∆ S D. None
30. Based on the first law of thermodynamics. Which one of the following is correct?
A. For an isothermal process q=+w B. For an isochoric process ∆ E = -q
C. For an adiabatic process ∆ E = -W D. For a cyclic process q= -W
31. Consider the following reaction at 25 ℃ 2Ag+(aq)+Fe(s) 2Ag(s)+Fe+2(aq) where as E° Fe+2/Fe
= -0.447v and E° Ag /Ag = -0.7996v .what are the standard free energy change and equilibrium constant
+

respectively A. ∆ G ° = -241KJ/mol, K= 1.3X1042 B. ∆ G ° =-241KJ/mol, K= 1.3X10-42

C. . ∆ G ° = 241KJ/mol, K= 1.3X1042 D. ∆ G ° = 241KJ/mol, K= 1.3X10-42
32. A. current of 1.26A is passed through electrolytic cell containing dilute aqueous solution of H 2SO4 for 7.44
hours. What are the volume of the oxygen gases generated at STP .uses electrolysis of dilute H 2SO4
Anode reaction 4OH-(aq) 2H2O(l)+O2(g)+4e-
Cathode reaction 4H+(aq)+4e 2H2(g)
R= 0.0821 L.atm/mol k A. 3.92L B. 1.96L C. 7.84L D. 4L
33. A certain current produces 0.50g of hydrogen gas in 2.0 hours. What is the amount of copper liberated from a
solution of copper sulfate by the same current following for the same time
A. 31.8 g B. 63.6g C. 15.9g D. 6.36g
34. During the electrolysis of CuSo4(aq) using carbon electrode .which of the following is the correct half-reaction
for the anode electrode?
A. Cu+2(aq)+2e- Cu(s) B. 4OH(aq) 2H2O(l)+O2(g)+4e-
C. 2H2O(l) O2(g)+4H+(aq)+4e-
 D. SO4-2(aq)+O2(g)+4H+(aq) SO4-2(aq)+2H2O(l)
35. During electrolysis of an aqueous solution of AgNO3. What would happen to the mass of silver metal deposited if
the current is double and the electrolysis times decreased to ½ of its initial value ?
A. It would stay the same B. It would increase twice the initial value
C. It would decrease to ¼ of its initial value D. It would decrease to ½ of its initial value
36. The two standard electrode potentials involves in the nickel –cadmium rechargeable cell are given below.
Calculate the ∆ G° in kJ of the cell
NiO2(s)+2H2O(l)+2e- Ni(OH)2(s)+2OH- E° = +0.39v
Cd(OHO2+2e- Cd(s)+2OH (aq) E° = -0.76v
-

A. -184 B. -153 C. -241 D. -206

37. If the standard reduction potential of
E° Zn+2/Zn = -0.76v, E° Cu+2/Cu = +0.34v E° Sn+2/Sn = -0.14v , E° Ni+2/Ni = -0.26v
Which one are the strongest oxidizing agent and reducing agent respectively
A. Zn,Cu+2 B. Cu+2,Zn C. Sn, Ni+2, D. Cu, Ni+2
38. Which of the following statement is true
A. the More Positive the Value of E°red, the greater the driving force for reduction
B. the more exothermic the value of E°red, the greater the driving force for reduction
C. the more endothermic the value of E°red, the greater driving force for reduction
D. the more negative, the value of E°red, the greater the driving force for the reduction
39. Laboratory technician are adds Na2SO4 to water to facilitate its electrolysis in a class demonstration. What are
the purpose of Na2SO4 ?
A. to increases concentration of water B. to maintain electrical conductivity
C. to increases the conductivity of water D. to decreases the conductivity of water
40. The standard emf for the all reaction Zn+Cu+2 Cu+Zn+2 is 1.1v. what would the emf for the all
+2 +2
reaction be when 0.1M Cu and 0.1M Zn solutions are used at 298k?
A. 1.10v B. 0.10v C. -1.10v D. 0.11v

GOOD LUCK PR.BY ABDI MOHAMMED