1. Reaction that involve the absorption of heat from surounding are called as..

a. Exothermic reaction
b. Endothermic reaction
c. Respiration reaction
d. Combustion reaction
e. Neutralization reaction

2. Below are observation on exothermic reaction, except...

a. Heat release
b. Light radiation
c. Σ(Hproduct) > Σ (Hreaction)
d. Negative ΔH value
e. Warm container

3. Take a look at the following thermochemical reaction equation:

H2 + O2  H2O2 ΔH=-187.8 kJ
Based on the ΔH value above, the ΔH of the value the following reaction is..
2H2O2  2H2 + 2O2
a. 93.9 kJ d. -375.6 kJ
b. -187.8 kJ e. +375.6 kJ
c. +187.8 kJ

4. Reaction whose ΔH0 represents the standard entalphy change of formation (ΔHf0) is...
a. ½ H2 (g)  H(g) ΔH0= +217.94 kJ
b. 2C(s,graphite) + O2  2CO2(g) ΔH0=-220.5 kJ
c. ½ N2(g) + O2(g)  NO2(g) ΔH0= +33.84 kJ
d. CH4(g) + 2O2(g)  CO2 + 2H2O(l) ΔH0= -890.5 kJ
e. N2(g) + 3H2(g)  2NH3(g) ΔH0=-92.38 kJ

5. A reaction of two substance with a total volume of 50 mL takin place in a calorimeter

results in a decreacseof temperature as much as 30C. The heat of reaction is...(assume that
the solution is dilute)
a. -62.7 kJ d. +627 kJ
b. +62.7 kJ e. -6270 kJ
c. -627 kJ

6. Combustion of a standard sample in a calorimeter involves 60 J of energy with a 0.30C

rise in temperature. The same calorimeter is used for the combustion of an inorganic
compound, which results in a 1.250 C increase in temperature. The heat of combustion of
the compound is...
a. 48 J d. 150 J
b. 60 J e. 250 J
c. 75 J

7. Which is the correct formulation of Hess’s Law for the diagram below?
A ΔH1 B

ΔH2 ΔH4

C ΔH3 D

a. ΔH1= ΔH2+ ΔH3+ ΔH4

b. ΔH1+ ΔH2= ΔH3+ ΔH4
c. ΔH1+ ΔH2+ ΔH3= ΔH4
d. ΔH1- ΔH2= ΔH3+ ΔH4
e. ΔH1= ΔH2+ ΔH3- ΔH4
8. Given that ΔH0f values for NH3(g), NO(g), and H2O are -46.2; 90.4; and -286 kJ/mol, the
ΔH for the oxidation of ammonia in the following reaction is...
4NH3(g) + 5O2(g)  4NO(g) + 6H2O(l)
a. -149.4 kJ d. -1169 kJ
b. 330.2 kJ e. -1892.8 kJ
c. -597.6 kJ

9. Data from table shows that the values of bond energy for C-H, C=C, and H-H are
413.938 and 436 kJ/mol respectively. The the ΔH for the following reaction is...
2CH4(g)  C2H2(g) + H2(g)
a. -331 kJ d. +449 kJ
b. 331 kJ e. 1203 kJ
c. -449 kJ

10. Which statement is not true about combustion?...

a. The heat of combustion of natural gas is greater than that of gasoline
b. The products of incomplete combustion are CO2,CO, and H2O
c. Combustions requires the presence of fuel, oxygen, and heat to initiate the reaction
d. Complete combustion release less heat than incomplete combustion
e. CO gas is toxic because it decrease the supply of O2 in the body

11. The following are several examples of endothermic reactions, except...

a. Melting ice d. Reaction between coke and water vapor
b. Photosynthesis e. respiration
c. Thermal decomposition

12. A student reacted 50 mL solution containing 0.05 mole of NaOH and 50 mL solution
containing 0.05 mol of HCl in a simple solution calorimeter. After stiring the solution,
she noticed that the temperature of the solution increased to 31.40 C. If the initial
temperature was 250 C. What is the heat of reaction (specific heat of 4.18 J/g0C and a
density of 1000 g/L)
a. -2675 J d. 2675 J
b. -25.67 kJ e. 2567 J
c. 2.6675 kJ

13. Based on no.12, what is the heat of reaction per mole NaOH
a. -535 kJ/mole d. 53.5 kJ
b. 55.3 kJ/mole e. 55300 J/mole
c. 535 kJ/mole

14. The thermochemical equation for no.12 is...

a. NaOH(aq) + HCl(aq)  NaCl(aq) + H2O ΔH=-2675 J
b. NaOH(aq) + HCl(aq)  NaCl(aq) + H2O ΔH=-2.675 kJ
c. NaOH(aq) + HCl(aq)  NaCl(aq) + H2O ΔH+2675 J
d. NaOH(aq) + HCl(aq)  NaCl(aq) + H2O ΔH=-53.5 kJ
e. NaOH(aq) + HCl(aq)  NaCl(aq) + H2O ΔH=53.5 kJ

15. A bomb calorimeter is used in a chemical experiment. What is Ccalorimeter given that the
combustion of a standard sample of 0.01025 g of benzoic acid (C7H6O2) produces a ΔT of
2.170 C. The ΔH0c of benzoic acid=-3227 kJ/mole?...
a. -2.711 kJ/0C d. 1249 kJ/0C
0
b. 2.711 kJ/ C e. 12.49 kJ/0C
c. -1.249 kJ/0C

16. By using result from no.15, 0.719 g of oxalic acid (C2O4H2) is reacted with excess oxygen
in the bomb calorimeter. If the Tinitial is 250 C and Tfinal is 26.60 C, calculate the heat of
reaction!...
a. -1998 J d. -250 kJ
b. 1998 kJ e. 250 J
c. -1998 kJ
17. By using result no.16, what is the ΔH of the combustion of 1 mole of oxalic acid?....
a. 250 kJ/mole
b. 250 J/mole
c. -2500 kJ/mole
d. -250 kJ/mole
e. -500 kJ/mole

18. The thermochemical reaction for no.15 is....

a. C2O4H2(s) + ½ O2(g)  2CO2(g) + H2O(l) ΔH=-500kJ
b. 2C2O4H2(s) + ½ O2(g)  CO2(g) +2 H2O(l) ΔH=250 kJ
c. C2O4H2(s) + 2O2(g)  2CO2(g) + H2O(l) ΔH=250 kJ
d. 2C2O4H2(s) + ½ O2(g)  2CO2(g) + 2H2O(l) ΔH=500 kJ
e. C2O4H2(s) + ½ O2(g)  2CO2(g) + H2O(l) ΔH=-250 kJ

19. A process occurs where the system absorb heat as much as 10 kJ from surrounding and
do the works as much as 100 J. The energy change of system is...
a. 9.9 kJ d. 100 kJ
b. 90 kJ e. 110 kJ
c. 10.1 kJ

20. What is the work if a gas system is pressed from 10 L to 2 L (250C, 1 atm)?...
a. 856.1 J d. 810.56 J
b. 810.65 J e. 865.1 J
c. 801.56 J

21. Combustion 44 gram of LPG (C3H8) results 2220 kJ. Combustion 11 kg of LPG will
result....(Ar H=1; C=12)
a. 244.20 kJ d. 5.55x103 kJ
b. 555 kJ e. 5.55x105 kJ
c. 24.420 kJ

22. A 100 mL of NaOH solution 1 M is reacted to 100 mL of HCl solution 1 M in calorimeter

and the temperature increases from 290C to 37.50C. if specific calor of water=4.2 J/gK
and density= 1g/mL, what is the change of entalphy from the reaction?....
a. 8.23 kJ d. -5.46 kJ
b. 7.14 kJ e. -4.59 kJ
c. -7.14 kJ

23. The correct diagram for the forming water vapor is...
a.
d.
2H2O(g)
H2(g) + ½ O2(g)

2H2 (g)+ O2(g) H2O(g)

b.
H2O(g)

e.
H2 (g)+1/2O2(g) H2O (g)

H2O(l)
 c.
H2(g)+O

H2O

24. Known :
ΔH0f H2O= -285.85 kJ
ΔH0f HNO3= -174.1 kJ
N2O5(g) + H2O(l)  2HNO3(l)
Δhreaction= -76.6 kJ
What is ΔHf N2O5?...
a. 14.25 kJ d. 28.3 kJ
b. -411.1 kJ e. 56.6 kJ
c. 14.15 kJ

25. Known: thermochemical equation

ΔH0f C2H6= -84.86 kJ/mol
ΔH0f C2H4= 53.30 kJ/mol
ΔH0f C2H2= 226.6 kJ/mol
ΔH0f C3H8= -103.85 kJ/mol
ΔH0f C6H6= 49.14 kJ/mol
ΔH0f CO2= -393.5 kJ/mol
ΔH0f H2O= -285.85 kJ/mol
From the below reaction, which reaction that has the greatest entalphy?...
a. 2C2H6(g) + 7O2(g)  4CO2(g) + 6H2O(l)
b. C2H4(g) + 3O2(g)  2CO2(g) + 2H2O(l)
c. 2C2H2(g) + 3O2(g)  4CO2(g) + 2H2O(l)
d. C3H8(g) + 5O2(g)  3CO2(g) + 4H2O(l)
e. 2C6H6(g) + 15O2(g)  12CO2(g) + 6H2O(l)
26. Known: the thermochemical equation
2NO(g) + O2(g)  N2O4(g) ΔH= a kJ
NO(g) + ½ O2(g)  NO2(g) ΔH= b kJ
The ΔH reaction: 2NO2(g)  N2O4(g) is...
a. (a+b) kJ d. (a-2b) kJ
b. (a+2b) kJ e. (2a+b) kJ
c. (-a+2b) kJ

27. If known the heat of combustion of cyclopropane ((CH2)3(g))= -a kJ/mol, the heat of
combustion of carbon= -b kJ/mol, and the heat of forming of water= -c kJ/mol. What is
the heat of forming of cyclopropane in kJ/mol?....
a. a-3b-3c
b. a-3b+3c
c. a+3b-3c
d. a+3b+3c
e. –a+3b+3c

28. If known:
Dc-c = 348 kJ/mol
DH-Cl = 431 kJ/mol
DC-H = 423 kJ/mol
DCl-Cl = 242 kJ/mol
DC-Cl = 328 kJ/mol
Entalphy of reaction for C3H8(g) + Cl2(g)  C3H7Cl(g) + HCl(g) is....
a. 104 kJ/mol d. -94 kJ/mol
b. 81 kJ/mol e. -208 kJ/mol
c. -81 kJ/mol
29. Entalphy of reaction for C2H2(g) + 2H2(g)  C2H6(g) is.... (DH-H = 436 kJ/mol and DC-
H= 413 kJ/mol)
a. -402 kJ/mol d. 402 kJ/mol
b. -112 kJ/mol e. 537 kJ/mol
c. 289 kJ/mol

30. The bonding energy data:

DH-H = 436 kJ/mol
DCl-Cl = 242 kJ/mol
DH-Cl = 431 kJ/mol
What is the calor which is needed to dissociate 146 gram of HCl into the its atoms?....
a. 92 kJ
b. 184 kJ
c. 247 kJ
d. 368 kJ
e. 495 kJ

ESSAY
1. A student uses a simple solution calorimeter to measure the ΔH for the following
reaction.
2NaOH(aq) + H2SO4(aq)  Na2SO4(aq) + 2H2O(l)
She reacts 50 mL of 0.02 mole of NaOH solution with 20 mL of 0.01 mole of H2SO4
solution. If the temperature of the solution increases by 3.610 C and it is assumed that the
solution is dilute, then:
a. Determine the heat of reaction
b. Determine the ΔH per mole of NaOH
c. Write down the thermochemical equation per mole of NaOH
2. 0.15 g of octane (C8H18) is burned with excess oxygen in a bomb calorimeter. If the
temperature of calorimeter increases by 1.140 C and the Ccalorimeter is 6.27kJ/0C, then:
a. Determine the heat of reaction
b. Determine the ΔH combustion of 1 mole of octane (Ar C=18 and H=1)
c. Write down the thermochemical equation for the combustion of 1 mole of octane
d. Octane is a component of gasoline fuel. The entalphy change of the combustion of
fuel is often given in kJ/g. State the ΔH of octane in kJ/g
3. In determining the entalphy change of the combustion of toluene (C7H8), a component of
TNT (trinitrotoluene), a bomb calorimeter is used.
a. When the bomb calorimeter is heated for 5 minutes using an electric heater rated at
15 watts (J/s), the temperature increases by 3.50 C. Determine the value of
Ccalorimeter
b. 0.14 g of C7H8 is reacted with excess oxygen in a bomb calorimeter. Given that the
temperature of the calorimeter increases by 4.600 C, determine the heat of reaction
(Ar C=12, H=1)
c. Calculate the ΔH for the combustion of 1 mole of toluene
d. Write down the thermochemical equation for the combustion of 1 mole of octane