1. If the NaOH crystal dissolved in water, then the glass will feel warm.

The reaction is
A. exothermic, there is energy transfer from the system to the surroundings
B. exothermic, there is energy transfer from the surroundings to the system
C. exothermic, no energy transfer
D. endothermic, there is energy transfer from the system to the surroundings
E. endothermic, there is energy transfer from the surroundings to the system
2. In the formation of SO2 is released heat, H = -395.7 kJ. Energy level diagram for the
reaction
S(s) + O2(g)  SO2(g) is

3. Known reaction:
H2(g) + Br2(g) → 2 HBr(g) H = -72 kJ
To decompose 11.2 L of HBr gas (STP) into H2 and Br2 gases needed the heat as much
A. 144 kJ C. 48 kJ E. 9 kJ
B. 72 kJ D. 18 kJ/
4. Given the thermochemical equation:
2N2(g)+ 6H2(g) 4NH3(g) ∆ H = 184 kJ
What is the ∆ H value for the decomposition of 1 mole of NH3?
(A) –184 kJ/mol (D) 736 kJ/mol
(B) –46 kJ/mol (E) 840 kJ/mol
(C) 184 kJ/mol
5. The standard enthalpy of combustion for ethanol is –1367 kJ:
C2H5OH(g) + 3 O2(g) → 2 CO2(g) + 3 H2O(l)
What is the standard enthalpy change for the following process?
4 CO2(g) + 6 H2O(l) → 2 C2H5OH(g) + 6 O2(g)
(A) –2734 kJ (D) 2734 kJ
 (B) –1367 kJ (E) 5468 kJ
(C) 1367 kJ
6. Pentaluminumnonahydride, Al5H9(s) burns vigorously in O2 to give Al2O3(s) and H2O(l).
Calculate ΔH°c of 1 mol of Al5H9, using ΔH°f [Al2O3(s)] = −1,073.5 kJ/mol ΔH°f[Al5H9(s)]
= 95.4 kJ/mol ΔH°f [H2O(l)] = −285.8 kJ/mol
(A) -1.274 kJ/mol (D) -8.448 kJ/mol
(B) -4.065 kJ/mol (E) -9.086 kJ/mol
(C) -4.534 kJ/mol

7. From the following data at 25⁰C,

H2(g) + Cl2(g) →  2HCl(g)          ∆Ho = -185 kJ

 2H2(g) +  O2(g) → 2H2O(g)     ∆Ho = -483.7 kJ

Calculate ∆Ho at 25⁰C for the reaction below.

     4HCl(g) + O2(g)   2Cl2(g) + 2H2O(g)

(A) –454,8 kJ (D) 227,4 kJ

(B) –227,4 kJ (E) 454,8 kJ
(C) -103 kJ
8. From the following equation:
1) CH4(g) + 202(g)  CO2(g) + 2 H2O(l) Hf = -802 kJ
2) H2(g) + 1/2O2(g) → H2O(1) Hf = -286 kJ
3) NO(g) → 1/2 N2(g) + 1/2O2(g) Hf = -91 kJ
4) C(s) + O2(g)  CO2(g) Hf = -394kJ
which the formation reaction are
A 1 and 2 D. 2 and 4
B. 1 and 3 E 3 and 4
C. 2 and 3
9. Calculate the ∆H for the following reaction using the bond enthalpies given below.
H2(g) + I2(g) → 2HI(g)
Bond enthalpies: H–H = 436 kJ/mol H–I = 297 kJ/mol
I–I = 151 kJ/mol
(A) 290 kJ (D) –7 kJ
(B) 170 kJ (E) –290 kJ
 (C) 7 kJ
10. Diketahui persamaan termokimia sebagai berikut :
½ N2(g) + 3/2 H2(g) → NH3(g) ∆H = - 46 kJ
Perubahan entalpi untuk menguraikan 5,1 gram NH3 (Mr = 17) adalah….
17 x(−46) 5,1 x17
A. 5,1 kJ D. (−46) Kj
5,1 x(−46) (−46)
B. 17 kJ E. 5,1 x17 Kj
5,1
C. 17 x(−46) kJ
11. Diketahui reaksi pembentukan H2O sebagai berikut
H2(g) + ½ O2(g) → H2O(g) ∆H = -286 kJ
Untuk menguraikan 36 gram H2O ….. ( Ar H=1, O=16 )
A. diperlukan 572 kJ kalor D. dibebaskan 572 kJ kalor
B. diperlukan 286 kJ kalor E. dibebaskan 286 kJ kalor
C. diperlukan 143 kJ kalor
12. Perhatikan beberapa gambar berikut!

Gambar yang menunjukkan terjadinya proses endoterm adalah gambar nomor ....
A. 1 dan 2 D. 1 dan 4
B. 2 dan 4 E. 3 dan 4
C. 2 dan 3
13. Diketahui reaksi pembentukan HCl sebagai berikut:
½ H2 (g) + ½ Cl2 (g) → HCl (g) ΔH = - 92,3 kJ/mol
Diagram tingkat energi yang sesuai dengan reaksi tersebut adalah ....
13. Perhatikan siklus energi berikut!

Harga perubahan entalpi pembentukan 1 mol gas SO3 adalah ....

A. +790kJ D. -396Kj
B. +395kJ E. -790kJ
C. - 395Kj
14. Diketahui data energi ikatan:
C – C : 348 kJ/mol; C – Br : 276 kJ/mol; C = C :
614 kJ/mol
C – H : 413 kJ/mol; H – Br : 366 kJ/mol;
Berapakah besarnya ∆H untuk reaksi berikut ini:
CH3 - CH = CH2 + HBr → CH3 – CH – CH3
|
Br
15. Pada pembakaran 3,2 gram gas metana CH4 dibebaskan 55,6 kJ. Tuliskan persamaan
termokimia yang menggambarkan reaksi pembakaran metana tersebut!
16. a students reacted 50 mL solution containing 0.05 mol of NaOH and 50 mL solution
containing 0.05 mol of HCl in a simple solution calorimeter.
NaOH(aq) + HCl(aq)  NaCl + H2O
After stirring the solution, she noticed that the temperature of the solution increased to
31.4C. if the initial temperature was 25C, then:
A. determine the heat of reaction (C= 4.18 J/gC, density 1.000 g/L)
B. Determine the heat of reaction per mole of NaOH
C. write down the thermochemical equation