A sample of aluminum metal absorbs 9.

86 J of heat, upon which the temperature of the sample increases from

23.2°C to 30.5°C. Since the specific heat capacity of aluminum is 0.90 J/g-K, the mass of the sample is (g)

A) 72
B) 1.5
C) 65
D) 8.1
E) 6.6

The temperature of a 15-g sample of lead metal increases from 22°C to 37°C upon the addition of 29.0 J of
heat. The specific heat capacity of the lead is ( J/g-K).
A) 7.8
B) 1.9
C) 29
D) 0.13
E) -29

Calculate the energy in joules required to convert a mole of ice at -10°C to steam at 120°C.
Given:

ΔHvap of H2O = 40.7 kJ/mol

ΔHfus of H2O = 6.02 kJ/mol
Cm (ice) = 37.6 J/mol°C
Cm (liquid H2O) = 75.3 J/mol°C
Cm (steam) = 36.5 J/mol°C

a) 8680 J
b) 356 J
c) 55,356 J
d) 196 J
A bomb calorimeter has a heat capacity of 2.47 kJ/K. When a 0.105-g sample of ethylene (C 2H4) was burned
in this calorimeter, the temperature increased by 2.14 K. Calculate the energy of combustion for one
mole of ethylene.
a) –5.29 kJ
b) –50.3 kJ
c) –572 kJ
d) –661 kJ
e) –1.41  103 kJ

The total volume of hydrogen gas needed to fill the Hindenburg was 2.00  108 L at
1.00 atm and 25.0C. How much energy was evolved when it burned?
H2(g) + (1/2)O2(g)  H2O(l), H = –286 kJ
a) 3.5  1011 kJ
b) 8.18 106 kJ
c) 2.86 104 kJ
d) 2.34 109 kJ
e) 5.72 1010 kJ
Carbon and oxygen react to give carbon dioxide. The reaction of 4.49 g C(s) with 9.21 g O 2(g)
releases -113.2 kJ of heat. What is the enthalpy of formation of CO 2(g)?

a) -393 kJ
b) -303 kJ
c) -285.8 kJ
d) -171 kJ
e) -113.2 kJ
At 25C, the following heats of reaction are known:
H (kJ/mol)
2ClF + O2  Cl2O + F2O 167.4
2CIF3 + 2O2  Cl2O + 3F2O 341.4
2F2 + O2  2F2O –43.4
At the same temperature, calculate H for the reaction:
ClF + F2  ClF3
a) –217.5 kJ/mol
b) –130.2 kJ/mol
c) +217.5 kJ/mol
d) –108.7 kJ/mol
e) none of these

Determine the heat of formation of sulfuric acid, H 2SO4(l), from the following thermochemical
equations:

S8(s) + 8 O2(g) ---> 8 SO2(g); ΔH = -2374.6 kJ

S8(s) + 12 O2(g) ---> 8 SO3(g); ΔH = -3165.8 kJ
H2O(l) + SO3(g) ---> H2SO4(l); ΔH = -132.4 kJ
2 H2(g) + O2(g) ---> 2 H2O(l); ΔH = -571.7 kJ

a) -814.0 kJ
b) -1099.9 kJ
c) -2164.7 kJ
d) -3869.9 kJ
e) -6244.5 kJ
Consider the following processes:
2A  1/2B + C H1 = 5 kJ/mol
(3/2)B + 4C  2A + C + 3D H2 = –15 kJ/mol
E + 4A  C H3 = 10 kJ/mol
Calculate H for: C  E + 3D
a) 0 kJ/mol
b) 10 kJ/mol
c) –10 kJ/mol
d) –20 kJ/mol
e) 20 kJ/mol
Which of the following is NOT a formation reaction?

a) 1/2 H2(g) + 1/2 Br2(l) ---> HBr(g)

b) H2(g) + 1/2 O2(g) ---> H2O(l)
c) Ca(s) + 1/2 O2(g) ---> CaO(s)
d) 4 Al(s) + 3/2 O2(g) ---> Al2O3(s)
e) H2O(l) + SO3(l) ---> H2SO4(l)