CHEMISTRY 204 Winter 2017

1Final Test for K61 Chemistry

Duration: 90 min
INSTRUCTIONS FOR THE ANSWER
1. Use back side of the sheets for your calculations.
2. Use a soft lead pencil and make dark marks. Do NOT use a pen. Erase all changes completely.
3. Mark only one answer for each question.
………………………………………………………………..……………………………………………

Part 1 Multiple choice questions

1. The following cell Zn(s) / Zn2+(aq) // H+(aq) / H2(g) has E°cell = 0.76 V
What must be the pH in the hydrogen compartment of the cell designated above if the cell voltage is
0.64 V? (Assume that both the [Zn2+] and the H2(g) pressure are at standard values and T = 25 °C.)
A. 4.11 B. 2.03 C. 0.51 D. 1.01

2. If the initial pH values are the same for titrations of separate 50 mL samples of weak and strong
monoprotic acids, which other value(s) is (are) also the same?
I. the pH at the equivalence point
II. the volume of base needed to reach the eq. point
A. I only B. II only C. Both I and II D. Neither I nor II

3. For the reaction: C3H8(g) + 5O2(g) 3CO2(g) + 4 H2O(l), Go = -2.10103 kJ/mol. What is the
value of the standard electrode potential, Eo for a fuel cell based on this reaction?
A. 1.09 V B. 2.18 V C. 4.37 V D. 21.8 V

4. Calculate the aqueous solubility of Ca(OH)2 in grams per liter. [Ksp = 8.0 10-6]
A. 5.9  10-4 B. 2.0 10-2 C. 0.93 D. 1.5

5. What is the pH of a 1.00 L sample of a buffer solution containing 0.10 mol of benzoic acid and 0.10
mol of sodium benzoate to which 0.010 mol of NaOH has been added? [Ka benzoic acid = 6.5 x 10-5]
A. 4.27 B. 4.23 C. 4.15 D.4.10

6. Use the following data to calculate the molar enthalpy of combustion of ethane, C2H6.
2C2H2(g) + 5O2(g) → 4CO2(g) + 2H2O(l) ΔH = –2511 kJ/mol
C2H2(g) + 2H2(g) → C2H6(g) ΔH = –311 kJ/mol
H2(g) + 1/2O2(g) → H2O(l) ΔH = –242 kJ/mol
A. –2856 kJ/mol B. –3306 kJ/mol C. –1428 kJ/mol D. –2684 kJ/mol

7. The gaseous compound NOBr decomposes according to the equation

2NOBr(g) ⇄ 2NO(g) + Br2(g)
At 350 K the equilibrium constant, Kp, is 0.0225. What is the value of ΔG°?
A. –5.5 × 103 J/mol C. –2.4 × 103 J/mol
B. 2.4 × 103 J/mol D. 5.5 × 103 J/mol(11)
8. C(s) + H2O(g) CO(g) + H2(g) H > 0
For the system above at equilibrium, which changes will increase the amount of H2(g)?
I Adding C(s)
II Increasing the volume of the container
III Increasing the temperature
A.I only B.III only C.II and III only D.I, II and III

9. Calculate the cell potential, E, for a silver-silver chloride electrode immersed in 0.800 M KCl at 25oC.
[Ag+ + e– Ag, Eo = 0.799 V; Ksp = 1.8 ×10-10]
A. 1.37 V B. 0.80 V C. 0.57 V D. 0.23 V

10. PCl5(s) reacts with H2O(l) according to the equation:

PCl5(s) + 4H2O(l) H3PO4(aq) + 5HCl(aq)
What is ΔH° for this reaction in kJ/mol
Substance PCl5(s) H2O(l) H3PO4(aq) HCl(aq)
o 443.5 285.8 1284.4 167.1
ΔH f

A. 722.2 B. 533.2 C. 533.2 D. 722.2

Part 2. Show your calculations on back side of the sheets

1. Consider the following galvanic cell at 250C: (-) Cu | CuSO4 (1M) || AgNO3(0.01M)‌‌| Ag(+)
a. Calculate the potential for this cell.
b. Write the chemical reaction when the cell in question a is working
c. Calculate the potential for this cell after adding 6.5 g KCN solid into the
silver compartment containing 50 mL of AgNO 3 (0.01M) solution. (Assume
that there is no change in volume)
d. Write the chemical reaction for the cell in question c.
ECu ¿ = 0.34 V ; E Ag ¿ = 0.80 V: Kf[Ag(CN)2]- = 1.0 × 1018
¿ ¿

2. Calculate the pH of each of the following solutions:

a. HF 0.14M (Ka = 7.1 x 10-4).
b. NaF 0.71 M.
c. The solution obtained by mixing 100 mL HF 0.14 M and 100 mL NaOH 0.058 M .

Dictionaries all kinds are allowed!

CHEMISTRY 204 Winter 2017

1Final Test for K61 Chemistry

Duration: 90 min
INSTRUCTIONS FOR THE ANSWER
4. Use back side of the sheets for your calculations.
5. Use a soft lead pencil and make dark marks. Do NOT use a pen. Erase all changes completely.
6. Mark only one answer for each question.
………………………………………………………………..……………………………………………

Part 1. Show your calculations on back side of the sheets

1. Consider the following galvanic cell at 250C: (-) Cu | CuSO4 (1M) || AgNO3(0.01M)‌‌| Ag(+)
a. Calculate the potential for this cell.
b. Write the chemical reaction when the cell in question a is working
c. Calculate the potential for this cell after adding 6.5 g KCN solid into the
silver compartment containing 50 mL of AgNO3 (0.01M) solution.
(Assume that there is no change in volume)
d. Write the chemical reaction for the cell in question c.
ECu ¿ = 0.34 V ; E Ag ¿ = 0.80 V: Kf[Ag(CN)2]- = 1.0 × 1018
¿ ¿

2. Calculate the pH of each of the following solutions:

a. HF 0.14M (Ka = 7.1 x 10-4).
b. NaF 0.71 M.
c. The solution obtained by mixing 100 mL HF 0.14 M and 100 mL NaOH 0.058 M .

Part 2 Multiple choice questions

1. The following cell Zn(s) / Zn2+(aq) // H+(aq) / H2(g) has E°cell = 0.76 V
What must be the pH in the hydrogen compartment of the cell designated above if the cell voltage is
0.64 V? (Assume that both the [Zn2+] and the H2(g) pressure are at standard values and T = 25 °C.)
A. 4.11 B. 2.03 C. 0.51 D. 1.01

2. If the initial pH values are the same for titrations of separate 50 mL samples of weak and strong
monoprotic acids, which other value(s) is (are) also the same?
I. the pH at the equivalence point
II. the volume of base needed to reach the eq. point
A. I only B. II only C. Both I and II D. Neither I nor II

3. For the reaction: C3H8(g) + 5O2(g) 3CO2(g) + 4 H2O(l), Go = -2.10103 kJ/mol. What is the
value of the standard electrode potential, E for a fuel cell based on this reaction?
o
A. 1.09 V B. 2.18 V C. 4.37 V D. 21.8 V

4. Calculate the aqueous solubility of Ca(OH)2 in grams per liter. [Ksp = 8.0 10-6]
A. 5.9  10-4 B. 2.0 10-2 C. 0.93 D. 1.5

5. What is the pH of a 1.00 L sample of a buffer solution containing 0.10 mol of benzoic acid and 0.10
mol of sodium benzoate to which 0.010 mol of NaOH has been added? [Ka benzoic acid = 6.5 x 10-5]
A. 4.27 B. 4.23 C. 4.15 D.4.10

6. Use the following data to calculate the molar enthalpy of combustion of ethane, C2H6.
2C2H2(g) + 5O2(g) → 4CO2(g) + 2H2O(l) ΔH = –2511 kJ/mol
C2H2(g) + 2H2(g) → C2H6(g) ΔH = –311 kJ/mol
H2(g) + 1/2O2(g) → H2O(l) ΔH = –242 kJ/mol
A. –2856 kJ/mol B. –3306 kJ/mol C. –1428 kJ/mol D. –2684 kJ/mol

7. The gaseous compound NOBr decomposes according to the equation

2NOBr(g) ⇄ 2NO(g) + Br2(g)
At 350 K the equilibrium constant, Kp, is 0.0225. What is the value of ΔG°?
A. –5.5 × 103 J/mol C. –2.4 × 103 J/mol
B. 2.4 × 103 J/mol D. 5.5 × 103 J/mol

8. C(s) + H2O(g) CO(g) + H2(g) H > 0

For the system above at equilibrium, which changes will increase the amount of H2(g)?
I Adding C(s)
II Increasing the volume of the container
III Increasing the temperature
A.I only B.III only C.II and III only D.I, II and III

9. Calculate the cell potential, E, for a silver-silver chloride electrode immersed in 0.800 M KCl at 25oC.
[Ag+ + e– Ag, Eo = 0.799 V; Ksp = 1.8 ×10-10]
A. 1.37 V B. 0.80 V C. 0.57 V D. 0.23 V

10. PCl5(s) reacts with H2O(l) according to the equation:

PCl5(s) + 4H2O(l) H3PO4(aq) + 5HCl(aq)
What is ΔH° for this reaction in kJ/mol
Substance PCl5(s) H2O(l) H3PO4(aq) HCl(aq)
ΔH o 443.5 285.8 1284.4 167.1
f

A. 722.2 B. 533.2 C. 533.2 D. 722.2

Dictionaries all kinds are allowed!