PRACTICE QUESTION PAPER

CLASS XI [2021-22] TERM 2

TOTAL TIME: 2 HRS SUBJECT – CHEMISTRY M.M.35
GENERAL INSTRUCTIONS- 1. There are 12 questions in this question paper with internal choice.
2. Section A – Q. No 1 to 3 are very short answer questions carrying 2 marks each.
3. Section B – Q. No 4 to 11 are short answer questions carrying 3 marks each.
4. Section C – Q. No 12 is case study based question carrying 5 marks.
5. All questions are compulsory. Use of log table and calculator not allowed.

SECTION A
Q1. Give reasons for the following (any two). (1X2=2)
a. Equilibrium is dynamic in nature.
b. Gas fizzes out when the soda water bottle is opened.
c. Clothes dry quicker when there is a breeze.

Q2. What happens to the given equilibrium: CO (g) + 2H2 (g) ⇋ CH3OH (g), ΔH < 0 (1X2=2)
(i) If He gas is added at constant volume (ii) CO is added
(iii) CH3OH is removed (iv) Temperature is increased

Q3. a) Write the conjugate acid of: i) H2O ii) HSO 4- (1X2=2)
b) Write the conjugate base of: i) NH3 ii) HCO3-

SECTION B

Q4. For an equilibrium reaction 2 H2 (g) + O2 (g) ⇋ 2H2O (g) if K = 2 x 102; calculate K’ for
(a) 2 H2O (g) ⇋ 2 H2 (g) + O2 (g)
(b) H2(g) + ½ O2(g) ⇋ H2O (g)
(c) 4 H2O (g) ⇋ 4 H2 (g) + 2 O2 (g)
OR
Q4. Write the relationship between Kp and Kc and units of both for the following equilibrium:
(a) N2 (g) + 3H2 (g) ⇋ 2NH3 (g) (b) H2O (l) ⇋ H2O (g)
(c) NH3 (aq) + H2O (l)⇋ NH4+ (aq) + OH- (aq)

Q5. Calculate Kp and Kc for the reaction at 300 K N2 (g) + 3 H2 (g) ⇋ 2 NH3 (g) ; if 2.5 mol of N2 , 4 mol
of H2 and 10 mol of NH3 taken in 2 lt vessel.
OR
Q5. For A(g) ⇋ 3B (g) + C (g) if 5 moles of A enclosed in 5 lt vessel. At equilibrium 40% of it dissociated
to give B and C. Calculate Kc.

Q6. Calculate [H3O+] and [OH-] concentration for the solution: (1X3=3)
(a) 0.05 M KOH (b) 0.001 M H2SO4 (c) 0.01 M CH3COOH

Q7. At 300K, Kc for the reaction, H2 (g) + I2 (g) ⇋ 2HI (g) is 50. Predict the direction in which the reaction
will proceed to reach equilibrium, if we start with 2 X 10-2 mol of HI, 1 X 10-2 mol of H2 and 3X10-2 mol of
I2 in a 2 L container.

Q8. a) The solubility product of CaF2 is 2.7 x 10-11 at 298K. Calculate the solubility of the salt in mol/L.
b) When is a precipitate formed when solutions of BaCl 2 and Na2SO4 are mixed? (2+1=3)
Q9. Calculate pH at 250C in
(a) 4.2 x 10-5 M HCl (b) 2.05 x 10-4 M H2SO4
(c) 0.05 M CH3COOH having Ka = 1 x 10-5
OR
Q9. Calculate pH of
a) 1.5 x 10-3 M NaOH (b) 10 -2 M Ca(OH)2
(c) 2 x 10-2 M weak acid having ᾳ = 0.2

Q10. A 0.001 M solution of CH3COOH is found to be 5% ionized at 250C. Calculate

(i) Ka for CH3COOH (ii) pH (iii) pOH

Q11.a) Calculate H3O+ ion concentration of a solution having pH 7.8.

b) How many grams of NaOH must be dissolved in one litre of water so that pH of the solution is 10.4?
OR
Q11. a) Define Buffer solution.
b) 9.8 g of H2SO4 is present in 250ml of the solution. Calculate the pH of the solution.

SECTION C

Q12. Read the passage given below and answer the questions that follow.

Equlibrium represents the state of a process in which the properties like temperature, pressure,
concentration of the system do not show any change with the passage of time. In all processes which
attain equilibrium, two opposing processes are involved and at equilibrium, the rates of two opposing
processes becomes equal. The value of equilibrium constant is not affected by the addition of catalyst
and is constant at constant temperature. The magnitude of the equilibrium constant gives the idea of
the relative amounts of the reactants and products. If in a system in equilibrium, the concentration at
any one part is disturbed, it no longer remains in equilibrium and readjusts its concentration to re-
establish the equilibrium .

1. Define Le Chatelier’s Principle.

2. Give two characteristics of chemical equilibrium.
3. Under what conditions, Kp = Kc for a gaseous reaction?
4. At equilibrium the mass of each of the reactants and products remain constant. Does it mean that the
reaction has stopped?
5. What do you conclude if : i) Q = K ii) Q > K iii) Q < K
OR
5. Which measurable property becomes constant in water ⇋ water vapour equilibrium at constant
temperature?