CHEMISTRY

CLASS XI CHEMICAL EQUILIBRIUM

Paper – 1

(One and a Half hours)

Answers to this Paper must be written on the paper provided separately.

Candidates are allowed additional 15 minutes for only reading the paper.

The time given at the head of this paper is the time allowed for writing the answers.

ALL QUESTIONS ARE COMPULSORY

The intended marks for questions or parts of questions are given in brackets [ ].

[1*25=25]

Question 1:

In the reaction: 𝑁 (𝑔) + 3 𝐻 (𝑔) ⇌ 2𝑁𝐻 (𝑔), the value of the equilibrium constant depends on:
(a) volume of the reaction vessel (b) total pressure of the system
(c) the initial concentration of nitrogen and hydrogen (d) the temperature.
Question 2:

In the reaction A + B ⇌C + D, 4 moles of A react with 4 moles of B and form 2 moles each of C and D. The value of Kc for the reaction is:

(a) 2 (b) 3 (c) 1 (d) 1.56

Question 3:

For the reaction: 2SO2 + O2 ⇌ 2 SO3, the units of k are:

(a) L mol-1 (b) mol L-1 (c) (mol L-1)2 (d) (L mol-1)2
Question 4:

For the reaction, H₂(g) +I2 (g) ⇌ 2HI(g), the equilibrium constant Kp changes with:

(a) total pressure (b) catalyst (c) the amount of H₂ and I2 present (d) temperature.

Question 5:

For the reaction CO(g) + ½ O2(g) ⇌ CO2(g) , Kp/Kc is equal to:

(a) 1 (b) RT1/2 (c) (RT)-1/2 (d) RT
Question 6:

1.1 moles of A are mixed with 2.2 moles of B and the mixture is kept in a one litre flask till the equilibrium: A + 2B ⇌ 2C + D is reached. At
equilibrium, 0.2 moles of C are formed. The equilibrium constant of the reaction is:
(a) 0.001 (b) 0.002 (c) 0.003 (d) 0.004
Question 7:

Consider the following two gaseous equilibria involving SO₂ and the corresponding equilibrium constants at 298 K:
SO2 + ½ O2 ⇌ SO3(g); K1 2SO3(g) ⇌ 2SO2(g) + O2(g) ; K2. The values of equilibrium constants are related by:
(a) K2=K1 (b) K2=K12 (c) K2=1/K12 (d) K2=1/K1
Question 8:

A mixture of 0.3 moles of H₂ and 0.3 moles of I 2 is allowed to react in a 10 litre evacuated flask at 500°C. The reaction is H₂ + I 2 ⇌ 2HI , the K is
found to be 64. The amount of unreacted I 2 at equilibrium is:
(a) 0.15 mole (b) 0.06 mole (c) 0.03 mole (d) 0.2 mole
Question 9:

28 g of N₂ and 6 g of H₂ were kept at 400°C in 1 litre vessel, the equilibrium mixture contained 27.54 g of NH 3. The approximate value of Kc for
the above reaction can be (in mol-2 L²)
(a) 75 (b) 50 (c) 25 (d) 100

1|P age Rajdeep Ghosh chemistry classes

Ph-9831293295
Question 10:

In the reaction H2(g) + Cl2(g) ⇌ 2HCl(g) ,

(a) Kp=Kc (b) Kp ≠ Kc (c) Kp>Kc (d) Kp<Kc
Question 11:

For the reaction PCl5(g) ⇌ PCl3(g) + Cl2(g) , the forward reaction at constant temperature is favoured by:

(a) introducing an inert gas at constant volume (b) introducing Cl₂ gas at equilibrium

(c) introducing an inert gas at constant pressure (d) decreasing the volume of the container.

Question 12:

Given HF + H2O ⇌ H3O++F-; Ka. F- + H2O ⇌ HF + OH-; Kb, Which of the following relations is correct:
(a) Kb=Kw (b) Kb=1/Kw (c) Ka X Kb=Kw (d) Ka/Kb=Kw
Question 13:

For the following reaction in gaseous phase, CO + ½ O2→ CO2, Kc/Kp is:

(a) (RT)1/2 (b) (RT)-1/2 (c) RT (d) (RT)-1

Question 14:

One of the following equilibria is not affected by change in volume of the flask:
(a) PCl5(g) ⇌ PCl3(g) + Cl2(g) (b) N2(g) + 3H2(g) ⇌ 2NH3(g) (c) N2(g) + O2(g) ⇌ 2NO(g) (d) SO2Cl2(g) ⇌ SO2(g) +Cl2(g)
Question 15:

Consider the reaction equilibrium, 2SO₂(g) + 0₂ (g) ⇌ 2SO3(g) , ΔH0=- 198 kJ. On the basis of Le-Chatelier's principle, the condition favourable
for the forward reaction is:
(a) lowering of temperature as well as pressure (b) increasing temperature as well as pressure
(c) lowering the temperature and increasing the pressure. (d) any value of temperature and pressure.
Question 16:

What is the kcfor the reaction, P4(s) + 5O2(g) ⇌ P4O10(s) ?

[ ] [ ]
(a) 𝐾 = [ ][ ]
(b) 𝐾 = [ ][ ]
(c) 𝐾 = [𝑂 ] (d) 𝐾 = [ ]
Question 17:

For the reaction: CO(g) + Cl2(g) ⇌ COCl2(g), the Kp/Kc is equal to:
(a) 1/RT (b) RT (c) √𝑅𝑇 (d) 1.0
Question 18:

Two moles of ammonia gas are introduced into a previously evacuated 1 L flask in which it partially dissociates at high temperature as:
2𝑁𝐻 (𝑔) ⇌ 𝑁 (𝑔) + 3 𝐻 (𝑔), At equilibrium 1.0 mole of NH3(g) is found. What is Kc?
(a) 0.75 (b) 1.5 (c) 1.7 (d) 0.46
Question 19:

For the reaction at 800 K: 𝑁 (𝑔) + 3 𝐻 (𝑔) ⇌ 2𝑁𝐻 (𝑔) the ratio of Kp and Kc is : (R= 0.082 L atm mol-1K-1)
(a) 2.3 X 10-4 (b) 3.2 X 10-6 (c) 2.3 X 104 (d) 3.2 X 106
Question 20:

The equilibrium constant of the reaction, H₂(g) +I2 (g) ⇌ 2HI(g), is 64. If the volume of the container is reduced to half of its original volume,
the value of equilibrium constant will be:
(a) 64 (b) 1/64 (c) 32 (d) 16
Question 21:

For the gaseous reaction : 𝑁 + 3 𝐻 ⇌ 2𝑁𝐻 the partial pressures of H₂ and N₂ are 0.4 and 0.8 atm respectively. The total pressure of the
entire system is 2.8 atm. What will be the value of Kp if all concentrations are given in atmospheres ?
(a) 50 (b) 0.02 (c) 250 (d) 31.25
Question 22:

For the reaction : PCl3(g) + Cl2(g) ⇌ PCl5(g) the value of Kc at 250°C is 26. The value of Kp at this temperature will be: (R= 0.082 L atm mol-1K-1)
(a) 0.61 (b) 0.46 (c) 0.92 (d) 0.57

2|P age Rajdeep Ghosh chemistry classes

Ph-9831293295
Question 23:

One mole of N₂ and 3 moles of H₂ are mixed in a litre flask. If 50% N₂ is converted into ammonia by the reaction, ) N2(g) 3H2(g) ⇌ 2NH3(g). then
the total number of moles of gas at equilibrium is :

(a) 1.5 (b) 3.0 (c) 4.5 (d) 6.0

Question 24:

0.84 moles of PCl5 and 0.18 moles of PCl3 are mixed in a one litre flask at 27°C. It is later found that 0.72 moles of PCl5 are present at
equilibrium. The Kc for the reaction, PCl5(g) ⇌ PCl3(g) + Cl2(g) is:
(a) 0.05 mol L-1 (b) 0.04 mol L-1 (c) 0.03 mol L-1 (d) 0.08 mol L-1
Question 25:
Wet clothes dry quicker when there is a breeze because:
(a) clothes swing in the presence of breeze
(b) breeze is hot and evaporates water quicker
(c) the evaporation process gets expedited due to removal of water vapour by the breeze
(d) breeze helps in quicker condensation of water vapour present in wet clothes.

3|P age Rajdeep Ghosh chemistry classes

Ph-9831293295