Quizizz: 25-minute Test Part VIII Chemical Reactions and Energy

Quizizz: 25-minute Test

Part VIII
Chemical Reactions and Energy

Name: ________________________ ( ) Class: ____________ Date: ________________

There are 20 multiple-choice questions in total.

Answer ALL questions. Marks: / 20
Time allowed: 25 minutes

1. Which of the following correctly represents the standard state of iodine?

A. I(s)
B. I2(s)
C. I2(l)
D. I2(g)

2. Which of the following processes is endothermic?

A. Burning of charcoal
B. Lowering soil pH by using slaked lime
C. Producing propane by heating octane in the absence of oxygen
D. Producing calcium sulphate by mixing calcium chloride and sodium sulphate

3. In which of the following reactions is there a work done on the system?

A. 2O3(g)  3O2(g)
B. H2(g) + O2(g)  H2O2(l)
C. H2(g) + Br2(l)  2HBr(g)
D. Ca(s) + 2H2O(l)  Ca(OH)2(aq) + H2(g)

4. Consider the following reaction.

Fe2O3(s) + 2Al(s)  Al2O3(s) + 2Fe(s) H < 0

Which of the following statements concerning the reaction is INCORRECT?

A. The temperature of the reaction mixture rises.
B. Heat is given out to the surroundings.
C. The total enthalpy of the products is less than that of the reactants.
D. The energy given out by forming bonds is less than that taken in by breaking bonds.

HKDSE CHEMISTRY — A Modern View (Second Edition)

© Aristo Educational Press Ltd 2019 1
Quizizz: 25-minute Test Part VIII Chemical Reactions and Energy

5. The change in internal energy and work done on the surroundings of a reaction are –256 kJ and
+35 kJ respectively. What is the heat change of the reaction at constant pressure?
A. –221 kJ
B. +221 kJ
C. –291 kJ
D. +291 kJ

6. Which of the following processes involves the largest absorption of heat energy for the same
mass of CCl4?
A. CCl4(g)  CCl4(l)
B. CCl4(l)  CCl4(g)
C. CCl4(g)  CCl4(s)
D. CCl4(s)  CCl4(g)

7. Given that:
2Br2(g) + 3F2(g)  2BrF3(g) ∆H = –511 kJ mol–1
2Br2(g) + 3F2(g)  2BrF3(l) ∆H = –602 kJ mol–1
What is the enthalpy change for the boiling of 1 mol of liquid BrF3?
A. –45.5 kJ mol–1
B. +45.5 kJ mol–1
C. –91.0 kJ mol–1
D. +91.0 kJ mol–1

8. Iron reacts with oxygen in a heat-pad according to the following equation:

4Fe(s) + 3O2(g)  2Fe2O3(s) ΔH = –1650 kJ mol–1

How much heat is released when 1.00 g of iron reacts completely?

(Relative atomic mass: Fe = 55.8)
A. 7.39 kJ
B. 14.8 kJ
C. 29.6 kJ
D. 59.2 kJ

9. Which of the following neutralization reactions causes the largest temperature rise?
A. 50 cm3 of 0.1 M HCl(aq) reacting with 50 cm3 of 0.1 M KOH(aq)
B. 50 cm3 of 0.1 M HCl(aq) reacting with 50 cm3 of 0.1 M NH3(aq)
C. 50 cm3 of 0.1 M HNO3(aq) reacting with 100 cm3 of 0.1 M NaOH(aq)
D. 100 cm3 of 0.1 M CH3COOH(aq) reacting with 100 cm3 of 0.1 M NH3(aq)

HKDSE CHEMISTRY — A Modern View (Second Edition)

© Aristo Educational Press Ltd 2019 2
Quizizz: 25-minute Test Part VIII Chemical Reactions and Energy

10. 120 cm3 of 0.20 M hydrochloric acid was mixed with 90 cm 3 of 0.30 M ammonia solution. The
temperature of the resultant solution rose from 22.8C to 24.2C. What is the enthalpy change
for the formation of one mole of ammonium chloride?
(Assume that the specific heat capacity and the density of the reaction mixture are the same as
those of water, i.e. 4.2 J g1 K1 and 1.0 g cm3 respectively.)
A. 45.7 kJ mol1
B. +45.7 kJ mol1
C. 51.5 kJ mol1
D. +51.5 kJ mol1

11. Given that:

Substance ΔH f / kJ mol1
ZnS(s) 206
ZnO(s) 351
SO2(g) 297

What is the standard enthalpy change of the reaction below?

2ZnS(s) + 3O2(g)  2ZnO(s) + 2SO2(g)

A. 442 kJ mol1
B. +442 kJ mol1
C. 884 kJ mol1
D. +884 kJ mol1

12. 1.15 g of ethanol was burnt completely to heat up some water with a mass of x inside a
calorimeter. The temperature rise of the water was 13.5C. The experiment was repeated using
1.84 g of ethanol but with a different mass of water inside the calorimeter. The temperature rise
of the calorimeter is 10.8C. What is the mass of water for the second experiment?
(Molar mass: ethanol = 46.0 g mol–1)
A.

B.

C.

D. 2x

HKDSE CHEMISTRY — A Modern View (Second Edition)

© Aristo Educational Press Ltd 2019 3
Quizizz: 25-minute Test Part VIII Chemical Reactions and Energy

13. Given that:

C(s) + O2(g)  CO(g) ΔH = –111 kJ mol–1

Mn(s) + O2(g)  MnO2(s) ∆H = –520 kJ mol–1

What is the enthalpy change of the reaction below?

MnO2(s) + 2C(s)  Mn(s) + 2CO(g)

A. –631 kJ mol–1
B. –298 kJ mol–1
C. +298 kJ mol–1
D. +409 kJ mol–1

14. Given that:

Substance ΔH f / kJ mol1
CH3OH(l) –239
CO2(g) –394
H2O(l) –286

What is the ΔH c [CH3OH(l)]?

A. –727 kJ mol–1
B. +727 kJ mol–1
C. –1205 kJ mol–1
D. +1205 kJ mol–1

15. Consider the following thermochemical equations.

(1) H2(g) + Cl2(g)  2HCl(g) ΔH1 = w kJ mol–1
(2) N2(g) + 3H2(g)  2NH3(g) ΔH2 = x kJ mol–1
(3) NH3(g) + HCl(g)  NH4Cl(s) ΔH3 = y kJ mol–1
(4) N2(g) + 4H2(g) + Cl2(g)  2NH4Cl(s) ΔH4 = z kJ mol–1
Which of the following expressions is the correct relationship among w, x, y and z?
A. w = z – x – 2y
B. x = z – 2w + y
C. y = w + x + z
D. z = 2x + y – w

HKDSE CHEMISTRY — A Modern View (Second Edition)

© Aristo Educational Press Ltd 2019 4
Quizizz: 25-minute Test Part VIII Chemical Reactions and Energy

16. A student determined the standard enthalpy change of neutralization between ethanoic acid and
sodium hydroxide solution using simple calorimetric method. Which of the following is NOT a
possible source of error in the experiment?
A. Some energy was used for the ionization of ethanoic acid.
B. There was heat loss to the surroundings.
C. The calorimeter and thermometer absorbed some heat.
D. The experiment was not done under standard conditions.

17. Consider the following reaction.

2N2(g) + 5O2(g)  2N2O5(g) ΔH = x kJ mol1

Which of the following statements is/are correct?

(1) The standard enthalpy change of formation of N2O5(g) is  kJ mol1.

(2) The standard enthalpy change of formation of N2O5(g) is x kJ mol1.

(3) The standard enthalpy change of combustion of N2(g) is +x kJ mol1.
A. (1) only
B. (2) only
C. (1) and (3) only
D. (2) and (3) only

18. Consider the following reaction:

PCl3(g) + Cl2(g)  PCl5(g)

Which of the following statements are correct?

(1) Cl–Cl bonds are broken in this reaction.
(2) P–Cl bonds form in this reaction.
(3) It is an exothermic reaction.
A. (1) and (2) only
B. (1) and (3) only
C. (2) and (3) only
D. (1), (2) and (3)

HKDSE CHEMISTRY — A Modern View (Second Edition)

© Aristo Educational Press Ltd 2019 5
Quizizz: 25-minute Test Part VIII Chemical Reactions and Energy

19. The enthalpy change of combustion of 116 g of butane gas (C 4H10) is –5756 kJ under standard
conditions. Which of the following statements are correct?
(Relative atomic masses: H = 1.0, C = 12.0)
(1) The combustion of butane is an exothermic process.
(2) The enthalpy change for the combustion of 2.5 mol of butane is –7195 kJ.
(3) ΔH c [C4H10(g)] is –5756 kJ mol–1.
A. (1) and (2) only
B. (1) and (3) only
C. (2) and (3) only
D. (1), (2) and (3)

20. Consider the following enthalpy level diagram.

CH4(g) + 2O2(g)
Enthalpy

∆H 2 = –803 kJ mol–1
∆H 1 = –891 kJ mol–1 CO2(g) + 2H2O(g)
∆H 3

CO2(g) + 2H2O(l)

All enthalpy changes are measured under standard conditions. Which of the following
conclusions can be made from the diagram?
(1) H 3 is –88 kJ mol–1.
(2) The standard enthalpy change of combustion of methane is –803 kJ mol–1.
(3) Energy is taken in when H2O(l) changes to H2O(g).
A. (1) and (2) only
B. (1) and (3) only
C. (2) and (3) only
D. (1), (2) and (3)

HKDSE CHEMISTRY — A Modern View (Second Edition)

© Aristo Educational Press Ltd 2019 6
Quizizz: 25-minute Test Part VIII Chemical Reactions and Energy

Answers

1. B

2. C
Option (B): a neutralization reaction occurs which is exothermic.
Option (C): it is cracking. Cracking is an endothermic reaction as the energy needed for
breaking the covalent bonds in the alkane molecules is greater than that released during the
formation of the covalent bonds in the products.
Option (D): it is a precipitation reaction which is exothermic.

3. B
During the formation of H2O2(l), there is a reduction in gas volume. There will be a work done
on the system by the atmospheric pressure.

4. D
As H < 0, the reaction is exothermic. In an exothermic reaction, the energy given out by the
bond-forming processes is greater than the energy taken in by the bond-breaking processes.

5. A
Heat change at constant pressure = Change in internal energy + Work done on the surroundings
= [–256 + (+35)] kJ = –221 kJ

6. D
Energy is needed for the conversion of solid to liquid and the conversion of liquid to gas.
CCl4(s)  CCl4(g) involves the largest absorption of energy as it involves both melting and
boiling processes.

7. B
Br2(g) + F2(g)  BrF3(g) ∆H = –511 × kJ mol–1 = –255.5 kJ mol–1

BrF3(l)  Br2(g) + O2(g) ∆H = +602 × kJ mol–1 = +301 kJ mol–1

Adding up the two thermochemical equations, we get the thermochemical equation for the
boiling of 1 mol of liquid BrF3:
BrF3(l)  BrF3(g)
∴∆H for the boiling of 1 mol of liquid BrF3 = [(–255.5) + (+301)] kJ mol–1 = +45.5 kJ mol–1

HKDSE CHEMISTRY — A Modern View (Second Edition)

© Aristo Educational Press Ltd 2019 7
Quizizz: 25-minute Test Part VIII Chemical Reactions and Energy

8. A
No. of moles of Fe reacted = mol

Heat change = –1650 × × kJ = –7.39 kJ

∴heat released is 7.39 kJ.

9. A
Option (A) leads to a larger temperature rise than option (B) as some energy is needed for the
complete ionization of NH3(aq).
Option (A) leads to a larger temperature rise than option (C) as the same amount of energy
released is used to heat up a larger volume of the reaction mixture in (C).
Option (A) leads to a larger temperature rise than option (D) as some energy is needed for the
complete ionization of CH3COOH(aq) and NH3(aq).

10. C
HCl(aq) + NH3(aq)  NH4Cl(aq)
Heat released during neutralization = mcΔT
= {(120 + 90) × 1.0 × 4.2 × [(24.2 + 273) – (22.8 + 273)]} J = 1234.8 J
No. of moles of HCl(aq) = 120 × 10–3 × 0.2 mol = 0.024 mol
No. of moles of NH3(aq) = 90 × 10–3 × 0.3 mol = 0.027 mol
From the equation, mole of HCl to NH3 = 1 : 1.
∴HCl is the limiting reactant.
No. of moles of NH4Cl = 0.024 mol
ΔH = – J mol–1 = –51 450 J mol–1 = –51.45 kJ mol–1 = –51.5 kJ mol–1

11. C
By applying Hess’s Law,
ΔH = ΣΔH f [products] – ΣΔH f [reactants]
= 2ΔH f [ZnO(s)] + 2ΔH f [SO2(g)] – 2ΔH f [ZnS(s)]
= [2(–351) + 2(–297) – 2(–206)] kJ mol–1
= –884 kJ mol–1

HKDSE CHEMISTRY — A Modern View (Second Edition)

© Aristo Educational Press Ltd 2019 8
Quizizz: 25-minute Test Part VIII Chemical Reactions and Energy

12. D
Let c be the specific heat capacity of water, m be the mass of water for the second experiment.
For the first experiment,

ΔH = – = –540xc

For the second experiment,

ΔH = –

–540xc = –270mc
m = 2x

13. C
2C(s) + O2(g)  2CO(g) ΔH = –111 × 2 kJ mol–1 = –222 kJ mol–1
MnO2(s)  Mn(s) + O2(g) ΔH = +520 kJ mol–1
Adding up the two thermochemical equations, we get the target thermochemical equation:
MnO2(s) + 2C(s)  Mn(s) + 2CO(g)
∆H = [(–222) + 520] kJ mol–1 = +298 kJ mol–1

14. A
The thermochemical equation for the standard enthalpy change of combustion of CH3OH(l) is:
CH3OH(l) + O2(g)  CO2(g) + 2H2O(l)

ΔH c [CH3OH(l)] = ΣΔH f [products] – ΣΔH f [reactants]

= [(–394) + 2(–286) – (–239)] kJ mol–1
= –727 kJ mol–1

15. A
(1): H2(g) + Cl2(g)  2HCl(g) ΔH = w kJ mol–1
(2): N2(g) + 3H2(g)  2NH3(g) ΔH = x kJ mol–1
(3) × 2: 2NH3(g) + 2HCl(g)  2NH4Cl(s) ΔH = 2y kJ mol–1
Adding up the above equations, we get equation (4):
(4): N2(g) + 4H2(g) + Cl2(g)  2NH4Cl(s) ΔH = z kJ mol–1
∴z = w + x + 2y
w = z – x – 2y

HKDSE CHEMISTRY — A Modern View (Second Edition)

© Aristo Educational Press Ltd 2019 9
Quizizz: 25-minute Test Part VIII Chemical Reactions and Energy

16. A
In the neutralization between CH3COOH(aq) (a weak acid) and NaOH(aq), some energy is
consumed for the ionization of the CH3COOH(aq) to produce H+(aq). Hence, the energy
released from the reaction is generally less than that from the reaction between a strong acid
and a strong alkali. However, it is not an experimental error.

17. A
The standard enthalpy change of formation of N2O5(g) is the enthalpy change when 1 mole of
N2O5(g) forms from N2(g) and O2(g) under standard conditions. The standard enthalpy change
of combustion of N2(g) is the enthalpy change when 1 mole of N2(g) is completely burnt in
oxygen under standard conditions.

18. D
PCl5(g)  PCl3(g) + Cl2(g) is a decomposition reaction which is endothermic.
PCl3(g) + Cl2(g)  PCl5(g) is the reverse of the decomposition reaction, so it is an exothermic
reaction.

19. A
(2): No. of moles of 116 g of C4H10 = mol = 2 mol

∴ΔH for the combustion of 2.5 mol of C4H10 = –5756 × kJ = –7195 kJ

(3): 116 g of C4H10 contains 2 mol of C4H10,

∴ΔH c [C4H10(g)] = – kJ mol–1 = –2878 kJ mol–1

20. B
(1): H 3 = H 1 – H 2 = [(–891) – (–803)] kJ mol–1 = –88 kJ mol–1
(2): The products of the combustion of CH4(g) under standard conditions are CO2(g) and
H2O(l). Therefore, ΔH c [CH4(g)] = ΔH 1 = –891 kJ mol–1.
(3): The enthalpy of H2O(g) is higher than that of H2O(l), so energy is taken in when H 2O(l)
changes to H2O(g).

HKDSE CHEMISTRY — A Modern View (Second Edition)

© Aristo Educational Press Ltd 2019 10