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DP10 Chemistry Online Quiz

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DP10 Chemistry Online Quiz

Name: Class:

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1. What is the maximum mass, in g, of magnesium oxide that can be obtained from the
reaction of oxygen with 2.4 g of magnesium?
A. 2.4
B. 3.0
C. 4.0
D. 5.6

2. What is the sum of all coefficients when the following equation is balanced using the
smallest possible whole numbers?
__ C2H2+ __ O2 → __ CO2+ __ H2O
A. 5
B. 7
C. 11
D. 13

3. 1.0 dm3 of an ideal gas at 100 kPa and 25 °C is heated to 50 °C at constant pressure.
What is the new volume in dm3?
A. 0.50
B. 0.90
C. 1.1
D. 2.0

4. Which graph represents the relationship between volume and pressure for a fixed
mass of gas at constant temperature?

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DP10 Chemistry Online Quiz

5. Equal masses of the metals Na, Mg, Ca and Ag are added to separate samples of
excess HCl(aq). Which metal produces the greatest total volume of H2(g)?
A. Na
B. Mg
C. Ca
D. Ag

6. 4.00 mol of a hydrocarbon with an empirical formula of CH2 has a mass of 280 g.
What is the molecular formula of this compound?
A. C2H4
B. C3H6
C. C4H8
D. C5H10

7. Which statement is correct for the equilibrium H2O(l) ⇌ H2O(g) in a closed system
at 100 °C?
A. All the H2O(l) molecules have been converted to H2O(g).
B. The rate of the forward reaction is greater than the rate of the reverse reaction.
C. The rate of the forward reaction is less than the rate of the reverse reaction.
D. The pressure remains constant.

8. Which statement is always correct for a chemical reaction at equilibrium?


A. The rate of the forward reaction equals the rate of the reverse reaction.
B. The amounts of reactants and products are equal.
C. The concentration of the reactants and products are constantly changing.
D. The forward reaction occurs to a greater extent than the reverse reaction.

9. Which variable affects the equilibrium constant, Kc?


A. Atmospheric pressure
B. Catalyst
C. Concentration of reactants
D. Temperature

10. Which statement is correct for a reversible reaction when Kc≫1?


A. The reaction almost goes to completion.
B. The reaction hardly occurs.
C. Equilibrium is reached in a very short time.
D. At equilibrium, the rate of the forward reaction is much higher than the rate of
the backward reaction.

11. Ethanoic acid reacts with ethanol in a reversible reaction represented by the equation
below. In an experiment 3.0 mol of ethanoic acid (CH3COOH) were mixed with 1.0
mol of ethanol (C2H5OH) and when the reaction had reached equilibrium 0.9 mol of
water had been formed.

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DP10 Chemistry Online Quiz

CH3COOH(l) + C2H5OH(l) ⇌ CH3COOC2H5(l) + H2O(l)


A. 0.20
B. 0.23
C. 3.9
D. 4.3

12. Which of the following shows chlorine in its correct oxidation states in the
compounds shown?
HCl KClO3 HClO
A -1 +3 +1
B +1 -5 -1
C -1 +5 +1
D +1 +5 -1

13. In which reaction is hydrogen acting as an oxidising agent?


A. Cl2 + H2 → 2HCl
B. (CH3)2CO + H2 → (CH3)2CHOH
C. N2 + 3H2 → 2NH3
D. 2Na + H2 → 2NaH

14. Which one of the following is not a redox reaction?


A. Br2 + SO2 + 2H2O → SO42− + 4H+ + 2Br−
B. SnCl2 + HgCl2 → Hg + SnCl4
C. Cu2O + H2SO4 → CuSO4 + Cu + H2O
D. 2CrO42− + 2H+ → Cr2O72− + H2O

15. Which of these pieces of apparatus has the lowest percentage uncertainty in the
measurement shown?
A. Volume of 25 cm3 measured with a burette with an uncertainty of ±0.1 cm3.
B. Volume of 25 cm3 measured with a measuring cylinder with an uncertainty of ±0.5
cm3.
C. Mass of 0.150 g measured with a balance with an uncertainty of ±0.001 g.
D. Temperature change of 23.2 °C measured with a thermometer with an uncertainty of
±0.1 °C.

16. A student is provided with a 5.00 cm3 sample of 1.00 × 10−2 mol dm−3 hydrochloric
acid. The student is asked to devise a method to prepare a hydrochloric acid solution
with a concentration of 5.00 × 10−4 mol dm−3 by diluting the sample with water. Which
of these is the correct volume of water that should be added?
A. 45.0 cm3
B. 95.0 cm3
C. 100 cm3
D. 995 cm3

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DP10 Chemistry Online Quiz

17. The removal of silicon dioxide with limestone in the Blast Furnace can be
represented by the following equation.
CaCO3(s) + SiO2(s) → CaSiO3(l) + CO2(g)
The volume of carbon dioxide, measured at 298 K and 1.01 × 105 Pa, formed in this
reaction during the removal of 1.00 tonne (1000 kg) of silicon dioxide is
A. 24.5 dm3
B. 408 dm3
C. 24.5 m3
D. 408 m3

18. Which one of the following samples of gas occupies the largest volume?
A. 1.0 g of ozone at l00 kPa and 300 K
B. 1.0 g of oxygen at 100 kPa and 300 K
C. 1.0 g of water vapour at 250 kPa and 450 K
D. 1.0 g of methane at 333 kPa and 500 K

19. At 700 ºC, the equilibrium constant, Kc, for the reaction is 1.075 × 108.
2H2(g) + S2(g) ⇌ 2H2S(g)
Which relationship is always correct for the equilibrium at this temperature?
A. [H2S]2 < [H2]2[S2]
B. [S2] = 2[H2S]
C. [H2S] < [S2]
D. [H2S]2 > [H2]2[S2]

20. What is the equilibrium constant expression, Kc, for this reaction?
2NO(g) + H2(g) ⇌ N2O(g) + H2O(g)
A.

B.

C.

D.

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DP10 Chemistry Online Quiz

(7 marks) 1. A sample of an unknown gas, X, with a mass of 3.620 g was made to


decompose into 2.172 g of O2 and 1.448 g of S.

(a) Determine the percentage by mass of sulfur and oxygen in gas X. [2]

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(b) Determine the empirical formula of gas X. [2]

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Before the decomposition, gas X occupied a volume of 1120 mL at 75cm Hg and 25℃.

(c) What is the molecular mass for this sample of unknown gas? [2]

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(d) Determine the molecular formula of this gas. [1]

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DP10 Chemistry Online Quiz

(8 Marks) 2. a) (i)Write the equilibrium constant expression of Kc for the reaction. [1]

IO4-(aq) + 2 H2O(l) ⇌ H4IO6-(aq) ,

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(ii) State the characteristic properties of chemical equilibrium. [2]

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(iii) At 298K, Kc = 3.5 x 10-2. If you start with 25.0 mL of a 0.905 mol dm-3 solution
of NaIO4, and then dilute it with water to 500.0 mL, what is the concentration of H4IO6-
at equilibrium? [2]

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b) i) Write the equilibrium constant expression for the following reaction [1]

COCl2 (g) ⇌ CO(g) + Cl2(g)

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DP10 Chemistry Online Quiz

ii) At 100 °C, the equilibrium constant for the reaction has the value
Kc = 2.19 x 10-10. Are the following mixtures of COCl2, CO, and Cl2 at 100 °C at
equilibrium? Showing your calculation. If not, indicate the direction that the reaction
must proceed to achieve equilibrium. [2]
[COCl2] = 2.00 x 10-3 mol dm-3, [CO] = 3.3 x 10-6 mol dm-3, [Cl2] = 6.62 x 10-6 mol dm-
3

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