Chemistry–FUNGAT/ECAT

(Chapter 8+9 B-I)

1. The pH of acetic acid /sodium acetate buffer having concentration of CH3COONa is 10
times lesser than CH3COOH (pKa of CH3COOH = 4.74):
(a) 4.74 (b) 3.74 (c) 5.74 (d) 6.74
2. o
The pKb value for aqueous ammonia at 25 C is 5.2. What is the pKa value for the
ammonium ion at this temperature:
(a) – 5.2 (b) 9.2 (c) 9.8 (d) 8.8
3. Among the following hydroxides; the one which has highest value of Ksp at room
temperature:
(a) Mg(OH)2 (b) Ba(OH)2 (c) Ca(OH)2 (d) Be(OH)2
4. The reaction which is favoured at low pressure:
(a) N 2  3H 2 2NH3 (b) N2 + O2 2NO
(c) PCl5 PCl3 + Cl2 (d) H2 + F2 2HF
5. Which of the following aqueous solution will have highest pH:
(a) CH3COOK (b) NH4Cl (c) Na2CO3 (d) (NH4)2CO3
6. When CO2 is added into water, then which is true:
(a) pH decreases (b) H+ concentration decreases
(c) pH increases (d) OH- concentration increases
7. Which one of the following is the conjugate base of the hydrogen sulphite ion (HSO -13 ) ?
(a) H2SO3 (b) H 2SO3+ (c) SO -23 (d) SO3-1
8. Nitrogen dioxide decomposes on heating according to the following equation.
2NO 2 g   2NO g  + O 2 g 
When 2 moles of nitrogen dioxide were put into a 1 dm3 container and heated, 0.8 moles of
NO2 changes into NO and O2 at equilibrium. What is the numerical value of the equilibrium
constant, Kc at the temperature of the experiment?
 0.4   0.4  0.8  0.4
2 2
0.4  0.4 0.8  0.4
(a) (b) (c) (d)
 2 1.2  1.2 
2 2 2
1.2
9. For which of the following reaction Kc has moles-2 dm+6 unit:
 2 NH 3 g 
(a) N 2  g   3H 2  g  
 PCl3 g   Cl2 g 
(b) PCl5 g  
 CH 3COOC2 H 5 aq   H 2O
(c) CH 3COOH  aq   C2 H 5OH  aq  
 2 SO3 g 
(d) SO2 g   O2 g  
10. Which of the following relationships is incorrect?
(a) Kp  Kc when n  0 (b) Kp  Kc when n  0
(c) Kp  Kc when n  0 (d) Kp  Kc when n  0
11. For the reaction value of Kc increases with increase in temperature, H for the reaction
would be:
(a) positive (b) negative (c) zero (d) can’t be predicted
12. One mole of ethyl alcohol was treated with one mole of acetic acid at 25oC. 2/3rd of acid
changes into ester at equilibrium. Equilibrium constant of reaction will be:
(a) 1 (b) 2 (c) 3 (d) 4
13. 
When the system H 2 g   I 2 g   2 HI  g  is in equilibrium at 44oC and 1 atm pressure
value of equilibrium constant Kp is 50 what is value of Kp at pressure 2 atm at same
temperature?
(a) 25 (b) 50 (c) 100 (d) 200

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14. The pH of 0.5 M H2SO4 is:
(a) 0.5 (b) 1.0 (c) 0.1 (d) 0.0
15. 2
The equilibrium expression for a reaction is Kc = x /V(a – x), what is true for this reaction:
(a) increase of pressure favours forward reaction
(b) decrease of pressure favours forward reaction
(c) decrease of pressure favours backward reaction
(d) increase of volume favours backward reaction
16. Which solution will have lowest vapor pressure?
(a) 0.1 m sucrose (b) 0.1 m NaCl (c) 0.1 m AlCl3 (d) 0.1 m C6H12O6
17. Which of the following pairs does not form ideal solution:
(a) C2 H 5 Br and C2 H 5 I (b) C 6 H 5 Cl and C 6 H 5 Br
(c) C 6 H 5 Cl and C 6 H 5 Br (d) C 2 H 5 Cl and C 2 H 5 OH
18. The depression of freezing point of equi molal aqueous solution of HCI, CuSO4 and
K 2 SO4 is:
(a) In the ratio 2 : 2 : 3 (b) In the ratio 1 : 2 : 3
(c) In the ratio 2 : 4 : 3 (d) In the ratio 3 : 2 : 1
19. Aqueous solution of glucose C6H12O6 boils at 100.52oC. The solution contains:
(a) 180 grams glucose in 1 kg water (b) 1.8 grams glucose in 1 kg water
(c) 18 grams glucose in 1 kg water (d) 3.6 grams glucose in 1 kg water
20. A solution containing 180g of urea in one kg of water should have boiling point
(a) 100oC (b) 100.52oC (c) 101.04oC (d) 101.56oC
21. For a dilute solution containing non-volatile solute, elevation of boiling point is given by
the expression:
Km K m 1000
(a) M 2  b 2 (b) M 2  b 2
 Tb m1  Tb m1
K  m2 1000 K  m2
(c) M 2  f (d) M 2  f
 Tb m1  Tb m1
22. Which solution will have highest concentration solute at 25oC
(a) 0.1m NaOH (b) 1M NaOH (c) 1m NaOH (d) 0.1 M NaOH
23. For which ion the enthalpy change of hydration likely to be the most exothermic:
Ionic radius (nm) Charge on ion
(a) 0.065 +2
(b) 0.095 +1
(c) 0.135 +2
(d) 0.169 +1
24. The molarity of solution containing 1.5 grams urea (N2H4CO) dissolved in 600 cm3 of the
solution is :
(a) 1 molar (b) 00.1 molar (c) 0.2 molar (d) 0.046 molar
25. The boiling point of an a zeotropic mixture of water and ethyl alcohol is less than that of
water and alcohol. The mixture shows?:
(a) That solution is highly saturated (b) No deviation from Raoult’s law
(c) Positive deviation from Raoult’s law (d) Negative deviation from Raoult’s law
26. Which of the following is correct for solution showing positive deviation from Raoult’s
Law?
(a) ∆V = +ve, ∆H = +ve (b) ∆V = -ve, ∆H = +ve
(c) ∆V = -ve, ∆H = -ve (d) ∆V = +ve, ∆H = -ve
27. Two percent by weight of NaCl solution is prepared, the molarity of this solution is:
(a) 0.34 molar (b) 0.25 molar (c) 2.0 molar (d) 0.02 molar
28. According to Raoult’s law, relative lowering of vapour pressure for a solution is equal to:
(a) Mole fraction of the solute (b) Mole fraction of a solvent
(c) Moles of a solute (d) Moles of a solvent
29. Osmotic pressure of a solution is____________ property:
(a) Obligative (b) Fractional (c) Colligative (d) Automated
30. The elevation in boiling point of a molal solution is called:
(a) cryoscopic constant (b) ebullioscopic constant
(c) boiling point constant (d) both (b) and c
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