CHEMISTRY

31. Choose the correct statements

(A) equivalent points in unit cells of a periodic lattice lie on a Bravais lattice
(B) equivalent points in unit cells of a periodic lattice do not lie on a Bravais lattice
(C) There are four Bravais lattices in two dimensions
(D) There are five Bravais lattices in three dimensions

32. Consider a Body Centered Cubic(bcc) arrangement, let de, dfd, dbd be the distances between
successive atoms located along the edge, the face-diagonal, the body diagonal respectively in a unit
cell.Their order is given by:
(A) de < dfd < dbd (B) dfd > dbd > de (C) dfd > de > dbd (D) dbd > de > dfd,

33. Volume of HCP unit cell is :

(A) 24 r3 (B) 8 r3 (C) 16 r3 (D) 24 r3

34. In a hypothetical solid C atoms form CCP lattice with A atoms occupying all the Tetrahedral Voids and
B atoms occupying all the octahedral voids.A and B atoms are of the appropriate size such that there
is no distortion in the CCP lattice.Now if a plane is cut (as shown) then type of voids and their
numbers whic are present at the cross section would be.
Plane

CCP unit cell

(A) O.V = 3, T.V. = 4 (B) O.V. = 2, T.V. = 4 (C) O.V. = 1, T.V. = 2 (D) O.V. = 0, T.V. = 4

35. The spinal structure (AB2O4) consists of an fcc array of O2– ions in which the :
(A) A cation occupies one-eighth of the tetrahedral holes and B cation occupies one-half of octahedral
holes
(B) A cation occupies one-fourth of the tetrahedral holes and the B cations the octahedral holes
(C) A cation occupies one-eighth of the octahedral hole and the B cation the tetrahedral holes
(D) A cation occupies one-fourth of the octahedral holes and the B cations the tetrahedral holes

36. Which of the following is true about the charge acquired by p-type semiconductors?
(A) positive (B) neutral
(C) negative (D) depends on concentration of p impurity

37. Which of the following curves represents theHenry’slaw?

(A) (B)

(C) (D)
38. When a liquid that is immiscible with water was steam distilled at 95.2ºC at a total pressure of 748
torr, the distillate contained 1.25 g of the liquid per gram of water. The vapour pressure of water is 648
torr at 95.2ºC, what is the molar mass of liquid?
(A) 7.975 g/mol (B) 166 g/mol (C) 145.8 g/mol (D) None of these

39. An ideal solution contains two volatile liquids A (pº = 100 torr) and B (pº = 200 torr). If mixture contain
1 mole of A and 4 mole of B then total vapour pressure of the distillate is:
(A) 150 (B) 180 (C) 188.88 (D) 198.88

40. When KCl dissolves in water (assume endothermic dissolution), then :

(A) H = + ve, S = + ve, G = + ve (B) H = + ve, S = – ve, G = – ve
(C) H = + ve, S = + ve, G = – ve (D) H = – ve, S = – ve, G = + ve

41. If Mnormal is the normal molecular mass and  is the degree of ionization of K 3[Fe(CN)6], then the
abnormal molecular mass of the complex in the solution will be:
(A) Mnormal (1 + 2)–1 (B) Mnormal (1 + 3)–1 (C) Mnormal (1 + )–1 (D) equal to Mnormal

42. The vapour pressure of a solution of a non-volatile solute B in a solvent A is 95% of the vapour
pressure of the solvent at the same temperature. If the molecular weight of the solvent is 0.3 times the
molecular weight of the solute, what is the ratio of weight of solvent to solute.
(A) 0.15 (B) 5.7 (C) 0.2 (D) none of these

43. Sea water is found to contain 5.85 % NaCl and 9.50% MgCl 2 by weight of solution. Calculate its
normal boiling point assuming 80% ionisation for NaCl and 50% ionisation of MgCl 2 (Kb(H2O) = 0.51
kgmol–1 K).
(A) Tb = 101.9°C (B) Tb = 102.3°C (C) Tb = 108.5°C (D) Tb = 110.3°C

44. Consider following cases :

I : 2M CH3COOH solution in benzene at 27°C where there is dimer formation to the extent of 100%
II : 0.5 M KCl aq. solution at 27°C, which ionises 100%
Which is/are true statements(s) :
(A) both are isotonic (B) I is hypertonic (C) II is hypotonic (D) none is correct

45. Water and chlorobenzene are immiscible liquids. Their mixture boils at 89ºC under a reduced
pressure of 7.7 × 104 Pa. The vapour pressure of pure water at 89ºC is 7 × 10 4 Pa. Weight percent of
chlorobenzene in the distillate is:
(A) 50 (B) 60 (C) 78.3 (D) 38.46

46. Calculate the amount of Ni needed in the Mond's process given below
Ni + 4CO Ni(CO)4
If CO used in this process is obtained through a process, in which 6 g of carbon is mixed with 44 g
CO2.
(Ni = 59 u)
(A) 14.675 g (B) 29 g (C) 58 g (D) 28 g

47. NX is produced by the following step of reactions

M + X2 M X2
3MX2 + X2 M3X8
M3 X8 + N2CO3 NX + CO2 + M3O4
How much M (metal) is consumed to produce 206 g of NX. (Take at wt of M = 56, N=23, X = 80)
 (A) 42 g (B) 56 g (C) g (D) g
48. The average oxidation state of Fe in Fe3O4 is :
(A) – 8/3 (B) 8/3 (C) 2 (D) 3

49. CN– is oxidised by NO3– in presence of acid :

aCN– + bNO3– + cH+ (a + b) NO + aCO2 + H2O

What are the whole number values of a, b, c in that order :
(A) 3, 7, 7 (B) 3, 10, 7 (C) 3, 10, 10 (D) 3, 7, 10

50. Mole fraction of A in H2O is 0.2. The molality of A in H2O is :

(A) 13.9 (B) 15.5 (C) 14.5 (D) 16.8

51. How many of the following are Covalent network solids?

S8, Bronze, SiO2, Diamond, ZnSO4, Si, AlN, SiC, CO2.

52. How many number of atom effectively present in a cubic unit formed by arrangement of eight B.C.C
unit cell.

53. How many spherical balls of radii 2 cm can be placed completely inside a cubical box of edge = 8
cm ?

54. In ABAB ....... arrangement if an atom is placed in A layer then calculate the number of atoms
touching in its adjacent B layers ?

55. What volume of 98% sulphuric acid (in ml) should be mixed with water to obtain 200 mL of 15%
solution of sulphuric acid by weight ? Given density of H 2O = 1.00 g cm–3, sulphuric acid (98%) = 1.88
g cm–3 and sulphuric acid (15%) = 1.12 g cm–3.

56. At 300 K, 40 mL of O3 (g) dissolves in 100 g of water at 1.0 atm. What mass of ozone (in gram)
dissolved in 1600 g of water at a pressure of 4.0 atm at 300 K?

57. An ideal aqueous solution containing liquid A(M.Wt. = 128) 64% by weight has a vapour pressure of
145 mm Hg. If the vapour pressure of A is x mm of Hg and that of water is 155 mm Hg at the same
temperature. Then find x/5. The solutions is ideal.

58. A and B form ideal solutions; at 50ºC, PAº is half PBº. A solution containing 0.2 mole of A and 0.8 mole
of B has a normal bolling point of 50ºC. Find 18 × PBº. (PBº is in atm)

59. The reaction Cl2 (g) + S2O32– SO42– + Cl– is to be carried out in basic medium. Starting with 1.5
mole of Cl2, 0.1 mole S2O3 and 3 mole of OH–. How many moles of OH– will be left in solution after
2–

the reaction is complete. Assume no other reaction occurs.

60. In the reaction : 2Al + Cr2O3 Al2O3 + 2Cr, 49.8 g of Al reacted with 200.0 g Cr 2O3. How much
grams of reactant remains at the completion of the reaction ?