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LEVEL-1
❖Laws of chemical combination
1. There are two common oxides of Sulphur, one of which contains 50% O 2 by weight, the
other almost exactly 60%. The weights of sulphur which combine with 1 g of O 2 (fixed)
are in the ratio of -
(A) 1 : 1 (B) 2 : 1 (C) 2 : 3 (D) 3 : 2
2. Iron forms two oxides, in first oxide 56 gram. Iron is found to be combined with 16 gram
oxygen and in second oxide 112 gram iron is found to be combined with 48 gram
oxygen. This data satisfy the law of -
(A) Conservation of mass (B) Reciprocal proportion
(C) Multiple proportion (D) Combining volume
4. The chloride of a metal contains 71% chlorine by weight and the vapour density of it is
50. The atomic mass of the metal will be (valency of metal is 2) -
(A) 29 (B) 58 (C) 35.5 (D) 71
5. A reaction required three atoms of Mg for two atoms of N. How many gm of N are
required for 3.6 gm of Mg ?
(A) 2.43 (B) 4.86 (C) 1.4 (D) 4.25
6. A hydrated salt of Na2SO3 loses 22.22 % of its mass on strong heating. The hydrated salt is
(A) Na2SO3.4H2O (B) Na2SO3.6H2O (C) Na2SO3.H2O (D) Na2SO3.2H2O
❖ Mole-concept
11. The number of molecules present in 88 g of CO2 (Relative molecular mass of CO2 = 44)
(A) 1.24 × 1023 (B) 3.01 × 1023
(C) 6.023 × 1024 (D) 1.2046 ×1024
12. The number of Ca2+ and Cl¯ ions present in anhydrous CaCl2 is 3.01 × 1023 and 6.023 × 1023
respectively. The weight of the anhydrous sample is -
(A) 40 g (B) 55.5 g
(C) 222 g (D) 75.5 g
14. If NA is Avogadro number, then the number of valence electrons in 4.2 g of N3– ions is -
(A) 2.4 NA (B) 4.2 NA
(C) 1.6 NA (D) 3.2 NA
15. Two oxides of a metal contain 50% and 40% metal M respectively. If the formula of the
first oxide is MO2, the formula of the second oxide will be -
(A) MO2 (B) MO3
(C) M2O (D) M2O5
17. Insulin contains 3.4% sulphur. What will be the minimum molecular weight of insulin ?
(A) 94.176 (B) 1884 (C) 941.176 (D) 976
18. The volume occupied by 7.23 × 1023 molecules of carbon dioxide and 3.01 × 1023
molecules of Argon at 0°C and 1 atm pressure is -
(A) 38 mL (B) 3.80 L
(C) 3.8 × 104 mL (D) 3.8 × 103 mL
19. A carbon compound containing carbon and oxygen has molar mass equal to 288. On
analysis it is found to contain 50% by mass of each element. Therefore molecular
formula of the compound is -
(A) C12O9 (B) C4O3 (C) C3O4 (D) C9O12
20. A sample of impure cuprite, Cu2O, contains 66.6% copper. What is the percentage of
pure Cu2O in the sample -
(A) 75% (B) 25% (C) 60% (D) 80%
21. A given sample of pure compound contains 9.81 gm of Zn, 1.8 × 1023 atoms of chromium,
and 0.60 mol of oxygen atoms. what is the simplest formula -
(A) ZnCr2O7 (B) ZnCr2O4 (C) ZnCrO4 (D) ZnCrO6
22. 510 mg of liquid on vaporization in Victor Meyer's apparatus displaces 67.2 cm 3 of air at
(STP). The molecular weight of the liquid is -
(A) 130 (B) 17 (C) 170 (D) 1700
23. When 3.2g S is vapourized at 450ºC and 723 mm pressure, the vapours occupy a
volume of 780 ml. What is the molecular formula of
S vapours under these conditions -
(A) S2 (B) S4 (C) S6 (D) S8
24. 2.76 g of silver carbonate on being strongly heated yields a residue weighing -
1
(Ag2CO3 ⎯⎯→ 2Ag + CO2 + O2)
2
(A) 2.16 g (B) 2.48 g (C) 2.32 g (D) 2.64 g
25. 1.84-gram mixture of CaCO3 and MgCO3 on heating gives CO2. Volume of CO2 obtained
is measured to be 448 mL at STP. mass of CaCO3 in mixture is -
(A) 0.5 gram (B) 0.84 gram (C) 0.92 gram (D) 1.00 gram
27. 0.54 gm of metal “M” yields 1.02 gm of its oxide M2O3. The at. wt. of metal “M” is -
(A) 9 (B) 18 (C) 27 (D) 54
28. Phosphine (PH3) decomposes to produce P4 (g) and H2 (g). What would be the change in
volume when 100 ml of PH3 (g) is completely decomposed ?
(A) 50 ml (B) 500 ml
(C) 75 ml (D) 250 ml
29. The minimum quantity in gram of H2S needed to precipitate 63.5 g of Cu2+ will be -
(Cu2+ + H2S ⎯⎯
→ CuS + 2H+)
Black
(A) 63.5 g (B) 31.75 g (C) 34 g (D) 2 g
❖Units of concentration
31. The density of 2.45 M methanol solution in water is 0.9766 g mL–1. The molality of the
solution is
(A) 27.3 (B) 2.73 (C) 2.45 (D) 0.273
32. Density of a solution of NaCl in a polar solvent is 1.2 gram/cc. If % by weight (W/W) of
NaCl in solution is 5.85, then formality and % by volume (W/V) of NaCl are, respectively,
(A) 1 and 5.85 (B) 0.1 and 0.585 (C) 1.2 and 7.02 (D) 1.1 and 7.2
33. Density of 3M Na2CO3 solution in water is 1.2 g mL–1. The percentage by weight and ppm
of Na2CO3 are respectively -
(A) 26.5 and 2.65 × 105 (B) 2.65 and 2.65 × 104
(C) 265 and 2.65 × 103 (D) 5.23 and 2.65 × 106
34. Mole fraction of methanol in its aqueous solution is 0.5. The concentration of solution in
terms of percent by mass of methanol is -
(A) 36 (B) 50 (C) 64 (D) 72
35. An aqueous solution of urea containing 18 g urea in 1500 cc of solution has a density of
1.052 g/cc. If the mol.wt. of urea is 60, then the molality of solution is
(A) 0.2 (B) 0.192 (C) 0.064 (D) 1.2
37. 20 ml of 0.2 M Al2(SO4)3 is mixed with 20 ml of 0.6 M BaCl2. Concentration of Al3+ ion in the
solution will be
(A) 0.2 M (B) 10.3 M (C) 0.1 M (D) 0.25 M
38. 50 ml of 0.01 M FeSO4 will react with what volume of 0.01 M KMnO4 solution in acid
medium?
(1 mole KMnO4 requires 5 mole of FeSO4 for complete reaction)
(A) 50 ml (B) 25 ml (C) 100 ml (D) 10 ml
39. The number of H+ ions present in 100 ml of 0.001M H2SO4 solution will be
(A) 120.4 1019 (B) 1.20 1020 (C) 6.023 1020 (D) 6.023 1021
40. 3.0 molal NaOH solution has a density of 1.11 g ml . The molarity of the solution is
(A) 2.97 (B) 3.05 (C) 3.64 (D) 3.050
41. 250 ml of a sodium carbonate solution contains 2.65 grams of Na2CO3. If 10 ml of this
solution is diluted to one litre, what is the concentration of the resultant solution? (mol
wt. of Na2CO3 = 106)
(A) 0.1 M (B) 0.001M (C) 0.01 M (D) 10−4 M
42. The mole fraction of NaCl in a solution containing 1 mole of NaCl in 1000g of water is:
(A) 0.0177 (B) 0.001 (C) 0.5 (D) 1.5
2. The density of a 3.60M sulphuric acid solution that is 29% H 2SO4 (molar mass
98g mol−1 ) by mass will be:
(A) 1.22 (B) 1.45 (C) 1.64 (D) 1.88
3. 10 moles N 2 and 15 moles of H 2 were allowed to react over a suitable catalyst. 10 moles
of NH3 were formed. The remaining moles of N 2 and H 2 respectively are:
(A) 5 moles, 0 mole (B) 0 moles, 5 mole
(C) 9 moles, 12 mole (D) 0 moles, 0 mole
5. How many gms of copper ( at.wt = 64 ) would be displaced from the copper sulphate
solution by adding 27 gm of aluminium ( at.wt = 27 )
(A) 32 (B) 64 (C) 96 (D) 160
7. 2.5 moles of a hydrocarbon C10 H x requires 32.5 moles of O2 for complete combustion.
Calculate value of x ?
(A) 24 (B) 32 (C) 12 (D) 22
8. Calcium carbonate reacts with aqueous HCl to give CaCl2 according to the reaction,
CaCO3 ( s ) + 2 HCl ( aq ) → CaCl2 ( aq ) + CO2 ( g ) + H 2O ( l ) . The mass of CaCO3 required to
react completely with 25mL of 0.75M HCl is
(A) 0.1 g (B) 0.84 g (C) 8.4 g (D) 0.94 g
9. 25.0 ml of HCl solution gave, on reaction with excess AgNO3 solution 2.125g of AgCl . The
molarity of HCl solution is
(A) 0.25 (B) 0.6 (C) 1.0 (D) 0.75
10. Element X reacts with oxygen to produce a pure sample of X 2O3 . In an experiment it is
found that 1.00 g of X produces 1.16 g of X 2O3 . Calculate the atomic weight of X .
Given: atomic weight of oxygen, 16.0 g mol −1 .
(A) 67 (B) 100.2 (C) 125 (D) 150
11. If half mole of oxygen gas combine with Al to form Al2O3 , the weight of Al used in the
reaction is:
(A) 27 g (B) 40.5 g (C) 54 g (D) 18 g
12. 8 g of sulphur is burnt to form SO2 which is oxidised by Cl2 water. The solution is treated
with BaCl2 solution. The amount of BaSO4 precipitated is
(A) 1 mole (B) 0.5 mole (C) 0.24 mole (D) 0.25 mole
13. A mixture of KBr and NaBr weighing 0.560 gm was treated with aqueous Ag+ and all the
bromide ion was recovered as 0.970 gm of pure AgBr. The weight of KBr in the sample is
(A) 0.25 gm (B) 0.212 (C) 0.36 (D) 0.285
15. A sample contains 200 atoms of hydrogen, 0.05 gm atom of nitrogen, 10−20 gm atom of
oxygen. What is the approximate no. of total atoms
(A) 200 (B) 6223
(C) 31022
(D) none of these
16. The element A at wt.=75 and B at wt. =32 combine to form a compound X. If 3 mol of B
combine with 2 mol of A to give 1 mol of X, the weight of 5 mol of X is
(A) 246 gm (B) 1230 amu
(C) 1.23 kg (D) None of these
18. Which of the following substances contains the greatest mass of chlorine
(A) 5 gm Cl2 (B) 60 gm NaClO3
(C) 0.10 mole of KCl (D) 0.5 mole of Cl2
19. Which of the following samples contains the smallest no. of atoms?
(A) 1 g of CO2 (g) (B) 1 g of C8H18 (l) (C) 1 g of C2H6 (g) (D) 1 g of LiF (s)
20. The wt. of NO having the same no. of oxygen atom present in 9.2 gm of NO2 is
(A) 9.2 gm (B) 6 gm (C) 12 gm (D) 24 gm
24. A mixture contains n moles of H2 and 2n moles of CH4.The ratio of no. of C:H atoms in the
mixture is:
(A) 1/5 (B) 2/3 (C) 4/5 (D) 1/3
25. The charge on 1 gram ion of Al3+ is (e represents magnitude of charge on 1 electron)
(A) 1/27 NAe coulomb (B) 1/3 NAe coulomb
(C) 1/9 NAe coulomb (D) 3 NAe coulomb
26. Cortisone is a molecular substance containing 21 atoms of carbon per molecule. The
weight percentage of carbon in cortisone is 69.98%. What is the molecular weight of
cortisone?
(A) 176.5 (B) 252.2 (C) 287.6 (D) 360.1
27. A partially dried clay mineral contains 8% water. The original sample contained 12% water
and 45% silica. % of Silica in the partially dried sample is nearly
(A) 50% (B) 49% (C) 55% (D) 47%
28. A compound contains 28% nitrogen and 72% metal by mass 3 atoms of the metal
combine with 2 atoms of nitrogen. The atomic mass of metal is
(A) 36 (B) 20 (C) 24 (D) 36
29. An organic compound on analysis was found to contain 0.014% of nitrogen. If its molecule
contains two N atoms, then the molecular mass of the compound
(A) 200 (B) 2000 (C) 20,000 (D) 200000
30. An element, X, have three isotopes X 20, X 21 and X 22. The percentage abundance of X 20is
90% and its average atomic mass of the element is 20.11. The percentage abundance of X
21
should be
(A) 9% (B) 8% (C) 10% (D) 0%
31. The O18/O16 ratio in some meteorites is greater than that used to calculate the average
atomic mass of oxygen on earth. The average mass of an atom of oxygen in these
meteorites is ………. that of a terrestrial oxygen atom.
(A) equal to (B) greater than (C) less than (D) None of these
32. 6.023 ×1023 molecules of Ca (OH)2 react with 3.01×1022 molecules of HCl, number of moles
of CaCl2 obtained are
(A) 0.05 (B) 0.10 (C) 0.025 (D) 3.01
33. A copper sulphate solution contains 1.595% of CuSO4 by weight. Its density is 1.2 g / ml, Its
molarity will be
(A) 0.12 (B) 0.06 (C) 1.20 (D) 1.595
35. Simplest formulae of a compound containing 20% of element X (atomic weight 10) and
80% of element Y (atomic weight 20) is
(A) XY (B) X2Y (C) XY2 (D) X2Y3
36. At room temperature and pressure two flask of equal volumes are filled with H 2 and SO2
respectively. Particles which are equal in number in two flasks are
(A) Atoms (B) Electrons
(C) Molecules (D) Neutrons
37. Chlorophyll contains 2.68% of magnesium by mass. Calculate the number of magnesium
atoms in 3.00 gms of chlorophyll.
(A) 2.01 1021 atoms (B) 6.023 1023 atoms
(C) 1.7 1020 atoms (D) 2.8 1022 atoms
38. What is the total number of atoms present in 25.0 mg of camphor C10H16O?
(A) 9.89 1019 (B) 6.02 1020
(C) 9.89 1020 (D) 2.67 1021
40. An ore contains 1.34% of the mineral argentite, Ag2S, by weight. How many grams of this
ore would have to be processed in order to obtain 1.00 g of pure solid silver, Ag?
(A) 74.6 g (B) 85.7 g (C) 134.0 g (D) 171.4 g
Level-3
Only single correct answer type questions
1. Four one litre flasks are separately filled with the gases hydrogen, helium, oxygen and
ozone at the same room temperature and pressure. The ratio of total number of atoms
of these gases present in the different flasks would be -
(A) 1 : 1 : 1 : 1 (B) 1 : 2 : 2 : 3
(C) 2 : 1 : 2 : 3 (D) 3 : 2 : 2 : 1
3. If mole percentage of C–12 and C–14 in nature is 98% and 2% respectively, then the
number of C–14 atoms in 12 g of carbon is -
4. A vessel contains 8 gram TiO2, 2.4 gram carbon and 28.4 gram Cl2. Maximum mass of
TiCl4 which can be produced is -
3TiO2(s) + 4C(s) + 6Cl2(g) ⎯⎯
→ 3TiCl4(g) + 2CO2(g) + 2CO(g)
(Consider reaction goes to completion; atomic mass of Ti = 48)
(A) 1.90 gram (B) 28.5 gram
(C) 19 gram (D) 38 gram
7. 25 gram of A sample of oleum is labelled as 110%. The amount of H2O which should be
added to this sample to get 50 % H2SO4(w/w) is -(assuming densily of H2O = 1 g/ml)
(A) 25 gram (B) 20 gram
(C) 30 gram (D) 27.5 gram
9. The vapour density of gas A is four times that of B. If molecular mass of B is M, then
molecular mass of A is -
(A) M (B) 4M
M
(C) (D) 2M
4
10. On analysis, a certain compound was found to contain iodine and oxygen in the ratio of
254 gm of iodine (at. mass 127) and 80 gm oxygen (at. mass 16). What is the formula of
the compound -
(A) IO (B) I2O
11. The hydrated salt Na2SO4.nH2O, undergoes 55% loss in weight on heating and
12. The mass of oxygen that would be required to produce enough CO, which completely
reduces 1.6 kg Fe2O3 (at. mass Fe = 56) is -(Fe2O3 + 3CO 2Fe + 3CO2)
13. 12g of Mg (atm. mass 24) will react completely with acid to give -
(C) 2/3 mol of O2 (D) Both 1/2 mol of H2 and 1/2 mol of O2
14. If one mole of ethanol (C2H5OH) completely burns to carbon dioxide and water, the
15. Calculate the weight of lime (CaO) obtained by heating 200 kg of 95% pure lime stone
(CaCO3).
16. The mass of 70% H2SO4 required for neutralization of 1 mol of NaOH
(A) 49 gm (B) 98 gm
(C) 70 gm (D) 34.3 gm
17. 12 litre of H2 and 11.2 litre of Cl2 are mixed and exploded. The composition by volume of
mixture is -
(A) 24 litre of HCl
(B) 0.8 litre Cl2 and 20.8 lit HCl.
19. The mole fraction of a given sample of I2 in C6H6 is 0.2. The molality of I2 in C6H6 is -
20. 1 mol of N2 and 4 mol of H2 are allowed to react in a vessel and after reaction, H2O is
added. Aqueous solution required 1 mol of HCl. Mol fraction of H2 in the remaining
21. Calculate the weight of BaCl2 needed to prepare 250 mL of a solution having the same
22. 0.2 mole of HCl and 0.1 mole of barium chloride were dissolved in water to produce a
23. A sample of H2SO4 (density 1.8 g/ml) is 90% by weight. What is the volume of the acid
(A) 16 mL (B) 10 mL
(C) 12 mL (D) 18 mL
24. A sample of Na2CO3. H2O weighing 1.24 g is added to 200 mL of a 0.1-N H2SO4 solution.
25. 125 mL of 10% NaOH (w/V) is added to 125 mL of 10% HCl (w/V). The resultant solution
becomes-
(A) alkaline (B) strongly alkaline
(C) acidic (D) neutral
26. Equal volumes of 0.50 M of HCl, 0.25 M of NaOH and 0.75 M of NaCl are mixed. The
molarity of the NaCl solution is -
(A) 0.75 M (B) 1/3 M
(C) 0.50 M (D) 2.00 M
27. How many grams of copper will be replaced in 2 L of a 1.50-M CuSO4 solution if the
28. The ratio of the molar amounts of H2S needed to precipitate the metal ions from 20 ml
31. 11.2 g of mixture of MCl (volatile) and NaCl gave 28.7 g of white ppt with excess of AgNO3
solution. 11.2 g of same mixture on heating gave a gas that on passing into AgNO3
33. 10 g of a sample of silver which is contaminated with silver sulphide produced 11.2 mL of
hydrogen sulphide at S.T.P. by treatment with excess of hydrochloric acid. The mass of
silver sulphide in the sample is -
(Ag = 108; S = 32)
34. 2.0 g of a tri-atomic gaseous element was found to occupy a volume of 448ml at 76cm
of Hg and 273K. The mass of its atom is ?
35. 2.4 g of pure Mg (at. mass 24) is dropped in 100ml of 1N HCl. What is true ?
(A) 1.122 L of hydrogen is produced at S.T.P.
(B) 0.01 mol of magnesium is behind
36. Assertion : Vapour density of sulphur vapour relative to oxygen is 2 because sulphur
atom is twice as heavy as that of O atom.
Reason : Vapour density depends upon the molecular state of the substance.
37. Assertion : Equal volumes of all the gases contain equal number of atoms.
Reason : Atom is the smallest particle which takes part in chemical reactions.
38.
Column-A Column-B
Concentration units
(A) independent of temperature (i) Molality
variation
Concentration units
(B) dependent on temperature (ii) Molarity
variation
mg of solute present in 1 kg ppm
(C) (iii)
of solution represent concentration
moles of
moles of solute present in 1 solute in
(D) (iv)
kg of solvent represent hundred moles
of solution
Level-3
1. [C] 2. [A] 3. [A] 4. [C]