A MULTIPLE CHOICE QUESTIONS

1. The molarity of water is

(a) 18 (b) 55 56
(c) 80 (d) 49 87
22. The molality of 40% H2,SO4 (by weight) is about
(a) 6-8 (b) 13.6
(c) 4-08 (d) 8-16
3. The molality of an
aqueous solution of urea is 4.44 m.
(a) 0-074 The mole fraction of urea in
(b) 0-00133 the sol
4. A 5 M H2 SO4 solution is (c) 0-08
diluted from 1 litre to 10 litres.
(d) 0-0044 olution
(a)1N The normality of the
(b) 2 N solution will he
5. 1000 g
CaCO3 solution contains 10 g carbonate. The (c) 0-1N (d) none of these
(a) 10000 ppm
(b) 1000 ppm
concentration of the solution is
6. Which one of the (c) 100 ppm (d) 10 ppm
following is a
colligative property?
(a) The half life of a radioactive element
(b) The conductance of solution
(c) The surface tension of solution
The relative (d) The osmotic pressure of solution
lowering of vapour pressure is equal to the molar fraction of solute. The law is
(a) Henry's law known a
(b) Raoult's law
(c) Ostwald's dilution law
(d) Van't Hoff law
If osmotic
pressure of 1 M aqueous solution of the
maximum osmotic pressure following solutes be measured, which one will show
(a) AgNO3 (b) MgCl2 (c) (NH4)3 PO4 (d) (NH4)2 SO4
Isotonic solutions have the same
(a) viscosity (b) molar concentration
(c) boiling point
(d) density
0. Compared to the osmotic pressure of 0.01 M
glucose, the osmotic pressure of 0-0IM NaCl will be
(a) approx. twice
(b) approx. half
(c) nearly the same
(d) none of these
1. The osmotic pressures of
equimolecular solution of glucose, NaCl and
(a) Glucose > NaCI> BaCl2 BaCl, will be in the orde
(b) NaCl> BaCl2 >Glucose
(c) BaCl2 >
NaCl>Glucose (d) Glucose> BaCl2 > NaCl
2. Solution A is a ternary electrolyte and solution B
is a non-electrolyte. If o f solut
produces an osmotic pressure of 2P then, 0.05 M 0.1 M solution or s
solution of A will produce an (at
same temperature) equal to osmotic pressu
(a) P (b) 1.5P
(c) 2P
(d) 3P
 Solutions 155

13 Ca(N03)2 solution has freezing point

(a) 0°C (b) <0°C (c)>0°C (d)-1°C
14 The correct relationship between the boiling points of equimolar solution of BaCl2 (1) and NaCltl2)B
(a) 2 (6)>2 (c)2 > (d)2 2/1
15. A solution containing 86 gl of urea (M.W. = 60) is isotonic with a 5% solution of an organic non-VO12ue
solute. The M.W. of the solute is nearly
(a) 125 (b) 250 (c)35 (d) none of these
16. The friezing point of 1 m NaCl solution assuming 100% dissociation of the salt will be
(a)-186C (6)-3-72°C (c)+1-86°C (d)+3.72°C
17. H-O2 solution used for hair bleaching is sold as solution of approx. 5- 0g of H,0, per 100 ml. of the
solution. The M.W. of H20, is 34. The molarity of this
(a) 0-15
bleaching solution is approximately
(b) 1-5 (c)30 (d) 50
18. Which of the following compounds corresponds to the Van't Hoff factor to be equal to 2 for dilute soBution?
a)K SO4 (b) NaHSO4 (c) Sugar (d) MgSO4
19. The solution containing 4.0g of a polyvinyl chloride polymer in 1 litre of dioxane was found to have an
osmotic pressure of 6-0x 10 atmosphere at 300 K. The value of R used is 0-082 litre atm/ deg. The
molecular mass of the polymer was found to be
(a) 3-6 x10 (b) 1-6x 10 (d) 6.4x 10
(C)5-6x10
20. If 18 g glucose is present in 1000 g of a solvent, the solution will be
(a) 1 molar (b) 0-1 molar
(c) 0-5 molal (d) 0-1 molal
21. At constant temperature, the osmotic pressure of a solution is
(a) directly proportional to the concentration
(b) inversely proportional to the concentration
(c) directly proportional to the square of the concentration
d) independent of concentration
22. The osmotic pressure of a 5% solution of cane sugar (M.W. = 342) at 15°C is
(a)4 atm (b) 3.45 atm (c) 3.65 atm (d) 2-45 atm

When a solute is dissolved in a solvent

(a) freezing point of the solution is depressed (b) freezing point of the solution is increased
c) boiling point of the solution is decreased (d) vapour pressure of the solution is increased

24. The osmotic pressure of a solution is given by the relation

(a) P RTIC (b) P =CTIR
(d) P/C = RT
(c) P =CR/T
25. The relationship between the values of oSmotic pressures of 0-1M solutions of KNO3 (P) and
CHCOOH(P2) is
(a) P> P2 (b) P2 >Pi
(c) P =
P2
P Pa
P+ P2 P + P2

The one which is not a colligative property is:

a) relative lowering of vapour pressure (b) osmotic pressure
c) elevation of b.p. (d) none of these
2Osmotic pressure of a sugar solution at 24°C is 2.5 atm. The concentration of the solution in g mole/litre
is
(a) 10-25 b)1-025 (c) 1025 (d) 0-1025
Elevation of boiling point was 0.018°C when 6 g of a compound X was dissolved in 100 g of water.
Molecular weight of X is (K, = 0.52 Km )
(a) 120 (b) 60 (c) 180 (d) 342
 156 | VK Chemistry-XII .
The value of colligative properties of a solution increase wlhen solute molecules undergo
4 (c) both (a) and (b) (d) None of these.
(a) association (b) dissociation
30. A pressure cooker saves cooking time because:
(a) the distribution of heat becomes more uniform (b) high pressure makes the food soft

(c) the b.p. of water inside the cooker increases (d) a long flame is used
31. Which solution will exert highest osmotic pressure?
(a) 0.1 M glucose (b) 0-1 M NaCl
()0-IM BaCl2 (d) 0-1 M urea
iraction of
C3Hs (OH)3 in solution containing 36 g of water and 46 g of glycerine:
oe a
(a) 0-46 (b) 0.40
(c) 0-20 (d) 0.36
33. Milli-equivalent of a solute in 60 ml of 4 M solution of H, SO are
(a) 240 (b) 480
(c) 24 (d) 48
34. Number of moles of the solution per litre of the solution is
(a) molality (b) molarity
(c) normality (d) formality
35. The boiling point of a solution containing a non-volatile solute is
(a) depressed (b) elevated
(c) does not change (d) none of these
36. The solution that has the
highest boiling point is
(a) 0-1 NNa 2 SO4 (b) 0-01 N MgSO4
(c)0-0INAl2 (SO4) 3 (d) 0-1 NBaSO4
37. An aqueous solution of methanol in water has
vapour pressure
(a) equal to that of water (b) equal to that of methanol
(c) more than that of water (d) less than that of water
38. Which of the following aqueous molal solution has the highest freezing point ?
(a) KBr (b) Urea
(c) BaCl2 (d) Al2 (S04)3
39. The freezing point of 0-05 molal solution of a non-volatile solute in water is
(a) -1-86°C (b) -0.93°C
(c) -0-093°C (d) 0.93° C
40. If 250 ml of 0-25 M NaCI solution is diluted with water to a volume of 500 ml, the
the solution is new concentration of
(a) 0-167 M (b) 0-125 M
(c) 0-0035 M (d) 0-0167 M
41. 5 mlNHCI, 20 ml N/ 2 H2SO4 and 30 mi
NI 3 HNO3
litre. The normality of the resulting solution is
are mixed together and the
volume is made to one
(a) N/5 (b) N/10
(c) N/ 20 (d) N/ 40
A2 The molal elevation of an unknown solution is equal to the molal elevation of 0.
concentration of the solution is 1M solution of urea. Tne
(a) 0-1 M (b) 001M
(c)1-0M
(d) none of these
43. A solution has an
osmotie pressure of 0.821 atms at 300 K. Its
(a) 0-66 M (b) 0.32 M concentration would be
(c) 0-066 M
500 ml of an (d) 0-033 M
AA
aqueous solution or Bucose contains 6 x 10 molecule. The
(a) 0-1 M (b) 0.2 M concentration of the solution is
(c)1-0 M
(d) 2-0 M
6. The molal elevanon constant of water is
0-51° C. The boiling temperature
solution is nearly of 0.1 molal aqueous Na
(a) 100-05°C (b) 100.1°C (c) 100-2°C (d) 101-0C
Amolal solution is one that contains one mole of a solute in
(a) 1000 g of the solvent
(b) one litre of the solution
(c) one litre of the solvent
(d) 22.4 litres of the solution
7. When Hgl2 is mixed with
aqueous solution of KI, then
(a) freezing point decreases
(b) freezing point does not change
(c) freezing point increases (d) boiling point remains unchanged
48. In which mode of expression, the concentration of solution remains
independent of temperature:
(a) Normality (b) Molarity
(c) Molality (d) Formality
49. Which of the following 0-1 M aqueous solution will have the lowest
freezing point?
(a) K2 SO4 (b) NaCl
(c) urea
(d) glucose
50. The freezing point of equimolal aqueous solutions will be highest for
(a) CgHs NH2. HCI
(b) Ca(NO3)2
(c) NaNO (d) CHi206
51. A solution is a

(a) heterogeneous (b) homogeneous

(c) colloidal (d) gel
52. An ideal solution is one which obeys
(a) Raoult's law b) Henry's law
(c) Both (a) and (b) (d) None of these

53. Activity of a component in an ideal solution

(a) ratio of concentrations (b) ratio of fugacities

(C)ratioof e.m.f. (d) none of these

54. Real solution shows deviation from Raoult's law

(a) positive (6) negative
(c) both (d) none of these

35. Critical solution temperature (CST) is a temperature at which

(a) two miscible liquids become partially miscible
(b) two patially miscible liquids become completely miscible
() two liquids freeze into each other
(d) none of the above
6. Phenol-water system is an example of
(a) homogeneous system (6) partially miscible liquids
(c) colloidal system (d) none of these
fractional distillation is done is case of
(a) liquids with close boiling points (b) liquids with quite different boiling points
() liquids with equal boiling points (d) none of these
 be in 20 8
S8. How many moles of each of the following will
(i) CH,COOH
(i) CH,OH
) CHi2O%
0-111
(a) 0111. 0-333, 0625 (b)0-333, 0625,
0-11
(c)0111, 0-625, 0-333 (d) 0-625, 0:333,
certain solute in a
ssion is 0-1R4
solvent if freezing point depression 184 0
59. What is
the molality fa solution of
and the k, is 18-4?
a

(a) 0-01 (b) 1

(c) 0-001 (d) 100

60. Increase of temperature of an aqueous solution will cause

(a) decrease in molality (b) decrease in molarity

(c) decrease in mole fraction (d) decrease in % (w/W)
o . In cold countries, glycol is added to water in car radiators during winter. It results in

(a) lowering of boiling point (b) reducing viscosity

(c) reducing specific heat (d) lowering freezing point.
62. Which of the following is a colligative property
(a) Meling point (b) Osmotic pressure
(c) Freezing point (d) Sublimation temperature
63.
Partial
known as
pressure of a solution component is directly proportional to its mole fraction. This statement s

(a) Henry's law (b) Raoult's law

(c) Distribution law (d) Ostwald's dilution law
64. The vapour pressure of a liquid in closed vessel
a
depends upon
(a) surface area of the vessel (b) amount of liquid
(C) temperature (d) none of the above
64. At high altitude the boiling point of water is lower because
(a) atmospheric pressure is low (b) Temperature is low
(c) atmospheric pressure is high (d) none of these
66. Which of the following aqueous solutions has lowest
freezing point?
(a) 0.I m glucose (b) 0.1 m NaCl
(c) 0.1 m sucrose (d) 0.1 m
BaCl2
67. An egg in saturated sodium chloride shrinks due to
(a) Exo osmosis (b) endo osmosis
(c) both (d) None