D P P - Da i ly Practice P roblems

C h a pter-wise S h eets

Date : L..�-----l Start Time : End Time :

C H E M I STRY (Cc1 �
SYLLABUS : Solutions

Max. Marks : 180 Marking Scheme : + 4 for correct & (-1 ) for incorrect Time : 60 min.

INSTRUCTIONS : This Daily Practice Problem Sheet contains 45 MCQ's. For each question only one option is correct.

Darken t he correct drcle/ bubble in the Response Grid provided on each page.

1. How many grams ofconcentrated nitric acid solution should 4. Which ofthe following aqueous solution will have highest
be used to prepare 250 mL of2.0M HN03 ? The concentrated depression in freezing point?
acid is 70% HN03 (a) 0. 1 MUrea (b) 0. 1 M Sucrose
(a) 90.0 g cone. HN03 (b) 70.0 g cone. HN03 (c) 0.1 MA1Cl3 (d) 0. 1 M K4 [Fe(CN)J
(c) 54.0 g cone. HN03 (d) 45.0 g cone. HN03 5. Two liquids Xand Yform an ideal solution. At 300 K, vapour
pressure ofthe solution containing I mol ofX and 3 mol of
Ps = xA (p0A p08 ) + P0a . Th e resulting solution will be
2. For a solution of two liquids A and B it was proved that
Y is 550 mmHg. At the same temperature, if 1 mol of Y is
-

further added to this solution, vapour pressure of the

(a) Non -ideal (b) ideal solution increases by I 0 mmHg. Vapour pressure ( in mmHg)
(c) semi-ideal (d) None of these ofX and Yin their pure states will be, respectively:
3. If the elevation in boiling point of a solution of 10 gm of (a) 300and400 (b) 400and600
solute (mol. wt. = 1 00) in 100 gm of water is �Tb, the (c) 500and600 (d) 200and300
ebullioscopic constant ofwater is 6. 6.02 x I 020 molecules of urea are present in I 00 ml of its
(a) 10 (b) 10 �Tb solution. The concentration ofurea solution is
(a) 0.02M (b) 0.01 M
(c) 0.001 M (d) 0.1 M
(Avogadro constant, NA 6.02 x 1 023 moi-1 )
=

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lc�2 �--- DPP/ C C 1 6
7. To neutralise completely 20 mL ofO. I M aqueous solution (a) 1 .78 M (b) 2.00 M
of phosphorous acid (H,P03), the value ofO.l M aqueous (c) 2.05 M (d) 2.22M
KOH solution required is 13. The vapour pressure of a solution of the liquids A
(a) 40mL (b) 20mL (p0 = 00 rrm Hg a1d x A =0.4)andB(p0= 120mmHg and
(c) IOmL (d) 60mL x 8 = 0.6) is fmmd to be 100 nun Hg. It shows that the
8. Two 1 -litre flask A and B are connected to each other by a
valve which is closed. Flask A has benzene in equilibrium solution exhibits
with its vapours at 30°C. The flask B, is evacuated, and the (a) positive deviation from ideal behaviour
valve is opened. Which of the following is true. I f (b) negative deviation from ideal behaviour
temperature is kept constant.' (c) ideal behaviour
(a) Some ofthe benzene molecules would move to flask B (d) positive deviation for lower cone. and negative for
from flaskA. higher cone.
(b) Vapour pressure will be halfthe initial value. 14. The vapour pressure oftwo liquids X and Y are 80 and
(c) The vapour pressure remains unchanged 60 torr respectively. The total vapour pressure of the
(d) Some more of the liquid benzene in flask A would ideal solution obtained by mixing 3 moles
X and
of 2 moles ofY
evaporate. would be
9. Two Aqueous solutions S 1 and S 2 are separated by a (a) 68Torr (b) 140Torr
semipermeable membrane . Solution S has got a greater (c) 48Torr (d) 72Torr
1
vapour pressure than solution S2 . Water will be flowing 15. Iodine and sulphur dissolve in
(a) from s, to s2 (a) water (b) benzene
(b) from s2 to s, (c) carbon disulphide (d) ethanol
(c) in both the directions 16. A 5% solution of cane sugar (molar mass 342) is isotonic
(d) in either direction depending upon the nature of the with 1% of a solution of an unknown solute. The molar
solute mass oftmknown solute in g/mol is :
10. Henry's law constant ofoxygen is 1.4 x 1 o-3 mol. lir1• atm- 1 at (a) 171.2 (b) 68.4 (c) 34.2 (d) 136.2
298 K. How much ofoxygen is dissolved in 100 m1 at 298 K 17. Coolent used in car radiator is aqueous solution ofethylene
when the partial pressure ofoxygen is 0.5 atm? glycol. In order to prevent the solution from freezing at
(a) 1.4g (b) 3.2g - 0.3 °C. How much ethylene glycol must be added to 5 kg
(c) 22.4mg (d) 2.24mg ofwater ? ( Kf = 1.86 K kg mol- 1)
11. Which of the following liquid pairs shows a positive
(a) 50 kg (b) 55 g
deviation from Raoult's law?
(c) 45 g (d) 40 g
(a) Water - nitric acid
(b) Benzene - methanol
18. A solution ofurea (mol. mass 56 g mol-1) boils at 1 OO.l 8°C
at the atmospheric pressure. lfKrand Kb for water are 1.86
(c) Water - hydrochloric acid and 0.512 K kg mol-1 respectively, the above solution will
(d) Acetone- chloroform freeze at
12. Dissolving 120 g ofurea (mol. wt. 60) in 1000 gofwater (a) 0.654"C (b) -0.654°C
gave a solution ofdensity 1 . 1 5 g/mL. The molarity ofthe
(c) 6.54"C (d) -6.54°C
solution is

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19. A solution is prepared bymixing 8.5 g ofC�Cl2 and 1 1 .95 g 25. A binary liquid solution is prepared by mixing n-heptane
ofCHC13. Ifvapour pressure ofC�Cl2 and CHC13 at 298 K and ethanol. Which one of the following statements is
are 4 1 5 and 200 mmHg respectively, the mole fraction correct regarding the behaviour ofthe solution?
of CHC13 in vapour form is : (a) The solution is non-ideal, showing- ve deviation from
(Molar mass ofCl =35.5 g mol-1 ) Raoult's Law.
(b) 0.675
(b) The solution is non-ideal, showing + ve deviation from
(a) 0.162 (c) 0.325 (d) 0.486
Raoult's Law.
20. If o. is the degree ofdissociation ofN�SO4, the Vant (c) n-heptane shows + ve deviation while ethanol shows
Hoff's factor (i) used for calculating the molecular mass is
(b) 1 - o.
-ve deviation from Raoult's Law.
(a) 1 + o. (c) 1 +2o. (d) 1 - 2o. (d) The solution formed is an ideal solution.
21. The molecular mass of a solute cannot be calculated by 26. Which one ofthe following salts will have the same value
which ofthe following? of van 't Hoff factor (i) as that of K4[Fe(CN)6].
(a) AllS04)3 (b) NaCI
M8 = �
Ws x RT
­
(a) � (c) Al(N03)3 (d) Na2S04.
rcV 27. Relation between partial pressure and mole fraction is stated

Po WBM A
by
(b) M s = ....:. (a) Graham's law (b) Raoult's law
(po -p)WA
----!:
..._ �
:....
(c) Le-Chatelier (d) Avogadro law
6.Tb WB x lOOO
28. Which is an application ofHenry's law?
(c) M s = (a) Spray paint (b) Bottled water
Kb WA (c) Filling up atire (d) Soft drinks (soda)
29. For which ofthe following parameters the structural isomers
Kb W8 x 1 000 C2H50H and CH30C� would be expected to have the same
(d) MB = ----"-
---"'-
6.Tb x W-
A values?
(Assume ideal behaviour)
22. We have three aqueous solutions of NaCl labelled as 'A', 'B'
(a) Boiling points
and 'C' with concentrations O.lM, 0.01M and 0.001M, (b) Vapour pressure at the same temperature
respectively. The value of van't Hoff factor for these (c) Heat ofvapourization
solutions will be in the order _ _ _
(d) Gaseous densities at the same temperature and pressure
00 � < � < � M �>�>� 30. 5 g ofNa2S04 was dissolved in x g ofHp. The change in
(c) iA = i8 = ic (d) iA< i8> ic freezing point was found to be 3.82°C. IfNa2S04 is 8 1 .5%
23. The value of Henry's constant KH is _ _ _ ionised, the value ofx
(Krfor water= 1.86°C kg mol-1) is approximately :
(molar mass ofS = 32 g mol-1 and that ofNa = 23 g mol-1 )
(a) greater for gases with higher solubility.
(b) greater for gases with lower solubility. (a) 1 5 g (b) 25g (c) 45 g (d) 65 g
(c) constant for all gases. 31. The vapour pressure ofacetone at 20°C is 185 torr. When
(d) not related to the solubility of gases. 1.2 g of a non-volatile substance was dissolved in 100
24. Which one of the following gases has the lowest value of g of acetone at 20°C, its vapour pressure was 183 torr.
Henry's law constant? The molar mass (g mol-') of the substance is:
(a) N2 (b) He (c) � (d) C02 (a) 128 (b) 488 (c) 32 (d) 64

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lc� �------ DPP/ C C 1 6
32. In mixture A and 8 components show -ve deviation as 39. A solution containing 0.85 g ofZnCI2 in 125.0 g of water
(a) !:l Vmix> O freezes at -0.23°C. The apparent degree of dissociation of
(b) !:l�nix < O the salt is (K1 for water = 1.86 K kg mol- 1 , atomic m ass:
(c) A -8 interaction is weaker than A - A and 8-8 Zn = 65.3 and Cl = 35.5)
interaction (a) 1.36% (b) 73.5% (c) 7.35% (d) 2.47%
(d) A - 8 interaction is stronger than A - A and B -8 40. During depression of freezing point in a solution the
interaction. following are in equilibrium
33. Which among the foJlm.ving will show maximum osmotic (a) liquid solvent, solid solvent
pressure? (b) liquid solvent, solid solute
(a) I MNaCl (b) I M MgCl2 (c) liquid solute, solid solute
(c) I M (NH.Jl04 (d) I M N�S04 (d) liquid solute, solid solvent
34. At 80° C, the vapour pressure of pure liquid 'A' is 520 mm 41. The molecular weight of benzoic acid in benzene
Hg and that ofpure liquid 'B' is 1000 mm Hg. If a mixture of as determined by depression in freezing point
solution of' A' and 'B' boils at 80° C and l atm pressure, the method corresponds to
amount of'A' in themixture is (1 atm = 760 mmHg) (a) ionization ofbenzoic acid (b) dimerization
(a) 52 mol percent (b) 34 mol percent ofbenzoic acid
(c) 48 mol percent (d) 50 mol percent
(c) trimerization ofbenzoic acid
35. The observed osmotic pressure for a 0.10 M solution of
(d) solvation of benzoic acid
Fe(NH.J2(S04)2 at 25°C is 10.8 atm. The expected and
42. How many grams of methyl alcohol should be added to I 0
experimental (observed) values ofvan't Hoff factor (i) will
be respectively: litre tank ofwater to prevent its freezing at 268 K ? (Krfor
(R = 0.082 Latm lc1 mol- 1)
water is l.86Kkgmol-1)
(a) 5 and 4.42 (b) 4 and 4.00 (a) 880.07 g (b) 899.04 g
(c) 5 and 3.42 (d) 3 and 5.42 (c) 886.02 g (d) 868.06 g
36. The freezing point of equimolal aqueous solution will be 43. The solubility ofN2 in water at 300 K and 500 torr partial
highest for pressure is 0.01 g L-1 .The solubility (in g L-1 )at 750 torr
(a) C<fis�+cl- (b) Ca(N03)2 partial pressure is :
(c) La(N03)2 (d) C6H1 p6 (a) 0.0075 (b) 0.005 (c) 0.02 (d) 0.015
37. Ifthe solution boils at a temperature T and the solvent at 44. When mercuric iodide is added to the aqueous solution
1
a of potassium iodide then
temperature T2 the elevation(b ) T 1 - Tpoint
ofboiling 2 is given by (a) freezing point is raised.
(a) T21 +
(c) - T21 (d) T 1 + T2 (b) freezing point is lowered.
38. The freezing point of a 1.00 m aqueous solution ofHF is (c) freezing point does not change.
found to be -1.91 °C. The freezing point constant ofwater, (d) boiling point does not change.
K1is 1 .86 K kg mol-1• The percentage dissociation ofHF at 45. Azeotropic mixture ofHCl and �0 has
this concentration is (a) 48%HCI (b) 22.2%HCI
(a) 30% (b) 10% (c) 5.2% (d) 2.7% (c) 36%HCI (d) 20.2%HCI

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