FIITJEE

Chapter Practice Problem

1 ELECTROCHEMISTRY
In the hall process, aluminum is produced by the electrolysit
second would it take to produce enough aluminum by the Hal Of molten Al.O, by the
rocess to make acase of following
24 cans ofreactions. How many
if each can uses
S0gof AI, a current of 9650 amp is enmployed dnd
(A) 2032 (B) 148.14 (C) 333 the current efficiency of the cell isaluminum
90 0%:
soft-drink,
108 gfairly concentrate solution of AgNO, is electrolyzeo
using 0.1 F
(C) 96.4 g of
(D) 6.17
3
(A) 94 g (B) 11.6 g
The electrolysis of acetate solution produces ethane
electricity.
The weight or resulting solution is

The current efficiencv of the according reaction:

to (D) None of these
process is 80%%. Wndt
of0.5 amp is passed through the solution for 96.45 min?
2CH,C00
5ases would be produced ’C,Hslg) + 2C0,(e) +2e
at 27°C and 740 torr, if the
(A) 6.0L
current
4
(B) 0.60 L (C) 1.36S L
Alayer of chromium metal 0.25 mm thick is to be plated on an auto (D) 0.91L
containing CrO, ? What current flow is required for this bumper with a total area of 32 m² from a solution
chromium metal is 7.20 g/cm. electroplate
if the
bumper is to be plated in 60 s? The density of
(A) 4.9 x 10 A (B) 1.78 x 10 A (C) S.3 x10 A
5 (D) 10.69 x 10° A
100 ml of 0.05 MCUSO, (aa) solution was electrolyzed using
solution was 2. The solution after electrolysis Was inert electrodes
by passing current till the pH of the resulting
0.04 M Na,S,O,. Calculate the required volume (in euoneu and then treated with excess Kl and
ml) of Na,S,0.: formed I, titrated with
(A) 112.5 ml (B) 100 ml (C) 125 ml
6 Ifthe eguilibrium constant for the reaction H (D) None of these
(aq) +OH J H0) is 10 at certain
the reaction, 2H,0(/)+2e f H,(g) +20H (aq) temperature then what is the E for
2.303RT
Given : =0.066

(A) 1.230 V (B) -0.858 V (C) -0.80 V

7. (D) -0.8274 V
Afuel celldevelops an electrical potential from the
combustion of butane at 1 bar and 298 K
C,Ho(e)+6.50,(&) ’ 4c0,(&)+ 5H,0(), 4,G° =-2746 kJ/ mol
What isE of acell?
(A) 4.74 V (B) 0.547 V (C) 4.37V
8. (D) 1.09V
The cell Pt|Hle, 0.1 bar)|H (ag), pH = X||CI (ag, 1 M)|Hg,|Hg| Pt, has e.m.f. of
electrode is-0.28 V, then pH of solution will be: 0.5755 V at 25°C. The SOP of calomel
(A) 11 (B) 4.5 (C) 5.5 (D) None of these
9. For a cell reaction 2H,lg) + O-\e) ’ 2H,0()4,Sy98°= - 0.32 kJ/K. What is the value of A,H
(H,0, /)?
Given: 0,(e) +4H (aq) +4e ’ 2H,0(), E° =1.23 V.
(A) - 285.07 kJ/mol (B) -570.14 kJ/mol (C) 285.07 ki/mol (D) None of these
10 What is the potential of an electrode which originallycontained0.1 MNO, and 0.4 M Hand which has been treated by
80% of the cadmium necessary to reduce all the NO. to
NOIg) at 1 bar?
Given : NO, + 4H +3e ’NO +2H,0, E° = 0.96V, log2
=0.3
(A) 0.84 V (B) 1.08 V (C) 1.23V (D) 1.36 V
11.
The standard reduction potentialof normal calomel electrode and reduction potential ofsaturated calomel electrodes are
0.27 and 0.33 volt respectively. What is the concentration of a' insaturated solution of KCI?
(A) 0.1 M (B) 0.01 M (C) 0.001 (D) None
12. Determine the potential of the following cell:
PjH, (e, 0.1 bar)|(aq, 10°MMno, (aq, 0.1M), Mn" (a4. 0.01M), H(a4, 0.01 M)Pt
Given : -1.51 V

(A) 1.54 V (D) None of these

(B) 1.48 V (C) 1.84V
13. Copper reduces NO, into NO and NO depending upon concentration ofHNO, in solution. Assuming [Cu] = 0.1 M, and
PNO = 10 bar. At which concentration of HNO,, thermodynaml tendency for reduction of NO, into NO and NO, by
copper is same?
(Given : Ep =0.34 volt,
(A) 102M
E=+0.96 volt)
volt, NO,NO +0.79
(D) 10°12M
(B) 10°56M (c) 10°MThemeasured potential at 298 Kis:
14. For the cell, Pt|Cl,lB, 0.4 bar)
(A) 0.051 V |cTag, 0.01 M)|CI,(g, 0.2 bar)|Pt (D) 0.0255 V
(B) -0.051 V (c)0.102V
CUTIGE td RRRSRO2(
Rlhanesuor CentreRNìart Sc
RGudes
 FIITJEE Electrochemistry
15. The chlorate ion can the
disproportionate in basic
equilibrium concentration of perchlorate ions from solution according to reaction, 2Clo; f Clo, +ClO,. What is
a solution initially at 0.1 M
in chlordte 1os dt 25o
Fco;Cio: 0.36 V and Een: =0.33 Vat 298 K
(A) 0.019 M (B) 0.024 M (D) 0.19 M
A Cen alagram shown below contains one litre of huffor(C)ealution
0.1 M
16.
the celle.m.f.? of HAQnK = A) and NaA in both compartment. vwiro

-Halg): 1bar Halg) :1bar

HA (aQ, 0.1 M)
and HA(ag, 1 M)
and
NaA (ag, 1M) NaA (aq, 1 M)
(A) 0.03 V (B) 0.06 V (C) -0.06 V (D) None of these
17. Given the cell : Cd(s) |Cd(OH)2(s)|NaOH(aq, 0.01M) | H,(e, 1 bar)|Pt(s) with Ecell = 0.0 V. If Ew, =-0.39 V, then Ksp OT
Cd(OH,) is:
(A) 0.1 (B) 10-13 (C) 10-1s (D) None of these
18. Calculate the e.m.f. (in V) of the cell:
Pt|H,lg)|BOH(aq)| |HA(aq) | Ha(g) |Pt
0.1 bar 1M 0.1 M 1 bar
Given : K, (HA)=10, K, (BOH) =10s
(A) 0.39V (B) 0.36V (C) 0.93V (D) None of these
19. Calculate the potential of a half cell having reaction : Ag,s(s) +2e° f 2Ag(s)+S (aq) in
[Given : K,(Ag,S)= 1o
(A) 1.18 (B) 0.19 (c) -0.19 V (D) None of these
20. The conductivity of 0.1 N NaOH solution is 0.022 S cm. When equal volume of 0.1 N HCI solution is added, the
conductivity of resultant solution is decreases to 0.0055 Scm. The equivalent conductivity in Scm² equivalent of NaCI
solution is:
(A) 0.0055 (B) 0.11 (C) 110 (D) None of these
21. In above question after formation of NaCl, further 0.1 NHCI is added, the volume of which is double to that of the first
portion added, the conductivity increases to 0.018 S cm´. The value of Aeq(HCI) is [assume no change in conductivity of
NaCl(aq)):
(A) 330 S cm² eg (B) 305S cm² eg (C) 415 Scm² eg (D) 360 Scm² eg
22. Given the following molar conductivity at 25°c, HCI, 426 2" cm² mol", NaCl, 126 2acm² molr, NaC (sodium crotonate),
0.001 M crotonic acid solution is
839. What is the jonization constant of crotonic acid? If the conductivity of
3.83 x 10Qcm
(B) 1.11 x 103 (C) 1.11x 10 (D) 0.01
(A) 105
Equivalent conductivity of BaCl,, H,SO, and HCI, are Xi, K and K3 Scm eq at infinite dilution. If conductivity of saturated
23.
BaSOA solution is xS cm then Kso of BaSO, is:
1

2.5x10°x² 0.25x
500x 10x (c) (D)
(A) (B)
(x, +x, -2x,) (x +X, - 2x, )' 2.6*:10 Scrm and increase to 7.0 x 10
The conductivity of 0.001 solution is Scm, when the solutions
24. saturated with CaSO4. The M Na,SO4
molar çonductivity of Na"*and Ca" are 50 and 120Scm²mol", respectively. Neglect conductivity
solubilityproduct of CasoO41
of used water. What is the (C) 4x 1o (D) 2.46 x 10
(A) 4 x 100 (B) 1.57x 10" the molar conductivity at infinite dilution is 380x 10
1,.6 x 10 and Sm² molr.If
25. The ionization constant of a weak. acid.is of 0.01 M acid solution is:
the cell constant is 0.01 m then conductance (C) 1.52 x 10"s (D) 1.52 x 10*s
(A) 1.52x 10°S (B) 1.52S
ANSWERS
A 16. 21, B
11.
6 B 12. 17. C 22. B
2.
7 C 18.
3 D 13 23 C
4 8 14. 19. 24. A
D
5 9 A 20.
A 15. 25. B
10. A
RCuidoe Camnlo.
Scots Rha0nOnd Coor R RRSRO Ddisha
CJNA8 Uit.